Chapter 20: Rocks and Minerals Objectives: Working through this chapter of the study guide will enable you to: 1. Name and describe some of the most abundant minerals found in Earth's crust. 2. State the basic physical properties that can be used to identify mineral samples. 3. Distinguish the physical properties that are useful in identifying minerals. 4. Distinguish the chemical characteristics that are useful in identifying minerals. 5. Distinguish between rocks and minerals. 6. List and distinguish among the common silicate minerals. 7. Describe the chemical classification of minerals. 8. List and describe the characteristics of intrusive/ extrusive igneous rocks. including textures. 9. Explain how sedimentary rocks are classified. 10. List and describe the characteristics of foliated/ non-foliated metamorphic rocks, including textures and composition. 11. Explain how new sedimentary rocks can be formed from the remains of previous rocks. 12. Distinguish among igneous, sedimentary, and metamorphic rocks. 13. Compare the origins of the fine-grained and coarse-grained igneous rocks and give several examples of each type. 14. Describe several fragmental sedimentary rocks. 15. Describe several metamorphic rocks and give their origins. 16. Describe the processes by which sediments become rock. 17. Draw a diagram that shows the rock cycle. Lecture Outline: The composition and structure of the planet that we live on has long been of great interest to scientists and laymen alike. Much of the raw materials that we use to enhance our existence comes from the crust of Earth itself. Mineral formations are not only pretty to look at, as in gem quality stones for personal adornment, but also are the basis for many of the chemical and industrial products that we use in our daily lives. The finding and identification of these materials can be an interesting and rewarding experience, and many people today make a living doing just that. Although many of the ideas that are covered in this chapter are somewhat complex, the overall discussion of Earth's crust and its physical composition is quite straightforward and can be easily grasped. Understanding this material is an important stepping stone for the next chapter in the textbook, which deals with the overall structure of Earth and the way that movements in its crust and mantle can produce significant, and sometimes catastrophic, events. Composition of the Crust A. The outer part of the earth is called the crust. B. The two most abundant elements of the earth's crust are oxygen and silicon. C. Most crustal rocks are composed of silicon compounds. 1. Silica is silicon dioxide (SiO2). Silicates are compounds of silicon with oxygen and one or more metals. 2. Silicates are crystalline solids whose basic structural unit is the SiO44– tetrahedron. The wide variety of silicate minerals is due to many different ways the SiO44– tetrahedron can combine with metal ions. Minerals Minerals are naturally occurring, inorganic, crystalline materials that have a well- defined chemical composition. They can be either elements or compounds, and each has a distinctive set of physical properties. Only about two dozen common minerals make up the majority of Earth's crust; however, in excess of 2000 have been found in small quantities. Over 98% of the crust is made up of only eight elements. In order of decreasing abundance by mass, they are oxygen, silicon, aluminum, iron, calcium, magnesium, sodium, and potassium. See Figure 11.9 in Chapter 11 of the textbook for a graphical representation of this distribution. The term mineral is also used when referring to the elements in foods that are necessary, in small quantities, for the proper functioning of the human body. These are often discussed at the same time as other vital organic substances known collectively as vitamins, so it is quite common to be concerned, for example, about the vitamin and mineral content of your morning breakfast cereal. Some minerals fitting this classification are iron, sodium, iodine, manganese, magnesium, and copper. Consolidated mixtures of crystalline minerals are called rocks. Most rocks are composed primarily of oxygen and silicon, much of which is in the form of silicon dioxide, commonly called silica. Combinations of these elements in which the oxygen-silicon ratios are greater than 2:1 are known as silicates. For example, quartz is composed of pure silica (SiO2), whereas olivine is made up of the silicate tetrahedron (SiO4)4- in combination with several trace metals. The most abundant mineral group in Earth's crust is the feldspar family. The members of this family are composed of oxygen, silicon, and aluminum plus at least one additional metallic element. The two main sub-classes of the feldspar family are plagioclase feldspar, which contains calcium or sodium, and orthoclase feldspar, which contains potassium. Many non-silicate minerals are found in Earth's crust, among which are carbonates such as calcite, oxides such as hematite, and sulfides such as galena. There are also rare but important pure elements such as gold, silver, sulfur, copper, and diamond (carbon). Most of these minerals, however, appear as ores in which the important minerals make up only a small percentage. The discovery, mining, and refining of these ore deposits is the basis for a large portion of the valuable and useful minerals needed in our modern industrial society. When discussing the physical properties of minerals, we use terms like crystal form, hardness (as measured on the Mohs' hardness scale), cleavage, fracture, color, and streak. Well-defined tests and observations can be made of these properties to help identify mineral samples. Applying these procedures to samples obtained from Earth's upper crust is quite easy and can even be fun. Many people have small personal collections of rocks and minerals that they have acquired through inexpensive purchase or simply by picking them up from the ground and bringing them home. Minerals A. Minerals are naturally occurring, crystalline, inorganic solids having fairly specific chemical compositions. B. More than 2000 minerals are known, but most are rare. C. Some physical properties of minerals are color, hardness, crystal form, and cleavage (tendency to split along certain planes). D. Examples of six common minerals are: 1. Quartz (SiO2) crystals are often found in narrow deposits called veins. 2. Feldspars are silicate minerals having very similar properties and are the most abundant single constituent of rocks. Varieties include orthoclase (silicate of K and Al) and plagioclase (silicate of Na, Ca, and Al). 3. Mica varieties include white mica (silicate of H, K, and Al) and black mica (silicate of H, K, Al, Mg, and Fe). 4. Ferromagnesian minerals are silicates of Fe, Mg, and usually other metals such as K, Al, and Ca. 5. Clay minerals are silicates of Al, some with a little Mg, Fe, and K. 6. Calcite (CaCO3) is the chief mineral in limestone and marble. Mineral 1. Naturally occurring 2. Inorganic 3. Solid 4. Definite chemical composition 5. Orderly internal crystal structure What are some examples of some mineral names? 1. Feldspar is the most abundant mineral in the Earth's crust. There are several types of feldspar including: a. Orthoclase feldspar b. Microcline feldspar c. Plagioclase feldspar (has striations - tiny parallel hairline grooves) 2. Quartz is the second most abundant mineral in the Earth's crust 3. Other common rock-forming minerals include: a. Muscovite mica b. Biotite mica c. Hornblende (part of the amphibole group of minerals) d. Augite (part of the pyroxene group of minerals) e. Olivine f. Calcite is common in some sedimentary rocks Rock A rock is an aggregate of one or more minerals Polymorphs Two minerals with the same chemical composition, but a different crystal structure. Physical Properties of Minerals 1. Color not always diagnostic (feldspar, quartz, fluorite come in many colors) Feldspar can be green, pink white, gray, etc. 2. Luster metallic non-metallic glassy or vitreous, dull, pearly, resinous, waxy, adamantine, silky 3. Streak unglazed porcelain plate note color, odor if any Both of these samples are hematite; both have a reddish-brown streak 4. Hardness scale of 1 to 10 (Mohs Scale) 1. Talc 2. Gypsum ________ fingernail 3. Calcite ________ penny (copper) 4. Fluorite _________ nail 5. Apatite _________ glass 6. Orthoclase feldspar (K feldspar) 7. Quartz 8. Topaz 9. Corundum 10. Diamond 5. Cleavage Breakage along planes Related to crystal structure 1 direction (muscovite, biotite) Muscovite (left) Biotite (right) 2 directions at 90° (feldspar, pyroxene) Pyroxene 2 directions not at 90° (amphibole at 60° and 120°) 3 directions at 90° (cubic) (halite, galena) Halite 3 directions not at 90° (rhombohedral) (calcite, dolomite) Cleavage fragments of calcite 4 directions (octahedral) (fluorite) Cleavage fragments of fluorite 6. Fracture irregular breakage (no cleavage) breakage not along smooth planes Conchoidal fracture smooth curved fracture surfaces occurs in quartz, chert, obsidian, glass Rose quartz lacks cleavage; it has conchoidal fracture Conchoidal fracture in the igneous rock, obsidian 7. Crystal form Some minerals that may or may not have cleavage GROW (not break) into crystals with flat sides. Examples quartz pyrite Quartz crystals 8. Specific gravity (similar to density) Weight of a mineral divided by weight of an equal volume of water. Chemical classification of minerals 1. Native elements (metal) native gold (Au), native copper (Cu), native sulfur (S), native silver (Ag), graphite (C), diamond (C) 2. Sulfides (metal + S) pyrite (FeS2), galena (PbS), sphalerite (ZnS) 3. Sulfates (metal + SO4) gypsum (CaSO4 · 2H2O), anhydrite (CaSO4), barite (BaSO4) 4. Oxides (metal + O) water ice (H2O), hematite (Fe2O3), magnetite (Fe3O4), corundum (Al2O3) 5. Halides (metal + Cl or F halogens) halite (NaCl), fluorite (CaF2) 6. Carbonates (metal + CO3) calcite (CaCO3), dolomite (CaMg(CO3)2) 7. Other - borates, urananates 8. Silicates (metal + Si and O) quartz (SiO2), potassium feldspar (KAlSi3O8), Ca Plagioclase feldspar (CaAl2Si2O8), Na Plagioclase feldspar (NaAlSi3O8) Silicate Structures Based on silicate tetrahedron 4 oxygen atoms and 1 silicon atom 9. Single tetrahedra olivine 10. Single chains pyroxene 11. Double chains amphibole 12. Sheets muscovite biotite 13. Frameworks quartz feldspar potassium feldspars (orthoclase and microcline) plagioclase feldspars The four most common elements in the Earth's crust: Element Approx. Weight % Oxygen (O) 46.6 Silicon (Si) 27.7 Aluminum (Al) 8.1 Iron (Fe) 5.0 Rocks Most minerals are not found in a pure state either on or beneath the surface of Earth. Large quantities of these materials are combined into aggregates called rocks. Rocks are classified by the three basic ways in which they are formed. Aggregates that have cooled from molten magma, whether on the surface or deep in Earth's interior, are known as igneous rocks. Those formed from the fragments of old rocks that have been deposited after erosion by air, water, or other chemical or mechanical means are called sedimentary rocks. Finally, any rocks that have changed their structures due to heat and/or pressure after the time they were initially formed are referred to as metamorphic rocks. These three types of rock are closely interrelated, as can be seen by studying the rock cycle, which is depicted in the spotlight feature in Chapter 21 of the textbook. Volcanoes A. The processes of vulcanism (the movements of molten rock) and diastrophism or tectonism (the movements of the solid materials of the earth's crust) act in opposition to the processes that would level the earth's surface. B. A volcano is an opening in the earth's crust through which molten rock (called magma while underground, lava above ground) pours forth. C. A volcano usually has a depression, or a crater, at its summit. D. The two main factors that determine whether an eruption will be quiet or explosive are: 1. Viscosity (resistance to flow) of the magma 2. Amount of dissolved gases, such as water vapor (the most prominent), carbon dioxide, nitrogen, hydrogen, and various sulfur compounds in the magma E. Magmas rich in silica (the most viscous) and dissolved gases result in explosive eruptions, while magmas with modest gas and silica contents result in quiet eruptions. F. Lava hardens into one or another type of volcanic rock including: 1. Basalt (the most common) 2. Rhyolite (the most silica rich) 3. Pumice (light and porous) Most active volcanoes occur around the borders of the Pacific Ocean, on some of the Pacific Islands, in Iceland, and in East Africa. Origin of Igneous Rocks The word igneous means "fire-formed". Igneous rocks form by cooling and crystallizing from hot molten magma or lava. Magma - hot molten rock below the Earth's surface Lava - hot molten rock that erupts onto the Earth's surface through a volcano or crack (fissure) Igneous rocks that cool and crystallize beneath the Earth's surface are called intrusive igneous rocks. Another name for intrusive igneous rocks is plutonic igneous rocks (named for Pluto, Roman god of the underworld). Igneous rocks that cool and crystallize on the Earth's surface are called extrusive igneous rocks. Another name for extrusive igneous rocks is volcanic igneous rocks (named for Vulcan, Roman god of the fire and forge). Cooling Rates Cooling rates influence the texture of the igneous rock: Quick cooling = fine grains. Extrusive igneous rocks tend to be fine grained or glassy. Sometimes they are vesicular with tiny holes formed by the release of trapped gases. Other extrusive igneous rocks have a fragmental or pyroclastic texture composed of pieces of volcanic rock and ash welded together by heat. Lava cools more quickly because it is on the surface. Slow cooling = coarse grains. Intrusive rocks tend to be coarse grained with intergrown crystals ranging from several millimeters to several inches in diameter. Magma cools more slowly because it is deep within the Earth where temperatures are high. Igneous Rocks It is believed that Earth began as a molten sphere of material, and thus the first rocks were formed from the cooling of hot magma into solid rock. This means that igneous rocks can be considered the basis of all other types of rocks. Today, igneous rock forms either deep beneath Earth's surface or at Earth's surface as the result of volcanic activity. Molten rock called magma is often forced to the surface by volcanic action. Once it reaches the surface, molten rock is referred to as lava. Cooled lava retains this name even after it has solidified into igneous rock. Igneous rock makes up about 80% of Earth's crust. Magma that cools and solidifies as lava at or near the surface of Earth is called extrusive rock, and magma that solidifies deep within Earth's interior is referred to as intrusive rock. The outermost layer of Earth is a thin, rigid outer shell called the lithosphere, which is split up into giant surface plates. The lithosphere rides on top of a semimolten region known as the asthenosphere. The rigid surface plates are driven across the asthenosphere by the slow convective circulation of this easily deformable plastic material as heat works its way outward from Earth's central core region. The motion of these large lithospheric plates of solid rock across Earth's surface is explained by a theory called plate tectonics. As plate tectonics occurs, the plates may bump into each other at convergent boundaries, pull away from each other at divergent boundaries, or slip past each other at transform boundaries. It is at these boundaries that we find most volcanic activity, and it is also where the majority of earthquakes occur. The actual interaction of plates in quite complex, as will be seen in even more detail in Chapter 22, but the basic ideas needed in this chapter are that new rock can form in regions where plates are diverging, because of the upwelling of magma from the asthenosphere, and that one plate often is driven under another plate when they converge, producing a subduction zone in which the descending plate melts and its lighter, volatile material works its way back to the surface as volcanic gases and lava. The texture of igneous rock is mainly determined by the type and size of mineral grains that form as it cools. Different minerals crystallize out of magma at different temperatures as the molten material cools. The order in which the most common minerals crystallize is related to the magma's temperature, and the size of the crystals that form from the various minerals present is dependent on the rate of cooling. When magma reaches the surface, a volcano is formed and lava can flow across Earth's surface. The texture, or grain size, in igneous rock created from this lava also depends on the rate of cooling, with the smallest grain size occurring in the fastest-cooling materials. On the other hand, if magma never reaches the surface, it tends to cool at a much slower rate, and the crystals formed in these subterranean regions will be much larger in size. The color of igneous rock is determined primarily by the silica content of the rock. Rocks that are rich in silica often contain sodium and potassium. Granite and similar silica-rich rock is generally light in color and low in density. Rock that has lower silica content usually contains iron, magnesium, and calcium, which make it darker in color and also denser than silica-rich rock. Rocks, such as basalt, make up the material found in low-lying crustal regions such as ocean basins. Because of its lower density and high-silica content, granite is the most common rock found at higher elevations in volcanic islands or in continental mountain ranges. Igneous Rocks Characteristics A. Igneous rocks, such as granite, basalt, and obsidian (natural glass), are rocks that have cooled from a molten state. Fine-grained igneous rocks (examples: rhyolite, andesite, basalt) have cooled rapidly at or near the earth's surface. Coarse-grained ones (examples: granite, diorite, gabbro) have cooled slowly well below the earth's surface. Igneous Activity Igneous rock that has cooled slowly below Earth's surface is found in formations called plutons. Such igneous bodies can be either concordant, if they form parallel to the grain in the surrounding rock, or discordant if they cut across this grain. Examples of concordant formations are sills and laccoliths, whereas examples of discordant bodies are batholiths and dikes. Volcanoes appear where magma is squeezed all the way to Earth's surface. In these cases, steam and other gases are often expelled together, with molten rock in the form of lava. Solid material ranging in size from dust particles to boulders is also a common product of volcanic eruptions. Violent eruptions occur in areas where great pressure is built up by gases that are trapped because the emerging lava is thick and does not flow easily. If the lava is more fluid (has a lower viscosity), volatile gases can more easily escape and the eruptions are usually less violent. This results in lava rivers or fountains that can often be safely observed close at hand, such as the brilliant pyrotechnic displays that occur frequently in the Hawaiian Islands. The viscosity of lava depends on its temperature and on its silica content, with the lower temperature and silica-rich lava being the thickest and most viscous. Volcanic eruptions can occur from long fractures in Earth's surface in the form of fissure eruptions, or in a more localized manner from the top or sides of large volcanic mountains. Fissure eruptions happen in continental regions where extensive surrounding areas can be covered by flood basalts, a very low-viscosity form of lava that can form flows several hundred meters thick, or they can occur in ocean basins at diverging plate boundaries where even more extensive flows can produce layers of lava several thousand meters thick. Volcanic mountains can take on several forms. Shield volcanoes are low-profile mountains with gently sloping sides and extremely wide bases formed from the flow of non-viscous basaltic lava. Another common type is the stratovolcano, which forms from high-viscosity lava eruptions in which the violent activity produces composite layers of lava and tephra in a characteristic high, steepsided formation. Yet another type of volcano can be formed almost completely out of tephra in a low, steeply sloped structure usually only a few hundred meters high, called a cinder cone. The eruption of any specific volcano is, for the most part, quite unpredictable. New volcanoes can form suddenly, and old dormant ones may spring to life with little warning. However, in some areas of Earth's surface such activity is quite commonplace and can be expected to occur quite regularly. The most famous of these areas is the outer rim of the Pacific Ocean basin, which forms nearly a complete circle of currently active or recently active volcanoes. This volcanic region is commonly referred to as the Ring of Fire. Other more localized regions of continual volcanic activity are the famous hot spots, over one of which the Hawaiian Islands are still forming. Another very active region is the mid-oceanic trench on the floor of the Atlantic Ocean about halfway between the Americas and the mainlands of Europe and Africa, where seafloor spreading was first discovered and where it is still taking place today. Intrusive Rocks A. Plutons are intrusive bodies formed by the solidification of magma under the earth's surface. B. Because plutons cool slowly, the resulting intrusive igneous rocks tend to be coarse-grained. An example is granite. C. A dike is a wall of intrusive igneous rock that cuts across existing rock layers. D. A sill is a pluton formation that lies between and parallel to existing rock strata. E. A laccolith is a pluton formation that forms a mushroom-shaped intrusion that pushes up overlying rock strata. F. A batholith is a very large pluton that can cover hundreds of thousands of square km. Batholiths are always associated with mountain ranges, past or present. Composition of Igneous Rocks Igneous rocks can be placed into four groups based on their chemical compositions: 1. Granitic 1. Dominated by silicon and aluminum (SiAl) 2. Usually light in color 3. Characteristic of continental crust 4. Forms a stiff (viscous) lava or magma 5. Rock types include: 1. Granite Granite 2. Rhyolite Rhyolite 2. Andesitic 1. Intermediate in composition between sialic and mafic Diorite 3. Basaltic 1. Contains abundant ferromagnesian minerals (magnesium and iron silicates) 2. Usually dark in color (dark gray to black) 3. Characteristic of Earth's oceanic crust, Hawaiian volcanoes 4. Forms a runny (low viscosity) lava 5. Also found on the Moon, Mars, and Venus 6. Rock types include: 1. Basalt Basalt Classification of Igneous Rocks: Igneous rocks are classified or named on the basis of their texture and their composition. Igneous rocks cannot be classified by their process of formation, because the processes are interpreted from the rocks. Classification of rocks is always based on objective, observable, measurable data (such as grain size and the percentages of various minerals), and not on interpretations. The igneous rocks classification diagram below shows varying percentages of minerals in each of the four major categories of igneous rocks (sialic, intermediate, mafic and ultramafic). The table below shows the rock names for the various textures, combined with the mineral information. Texture Aphanitic Rhyolite Andesite Basalt -- Phaneritic Granite Diorite Diabase Gabbro Periodotite Pegmatitic Granite Pegmatite Diorite Pegmatite Gabbro Pegmatite -- Porphyritic Aphanitic Phaneritic Porphyritic Rhyolite Porphyritic Granite Porphyritic Andesite Porphyritic Diorite Porphyritic Basalt Porphyritic Gabbro Porphyritic Periodotite Pumice Pumice Vesicular -- Vesicular Texture Basalt & Scoria Glassy Obsidian -- -- -- Fragmental Tuff (ash) Volcanic Breccia Tuff (ash) Volcanic Breccia -- -- 0 - 15 20 - 40 50 - 60 95 - 100 COLOR INDEX (% Dark Minerals) Sedimentary Rocks Loose sediment is created by various forms of decomposition and erosion that will be discussed in detail in Chapter 23. The consolidation of this sediment forms sedimentary rock. This type of rock makes up only about 5% of Earth's entire crust, but it covers the surfaces of more than 75% of the continents and ocean basins. This means that sedimentary rock forms in relatively thin layers. Sedimentary deposits are also important because they contain abundant supplies of oil and coal, as well as metal deposits and other materials used primarily in the construction industry. Sedimentary rock is made up of detrital sediments (rock and mineral fragments), organic sediments, and chemical sediments. These materials are transported by streams and rivers and eventually deposited in layers at the bottom of lakes and oceans. The consolidation of these layers leads to the formation of sedimentary rock. The conditions under which sedimentary rock was formed can be determined by studying characteristics such as color, sorting, rounding, bedding, fossil content, ripples, and mud cracks. Tables 21.5 and 21.6 in the textbook show some of the most common classifications of sedimentary rock and describe their properties. Sedimentation A. The eroded material transported by the agents of erosion is eventually deposited to form sediments. B. The most widespread sediments collect near continental margins. C. There are four common sites of deposition: 1. Flood-deposited debris in stream gravel banks and sandbars 2. The flood plains of meandering rivers 3. Alluvial fans, which are deposits of sediments where streams emerge from steep mountain valleys and flow onto plains 4. Deltas, which are deposits of sediments where a stream enters a lake or sea D. Moraines are piles of debris that accumulate around the ends and along the sides of glaciers. This material is called till. E. The most important agents of deposition are ocean currents because of the large volume of sediment they carry and deposit. F. Examples of groundwater deposition include: 1. Deposition of minerals in veins within rock 2. Cave deposits including stalactites (hanging from cave ceilings) and stalagmites (rising from cave floors) 3. Deposits around hot springs and geysers G. Lithification is the process by which sediments become rock. H. Lithification includes: 1. Compaction, in which the sediment grains are squeezed together under the pressure of overlying deposits Concentration, in which the sediment grains are bound together by chemical changes brought about by circulating groundwater Sedimentary Rocks A. Sedimentary rocks have consolidated from materials derived from the disintegration or solution of other rocks and deposited by water, wind, or glaciers. B. Sedimentary rocks are divided into two categories: 1. Fragmental rocks 2. Chemical and biochemical precipitates C. Three types of fragmental sedimentary rocks are: 1. Conglomerate (cemented gravel) 2. Sandstone (cemented sand grains) 3. Shale (consolidated mud or silt) D. Examples of precipitated sedimentary rocks are: 1. Limestone (mostly the mineral calcite) Sediment and Sedimentary Rocks Sediment = loose particulate material (clay, sand, gravel, etc.). Most sediment is derived from the weathering (breakdown) of pre-existing rocks. Some sediment is formed through chemical and biochemical processes acting in the depositional basin, For example, broken shell fragments or lime mud formed from calcareous algae would be sediment formed through biochemical processes. Sediment becomes sedimentary rock through lithification, which involves: 1. Compaction due to pressure or weight of overlying sediments 2. Cementation by deposition of minerals in pore spaces from waters carrying ions in solution Types of sedimentary rocks Clastic (terrigenous or detrital) sedimentary rocks o Conglomerate or Breccia o Sandstone o Siltstone o Shale Non-clastic (chemical/biochemical) sedimentary rocks o Carbonate sedimentary rocks (limestones and dolostone) A. Clastic sedimentary rocks (also called terrigenous or detrital) Clastic sedimentary rocks are derived from the weathering of pre-existing rocks, whch have been transported to the depositional basin. They have a clastic (broken or fragmental) texture consisting of: 1. Clasts (larger pieces, such as sand or gravel) Clasts and matrix (labelled), and iron oxide cement (reddish brown color) Clastic sedimentary rocks are classified according to their texture (grain size, as well as shape for gravel-sized clasts): Gravel: Grain size greater than 2 mm o If rounded clasts = conglomerate o If angular clasts = breccia Conglomerate Breccia Sand: Grain size 1/16 to 2 mm o Sandstone o If dominated by quartz grains = quartz sandstone (also called quartz arenite) Quartz Sandstone o Silt: Grain size 1/256 to 1/16 mm (gritty) o Siltstone Siltstone Clay: Grain size less than 1/256 mm (smooth) o Shale (if fissile) o Claystone (if massive) Note: Mud is technically a mixture of silt and clay. It forms a rock called mudstone (or mudshale if fissile). Shale - fissile B. Non-clastic sedimentary rocks (also called chemical and biochemical sedimentary rocks) This group includes the carbonates (limestones and dolostone) 1. Carbonates - The carbonate sedimentary rocks are formed through both chemical and biochemical processes. They include the limestones (many types) and dolostones. 1. Two minerals are dominant in carbonate rocks: 1. Calcite (CaCO3) 2. Dolomite (CaMg(CO3)2) 3. Remember which of these fizzes readily, and which of these must be scratched or powdered! Metamorphic Rocks Metamorphism means "changed form". Metamorphic rocks are important because they remind us that rocks are changeable. The rock cycle describes how one type of rock can be converted into another. Metamorphic rocks are formed primarily by the action of heat and/or pressure on other types of rocks. In many parts of the U.S., metamorphic rocks are deeply buried beneath layers of sedimentary rocks. In Georgia, however, metamorphic rocks are exposed throughout much of the central and northeastern part of the state in the Piedmont and Blue Ridge physiographic provinces. Metamorphic processes are difficult to observe because they generally occur deep within the Earth, unlike the deposition of sediment or the eruption of volcanic igneous rocks. Much of what we know about metamorphic processes is the result of laboratory experiments and theoretical models that simulate conditions deep within the Earth. Metamorphic rocks, and the minerals found within them, are economically value. They include marble and soapstone for carving, slate for billiard tables and roofing, various types of building stone, crushed stone for road construction, asbestos for fire-retardant materials, talc for talcum powder, graphite for lubricants and pencil "leads", garnet for abrasives, and a number of types of semi-precious stones including garnet and tourmaline. Economically valuable mineral deposits can be found in metamorphic rocks, including gold, copper, iron, lead, and zinc. In addition,anthracite, a type of coal (used for heating or electricity generation), is a metamorphic rock. Metamorphic rocks have been changed under the influence of high temperature and/or extreme pressure deep beneath the Earth's surface. Sedimentary, igneous, and metamorphic rock can all undergo metamorphic changes, but sedimentary rock is especially susceptible to such processes. Metamorphic changes can be either mechanical or chemical, and they may involve only the materials present in the original rock, or, in some cases, may have additional minerals introduced into the formation by the metamorphic process itself. There are three basic types of metamorphism: (1) contact metamorphism, caused by thermal processes, (2) shear metamorphism, induced by highpressure conditions, and (3) regional metamorphism, involving a combination of both thermal and high-pressure influences over large areas deep underground. Once the changes have occurred, metamorphic rock is classified according to its texture, mineral composition, and ability to split along smooth planes. In advanced metamorphism this splitting is referred to as foliation. Marked foliation is most often associated with extensive regional metamorphic activity. Table 21.7 in the textbook shows the common types of metamorphic rock, together with some of the identifying characteristics associated with each of these types. Metamorphic Rocks A. Metamorphic rocks are formed from preexisting rocks that have been altered by heat and/or pressure. B. Many metamorphic rocks display foliation, which is an arrangement of flat or elongated mineral grains in parallel layers that give the rocks a banded or layered appearance. C. Examples of foliated metamorphic rocks are: 1. Slate (weakly metamorphosed shale) 2. Schist (severely metamorphosed shale or fine-grained igneous rock) 3. Gneiss (severely metamorphosed rocks, except pure limestone and pure quartz sandstone) D. Examples of nonfoliated or weakly foliated metamorphic rocks are: 1. Marble (metamorphosed limestone) 2. Quartzite (metamorphosed sandstone) Agents of Metamorphism Changes occur to rocks because of the action of: Heat Pressure Chemical fluids Rocks adjust to become more stable under new, higher temperatures and pressures. 1. Heat There are several sources of heat for metamorphism. 1. Geothermal gradient Temperature increases with depth at a rate of 20 - 30 degrees C per km in the crust. Ultimate source of the heat? Radioactive decay. Increase of temperature and pressure with depth causes Regional Metamorphism Heat may come from large bodies of molten rock rising under a wide geographic area. 2. Intrusions of hot magma can bake rocks as it intrudes them. Lava flows can also bake rocks on the ground surface. Lava or magma in contact with other rock causes Contact Metamorphism. 2. Pressure 3. Chemical Fluids In some metamorphic settings, new materials are introduced by the action of hydrothermal solutions (hot water with dissolved ions). Many metallic ore deposits form in this way. Hydrothermal (hot water) solutions associated with magma bodies can introduce new ions and remove existing ions (ion exchange) How do rocks change? Metamorphism causes changes in: 1. Texture 2. Mineralogy The original rock (usually sedimentary or igneous) which is changed by metamorphism is referred to as the parent rock. Texture The processes of compaction and recrystallization change the texture of rocks during metamorphism. 1. Compaction o The grains move closer together. o The rock becomes more dense. o Porosity is reduced. o Example: clay to shale to slate 2. Recrystallization Growth of new crystals. No changes in overall chemistry. New crystals grow from the minerals already present. A preferred orientation of minerals commonly develops under applied pressure. Platy or sheet-like minerals such as muscovite and biotite become oriented perpendicular to the direction of force. This preferred orientation is called foliation. Metamorphic Textures Foliation is a broad term referring to the alignment of sheet-like minerals (such as the micas, muscovite and biotite). Examples of foliated metamorphic rocks (see pictures and more detailed information below): 1. Slate 2. Phyllite 3. Schist 4. Gneiss Non-foliated or granular metamorphic rocks are those which are composed of equidimensional grains (such as quartz or calcite). The grains form a mosaic. Examples of non-foliated metamorphic rocks (see pictures and more detailed information below): 1. Quartzite derived from the parent rock, quartz sandstone 2. Marble derived from the parent rock, limestone. Note: Not all quartzites and marbles are pure. Some contain impurities that were originally mud interlayered with (or mixed with) the original quartz sand or lime mud. These clay impurities metamorphose to form layers of micas or other minerals, which may give marble a banded, gneissic appearance, or which may give a slight foliation to some quartzites. The foliated metamorphic rocks As shale is subjected to increasing grade of metamorphism (increasing temperatures and pressures), it undergoes successive changes in texture associated with an increase in the size of the mica grains. 1. Slate - very fine grained rock. Resembles shale. Has slaty cleavage which may be at an angle to the original bedding. Relict bedding may be seen on cleavage planes. Often dark gray in color. "Rings" when you strike it. (Unlike shale, which makes a dull sound. Temperature about 200 degrees C; Depth of burial about 10 km. Shale is the parent rock of slate. Slate 2. Schist - metamorphic rock containing abundant obvious micas, several millimeters across. Shale is the parent rock of schist. Muscovite Schist 3. Gneiss - (pronounced "nice") - a banded or striped rock with alternating layers of dark and light minerals. The dark layers commonly contain biotite, and the light layers commonly contain quartz and feldspar. Shale is the usual parent rock of gneiss. Granite is Shale is the parent rock of the parent rock of some gneisses. Gneiss The non-foliated metamorphic rocks 1. Marble - fizzes in acid because its dominant minerals is calcite (or dolomite). The parent rock is limestone. Marble 2. Quartzite - interlocking grains of quartz. Scratches glass. The rock fractures through the grains (rather than between the grains as it does in sandstone). The parent rock is quartz sandstone. Quartzite Mineral changes in metamorphic rocks 1. Recrystallization - rearrangement of crystal structure of existing minerals. Commonly many small crystals merge to form larger crystals, such as the clay in shale becoming micas in slate, phyllite, and schist. Also, fine-grained calcite in limestone recrystallizes to the coarse-grained calcite mosaic in marble. 2. Formation of new minerals - there are a number of metamorphic minerals which form during metamorphism and are found exclusively (or almost exclusively) in metamorphic rocks: o Garnet - dark red dodecahedrons (12 sides) o Talc - white or pale green and soft. o Graphite - metamorphosed carbon o Micas - muscovite (silvery), biotite (dark brown), phlogopite (light brown) Principle of Uniform Change A. Seventeenth-century theologian Bishop Ussher, using stories in the Bible, determined that earth was created at 9 o'clock in the morning of October 12, 4004 B.C. B. The German geologist Abraham Gottlob Werner believed that all rocks were sedimentary rocks and that the geologic history of the earth consisted of three sudden precipitations from an ancient ocean that were followed by the disappearance of the water. C. The French biologist Georges Cuvier regarded the earth's history as a succession of catastrophes. Cuvier based his ideas of earth's history on the study of fossils, the remains or traces of organisms preserved in rocks. D. The Scottish geologist James Hutton proposed that earth's history could be understood in terms of processes under way in the present-day world. E. The English geologist Charles Lyell (1797-1875) modified and expanded Hutton's ideas and proposed the principle of uniform change, which stated that geologic processes in the past were the same as those in the present. Rock Formations A. It is often possible to reconstruct past geologic events in terms of processes still at work reshaping the earth's surface. B. The science of geology is faced with two fundamental problems: 1. To arrange in order the events recorded in the rocks of a single outcrop or small region 2. To correlate events in various regions of the world to give a connected history of the earth C. Basic principles of historic geology include: 1. In a sequence of sedimentary rocks, the lowest bed is the oldest and the highest bed is the youngest. 2. Sedimentary beds were originally deposited in more or less horizontal layers. 3. Tectonic movement took place after the deposition of the youngest bed affected. 4. An igneous rock is younger than the youngest bed it intrudes. D. An unconformity is a buried surface of erosion and involves at least four geologic events: 1. The deposition of the oldest strata 2. Tectonic movement that raises and perhaps tilts the existing strata 3. Erosion of the elevated strata to produce an irregular surface 4. A new period of deposition that buries the eroded surface The Rock Cycle A. Rocks can change from one kind to another in a variety of ways. The rock cycle is a never-ending process. Here is another diagram of the rock cycle. How is it like the one above? How is it different? 1. Magma cools and crystallizes to form igneous rock. 2. Igneous rock undergoes weathering (or breakdown) to form sediment. The sediment is transported and deposited somewhere (such as at the beach or in a delta, or in the deep sea). 3. The deposited sediment undergoes lithification (the processes that turn it into a rock). These include cementation and compaction. 4. As the sedimentary rock is buried under more and more sediment, the heat and pressure of burial cause metamorphism to occur. This transforms the sedimentary rock into a metamorphic rock. 5. As the metamorphic rock is buried more deeply (or as it is squeezed by plate tectonic pressures), temperatures and pressures continue to rise. If the temperature becomes hot enough, the metamorphic rock undergoes melting. The molten rock is called magma. This completes the cycle. Now if you look at the processes going on in the middle of the diagram, note that: 1. Any rock type can undergo weathering (breakdown) to form sediment, followed by transportation and deposition of the sediment. Both metamorphic and sedimentary rocks can undergo weathering. 2. Igneous rocks can undergo metamorphism (as a result of heat and pressure) to form metamorphic rocks.