Chem 200 Dr. Saidane Lecture Notes Chap 1, Part 1 Matter and Changes Chemistry is the study of matter and the changes it can undergo. Chemistry deals with questions such as: 1. What is that material made of? 2. What is its makeup and internal arrangement? 3. How does it behave and change when heated, cooled, or mixed with other materials? 4. Why does this behavior occur? Matter is anything that has mass and takes up space. Matter appears in a huge variety of forms. It includes anything we can touch or see as well as anything we cannot touch or see. Therefore the knowledge of chemistry is essential if we want to understand how the world works. Matter is made of atoms, elements, and compounds. It has different states, properties and undergoes changes. Building Blocks of Matter: 1. An atom is the building block of matter. It is the smallest unit of an element that maintains the properties of that element. 2. An ion is a positively or negatively charged atom or group of atoms. 3. An element is a pure substance made of only one kind of atom. 4. A compound is a substance that is made from the atoms of two or more elements that are chemically bonded. They are classified as either molecular compounds or ionic compounds. 5. A molecule or a molecular compound is a definite and distinct electrically neutral group of bonded atoms. 6. An ionic compound is a definite and distinct electrically neutral group of bonded ions. 1 States of Matter Matter can be gas, liquid, or solid. 1. Matter in the gas state has neither definite volume nor definite shape. It takes the volume and shape of container. The particles are far apart from each other and move in strait lines freely, randomly and rapidly inside the container. 2. Matter in the liquid state has a distinct volume independent of the container. It has no specific shape. The particles are close to each other. They move around but not as fast as in the gas state. 3. Matter in a solid state has definite volume and definite shape. The particles are packed in a definite, ordered arrangement. They can only rotate and vibrate in a fixed position. Properties of Matter Properties of matter allow chemists to distinguish between substances and to separate them. A property is a characteristic that defines an entire group or subgroup of substances such as electric conductivity. Comparisons of several properties can be used together to establish the identity of an unknown. There are two ways of grouping properties of substances: 1. Properties are either intensive or extensive. 2. Properties are either physical or chemical. 1. a) Extensive properties depend on the amount of matter that is present. Such properties include volume, mass, and the amount of energy in a substance. b) Intensive properties do not depend on the amount of matter present. Such properties include the melting point, boiling point, density, and the ability to conduct heat or electricity. 2. a) A physical property is a characteristic that can be observed or measured without changing the identity of a substance. Such properties are color, melting point, boiling point, mass, and volume. b) A chemical property relates to a substance’s ability to undergo changes that transform it into different substances. For example the ability of charcoal to burn in air is a chemical property. 2 Changes in Matter Matter can undergo physical or chemical changes. 1. A physical change is a change in a substance that does not involve a change in the identity of the substance. Such physical changes include cutting, melting, grinding, and boiling a substance. 2. A chemical change is a change in which one or more substances are converted into different substances. A chemical change is also called a chemical reaction. Such chemical changes are the burning of charcoal, the corrosion of an iron bar, and the baking of bread. The substances that react in a chemical change are called reactants. The substances that are formed in a chemical change are called products. Classification of Matter Matter can be classified in terms of uniformity of composition and properties of a given sample into one of two groups: pure substances or mixtures. 1. A pure substance is made of one kind of matter. A pure substance can be an element or compound. a) Every sample of a given pure substance has exactly the same characteristic physical and chemical properties. These properties are so specific that they can be used to identify the substance. b) The composition of a pure substance is the same throughout and does not vary from sample to sample. This characteristic is also known as the law of constant composition or the law of definite proportions. For example, pure water is always 11.2% hydrogen and 88.8% oxygen by mass. 2. A mixture is a blend of two or more kinds of matter each of which retains its own identity and properties. It is a form of matter that can be separated by making use of the physical properties of the components. a) The properties of a mixture depend on the relative amounts of the mixture’s components. b) Mixtures are made of various amounts of different substances of different compositions. 3 Based on the uniformity of their compositions, mixtures can be classified as homogeneous or heterogeneous. A homogeneous mixture, also called solution, has a uniform composition. This means that it has the same proportion of components throughout. A salt-water solution is an example of such mixtures. A heterogeneous mixture has a non-uniform composition. It has different proportions of components throughout. An oil and water mixture is an example of heterogeneous mixture. Separation of Mixtures Mixtures are separated by making use of the differences in physical properties of the components. Techniques include filtration, distillation, and chromatography. 1. Filtration makes use of the differences in solubility (the ability to dissolve in a liquid). The soluble material dissolves in the liquid and passes through the filter. The insoluble material does not dissolve and is captured by the filter. This technique can be used to separate sugar from sand. 2. Distillation makes use of differences in boiling points. Distillation separates the components of a mixture by vaporizing one or more of the components. It can be used to remove water from salt, or remove alcohol from water. 3. Chromatography relies on the different abilities of substances to stick to surfaces. The mixture is separated as it travels through a surface carried by a fluid substance. Some molecules are adsorbed more readily than other and therefore emerge later with the carrier. This technique is the most sensitive. It allows separating, as well as identifying the different components of a mixture. Skills you should have mastered Conceptual 1. Define chemistry. 2. Define matter. 3. Distinguish atoms, ions, elements, compounds, and molecules. 4. Give the name of elements given their symbol and vice versa. 5. Distinguish physical properties and chemical properties. 6. Distinguish intensive properties and extensive properties. 4 7. Identify physical and chemical changes. 8. Distinguish mixtures, and pure substances. 9. Define the law of constant composition. 10. Distinguish homogeneous and heterogeneous mixture. Descriptive 1. Describe how matter is classified. 2. Describe the difference between gas, liquid, and solid state. 3. Describe how mixtures are separated. 5 Differences between mixtures and compounds Mixture Compound Components can be separated by using Components cannot be separated by physical techniques using physical techniques Composition is variable Composition is fixed Properties are related to those of its Properties are unlike those of its components components Differences between a pure substance and a mixture Pure Substance Mixture Every substance has the same physical Properties depend on relative amounts and chemical properties of different substances in mixture Uniform composition throughout the Different sample composition for each various amounts substance Constant composition from sample to May sample have of substances in each sample Differences between the three states of matter Gas No definite volume No definite shape. Takes shape of container Particles far apart from each other Particles move around in strait lines, freely, Liquid Solid Definite volume Definite volume independent of container Definite shape No definite shape. Takes Particles packed in a shape of container definite ordered Particles are close to Particles each other Particles move around in randomly, and rapidly strait inside the container randomly, arrangement lines, and can’t move around freely, in strait freely, lines. They can only slowly rotate and vibrate in a inside the container fixed position. 6