VIP . Formulas and Rules for designers and final users Ing. Pierattilio Di Gregorio Saes Advanced Technologies S.p.A. Email: pierattilio_di_gregorio@saes-group.com t (atm)-(0) Introduction. The design of a Vacuum Insulated Panel (VIP) is a multidisciplinary activity that implies a close interaction between designer (or supplier) and final user. Differently from conventional insulation materials, Vips are complex items whose final performances are [mW/m.K] resulting from a multi steps design PUR a-a approach. Herein after the foremost rules for shelf life VIP estimation and thermal design are exposed. Moreover some practical w log10(p) rules for proper usage are also mentioned. S Busta Getter pext V T(x) Working principle. In Fig.1 is shown the general structure of a (T)Pt/w[pext-p(t)] VIP. It comprises an inner "core" p(t) made of an highly porous matrix a-a (with porosity > 90%) having x low bulk thermal conductivity. Core Fig.1 (T)S [pext-p(t)] The core must have a completely "open cells" structure. This means that is forbidden the presence of any closed cell entrapping some residual gases. An outer envelope, or "pouch", seamed all around, encloses hermetically the inner core. Pouches are manufactured with not conventional and high tech packaging materials with ultra high barrier property. In a conventional porous material, like PUR foam, overall thermal conductivity is resulting from (see eq. 1): bulk conduction S , radiative heat transfer R , and gaseous conduction G . In isothermal conditions R depends on cell average diameter and porosity . In turns, S is function of porosity , matrix conductivity M and shape (a/b) of cells. Instead, G is monotonically p related to inner pressure p , to porosity and cell average diameter. Gaseous conduction is the most important term , being responsible for about 80% of overall thermal conductivity. Hence, if inner pressure is reduced up to cancel out G , overall (1) R ( , ) S ( , M , a / b) G ( p, , ) thermal transmission Fig.2 will depend on solid and radiative terms only. Actually eq. (1) is S M R G experimentally deduced, measuring thermal conductivity just in center of a VIP, as here the flow is unidirectional. A relationship as (2) has been (atm, T ) (0, T ) found out where first term (0, T ) is the sum (2) ( p, T ) (0, T ) A S R , and second term is G . In Eq. (2) with ~ p 1 (atm, T ) we designate VIP thermal conductivity p at high pressure, i.e. close to atmospheric value. Instead, A is a shape factor generally very close to 1. Obviously , for very low inner Core type (0,24C) (atm,24C) pCR pressure p , below a critical value pCR , Eq. [mW/m.K] [mW/m.K] [mbar] (2) simplifies to ( p, T ) (0, T ) . PolyStyrene “open cells” 4.5-5.5 33 0.5 Experimentally has been founded that PolyUrethane “open cells" 6-8 33 0.01-0.1 ( p, T ) depends not only on inner pressure Silica powder 3.5-5 22 1-10 p , but on VIP average temperature T too. Glasswool 2.5-3 33 0.01 Some reference values for the most used Tab.1 "core" are listed in Tab.1. Shelf life estimation. However good may be barrier property of materials used for pouch manufacturing, inner pressure p doesn't remain fixed to the initial value p evac , but slightly grow up over the time because of permeation of external gases that are at pressure p est p . The foremost permeation takes place through the "all around" flanges where the upper face of pouch is sealed to the bottom one. As shown in Fig.1, permeation depend on “permeability “ of sealing polymer (normally polyethylene), flange perimeter P , width w and thickness t of seam. There is also a secondary permeation through the pouch faces themselves. These faces come as multi-layers of plastic sheets (i.e. metallized PET ), eventually coextruded with a foil of solid aluminum having thickness 5m . As in Fig.1 permeation through faces depends on "permeance" and outer surface S . Permeance is close to zero if an aluminum foil is embedded in the multilayer. However the drawback in using an Al foil is a leak of thermal effectiveness (see later the problem of "edge H i effects"). Therefore multilayers H i i 0i exp i 0i exp made exclusively of aluminum RT RT metallized polymeric films are (3) dpi RT P t S ( p ext p ) often preferred. Generally the p est piest i i i i dt V i V w number n of metallized layers ranges between 1 and 3. Thickness p evac pi (0) p pi (t ) of sputtered aluminum is i i normally below 1000Å. Metallized films avoid problems related to edge effect even if to the detriment of a higher permeance. It's important to notice that e depends on barrier material and are specific for the gas/vapor passing through. Moreover are exponentially related to absolute temperature. If we know and for all the gases/vapors of the outer atmosphere, the panel geometry (i.e. volume V , flange perimeter P , ….), as well as temperatures "seen" by each face and by flanges, it's possible to estimate the growing of inner pressure p (t ) , by integration of equations (3). Once the function p p (t ) is known, by means of eq. (2) we can estimate the evolution over the time of thermal conductivity , and consequently, establish the amount of getters and dryers according to cost/opportunity ratios. This allow us a fine control of the thermal performance of the VIP and in such a way that it could evolve, with specified safety margins, from the requested value at beginning of life (BOL) to the end of life (EOL) one. Careful examination of Eq.(3) leads to interesting conclusions. For example it's a good rule to place the most permeable face of the panel in the colder area, because , as well as , strongly increase with temperature,. Moreover, big panels, with high ratio V/S or V/P, are to be preferred over small ones because the growing rate of inner pressure is directly related to this ratios Thermal design. Now we put our attention to a flat VIP, having sizes LxWxT , thermal conductivity , and an outer pouch of thickness s and flange thermal conductivity F . By formula (4), we can estimate the overall thermal conductivity VIP of the VIP. P 2(W L) s (4) VIP F F s The second term of (4) is referred to as "edge LW A effect" and models heat transmission through peripheral flanges It depends on thermal conductivity of flange F , ratio Pouch with “metallized” barrier F PM n AL Po lim perimeter/surface P / S , and pouch s thickness s . In turns (see Tab.2) F Pouch with “Al foil” depends on flange geometry (standard or barrier F AL 1 PM with folded-back flanges), type of s s multilayer (with Al "foil" or metallized Hybrid pouch 2PM film), thermal conductivity of barrier F "metallized" and "Al material Al and Po lim , pouch total s foil" 1 PM thickness s , aluminum foil thickness , AL number n of metallized layers, and Hybrid pouch 2PM F 2PM "metallized" and "Al thickness of sputtered aluminum. s PM foil", with folded 1 Typical values are Al =270E+3, back flanges 2 AL Po lim =240 mW / m.K , s =100, =6, Pouch with “Al foil” 3 F AL1 PM =0.1 m , n=1-3. barrier and folded 2 s s back flanges Current tendency is to use hybrid pouch Pouch with and with folded back flanges. This 3 F PM “metallized” barrier solution allows the highest coverage ratio 2 and folded back (see later), a negligible "edge effect" and flanges a low overall permeance, being limited to Tab.2 the metallized face only. TWALL T A AWALL Fig.3 Rapporto (lambda Wall / lambda Vip) 1 0 1.2 0.8 9 1.5 9 1.7 0.7 9 2.1 80 1. 8 2.1 Rapporto di Riempimento (T / T Wall) 0.9 0 1.4 VIP 0 1.4 FOAM 60 1. Now we turn our attention to Fig. 3 in which is shown a Vip foamed inside a wall using conventional insulation foam, for example PUR foam. This case is typical of RF/FZ industry. The thermal conductivity of the entire wall can be estimated by means of formula (5), where we've denoted with the "coverage ratio" A AW , i.e. the ratio between the Vip and wall projected areas, with the "fill ratio" T T W , that is the ratio between Vip and wall ~ thickness', and with the dimensionless ratio FOAM VIP between thermal conductivity's of foam and VIP. ~ (1 ) (5) W all VIP ~ 1 1 58 2. 0.6 In graph shown in Fig.4 are drawn the level curves 2. 00 of ratio W all / VIP , assuming and as, 2. 2. 21 98 0.5 respectively, the abscissa and ordinate variables. ~ Here the value of parameter ranges from 3 to 7. 2.4 3. 3. 38 1 0.4 95 From Fig.4 we observe that to achieve maximum 3.7 7 4. 54 thermal efficiency, should be as close as 5.1 3 0.3 possible to 1. This justify current tendency to use 0.5 0.6 0.7 0.8 0.9 1 Rapporto di ricoprimento (A / A Wall) folded back flanges. Also should be close to 1 , Fig.4 even if a gap TW all T of 12-15 mm at least, is necessary for proper foam flowing. Conclusions. In the present paper we have touched the foremost rules and formulas for designing and proper usage of VIPs. In particular has been underlined as mounting rules, component choice, flange design, thermal analysis, and shelf life estimation are strictly interconnected. Has been shown as the use of dimensionless ratios allows a fast and preliminary design of a vacuum panel. This is beneficial also for final user, as he can understand the underlying phenomena and, hence, interact properly with designer/supplier to optimize the VIP design. 7 2.7 36 3.