Honors Chemistry Chapter 10 Take-Home Quiz 1) Give the approximate bond angle for a molecule with a trigonal planar shape. A) 109.5° C) 120° B) 180° D) 105° E) 90° 2) Determine the electron geometry (eg) and molecular geometry (mg) of BCl3. A) eg=trigonal planar, mg=trigonal planar D) eg=trigonal planar, mg=bent B) eg=tetrahedral, mg=trigonal planar E) eg=trigonal bipyramidal, mg= trigonal C) eg=tetrahedral, mg=trigonal pyramidal bipyramidal 3) Determine the electron geometry (eg) and molecular geometry (mg) of CH 3+1. A) eg=tetrahedral, mg=tetrahedral D) eg=trigonal planar, mg=trigonal planar B) eg=tetrahedral, mg=trigonal pyramidal E) eg=tetrahedral, mg=trigonal planar C) eg=trigonal planar, mg=bent 4) Determine the electron geometry (eg) and molecular geometry (mg) of the underlined atom CH3OCH3. A) eg=tetrahedral, mg=tetrahedral D) eg=trigonal bipyramidal, B) eg=linear, eg=linear mg=tetrahedral C) eg=tetrahedral, mg=bent E) eg=octahedral, mg=square planar 5) Consider the molecule at right. Determine the molecular geometry at each of the 2 labeled carbons. A) C1 = tetrahedral, C2 = linear B) C1 = trigonal planar, C2= bent C) C1 = bent, C2 = trigonal planar D) C1 = trigonal planar, C2 = tetrahedral E) C1 = trigonal pyramidal, C2 = see-saw 6) Consider the molecule at right. Determine the molecular geometry at each of the 3 labeled atoms. A) 1=trigonal planar, 2=tetrahedral, 3=trigonal pyramidal B) 1=tetrahedral, 2=tetrahedral, 3=tetrahedral C) 1=trigonal planar, 2=tetrahedral, 3=tetrahedral D) 1=tetrahedral, 2=tetrahedral, 3=trigonal planar E) 1=trigonal planar, 2=trigonal pyramidal, 3=trigonal pyramidal 7) Place the following in order of increasing X-Se-X bond angle, where X represents the outer atoms in each molecule. SeO2 SeCl6 SeF2 SeCl < SeF < SeO A) 6 2 2 D) SeO2 < SeF2 < SeCl6 B) SeF2 < SeO2 < SeCl6 E) SeCl6 < SeO2 < SeF2 SeF < SeCl < SeO C) 2 6 2 8) A pilot checks for water in the gas before flying a small airplane. How does she do it? A) Drain a little bit of gas from the bottom and look for two layers. B) Smell it. C) Shake the wings. D) Pipet the liquid from the top of the tank and look for two layers. E) Check the gas gauge. 9) Determine the electron geometry (eg), molecular geometry (mg), and polarity of SO 3. A) eg=tetrahedral, mg=trigonal pyramidal, polar B) eg=tetrahedral, mg=tetrahedral, nonpolar C) eg=trigonal planar, mg=trigonal planar, nonpolar D) eg= trigonal bipyramidal, mg=trigonal planar, polar E) eg=trigonal pyramidal, mg=bent, nonpolar 10) Determine the electron geometry (eg), molecular geometry (mg), and polarity of SO 2. A) eg=tetrahedral, mg=bent, polar B) eg=trigonal planar, mg=bent, polar C) eg=linear, mg=linear, nonpolar D) eg=tetrahedral, mg=tetrahedral, nonpolar E) eg=trigonal pyramidal, mg=trigonal pyramidal, polar 11) Choose the compound below that contains at least one polar covalent bond, but is nonpolar. A) HCN D) ICl3 E) Both B and C are nonpolar and contain B) CF4 SeBr a polar covalent bond. C) 4 12) Place the following in order of increasing dipole moment. I. BCl3 II. BIF2 III. BClF2 A) I < II = III D) II < I < III B) II < III < I E) I < III < II C) I < II < III 13) Describe a pi bond. A) side by side overlap of p orbitals B) end to end overlap of p orbitals C) s orbital overlapping with the end of a p orbital D) overlap of two s orbitals E) p orbital overlapping with a d orbital 14) Describe a sigma bond. A) side by side overlap of p orbitals B) end to end overlap of p orbitals C) s orbital overlapping with the side of a p orbital D) overlap of two s orbitals E) p orbital overlapping with a d orbital 15) A molecule containing a central atom with sp hybridization has a(n) __________ electron geometry. A) linear D) tetrahedral B) trigonal bipyramidal E) bent C) trigonal planar 16) Identify the number of electron groups around a molecule with sp hybridization. A) 1 D) 4 B) 2 E) 5 C) 3 17) A molecule containing a central atom with sp2 hybridization has a(n) __________ electron geometry. A) linear D) tetrahedral B) trigonal bipyramidal E) bent C) trigonal planar 2 18) Identify the number of electron groups around a molecule with sp2 hybridization. A) 1 B) 2 C) 3 D) 4 E) 5 19) A molecule containing a central atom with sp3 hybridization has a(n) __________ electron geometry. A) linear D) tetrahedral B) trigonal bipyramidal E) bent C) octahedral 20) Identify the number of electron groups around a molecule with a tetrahedral shape. A) 1 B) 2 C) 3 D) 4 21) Identify the number of electron groups around a molecule with a trigonal bipyramidal shape. A) 1 D) 4 B) 2 E) 5 C) 3 22) Determine the electron geometry (eg) and molecular geometry (mg) of the underlined carbon in CH3CN. A) eg=tetrahedral, mg=tetrahedral B) eg=linear, mg=trigonal planar C) eg=trigonal planar, mg=bent D) eg=linear, mg=linear E) eg=trigonal planar, mg=trigonal planar 23) Determine the electron geometry (eg) and molecular geometry (mg) of H 2CO. A) eg=tetrahedral, mg=tetrahedral B) eg=linear, mg=trigonal planar C) eg=trigonal planar, mg=bent D) eg=linear, mg=linear E) eg=trigonal planar, mg=trigonal planar 24) Draw the Lewis structure for OF2. What is the hybridization on the O atom? A) sp C) sp2 B) sp3 D) sp3d E) sp3d2 25) Draw the Lewis structure for H3O+. What is the hybridization on the O atom? A) sp C) sp2 B) sp3 D) sp3d E) sp3d2 26) Consider the molecule at right. Determine the hybridization at each of the 2 labeled carbons. D) C1 = sp3d, C2 = sp3d2 A) C1 = sp3, C2 = sp3d B) C1 = sp, C2 = sp2 E) C1 = sp2, C2 = sp3 C) C1 = sp2, C2 = sp3d 27) Consider the molecule at right. Determine the hybridization at each of the 3 labeled atoms. A) 1=sp2, 2=sp3, 3=sp2 D) 1=sp3, 2=sp3, 3=sp2 B) 1=sp2, 2=sp3, 3=sp3 E) 1=sp, 2=sp2, 3=sp2 C) 1=sp3, 2=sp3, 3=sp3 3 E) 5 28) How many of the following molecules have sp hybridization on the central atom? C2Cl2 CO2 O3 H2O A) 0 B) 1 C) 2 D) 3 E) 4 29) How many of the following molecules have sp 2 hybridization on the central atom? HCN SO2 OCl2 XeCl2 A) 4 B) 3 C) 2 D) 1 E) 0 30) List the number of sigma bonds and pi bonds in a single bond. A) 1 sigma, 0 pi C) 1 sigma, 1 pi B) 0 sigma, 1 pi D) 1 sigma, 2 pi 31) List the number of sigma bonds and pi bonds in a double bond. A) 1 sigma, 1 pi C) 2 sigma, 2 pi B) 2 sigma, 1 pi D) 1 sigma, 2 pi 32) List the number of sigma bonds and pi bonds in a triple bond. A) 1 sigma, 1 pi C) 2 sigma, 2 pi B) 2 sigma, 1 pi D) 1 sigma, 2 pi 33) Draw the Lewis structure for the molecule C3H4. How many sigma and pi bonds does it contain? A) 7 sigma, 1 pi D) 10 sigma, 0 pi B) 8 sigma, 0 pi E) 8 sigma, 2 pi C) 6 sigma, 2 pi 34) Which of the following statements is TRUE? A) The total number of molecular orbitals formed doesn't always equal the number of atomic orbitals in the set. B) A bond order of 0 represents a stable chemical bond. C) When two atomic orbitals come together to form two molecular orbitals, one molecular orbital will be lower in energy than the two separate atomic orbitals and one molecular orbital will be higher in energy than the separate atomic orbitals. D) Electrons placed in antibonding orbitals stabilize the ion/molecule. E) All of the above are true. 35) Is it possible for a molecule to be nonpolar even though it contains polar bonds? Explain your answer and give an example. 36) Explain why oil and water do not mix. 37) Determine the molecular geometry about each interior atom in CH2CHCCCH3. Sketch the threedimensional structure and label the interior atoms with the corresponding molecular geometry. Determine the hybridization about each interior atom in the following structure. 4