Thematic Unit Introductory Paragraph The theme of this unit is Molecular Shapes and Covalent Bonds. On Day 1, we introduced Covalent Bonding and electron dot structures. We referred back to prior learning on the topics of Ionic Bonding and chemical formulas, taking advantage of 3D models that the students used to discover for themselves how the atoms in a molecule might bond together (this was starting with the application). We compared and contrasted the 2 types of bonding, using a rich variety of language to inform students’ understanding of them. We used Teach the Text Backwards and Think-Pair-Share (and guided discussion) as strategies to address the 3 principles of sheltered instruction on the first day. We also began to teach them step-by-step how to draw/represent molecules using Electron Dot Structures. We explored language by making comparisons and activating prior knowledge regarding “covalent,” “notation,” “ionic,” “octet,” and “sharing” vs. “giving and taking.” On the second day, we introduced the students to more advanced molecular structures and the idea of bond order, using guided discussion, models and guided notes. We had time for the students to practice using the steps outlined on day 1 to draw/represent additional molecules. Think-Pair-Share was utilized on several occasions, as was Teach the Text Backwards for each section of this unit. On the third day, we introduced the shapes (molecular geometry). We used different colored balloons to represent the electrons in each bond. Balloons were added to signify more-complicated molecules, and students drew on known language to make connections to the new geometrical-shape vocabulary being introduced. We used guided discussion, guided notes, models, and practice problems. Embedded in Day 2 and 3 was the vocabulary from Day 1 and new vocabulary such as “pyramid,” “linear,” and “planar.” Prior knowledge was activated with words such as “tri-,” “tetra-,” “bi-,” and “oct-.” Student Composition Grade level – 11 Native Language – Arabic Proficiency Level – Transitional Number students at Transitional Level – 1 Unit Graphic Organizer Ionic Valence Electrons Covalent Octets Molecular Shapes and Bonds Shapes / Molecular Geometry Lewis Dot Structures Bond Order / Strength / Length Resonance Lesson Plan Format 1. Preparation Before Class Standard/s: Content Area Curriculum Frameworks: ELPBO: Objectives: Students will be able to (finish with active verbs) Content: Massachusetts Curriculum Learning Standards – High School Chemistry 4.1 Explain how atoms combine to form compounds through both ionic and covalent bonding. Predict chemical formulas based on the number of valence electrons. 4.2 Draw Lewis dot structures for simple molecules and ionic compounds. 4.4 Use valence-shell electron-pair repulsion theory (VSEPR) to predict the molecular geometry (linear, trigonal planar, and tetrahedral) of simple molecules. Language: Learning Strategies: Think-Pair-Share Teach the Text Backwards Key Vocabulary: (list) ionic, covalent, metallic, bond, octet, sharing, pyramid, linear, planar, bi-, tri-, tetraKey Grammatical Structures/Uses of Language: (list) Materials, Texts, and/or Other Resources: (list) Model kits Addison-Wesley textbook Guided notes Balloons Lesson Plan Graphic Organizer Day 1 (lesson 1) Three-column chart comparing and contrasting ionic, covalent and metallic bonds & compounds. Even though this unit focuses on covalent bonds & molecules, prior knowledge of ionic & metallic bonds is drawn on to complete the chart. Ionic Covalent Metallic Relative Melting High Low High point/boiling point Electrical molten state or None solid state conductivity aqueous solution Appearance crystalline solids can be any phase of Lustrous, ductile, matter malleable Solubility in water Soluble insoluble insoluble (in general) General types of Metal & non-metal 2 Non-metals 2 Metals atoms involved Lesson Plan Graphic Organizer Day 2 (lesson 2) Three-column chart relating bond energy, bond length and bond order. Bond Bond Energy (kJ/mol) Bond Length (pm) Bond Order C–C 347 154 1 C=C 657 133 2 C≡C 908 121 3 Lesson Plan Graphic Organizer Day 3 (lesson 3) Chart relating steric number to molecular geometries. Images are also included to show visual examples of each geometry, in addition to new vocabulary. Steric Number 1 # of Atoms Connected to Central Atom 1 Molecular Geometry linear Example Formula(s) H2,F2 Image of example H–H 2 3 2 3 linear trigonal planar BeCl2 BF3 4 4 tetrahedral NH4+ 3 trigonal pyramidal NH3 2 bent NH2- 5 5 trigonal bipyramidal PF5 6 6 octahedral IF6+ Rubric for lab Criteria Physically build the models 4 - Exemplary • 100% Accuracy • No missing bonds/electron pairs • Correct color of beads (atoms) 3 – Proficient • One missing bonds/electron pair • Correct color of beads (atoms) Correct Electron dot structures (drawings) • Total number of valence electrons represented • Each atom has a full octet (if applicable) • Connectivity of atoms correct (central atom chosen correctly) • All characteristics of specific atoms are represented correctly (i.e. no double bonds with halogens or hydrogen) • Total number of valence electrons represented • Each atom has a full octet (if applicable) • Connectivity of atoms correct (central atom chosen correctly) • Some characteristics of specific 2 - Developing • Several missing bonds/electro n pairs • Correct color of beads (atoms) • Total number of valence electrons represented • Some atoms lack a full octet • Connectivity of atoms correct (central atom chosen correctly) • Several characteristics 1 - Beginning • Several missing bonds/electron pairs • Incorrect color of beads (atoms) Points ____ X 2 • Total number of valence electrons represented incorrectly • Some atoms lack a full octet • Connectivity of atoms incorrect (i.e. central atom chosen incorrectly) • Many characteristics of specific atoms are represented ____ X ½ per structure atoms are represented incorrectly (i.e. double bonds with halogens or hydrogen) Molecular shapes • Correct geometric shape chosen for molecule • Accurate threedimensional sketch illustrating location of atoms • Correct geometric shape chosen for molecule of specific atoms are represented incorrectly (i.e. double bonds with halogens or hydrogen) • Incorrect geometric shape chosen for molecule incorrectly (i.e. double bonds with halogens or hydrogen) • Incorrect geometric shape chosen for molecule ____ X ½ per molecule