Hiram College, Chem. 161 Fall 2007 Chemistry 161 Exam 1 September 21, 2007 Name:____________________________________ Useful Information F = 9/5 (C) + 32 C = 5/9 (F -32) 1 in = 2.54 cm 1 m = 39.37 in 1 mi = 63,360 in = 1609 m 1 kg = 2.205 lb 1 lb = 453.6 g 1 Hiram College, Chem. 161 Fall 2007 Part 1: Multiple Choice Place the letter of the best answer in the space provided. ____1. PET scans using Tc-99 tracers can be used to detect abnormalities in bone tissue. PET stands for a. b. c. d. positron electrical tomography. positron emission tomography. positive electron topography. positional electronic topography. ____2. The correct name for the formula Cu3(PO4)2 is a. b. c. d. copper phosphate. copper (I) phosphate. copper (II) phosphate. copper (III) phosphate. ____3. The average speed of a fastball thrown by “Black Jack” McDowell is 91 mi/h. The best expression of this in km/h is a. b. c. d. 146.77 km/h. 1.47 102 km/h. 1.5 102 km/h. 1.50 102 km/h. ____4. A covalent compound differs from an ionic compound in that a. b. c. d. covalent compounds have shared electrons. covalent compounds have higher melting points. covalent compounds have half-filled bonding orbitals. covalent compounds have long half-lives. ____5. The correct electron configuration for the chloride ion is a. b. c. d. 1s22s23s22p63p5 1s22s22p63s23p5 1s22s23s22p63p6 1s22s22p63s23p6 2 Hiram College, Chem. 161 Fall 2007 ____6. Of the following sets of elements, which contain only elements essential for life? a. b. c. d. N, Mg, K, Co, Sc Ca, Fe, Mg, K, Zn P, Fe, Mn, Zn, Li C, H, I, Pb, Ca ____7. In the third row of the periodic table, there are a. b. c. d. 3 metals, 1 metalloid and 4 non-metals. 3 metals, 2 metalloids and 3 non-metals. 2 metals, 2 metalloids and 4 non-metals. 2 metals and 6 non-metals. ____8. Boron-11 is used in nuclear reactors to absorb excess neutrons because it is a gamma emitter. When boron-11 undergoes gamma emission, what is the resulting nucleus? a. b. c. d. 10 5B 11 5B 11 6B 11 6C ____9. In the covalent compound sulfur dioxide, a. b. c. d. sulfur has 8 electrons, two bonds and two lone pairs of electrons. sulfur has 8 electrons, four bonds and one lone pair of electrons. sulfur has 10 electrons, two bonds and two lone pairs of electrons. sulfur has 10 electrons, four bonds and one lone pair of electrons. ____10. Which of the following is not true for a silicon-28 atom (Si): a. b. c. d. Silicon has 14 valence electrons. Silicon has 2 electrons in the 1s orbital. Silicon has 2 electrons in the 3p orbital. Silicon has 6 electrons in the 2p orbital. 3 Hiram College, Chem. 161 Fall 2007 Part 2: Matching Place the letter of the description in column 2 with the proper item in column 1. Column 1 Column 2 ____Salt water a. Form of energy ____Nuclear Fusion b. Chemical property ____Liquid mercury c. Physical property ____Magnesium sulfate d. Physical change ____Concrete e. Chemical change ____Silicon dioxide f. Pure elemental substance ____Melting ice g. Covalent compound ____Boiling point h. Ionic compound ____Oxidizes in air i. Homogeneous mixture ____Gamma radiation j. Heterogeneous mixture Part 3: Short answer Give the best answer to the questions below. If doing a calculation, be sure to show all work for full credit. 1. Phosphorous-32 is a radioactive isotope commonly used in nuclear medicine to detect eye tumors. It has a half-life of approximately 14 d and decays by beta emission. a. What is an isotope? b. How many protons, neutrons and electrons does phosphorous-32 have? c. Write the balanced nuclear equation for the beta emission decay of phosphorous-32. 4 Hiram College, Chem. 161 Fall 2007 d. Is the resulting nucleus stable? How do you know? e. 0.68 mg is a typical dosage for an adult patient. How much phosphorous-32 is left in the patient after 21 days? 2. A child was rushed to the hospital by an ambulance traveling at 62 mi/h. The child weighed 32 lb. a. The hospital was 41 km from the child’s house. How long did it take the ambulance to get to the hospital from the child’s house? b. Normal body temperature is 98.6F. The body temperature of the child was found to be 38.7C. Did the child have a fever? c. The child was diagnosed with bronchitis and was ordered ammonium carbonate as an expectorant. Write the formula for ammonium carbonate. d. If the typical dosage of ammonium carbonate is 50 mg/kg, how much should be administered to the child? 5 Hiram College, Chem. 161 Fall 2007 3. Nitrogen triiodide is a shock sensitive explosive made from ammonia (NH3) and elemental iodine (I2). a. Is nitrogen triiodide ionic or covalent? How can you tell? b. Write the valence electron configurations for nitrogen and iodine (only outer shell electrons). N I c. Give the formula for nitrogen triiodide. d. Draw the Lewis electron dot structure of the compound? e. What is the geometry around the central atom? Bonus Question If you could be anywhere else in the world right now, where would you be? 6