Name: Periodic Trends Lab Introduction In 1869, aware of the need to organize elements in a meaningful way, Dmitri Mendeleev developed a classification scheme based upon increasing atomic mass. Elements that demonstrated similar patterns of chemical behavior were placed into eight groups. Members of these groups were displayed in vertical columns of his periodic table. Even though his chart was incomplete, Mendeleev was able to predict the properties of elements yet to be discovered. Over the next two years, Mendeleev published modified versions of his original periodic table. Today’s periodic table accommodates at least 50 additional elements. Although the scheme is based upon increasing atomic number, the arrangement of elements within the chart is similar in organization to the table published by Mendeleev in 1871. Trends in the chemical and physical properties of the elements may be seen as a periodic function of electron configuration. In this exercise, you will examine several properties of elements and observe how these properties may be interpreted with respect to periodic law. Your knowledge of the modern periodic table and facts about the elements will then allow you to construct the periodic table published by Mendeleev in 1871. Procedure Using Table S of the Reference Tables, obtain The following data for elements #1-36: Atomic Radius, Ionization Energy, and Electronegativity. Use the data table on the following page to organize your data. Plot the following graphs. a. Atomic Number on x axis vs. Atomic Radius on y axis b. Atomic Number on x axis vs. Ionization Energy on y axis c. Atomic Number on x axis vs. Electronegativity on y axis On each graph, indicate by using colors or different symbols the members of Group 1, Group 2, and Group 18. Analysis Look at your graph of Atomic Number vs. Atomic Radius. 1. As the atomic number increases from left to right across the period, the atomic radius ______________ 2. As the atomic number increases from top to bottom in a group, the atomic radius _________________ Look at your graph of Atomic Number vs. Ionization Energy. 1. As the atomic number increases from left to right across the period, the ionization energy ___________ 2. As the atomic number increases from top to bottom in a group, the ionization energy ______________ Look at your graph of Atomic Number vs. Electronegativity. 1. As the atomic number increases from left to right across the period, the electronegativity ___________ 2. As the atomic number increases from top to bottom in a group, the electronegativity _______________ Questions 1. What factor may account for the observed trend in atomic radii as one proceeds across a period? ______________________________________________________________________ 2. What factor may account for the observed trend in atomic radii as one proceeds down a group? ________________________________________________________________________ 3. Explain the reason for the trend in ionization energy across a period. ________________________________________________________________________ ________________________________________________________________________ 4. Explain the reason for the trend in ionization energy down a group. ________________________________________________________________________ ________________________________________________________________________ 5. Explain the reason for the trend in electronegativity across a period. ________________________________________________________________________ ________________________________________________________________________ 6. Explain the reason for the trend in electronegativity down a group. ________________________________________________________________________ ________________________________________________________________________ 7. Which group appears to have members of the largest atomic radii? __________________ 8. Which group appears to have members of has the smallest atomic radii? _____________ Data Atomic Number 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 Atomic Radius Ionization Energy Electronegativity