Chemistry 312 – Chapter 9 Review Assignment Given: A compound containing 3 chlorine atoms and a nitrogen atom Chemical Formula _______NCl3_________ Name ________Nitrogen trichloride__________ Molecular Structure (Show all bonds and lone pairs with the approximate geometry of the molecule) Only picture I could find. Replace bonding electrons with lines. Shape ______trigonal pyramidal____ Polarity _______Non polar__________________ How many sigma bonds? _3___ How many pi bonds? __0__ Will this compound dissolve in water? ___NO___ Given: A compound that contains 2 oxygen atoms and a sulfur atom. Chemical Formula ____SO2____________ Name _________Sulfur dioxide__________________ Molecular Structure (Show all bonds and lone pairs with the approximate geometry of the molecule) Shown with all of its resonance structures Shape ____Trigonal planar______________________ Polarity ____________nonpolar_____________ How many sigma bonds? __3___ How many pi bonds? ___1__ Will this compound dissolve in water? ___no____ Given: A polyatomic anion that contains carbon and three oxygens. Chemical Formula ____CO32-____________ Name _______Carbonate ion____________________ Molecular Structure (Show all bonds and lone pairs with the approximate geometry of the molecule) Shape ______trigonal planar____________________ Polarity _________nonpolar________________ How many sigma bonds? __3___ How many pi bonds? _1____ Will this compound dissolve in water? ___no____ Given: A molecule that contains 4 iodine atoms and one silicon atom. Chemical Formula _____SiI4___________ Name __________Silicon tetraiodide_________________ Molecular Structure (Show all bonds and lone pairs with the approximate geometry of the molecule) Best I could do Shape _______tetrahedral___________________ Polarity _______non polar__________________ How many sigma bonds? ___4__ How many pi bonds? _0____ Will this compound dissolve in water? ____no___ Name the following compounds/acid Write the formulas for the following compounds/acids H2PO3 _______Phosphorus Acid Pentanitrogen dichloride ___N5Cl2____ HBr _________Hydrobromic Acid Chloric acid __HClO3________ Si4O7 ______Tetrasilicon heptoxide Octaselenium hexafluoride _____Se8F7____ Chemistry 312 – Chapter 9 Review Assignment Name ___________________________ Given: A polyatomic cation that contains four hydrogen atoms and one nitrogen atom Chemical Formula _____NH4+_______ Name _____ammonium ion______ Molecular Structure (Show all bonds and lone pairs with the approximate geometry of the molecule) Shape ______Tetrahedral____________________ Polarity ________nonpolar_________ How many sigma bonds? __4___ How many pi bonds? __0___ Will this compound dissolve in water? ____no___ Given: A compound that contains two chlorine atoms and an oxygen atom. Chemical Formula ___Cl2O_____________ Name _______Dichlorine monoxide____________________ Molecular Structure (Show all bonds and lone pairs with the approximate geometry of the molecule) Shape ______Bent ____________________ Polarity ________Polar_________________ How many sigma bonds? ___2__ How many pi bonds? ___0__ Will this compound dissolve in water? ____yes___ Additional Questions: 1. Which of the following compounds are covalently bonded? (circle all that apply) a. NO2 2. b. CCl4 d. NH4Cl e. BH3 f. BaCO3 How many sigma and pi bonds are there in the following molecule? Sigma __3__ 3. c. CuS Pi __2__ In the diagram above, which has the shorter bond length, the carbon to carbon bond, or the carbon to hydrogen bond? Which bond would require more energy to break? Explain. Carbon to Carbon. As the bond number increases the bond length decreases. The carbon to carbon bond would be harder to break because you would essentially need an amount of energy equal to the that amount that is given off as the bond forms. 4. Draw two resonance structures for the polyatomic anion CO 32- Pi bond 5. Which of the following compounds contains at least one pi bond? a. 6. CO2 b. CHCl3 c. AsI3 d. BeF2 Draw the structure of your answer to #4 and indicate where the pi bond(s) are in the structure. See above 7. Chloroform (CHCl3) was one of the first anesthetics used in medicine. The chloroform molecule contains 26 valence electrons in total. How many of these valence electrons take part in covalent bonds? 8 8. All of the following compounds have bent molecular shapes except____________. a. 9. BeH2 b. H2S c. H20 d. SeH2 What shape does your answer to #6 have? _____Linear______ 10. Which of the following compounds is not polar? a. H2S b. CCl4 c. AsH3 d. CH2Cl2 11. Draw the structural formula for your answer to #9 and explain why this molecule is non-polar. The individual bond polarities cancel eachother out. 12. Name the following acids or write their formulas H3PO3 ___Phosphorus acid HCl ____hydrochloric acid HClO3 _____Chloric Acid_ ____________________