Test Review Guide: Use your notes and the worksheets provided to complete your own study guide for the test next Tuesday. Predict what type of bond will occur between the elements in problems 1 – 10. Please answer Ionic, Covalent, Metallic, Hydrogen or Van der Waals. You may use rule of thumb, but hydrogen and Van der Waals bonds are not included in “Rule of Thumb”. For this review sheet, please include all bond options. 1. Ca + O __ionic_________(intramolecular)_______________________ 2. 3. 4. 5. 6. 7. 8. 9. 10. Sc + P ___ionic_______(intramolecular )_______________________________ N + O ___covalent (polar)__ _______(intramolecular )__________________ Cs + Br _____Ionic__________(intramolecular )_____________________ Xe + Xe _Van der Waals___________(intramolecular )__________________________ W + Ir __metallic_____________(intramolecular )____________________ I + I ___covalent (non-polar)_____ _______(intramolecular )______________________ H2O + H2O __(between different molecules)___Hydrogen (intermolecular)_______________ H + H ___covalent (non-polar)_____ _______(intramolecular )__________________ O + H ____covalent (polar)____ _______(intramolecular )_____________________ Please list the bond type given by the description: 11. Bonds that are described by a "sea of electrons." Metallic 12. Bonds that do not melt from the heat of a candle. (Strong bonds) Ionic 13. Formed when 2 atoms share electrons Covalent 14. Bonds that dissolve in water ionic 15. If a conductivity test is performed, the light bulb will…light. ionic 16. Bonds that are described using large numbers of cations and anions. Ionic 17. Bonds that melt from the heat of a candle. Covalent 18. Bonds that transfer electrons from one element to another. Ionic 19. Intermolecular – attraction between molecules Hydrogen bonds 20. Electronegativity difference is between basically 0 non-polar covalent 21. Electronegativity difference is between 0.3 – 1.7 polar covalent 22. Electronegativity difference >1.7 ionic 23. Bonds that involve the noble gases. Van der Waals 24. If a conductivity test is performed, the light bulb will not light. Covalent 25. Bonds that will form solids, liquids, and gases. covalent 26. What is the electronegativity range for non-polar covalent bonds? 0-<0.3 27. What is the electronegativity range for polar covalent bonds? 0.3-1.7 28. What is the electronegativity range for ionic bonds? 1.8-4.0 29. Bond type that involves the unequal sharing of the valence shell electrons between the elements. Polar covalent 30. Bond type in which the valence shell electrons are shared equally between the elements. Nonpolar covalent 31. Electronegativity difference is between 0.4 – 1.7 polar covalent 32. Usually found between diatomic molecules – two of the same atoms non-polar covalent 33. The compound will fall apart (dissociate) into its original ions when dissolved in water ionic 34. These bonds are important for Noble Gases Van der Waals 35. What is the electronegativity difference in the compound NaCl? 3.0-0.9=2.1 36. Based on the electronegativity difference in the compound NaCl, what type of bond is occurring? ionic 37. What is the electronegativity difference in the compound AlF? 4.0-1.5=2.1 38. Based on the electronegativity difference in the compound AlF, what type of bond is occurring? ionic 39. What is the electronegativity difference in the compound I2? 0 40. Based on the electronegativity difference in the compound I2, what type of bond is occurring? Non-polar covalent 41. What is the electronegativity difference in the compound CaS? 2.5-1.0=1.5 42. Based on the electronegativity difference in the compound CaS, what type of bond is occurring? ionic 43. What is the electronegativity difference in the compound CuCl? 3.0-1.9=1.1 44. Based on the electronegativity difference in the compound CoBr, what type of bond is occurring? 2.8-1.9=0.9 polar covalent 45. Since water is polar, which bonds break apart in it? a. Ionic b. Polar Covalent c. Nonpolar Covalent d. Both a and b e. Both b and c 46. If ethanol is nonpolar, which bonds will dissolve in it? a. Ionic b. Polar Covalent c. Nonpolar Covalent d. Both a and b e. Both b and c 47. Which compounds will conduct electricity? Ionic and metallic 48. Why does atomic radius change as you go down a group? Energy levels are added to hold the extra electrons 49. A measure of the ability of an atom in a chemical compound to attract electrons is called Electron affinity 50. Most chemical bonds are intramolecular 51. In a compound, the sum of the cation and anion charges will be Zero 52. What is the charge on a cation? + 53. What is the charge on an anion? 54. Metals bound metals to form these bonds. metallic 55. Nonmetals bound to nonmetals form these bonds. covalent 56. Metals bound to nonmetals form these bonds. ionic 57. Draw the electron cloud that would surround the following compounds and tell what the type of bond it is and what the electronegativity difference is. Describe how these bonds differ and why or if they should be drawn differently. Au I H H EN of Au __2.4_______ EN of I ___2.5_______ Difference ___0.1______ bond type _non-polar covalent_______ EN of H _2.1______ EN of H___2.1_____ Difference _0_____ bond type _non-polar covalent_____ Fr Br EN of Fr __0.7_____ EN of Br ____2.8_____ Difference __2.1_____ bond type __ionic______ Description of differences or similarities between and among the three bonds you drew ______Francium and Bromine do not share electrons. They transfer electrons. Au and I share as do the hydrogens. Sharing equally means non-polar covalent bonds are formed. Transfer means ionic bonds form. ___________________________________ Based on the following atom’s nuclear symbol: 113 56 Ba 58. How many electrons does Barium have? 56 59. What is the mass number of Barium? 113 60. How many neutrons does Barium have? 57 61. How many protons does Barium have? 56 62. Based on the average atomic mass of Ba, what is the difference between the above atom and elemental Barium found on the periodic table? Why? Average atomic mass from the table is 137amu. This isotope has fewer neutrons and represents only one isotope where the periodic table’s number represents all the isotopes. 63. Given the quantum numbers, 3 2 -2 -½ , draw the correct electron (arrow): _ __ _ _ _ _ 3d 64. Draw the electron configuration for Bromine. Br = 35e1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p5 65. Draw the noble gas notation for Bromine. [Ar] = 18e[Ar] 4s2 3d10 4p5 66. What is the quantum number for the last electron in Bromine? 4 1 0 -1/2 Based on the following atom’s hyphen notation: Sc-21 67. How many neutrons does Sc have? __21____ 68. How many protons? __21____________ 69. How many electrons? ______21___________ 70. What would the mass number of Sc be? ______42_______ 71. Given the three isotopes of element X, find its average atomic mass. 60% =X-12, 25%= X-13, and 15% = X-11. Show your work. Using only the Rule of Thumb, what type of bond will occur between the following elements. 72. Mg + S a. Metallic Bond b. Ionic Bond c. Covalent Bond d. No Bond 73. Ca + S a. Metallic Bond b. Ionic Bond c. Covalent Bond d. No Bond 74. C + C a. Metallic Bond b. Ionic Bond c. Covalent Bond d. No Bond 75. Rb + N a. Metallic Bond b. Ionic Bond c. Covalent Bond d. No Bond 76. Mn + Rn a. Metallic Bond b. Ionic Bond c. Covalent Bond d. No Bond 77. Ac + Sg a. Metallic Bond b. Ionic Bond c. Covalent Bond d. No Bond 78. F + F a. Metallic Bond b. Ionic Bond c. Covalent Bond d. No Bond Most missed questions from the last test: 1. Which of the following is the least shiny metal? a. Na b. Cs c. Fr d. S 2. Which element is made in the laboratory (not found in nature)? a. He b. N c. Es d. Li 3. Which factor best accounts for the trend of atomic radius as you go down a group? a. Fewer protons in the nucleus. b. Electrons are being placed in higher energy levels. c. More protons in the nucleus. d. Ionization energy increase. 4. The energy needed to remove an electron from an atom is called a. electronegativity b. ionization c. electron affinity Use the choices to the right to classify the elements in questions 5-13 5. 6. 7. 8. 9. 10. 11. 12. 13. Na Si Br Ag Ca S Ga H Ne ___a____________ ___h_____________ ___c_____________ ___e_____________ ___b_____________ ___h_____________ ___g____________ ___h_____________ ___d_____________ a. Alkali metal b. Alkaline earth metal c. Halogen d. Noble gas e. Transitional metal f. Inner Transition Metal g. Post Transition metal h. Other nonmetal i. Metalloid More important review: 1. Fill in the table below: Mass Number Nuclear Symbol Notation # of Protons # of Neutrons # of electrons 61 47 45 35 5 8 5 53 74 108 108 47 Ag 47 80 80 35 Br 35 13 13 5 127 127 53 B I 2. Write the full electron configuration for Nickel (#28). 1s2 2s2 2p6 3s2 3p6 4s2 3d8 3. Write the noble gas notation for Phosphorus (# 15) [Ne] = 10 [Ne] 3s2 3p3 4. Identify this piece of lab equipment: __crucible tongs________ 5. Identify this piece of lab equipment ___graduated cylinder_______ *know all of the glassware we studied 53