Virtual Science Pro Lesson Guide Ice on Fire! Level of difficulty: Difficult (9th - 12th Grade) How to Use this Lesson Guide ACTIVITIES: DAY 1 ESTIMATED TIMING Welcome to the Science WoRx Virtual Science “Ice on Fire!” lesson guide! As the name suggests, this tool is meant to be used as a guide to accompany the Virtual Science Pro video “Ice on Fire!” You may wish to use it as a two-day lesson plan, as presented, or you may wish to tailor the activities to your Warm Up 10 minutes 1. Pose the question: “What are some of the most heroic professions you can think of?” 2.If necessary, prompt the class to call out “mining” by reminding them of current events (i.e., heroic rescue effort of the Chilean miners). 3.Write several responses on the board, including mining, and ask the students to come up with different ways science might be involved in each profession with a focus on the necessary safety precautions associated with each job. students’ skill levels and class time parameters. It is designed to bring science to life in the classroom through exposure Introduce Relevant Vocabulary Suggested terms: 15 minutes to real-world scientists and engaging activities that demonstrate everyday applications for science. Have fun with it! And do let us know what you think – e-mail us at science.worx@us.astellas.com – as we hope to provide more videos and lesson guides in the future. Together we can inspire acetylene coefficient combustible flammable product reactant subscript the next generation of scientists! Adult supervision required. Utilize appropriate Personal Protective Equipment (PPE) such as safety goggles, aprons and gloves when conducting experiments. Page 1 Introduce Objectives of Lesson After today’s lesson, students will be able to: 1. Identify the coefficients and subscripts in a chemical equation 2.Label the reactants and products of a chemical equation 3.Balance chemical equations 4.Explain the law of conservation of mass 5.Describe measures for enhancing mining safety 5 minutes Watch Science WoRx Video “Ice on Fire!” Note: If you wish to conduct the “Ice on Fire!” experiment in your classroom, please contact the Science WoRx team (science.worx@us.astellas.com) for the protocol and specific safety instructions. 10 minutes Virtual Science Pro Lesson Guide Ice on Fire! Q&A To encourage students’ inquisitive tendencies, you may want to open the discussion to questions, or assign questions for them to respond to on their own. To get you started, we’ve provided sample questions below. 10 minutes 1. Why is it necessary to extinguish the fire with a lid and not water? 2.Other than mining headlamps, what are some other applications for acetylene? A few examples include early automobile, motorcycle and bicycle headlights, early street lamps, radio carbon dating, welding (mostly artistic) and the manufacture of plastics. ACTIVITIES: DAY 2 ESTIMATED TIMING Follow-Up Activity (to Weave in Curriculum-Based Competency) 15 minutes 1. Write “H2 + O2 → H2O” on the board. 2.Walk the class through balancing chemical equations using the above example, explaining how each atom must be represented in equal amounts, and as integers, on both sides of the equation. 3.Explain the law of the conservation of matter and that it is critical to understand how to balance a chemical equation in order to predict the quantity of the chemical compound yielded by the original molecules. 4.Write “CaC2 + H2O → C2H2” on the board and ask the students to help you balance the equation for acetylene. Follow-Up Activity (to Reinforce Knowledge and Test Comprehension) 1. Divide class into small groups, asking them to come up with a name. Each group will represent a consulting group or environmental nonprofit group. Page 2 30 minutes Virtual Science Pro Lesson Guide Ice on Fire! 2.Provide students the following scenario: An unfortunate incident occurred at the Coral Mesa mine in [insert name of local town students are familiar with]. Luckily, the mine’s gas detectors and communication devices worked properly, so all 20 miners were able to seek refuge in the mine’s safe room until a rescue robot was able to escort the miners to safety above ground. Mr. Wilson, a local farmer, wasn’t as lucky. Coral Mesa owns the mineral rights on Mr. Wilson’s property. It turns out that one of his cows cut her leg on barbed wire that was erected to keep the cattle away from the mine shaft. In response to her distress calls, a group of cattle had surrounded her when the incident occurred, putting them in harm’s way. Mr. Wilson lost a dozen head of cattle. To add an additional twist to the matter, the local municipality maintains a landfill adjacent to Mr. Wilson’s property, not far from the mine. Mr. Wilson sued Coral Mesa, claiming that the company failed to follow all appropriate safety precautions. Mr. Wilson also sued the local municipality, claiming that it failed to enforce appropriate zoning laws by allowing the mine to operate near a landfill. A county judge ruled that all parties were responsible for the accident and livestock casualties, citing that it was impossible to determine if the increased concentrations of methane that gave rise to the event were caused by the landfill or the proximity of the cattle to the mine. Further, even though Coral Mesa effectively implemented reactive safety measures, the company failed to follow appropriate preventive measures. The judge called for each of the three parties in the lawsuit to pay fines (the fines for each individual party were not disclosed) for a combined total of $1.5 million. The county then issued a request for proposals for a $1.5 million contract to implement innovative safety measures to prevent a similar incident in the future, and to provide a model for neighboring counties. Page 3 Virtual Science Pro Lesson Guide Ice on Fire! 3.Tell the groups that they will compete for the contract, and that the first phase of the selection process is to correctly balance as many chemical equations as possible (you may want to provide each group a hand out of the equations to balance). Some suggested equations to balance are: a) _CH4 + _O2 → _CO2 + _H2O (methane combustion) b)_Mg + _O2 → _MgO (fireworks) c) _O2 + _H2 → _H2O (hydrogen combustion, responsible for the Hindenburg blimp incident) 4.Provide bonus points to the teams who can answer why cows and landfills would contribute to the elevated levels of methane in the mine. 5.Provide bonus points to the teams who come up with the most safety measures. 6.Announce the winning group at the end of class. Note: If desired, and depending on time constraints, there are a number of ways to extend this activity, including making it a more formal project for each group to present to the class. You could also change steps 4 and 5 from bonuses to required assignments. Homework Assignment 5 minutes (to provide Ask students to research a famous chemical mishap (i.e., the assignment) West Virginia mining incident in early 2010) and to bring the following to the next class: 1. A one-paragraph summary of the details surrounding and circumstances leading to the event. 2.The correct, balanced chemical equation that led to the event. 3.A recommended safety measure to prevent future mishaps of the same kind. Additional Resources For additional resources, visit our partner websites: http://www.nsta.org http://www.ibioinstitute.org Page 4 Virtual Science Pro Lesson Guide Ice on Fire! Balancing Equations Practice Worksheet Balance the following equations. Explosion Reactions: 1)___CH4 + ___O2 → ___CO2 + ___H2O (methane combustion) 2)___Mg + ___O2 → ___MgO (fireworks) 3)___O2 + ___H2 → ___H2O (hydrogen combustion) 4)___C8H18 + ___O2 → ___CO2 + ___H2O (gasoline combustion) 5)___C3H5(NO3)3 → ___CO2 + ___H2O + ___N2 + ___O2 (detonation of nitroglycerin) Additional Reactions: 1)___ NaNO3 + ___ PbO → ___ Pb(NO3)2 + ___ Na2O 2)___ AgI + ___ Fe2(CO3)3 → ___ FeI3 + ___ Ag2CO3 3)___ SiCl4 + ___ H2O → ___ H4SiO4 + ___ HCl 4)___ ZnSO4 + ___ Li2CO3 → ___ ZnCO3 + ___ Li2SO4 5)___ V2O5 + ___ CaS → ___ CaO + ___ V2S5 6)___ Mn(NO2)2 + ___ BeCl2 → ___ Be(NO2)2 + ___ MnCl2 7)___ AgBr + ___ GaPO4 → ___ Ag3PO4 + ___ GaBr3 8)___ H2SO4 + ___ B(OH)3 → ___ B2(SO4)3 + ___ H2O 9)___ Fe2(SO4)3 + ___ KOH → ___ K2SO4 + ___ Fe(OH)3 10)___ H2SO4 + ___ HI → ___ H2S + ___ I2 + ___H2O Page 5 Virtual Science Pro Lesson Guide Ice on Fire! Solutions for the Balancing Equations Practice Worksheet Explosion Reactions: 1)CH4 + 2 O2 → CO2 + 2 H2O (methane combustion) 2)2 Mg + O2 → 2 MgO (fireworks) 3)O2 + 2 H2 → 2 H2O (hydrogen combustion) 4)2 C8H18 + 25 O2 → 16 CO2 + 18 H2O (gasoline combustion) 5)4 C3H5(NO3)3 → 12 CO2 + 10 H2O + 6 N2 + O2 (detonation of nitroglycerin) Additional Reactions: 1)2 NaNO3 + PbO → Pb(NO3)2 + Na2O 2)6 AgI + Fe2(CO3)3 → 2 FeI3 + 3 Ag2CO3 3)SiCl4 + 4 H2O → H4SiO4 + 4 HCl 4)ZnSO4 + Li2CO3 → ZnCO3 + Li2SO4 5)V2O5 + 5 CaS → 5 CaO + V2S5 6)Mn(NO2)2 + BeCl2 → Be(NO2)2 + MnCl2 7)3 AgBr + GaPO4 → Ag3PO4 + GaBr3 8)3 H2SO4 + 2 B(OH)3 → B2(SO4)3 + 6 H2O 9)Fe2(SO4)3 + 6 KOH → 3 K2SO4 + 2 Fe(OH)3 10)H2SO4 + 8 HI → H2S + 4 I2 + 4 H2O Page 6