Chemistry 105 Laboratory Name:___________________ LABORATORY 7: CHEMICAL BONDING Atoms form bonds with other atoms in order to achieve stability, 8 valence electrons. This is the Octet rule. Types of bonds There are 2 ways that atoms form bonds. Sharing electrons : Covalent Bonds Transferring electrons : Ionic Bonds Covalent Bonds: When 2 nonmetal atoms share at least one pair of electrons a covalent bond is formed Lewis dot diagrams of diatomic elements: Hydrogen Chlorine Oxygen Nitrogen HONC Rule The most bonds between any two atoms is: Lewis dot diagrams of diatomic some simple compounds: 2/13/16 Water Carbon dioxide Ammonia Methane Carbon tetrachloride Carbon monoxide 1 Ionic Bonds: When a metal atom and a nonmetal atom react they form a bond in which the metal atom loses one or more electrons and the nonmetal atom gains one or more electrons. The bond is the attraction between a negative ion and a positive ion. Ion an atom or molecule that has a charge due to gaining or losing an electron Cations: Positively charged ions. Atoms that have lost an electron leaving more protons in the nucleus than there are electrons Anions: Negatively charged ions. Atoms that have gained an electron leaving more electrons than protons in the nucleus. Examples Sodium chloride Magnesium oxide Calcium bromide 2/13/16 2 Electronegativity: how attracted an atom is towards the electrons in a bond Patterns of electronegativity on the periodic table High electronegativity elements Low electronegativity elements Electronegativty and chemical bonds Ionic bonds Covalent bonds Polar covalent Nonpolar covalent Types of Molecules Just as bonds can be polar or nonpolar, molecules can also be polar or nonpolar. This polarity significantly affects the properties of the molecule. Nonpolar molecules: Polar Molecules: 2/13/16 3 Intermolecular bonds: Bonds can form between atoms of different molecules or molecules and ions. These bonds are not as strong as the covalent and ionic bonds. Ion-dipole attractions between an ion and the partially charged part of a polar molecule Hydrogen bond A hydrogen bond is a relatively strong dipole-dipole attractive force between a hydrogen atom and a pair of nonbonding electrons on a F,O, or N atom Dipole-dipole interactions are electrostatic attractions between polar molecules London Forces London forces are very weak electrostatic forces of attraction between molecules with "temporary" dipoles. 2/13/16 4 Purpose: To make models of organic compounds Procedure and Observations and Data: 1. Building molecules (This is to be done in groups of 2) Obtain the molecular modeling kits from the stockroom 1. Build the following molecules and draw the structure after you have built it. Show each model to your instructor before you take it apart. Do not take them apart until you have the initials. H2 N2 O2 Cl2 I2 H 2O NH3 Instructor’s Initials__________________________ 2/13/16 5 CH4 Name: CCl4 Name: C2H6 Name: C3H8 Name: C8H18 Name: CO2 C2H5OH Name: Instructor’s Initials__________________________ 2/13/16 6 Show 2wo different ways to make C4H10 Name: Name: Show two different ways to make C3H7Cl Name: Name: Show 3 different ways to make C5H12 Name: Name: Name: Instructor’s Initials__________________________ 2/13/16 7 Show how to make C2H4 Name: Make a benzene ring C6H6 Instructor’s Initials__________________________ Organize your atoms and bonds as they were when you checked them out. Return them to the stockroom. Questions and Answers: 1. How do you know if a compound is ionic or covalent by looking at the formula? ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ 2. What are the properties of ionic compounds? ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ 3. What are the properties of covalent compounds? ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ 2/13/16 8 Conclusions and Reflections 1. Did you learn better by building models of the molecules? Why? ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ 2. Write two questions you have about chemical bonding. ______________________________________________________________________________ ______________________________________________________________________________ 3. ______________________________________________________________________________ Are all covalent bonds equal? ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ 4. How can we measure if there are differences? ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ 2/13/16 9