Curriculum Topic Study: Mixtures and Solutions FOSS kit: Mixtures and Solutions Curriculum Topic Study SCED 480 Laura Holzer, Ashley Stone, and Meagan Follett Big Ideas: (adapted from Page 1 of FOSS kit mixtures and solutions) Gain experience with the concepts of mixture and solution, concentration and saturation, and chemical reactions. Apply an operational definition to determine the relative concentrations of solutions. Use group problem solving techniques to plan investigations, measurement in the context of scientific investigations, and scientific thinking processes to conduct investigations and build explanations. (Observing, communicating, organizing, comparing, and relating). Apply mathematics in the context of science. Acquire vocabulary associated with chemistry and the periodic table. Identify Adult Content Knowledge What enduring understanding should all adults, including teachers, know about this topic (Keeley, 37)? “…everything is really made up of a relatively few kinds of basic material combined in various ways” (SFAA, 46). “When two or more substances interact to form new substances (as in burning, digestion, corrosion, and cooking), the elements composing them combine in new ways… The basic premise of the modern theory of matter is that the elements consist of a few different kinds of atoms—particles too tiny to see in a microscope—that join together in different configurations to form substances. There are one or more—but never many—kinds of these atoms for each of the approximately 100 elements. There are distinct patterns of properties among the elements” (SFAA, 47). These first two quotes emphasize the importance for adults to understand how atoms are constructed and how they connect to form elements. This knowledge is important background information for understanding why solutions interact in certain ways. This big idea is not explicitly represented in the Mixtures and Solutions FOSS kit. Instead, the FOSS kit facilitates and supports the notion that kids need to experience things firsthand and see what chemical reactions look like on a meaningful level. The knowledge gained through the FOSS kit investigations may serve as a base for learning about atoms and the structure of matter in later years. However, it is important that instructors understand the big picture so that they can effectively guide and make connections for students. “The arrangement of the outermost electrons in an This third quote is specifically important atom determines how the atom can bond to others and form materials…Depending on what kinds of bonds are made, the atoms may link together in chaotic mixtures, in distinctive molecules that have a uniform number and configuration of atoms or in the symmetrically repeated patterns of crystal arrays” (SFAA, 48). The rates at which reactions occur in large collections of atoms depend on how often the reactants encounter one another—and so depend on the concentration of reactants and how fast they are moving (that is, on temperature)… In particular, reactions occurring in water solution may be affected significantly by the acidity of the solution” (SFAA, 48-49). because it strongly correlates with the observing crystals section in the FOSS kit. It is essential for adults and teachers to understand how atoms are constructed so that they can understand how crystals are formed in order to effectively to support students’ inquiry and learning. We feel that this quote is quite relevant to the Mixtures and Solutions FOSS kit. Once you understand this idea you can understand many different areas of science. This information is specifically relevant to this FOSS kit in relation to saturation and concentration of solutions and how they impact chemical reactions. It is essential for teachers to be confident in their knowledge of this topic so that they can successfully facilitate student learning. If teachers understand this information, they can take this knowledge and pose thought provoking questions to students in order to promote inquiry based learning. Inquiry learning will help students internalize knowledge about molecular structures, which is an abstract idea to students. Teachers need to know this information to successfully lead students’ inquiry. Examine Research on Student Learning What specific misconceptions or alternative ideas might a student have about this topic (Keeley, 38)? Mixtures & Solutions “Most of the materials children encounter in everyday life are mixtures and therefore, from a science viewpoint, cannot be regarded as ‘pure’. However, some materials (such as air, water, honey, yogurt, and other foods) are frequently labeled ‘pure’, although they are really mixtures of substances” (Driver, 74). “The tendency for pupils to regard everyday materials as single substances was evident in an interview study where many 15-year-olds were unable to give examples of mixtures or explain them. Children could more readily recognize heterogeneous mixtures, such as granite, than homogeneous ones, such as solutions” (Driver, 74). “Children do not always appreciate that their statements about the properties of a mixture are of little value unless they state the composition of the mixture too” (Driver, 74). “Other children, because they did not see a boundary between solute and solvent, regarded a solution as a single substance rather than as a homogeneous mixture” (Driver, 84). “[Holding] asked five groups of pupils to place some sugar in water and stir the mixture until the sugar could no longer be seen. He then asked them to draw their idea of what was ‘there’…The majority of children depicted ‘bits of sugar’ distributed in several ways without drawing the water….The next most prevalent picture of a Mixtures & Solutions Some of children’s misconceptions of science terminology are brought into the class with them. Words such as ‘pure’ have connotations of being ‘clean’ or ‘untainted’. Students see substances such as yogurt as pure because it is seen as ‘purely yogurt’. Students must relearn some terminology from a science perspective, to understand that words can have different meanings in everyday life and in a science context. FOSS addresses these misconceptions in investigation 1 part 1 where students differentiate between a mixture and solution; students make and separate mixtures of water and solid materials. They discover that water and salt make a special kind of mixture: a solution, which cannot be separated with a filter. In investigation 1 part 4 students separate a dry mixture using the techniques of filtering and evaporation. Even adults confuse the idea of solvents and single substances. We do not often think of substances such as Pepsi as a solution; rather we see it as a single substance. The students we teach have similar misconceptions, it is important to confront these misconceptions with hands on experience. The FOSS kit addresses these misconceptions; in investigation 1 part 2, students separate salt solution was ‘continuous’ shading throughout… Molecules were rarely mentioned in the earlier years but later an appreciable proportion depicted ‘molecular particles’ of sugar – at age 15 and age 17 – but only half of these pupils also depicted molecules of water. It would appear that a continuous view of water is still quite prevalent in older pupils’ thinking about solutions (Driver, 95).” from a water solution. Concentration & Saturation “…there are several conceptions of ‘dissolving’…Up to age 8, there is a tendency to focus on the solute only and say it ‘just goes’, ‘disappears’, melts away’, ‘dissolves away’, or ‘turns into water’….Frequently, older pupils imagine that as sugar dissolves it ‘goes into tiny little bits’. Later on some say that ‘sugar molecules fill spaces between water molecules’ or else ‘mix with water molecules’” (Driver, 83). “…when probed about the weight of the solution, only about 50 percent of those who said the sugar is ‘there’ also say that ‘it weighs something’” (Driver, 84). Concentration & Saturation As stated earlier, students experience difficulty with differentiating science vocabulary from everyday vocabulary. In order for students to understand that there are actual parts (atoms and molecules) within a substance, they must experience various substances first hand. One way to experience this is through experiments. Students are able to physically ass a solute into a solvent (such as salt into water) before they will ever understand concentration and saturation of water. Students take their understanding to the next level, in investigation 2 part 1 students learn that a solution is saturated when as much solid material (such as salt) has dissolved in the liquid as possible. Investigation 2 part 3 requires students to experiment with an unknown material (Epsom salts) which leads to an understanding that solubility is the property that substances have of dissolving in solvents, and solubility is different for different materials and can change with temperature and different solvents. “After age 8, pupils increasingly generate more ideas about the kind of changes they imagine the solute undergoes…However, they do not regard weight as a gravitational force acting on the ‘bits’…After age 12, many pupils begin to develop a gravitational view of weight and also a science conception of mass so that eventually many, but by no means at all, conserve both weight and mass of a solute” (Driver, 84). “Although some students may think that substances can be divided up into small particles, they do not recognize the particles as building blocks, but as formed of basically continuous substances under certain conditions” (Atlas, 336). “Although some 3rd graders may start seeing weight as a fundamental property of all matter, many students in 6th and 7th grade still appear to think of weight simply as “felt weight”—something whose weight they can’t feel is considered to have no weight at all” (Atlas, 336). Chemical Reactions “By 5 grade, many students can understand qualitatively that matter is conserved in transforming from solid to liquid. They also start to understand that matter is quantitatively conserved in transforming from solid to liquid and qualitatively in transforming from solid or liquid to th These three quotes address students’ misconceptions about weight; students tend to believe that if they cannot see of feel something, then it does not have weight. This misconception has to be addressed before the weight of solutions can be understood. This concept is important to understanding that all things are made up of some kind of material. For example students don’t think that air has weight, but air is not just blank space, it is made up of atoms and molecules that do indeed have weight. The FOSS kit first introduces the concept of weight in investigation 1 part 2 when they separate salt from the water solution; they compare the total mass of the mixture from the mass of its parts. Then in investigation 2 part 2 students compare the solubility of salt and citric acid by comparing the mass solid materials dissolved in the saturated solution. Chemical Reactions Once students have gained an understanding of concentration they are prepared to move on to chemical reaction experiments. Investigation 4 focuses on chemical reaction experiments with the ultimate goal of teaching students they can apply techniques Examine Coherency and Articulation gas –if the gas is visible. For chemical reactions, especially those that evolve or absorb gas, weight conservation is more difficult for students to grasp” (Atlas, 337). “Middle—and high-school student thinking about chemical change tends to be dominated by the obvious features of the change…further, many students do not view chemical changes as interactions. They do not understand that substances can be formed by the recombination of atoms in the original substances. Rather, they see chemical change as the result of a separate change in the original substance, or changes, each one separate, in several original substances” (Atlas, 337). “They lack an appreciation of the very small size of particles; attribute macroscopic properties to particles; believe there must be something in the space between particles; have difficulty in appreciating the intrinsic motion of particles in solids, liquids, and gases; and have problems in conceptualizing forces between particles” (Atlas, 337). of separating mixtures and solutions to chemical reactions. In the investigation students mix combinations of solid materials with water and observe the changes that occur; they identify changes such as gas, and white precipitate as evidence of chemical reactions. They use the techniques of filtering and evaporating that they acquired in previous investigations to separate and study the products of reactions. Students conduct chemical reaction experiments in closed systems such as Ziploc bags, which enable them to observe the gas more critically. In the FOSS kit investigation 2 part 4 the students observe and compare citric acid and salt crystals and learn that crystals have specific shapes and patterns. Through observations students will gain an understanding of how the specific shape of individual atoms and molecules is a smallscale version of the large-scale crystals they have made. What pre-requisite ideas can you identify for learning the topic at your grade level (Keeley, 39)? The following points are from the Atlas of Science Literacy web of student understanding, found on page 57. K-2: “Objects can be described in terms of the materials These concepts are key in laying the 3-5: 6-8: they are made of.” “Things can be done to materials to change some of their properties, but not all materials respond the same way to what is done to them.” Most things are made of parts.” “People can keep track of some things, seeing where they come from and where they go.” “Some features of things may stay the same, even when other features change.” groundwork towards understanding mixtures and solutions. Students must understand that “things are made up of parts” and “objects can be described by the materials they are made of” to understand the basic concepts of mixtures and solutions. In the FOSS curriculum, students work with examining large scale manipulatives to build an understanding pf smaller scale unseen particles. “No matter how parts of an object are assembled, the weight of the whole object is the same as the sum of the parts.” “Substances may move from place to place, but they never appear out of nowhere, and the never just disappear.” Weight can be a tricky concept for kids, especially when they cannot see a substance, of the parts of a whole. Understanding the sum of an objects parts and that all substances are constant is integral to understanding mixtures and solutions. If students mix together salt and water they must understand that the salt is still ‘there’ and it still has weight. “No matter how substances within a closed system interact, the total mass of the system remains the same.” “All matter is made up of atoms, which are far too small to see directly through a microscope.” “The idea of atoms explains the conservation of matter; if the number of atoms stays the same no matter how the same atoms are rearranged, then their total mass stays the same.” Once students understand the concepts outlined for K-5th graders, they have laid the groundwork for understanding more abstract concepts such as mass, atoms, and molecules. These higher-level concepts are not addresses directly in the FOSS kit, but those lessons do address the pre-requisite knowledge that must be gained at the younger grades in order to move on to these concepts. References Key American Association for the Advancement of Science, National Science Teachers Association. (2001). Atlas of Science Literacy. Washington D.C. American Association for the Advancement of Science. (1993). Benchmarks for Science Literacy. New York, Oxford: Oxford University Press. American Association for the Advancement of Science. (1990). Science For All Americans. New York, Oxford: Oxford University Press. Driver, R., Squires, A., Rushworth, P., & Wood-Robinson, V. (1994). Making Sense of Secondary Science. London and New York: Routeledge Falmer. Keeley, P. (2005). Science Curriculum Topic Study. Thousand Oaks, California: Corwin Press. Atlas= Atlas of Science Literacy Benchmarks= Benchmarks for Science Literacy FOSS= Full Option Science System SFAA= Science for all Americans