Name 1_______________________________Name 2___________________________ Section 1 2 Geoscience 100 Lab 5 – Fall 2014: Igneous Rocks and Processes Over 90% of the Earth’s crust and all of the mantle formed via igneous processes. These rocks make up over half the volume of the planet. This part of your lab work is worth 2% of the course total. In addition, inspect laboratory specimens of igneous rocks in the ward’s kit and hand specimens to see real examples corresponding to the photos in the AGI lab manual, in order to practice the identification of texture, contained minerals and other constituents, and to classify the rocks. Remember that there will be a rock quiz in a few weeks. It is useful also to compare igneous rocks with other rocks (sedimentary & metamoprphic). In order to interpret the nature and origin of igneous rocks it is very important to learn the names and to be able to interpret the significance of the textures especially those which are particular to igneous rocks. Also know how to identify the minerals and other constituents using your hand lens, hardness kits and the tables in Chapter 2. To do this rock lay you’ll need to work with the figures and tables in the manual so start by reading pages 129 through 142 in chapter 5. Where Igneous Rocks Originate and 3 Dominant Processes Which Affect Them: Igneous rocks are the result of 3 processes: partial melting, buoyant rise and solidification via cooling. Igneous rocks all originated by partial melting usually in the upper mantle asthenosphere of peridotites or sometimes in the lower crust via partial melting of amphibolites, gneisses or gabbros). Once the partial melt forms, it separates by wetting mineral grain surfaces, fracturing source rocks, shear and compaction (due to local directed forces) to buoyantly rise up into or even through the crust. The most common magma in all igneous settings is mafic basalt from > 1250°C in the upper mantle. Sometimes the lower crust in arcs or hotspots gets heated enough by basalts to stat melting in its own right ~ 1050°C to produce rhyolites or dacites. Magma buoyancy varies with: 1) temperature (due to thermal expansion), 2) with composition such that silica rich magmas (felsic) are lighter and more ferromagnesian rich magmas are denser and 3) by gas or fluid content ((H2O and CO2) such that gassy magmas are lighter and can even resemble foams. The final step is cooling which increases viscosity, slowing flow and causing a sequence of minerals to crystallize. If the cooling is super fast, the magma or lava at the surface quenches as a glass. If cooling is slower, crystals have time to nucleate and grow. When gases (fluids) are present, they act like solvents and thin the magma permitting faster flow, diffusion and crystal growth. Because the amount of magma is limited in volume and the crust, sea or air are cold, so cooling and solidification of magma or lava to rock is inevitable. The 2 main environments are plutonic for intrusive rocks and volcanic for extrusive rocks. Analyzing Rocks: Textures, Mineralogy and Mafic Colour Index: Review figures 5.4 (p.136) for general textures, names and rock forming environments. Review figure 5.5 (p. 137) for igneous rocks derived from silicate melts to see how their names relate to textures, percentage of dark minerals (Mafic Colour Index CI) and general chemical composition. Review figure 5.6 (p.138) for Bowen’s Reaction series to understand the order in which minerals crystallize from cooling melts. Rock colour is an approximate indication of iron content in minerals or quenched glasses. Colour Index means the sum total of dark ferromagnesian minerals. The most common ones in igneous rocks are: Olivine, Pyroxenes, Amphiboles, Biotite and Iron-Titanium Oxides, but other iron bearing silicates and metal oxides or sulphides also count as dark minerals too: Tourmaline, Epidote, Sphene (Titanite), Hematite, Rutile, Pyrrhotite, Cassiterite etc. You may not be able to identify all of these but if it is dark add it into the total percentage of dark minerals to calculate the colour index. Texture and crystal size relates to cooling rate, because most crystal growth only happens within 100-150° below the liquidus temperature (point at which the first crystals appear upon cooling). Phaneritic (coarsely 1 crystalline rocks with grain sizes > 1 mm) are easiest to describe and analyse. They cooled slowly enough at depth inside the Earth for crystals to nucleate and grow. We may see their phaneritic texture but form this we can interpret that they originated as intrusive magmas deep in the Earth so we give them the environmental name “Plutonic” or simply “Intrusive”. When igneous rocks extruded from volcanoes, they cool quickly and once they cool by 100 to 150°C they cool through the glass transition temperature and they solidify and cease to flow. Because of this, crystals can only nucleate and grow when magmas are hotter and closer to their liquidus temperatures. When volcanic rocks have broken angular clasts or fragments they are collectively termed pyroclastic. When they are wholly glassy they are termed obsidian. Most volcanic rocks erupted and cooled more slowly to form many smaller or tiny crystals. These fine grained sugary textured rocks are called aphanitic and we interpret them to have cooled quickly in an extrusive environment. Rocks with a few large crystals and the majority smaller ones are called porphyritic. This means they had a 2 stage cooling history, slowly at first to form the big phenocrysts and fast at the end as they hit the cold ground, air or water. Shallow intrusions within volcanoes also have porphyritic textures especially for small plugs or thin dykes so we interpret them to have cooled in a hypabyssal (not very deep) environment. Activity 5.1 Igneous Rock Inquiry: Find numbered rocks in the lab like those in the table below and pictured in your lab manual on p. 143. Use the terms from the guide figures and tables mentioned in the paragraph above to practice observing and interpreting: rock texture names (size, shape and arrangement of crystals, groundmass, phenocrysts, vesicles or rock fragments. CI or mafic colour index as your manual calls it is a percentage equal to the sum of all dark minerals present. There is a tendancy to overestimate dark things and underestimate light ones. Imagine as you look at a rock that you could take a little broom and sweep all the dark mineral crystals to one corner of the rock and compare the area they would cover to 25% of the circle or square area you are staring at to tell whether it would take up all 25% or only a fifth, quarter, third, half of that. Once you have number for the CI you can decide whether the rock is felsic, intermediate, mafic or ultra mafic. Next compare the crystal sizes, at first using your hand lens, but eventually with your eyes alone. Distinguish coarse grained (> 1 mm) from fine grained or glassy rocks and additionally note whether they are pyroclastic and fragmental versus interlocking crystalline in their textures. After a few practice rocks you’ll be able to see a coarse grained intermediate colour index rock like a diorite and be thinking of the pluton it came from deep in the crust. Also rocks with glass fragments, shards and vesicles should cause you to think of volcanoes. Fill out the table below for the rocks pictured in 5.1 on p. 143. (22) Rock Name Colour Composition Texture Environment Of Formation 1. __________ Diorite Black & White Plutonic or Intrusive 2. ____________ Felsic Glass 3. Olivine Basalt Olivine, ____ ______ with Phenocrysts & ___________ 4. Granite 5. Tourmaline bearing Granite Pegmatite 6. Scoria Pegmatitic Brown Volcanic or ______ 2 Activity 5.2 Minerals Which form Igneous Rocks: (36) The find samples of the minerals pictured on page 144 in labeled trays 5.2.1-10. The purpose of reexamining these minerals is they crystallize in an orderly sequence and comprise more than 99% of most common igneous rocks. These are called the primary rock forming minerals. Rarely small amounts of partial melts form in short lived isolated small environments when lightening strikes to fuse sands at the surface to glassy fulgurites, meteorite strikes to form impact glasses such as tektites or lechatelierite, coal seams burning sediments to clinker and slag. Other more unusual minerals may form there owing to different starting compositions than the common peridotie in the upper mantle or the gabbro of the lower crust. Because minerals crystallize over a range of temperatures (see Bowen’s Reaction Series), the simple act of their crystallization changes the composition of the residual magma. Also because magmas flow, early formed crystals may separate by settling or floatation. When magmas rise up into crustal rocks, depending on what minerals are present in the roof or wall rocks such as quartz, calcite, shales, or salts contamination drives the magma in new compositional directions (silica rich explosive, calcium rich plagioclase or pyroxene, peraluminous, or peralkaline). In active magmatic regions new magmas may rise into older cooler magma chambers mixing magmas or even heating things up enough to cause eruptions. As these processes occur, igneous rocks may solidify from one or 2 minerals (OlivineDunite, Augite, enstatite Pyroxenite, Plagioclase Anorthosite) whose composition is rather different from the starting magma. Because of this there are many different igneous rocks, and more rocks than the simpler, few parental magmas they crystallized from. Complete the table below keeping in mind the igneous rocks these minerals comprise. Plagioclase feldspar ranges from the high temperature Ca-Al rich Anorthite through, Bytownite, Labradorite, Andesine, Oligoclase to Na-Si rich Albite. Volcanics may contain Sanidine or Anorthoclase instead of Sanidine. 9-12 are minor accessories. Mineral Name Chemical Formula Rock(s) containing it 1. Olivine 2. Muscovite 3. Quartz 4. Biotite 5. Augite 6. Plagioclase 7. Orthoclase 8. Hornblende 9. Magnetite 10. Ilmenite 11. Apatite 12. Zircon 3 Describe in your own words to recognize Activity 5.3 Igneous Rock Compositions: The first step is to use colour index Figure 5.5 p. 137 shows 5 minerals on the vertical axix and Mafic Colour Index on the horizontal axis. Notice dark minerals are all in shades of green or brown at the bottom of the graph. Igneous rocks become lighter in CI and cooler for their melting interval as they contain less Fe and Mg and the dark minerals which crystallize from them. You may also use the grey scale bar or dot bar at the top of the page. The Geo tools in the back have dot cards for the critical divisions at 85%, 45%, 15% and 5% as well. To use this chart to classify a rock first total up all of its darl minerals as a % area of a face on the rock or thin section. See whether this CI % is < 15 % for Felsic, between 15-45% for Intermediate, between 45-85% for Mafic or > 85% for Ultramafic. Next, determine the grain size of the crystals. Phaneritic or coarsely crystalline rocks get a name from the Yellow “Intrusive” or Plutonic part of the chart below. Aphanitic or fine grained rocks get a pink Extrusive or volcanic name from the bottom of the chart. Vesicular rocks were blown to foams by superheated expanding hot gases (H2O, CO2). Scoria can be grey, black or oxidized red-brown from hematite or limonite. This figure is a good summary but remember that it is generalized. For example, although a distinction is made between intrusive and extrusive rocks, be aware that texture can vary within a given intrusion or extrusion, dependent on size, composition, temperature, viscosity, etc. of the magma or lava. Thermal gradients can vary as can cooling times and even the composition of the original melt. One rock name does not describe a whole batholith or even the entire thickness of a thick lava flow, let alone a single volcano. Often many closely related rocks occur together in close map proximity or stratigraphic association. A. Fill out the following table for rocks pictured and provided as hand specimens 5.3-A.1-A.4 Rock name M.C.I.% Compositional Group Texture Geological Environment A.1 A.2 A.3 A.4 4 B. Discuss the relative ease or difficulty of classifying rocks via visual estimates versus point counts for: 1. phaneritic (3 & 4) versus _________________________________________________________ (1) ___________________________________________________________________________________ 2. aphanitic or glassy (1 & 2) ________________________________________________________ (1) ___________________________________________________________________________________ C. (Off book) Use the textural descriptions provided and mineral content % to classify the following rocks or to answer the question. Look at Fig. 5.5 and answer the following questions giving both word and numerical values for each colour index. Eg. CI = Sum (all dark “MAFIC” minerals). For (1%Biotite + 2% Amphibole + 3% Magnetite), CI = 6 and the rock is Felsic. If its texture is fine grained with a few large phenocrysts, it is a porphyritic rhyolite. 1. If a rock contains 3% Biotite and 5% Amphibole, what is its numerical colour index? CI =_____ & general compositional group using the top row of Figure 5.5.1 _____________________________. (2) 2. A rock with 0% Quartz, has a Colour Index______ & general compositional group ___________. (2) 3. A fine grained rock with both Quartz & Pyroxene is classified as a/an _____________________. (2) 4. A phanertic-porphyritic rock with predominant large phenocrysts of Amphibole & Plagioclase is called a/an ________________ ________________. (2) D. (Off book) Use the textural descriptions provided and mineral content % to classify the following rocks or to answer the question. Examine figure 5.5 for classification and 5.6 for the approximate temperature according to the 1st mineral to crystallize in Bowen’s Reaction Series for each rock type below. As magmas cool, silica tetrahedral link up (polymerize) and make minerals richer in 5 SiO2 and more connected (chains after lone tetrahedral, sheets after double chains etc. The percentages of constituent minerals and textures come from examining thin sections and point counting on grids instead of dashed lines like you tried above. Recall that the CI is only the sum of the mafic or dark coloured minerals, not the felsic ones! Give the CI and identify the corresponding names of the rocks. 1. Aphanitic rock: 18% Amphibole, 19% Pyroxene, 59% Plagioclase, 1% K-Feldspar, 3% Quartz CI ____ Name ______________ (2) 2. Pegmatitic rock: 8% Amphibole, 5% Biotite, 9% Ca-Plagioclase, 55% K-Feldspar, 4% Muscovite, 25% Quartz. CI ______ Rock Name ________________________________________________ (2) 3. Coarse pyroclastic 8% Biotite, 12% Amphibole, 30% Plagioclase, 3% K-feldspar, 16% Quartz CI ________ Rock Name ___________________________________________________________ (2) 4. Plutonic rock: 9% Amphibole, 35% Pyroxene, 51% Olivine, 5% Plagioclase CI ________ Rock Name ___________________________________________________________ (2) Activity 5.4: Glassy and Vesicular Texture of Igneous Rocks (Candy Lava Flow) Examine the laboratory demonstration put on by your instructor using Sugar, Water, A hot plate and an aluminum foil “river bed” for your lava flow to move down. A. Describe the initial viscosity (resistance to flow or deformation, shear stress/shear strain) and temperature of the molten sugar candy lava flow. How did the boiling lava behavior change as the water (solvent) boiled off? ________________________________________________________________ (2) ___________________________________________________________________________________ B. Describe what happened to the viscosity and temperature as the flow moved and hardened. _______ _________________________________________________________________________________ (2) C. Compare the final broken texture of the sugar lava flow to 2 objects in the lab. What can you infer about the cooling history of those other items? _____________________________________________ _________________________________________________________________________________ (2) D. Observe the texture of the cooled “candy lava” with a hand lens. Note the vesicles of trapped air or steam. What prevented them from leaving the lava? _________________________________________ _________________________________________________________________________________ (2) E. When sugar solutions slowly evaporate at room temperature they crystallize to relatively large rock candy crystals. Since crystal formation depends on ordering and diffusion of atoms or molecules, what 2 processes or conditions prevented surgar crystals from forming in the candy lava? _________________ _________________________________________________________________________________ (2) 6 F. Find a labelled igneous rock pictured in the book and one like it in the lab that have a texture resembling the candy lava from step C above. Record its number _______ & name ___________ . (2) G. Find a labelled igneous rock pictured in the book and one like it in the lab that have a texture resembling the candy lava from step D above. Record its number _______ & name ___________ . (2) Activity 5.5: Crystalline Textures of Igneous Rocks Crystallization experiments of a model compound (mint alcohol): Menthol C10H3(OH) Quench 2 minutes 2mm x 20 mm Quench 5 minutes 5 mm x 25 mm A. Describe how the crystal size and shapes above vary with quench rate or cooling time. _________ _________________________________________________________________________________ ________________________________________________________________________________ (2) B. Examine the 3 rock pictures and lab specimens. Describe the relative cooling rate for the following crystallinity or textures: 1. Aphanitic: _____________________________________________________________________ (1) 2. Phaneritic: _____________________________________________________________________ (1) 3. Pegmatitic: _____________________________________________________________________ (1) 7 C. Examine the specimens with porphyritic texture and describe how they might have formed. Consider that more than one process or sequence of events might be possible: 2 cooling events, gas build up, crystal floatation or settling… 1. Porphyritic Granite (K-Spar) 3. Porphyritic Oceanite-Basalt (Olivine) 2. Porphyritic Andesite (Andesine & Hornblende) 4. Porphyritic Peridotite (Olivine-Dunite) Largest sizes are respectively: 1) 5 cm, 2) 2 cm, 3) 8 mm 4) 12 cm Label as aphanitc or phaneritic & describe possible origins for the porphyritic texture for each rock: 1) _____________________________________________________________________________ (2) 2) ____________________________________________________________________________ (2) 3) ____________________________________________________________________________ (2) 4) ____________________________________________________________________________ (2) 8 Activity 5.7: Bowen’s Reaction Series & Crystallization Sequence from Thin Section Petrography Look at Figure 5.6 of Bowen’s Reaction Series and note the relationship of igneous minerals to their respective ranges of crystallization temperature. Note that most common magmas have a crystallization interval or melting range of about 200°C between the liquidus and the solidus. Once a magma cools by about 200° C it is too stiff to flow or for diffusion to let ions move around and grow any more crystals. Build up of solvents (volatile fluids) or contamination by salts extends this up to another 150°C. This is an “idealized model” subject to “real-world” modifications. Notice the sequence of crystallization from the top of the diagram down and how this relates to the position of minerals as read from right to left on Fig. 5.5. Lunar Basalt – Mare Procellarum – Apollo 12 Mission. 40X – 4mm wide Left: Plane Polarized Light. Large opaque euhedral Ulvospinel Fe2TiO4 . Clear, high relief, fractured, subhedral forsteritic Olivine. Pale pinkbrown pyroxene Augite with 2 cleavages. Clear white, low relief calcic Plagioclase. Both Plagioclase and Pyroxene have inclusions of Olivine and small opaque cubic Chromite FeCr2O4 . Right: Cross Polarized Light. Same image and power. Fractured olivine crystals have high birefringence colours (blue, pink, yellow, green & black) depending on crystal orientation and refraction. Augite appears pale white to beige or black. Plagioclase shows albite twinning and blue-white to black colours. Ulvospinel and chromite are opaque , so they are black. A.1 Label all 4 minerals on the Plane light image on the right: Ol, Au, Pl, Ul, Cr. Look at Bowen’s Reaction Series and explain what process caused the textural relationship between the Olivine (or 9 opaque minerals) and the plagioclase or Pyroxene (Augite) crystals? _______________________ ____________________________________________________________________________ (7) A.2 Examine a thin section of Precambrian Keewanawan Basalt from the North American Mid Continent Rift, when the continent almost split apart at 1.1 billion years ago. Notice the red oxidation of glass to hematite, vesicle infillings of quartz and calcite and some residual primary plagioclase and pyroxene (high birefringence colours). The Lunar Basalts from Mare Procellarum are over 2.4 Ga, more than twice as old. Describe what caused the difference between these 2 mafic basalt lavas as seen in thin section? ___________________________________________________________________________ ______________________________________________________________________________ (2) Left: Cross Polarized photo. Andesite tends to be crystal rich and have fragments of broken crystals, here 25-30 % of the volcanic rock. The crystals often show concentric zonation in composition from Carich cores to Na-rich rims. Aggregates of 2-3 different minerals form some of the crystal clots. Plagioclase here is albite twinned in shades of white-grey-black. Hot birefringence colours are hornblende. The groundmass is fine grained feldspar and brown glass. Some black crystals are extinct silicates, others are opaques like magnetite. Right: Cross polarized Dacite Porphyry with large oscillatory zoned plagioclase feldspar that zoned from Ca-rich Labradorite to Na-Rich Albite at least 6 times. Note some of the zones have well formed crystal outlines while others seem to be embayed or resorbed. Groundmass is dark glass, and fine grained feldspar and quarts. B.1 How hot was the magma on the left when it crystallized hornblende and intermediate plagioclase? ______________________________________________________________________________ (1) B.2 Explain what caused the multiple zones in the plagioclase crystal on the right? _______________ _______________________________________________________________________________ (2) 10 B3. Examine the thin section of the Hornblende andesite over on our microscope. Is the brown hornblende uniform in composition yes or no and describe or draw how it looks. Where are the magnetites in this rock? What do you think caused these textures? ___________________________ (3) _________________________________________________________________________________ _________________________________________________________________________________ This is a crossed polarized image of graphic or “cuneiform” granite. Here blebs of irregular white to grey quartz are intergrown with light grey-green alkalie feldspar. They seem ot radiate outwards from large blocky crystals for grey and black albite (Na-rich) plagioclase with multiple albite or paired Carlsbad twins. The grains with the hot birefringence colours are hornblende. C.1 Explain what caused the intergrowth of quartz and alkali feldspar? ________________________ ________________________________________________________________________________ (2) D. For the last 4 rocks: A1, B1, B2, C1 write their letters and names on the chart above where they formed. __________________________________________________________________________ (8) 11 Activity 5.9 Geological map of SE Pennsylvania, Fig 5.15. Examine the inset for the geographic location near the western margin of the Atlantic Ocean, which you’ll recall started forming when Pangea began to rift at about 200 Ma. The brown-tan areas are old Paleozoic basement rocks from a previous Wilson Cycle. The green areas are sub-horizontal, 220-200 Ma Permian continental red beds sediments of sands and muds deposited in narrow river valleys, shed off the Paleozoic highlands in the middle of Pangea. The pink areas are 190 Ma Jurassic mafic magmatic rocks which outcrop from Nova Scotia to New Jersey and in Morocco on the other side of the Atlantic.. A. Describe the shapes of the pink igneous bodies, interpret their 3 dimensional geometry from the map view and discuss the reasons for your answers: _____________________________________________ ___________________________________________________________________________________ ___________________________________________________________________________________ ________________________________________________________________________________ (2) B. Notice the igneous bodies labeled B. Describe these shapes and interpret their 3-dimensional geometry. Explain what you think they are and discuss your reasons. ___________________________ ___________________________________________________________________________________ ___________________________________________________________________________________ ________________________________________________________________________________ (2) C. What other landforms must have been present at 180 Ma in this active igneous landscape? Give your reasons. ____________________________________________________________________________ ___________________________________________________________________________________ ___________________________________________________________________________________ _________________________________________________________________________________ (2) 12 7. Fill out descriptions of the rock photos in figures 5.6-5.18 on table 5.24. 5.10 (rocks in Lab) Drawing & Labelling specimens (40 points) Draw & label 5 hand specimens including a scale bar & correct terms for minerals, textures. Interpret the igneous name for each rock and describe where and how it formed. (5 points each – 25 total) 5.10-A. Peridotite 5.10-B. Gabbro-Pegmastite 5.10-C. Scoria 5.10-D Diorite 5.10-E Welded Tuff 13