UNIT 8 EXAM REVIEW C/P: Chp 15 and 19 Honors: Chp 12, 14 and 15 Solutions plus Acid/Base Chemistry 2013 Chp 15 • Solutions contain a solute dissolved in a solvent. They are always homogeneous! • How do you know if a substance will dissolve in water? “Like dissolves like” • Water is polar so nonpolar substances like oil and other hydrocarbons will not dissolve in water. Concentrations • Know the concentration units for molarity, ppm and dilution. Reminder: Molarity = moles solute ÷ L of solution Parts per million = mass solute x 1,000,000 mass of solvent Dilution formula: M1V1=M2V2 Solubility and Solvation • Three things that affect solubility/solvation: • Agitation • Temperature • Surface area ***Plus Pressure for gases only Colligative Properties • Adding a solute (like salt) to water changes the properties: • Freezing point depression or lowering (< 0oC) • Boiling Point Elevation (>100oC) • Vapor Pressure Lowering – less molecules in gas phase. This is why BP increases. Remember: CP depend on the number of particles in solution, not the type of particles C12H22O11=1 particle, NaCl=2 particles and CaCl2= 3 particles Sample Problems 1. If the solubility of NaCl is 30g/100g H2O, how many grams can be dissolved in 250 g of water? 2. Will these substances dissolve in water? NaCl, vegetable oil, gasoline- C8H18 3. What is the molarity of a solution that contains 250 g of NaCl in 500 mL of water? Sample Problems 1. If the solubility of NaCl is 30g/100g H2O, how many grams can be dissolved in 250 g of water? 75g NaCl 2. Will these substances dissolve in water? NaCl, vegetable oil, gasoline- C8H18 3. What is the molarity of a solution that contains 250 g of NaCl in 500 mL of water? 8.56M NaCl Sample Problems 4. Why did you add rock salt to the ice in the Ice Cream Lab? 5. Name 3 things that would decrease the solubility of sugar in tea? 6. If the attractive forces between solid particles are stronger than those between the solid and water, would the solid dissolve? Sample Problems 4. Why did you add rock salt to the ice in the Ice Cream Lab? To lower the temperature so ice cream would solidify 5. Name 3 things that would decrease the solubility of sugar in tea? Don’t stir it, cool it down and use sugar cubes instead of granulated sugar. 6. If the attractive forces between solid particles are stronger than those between the solid and water, would the solid dissolve? Nope Chp 19 • H+ acid • OH- base • H2O neutral pH = 0 - 6.9 blue to red pH = 7.1 -14 red to blue pH = 7 no change to litmus • Neutralization reaction: equal amounts of acid and base H+ + OH- H2O Strong vs Weak Acids & Bases • Strong acid and bases dissociate (separate) completely – strong electrolyte • Stg acid = HCl • Stg Base = NaOH • Weak acid and bases do not dissociate completely – weak electrolyte • Wk acid: CH3COOH • Wk base: NH3 pH and pOH Scale • Goes from 0-14 • 0 strong acid, 7 neutral, 14 strong base • pOH = 14- pH • If pH = 2 then pOH = 12 Sample Questions 1. What is the formula of the hydronium ion? 2. What does water contain? 3. A substance has a pH of 5.5: a) Classify it as a strong/weak acid or base. b) What is the pOH of the solution? Sample Questions 1. What is the formula of the hydronium ion? H3O+ 2. What does water contain? Water molecules, hydronium ions and hydroxide ions 3. A substance has a pH of 5.5: a) Classify it as a strong/weak acid or base. b) What is the pOH of the solution? 14 - 5.5 = 8.5