Chemistry 11 Chemical Reactions Some background information on compounds: Can be divided into roughly 6 categories – 1. ________{formulas begin with “H”, except for organic acids which are often written with “H” at the end, eg CH3COOH = acetic acid} 2. ________ {formulas end in “OH” except for ammonia (NH3) and organic bases which are similar to ammonia and contain nitrogen} 3. Metal oxides {binary compounds of a metal and oxygen, eg. MgO} 4. Non-metal oxides (binary compounds of a non-metal and oxygen, eg CO2} 5. ________{ionic compounds that are neither acids, bases or oxides eg. KNO3} 6. Others? {most compounds belong here!!} You will be required to “predict” what products will be formed, given the reactants. Note about states: (s) = _______ (aq) = __________ (l) = _____________ (g) = ________ These should be included in chemical equations. Synthesis (Combination) This refers to the simple reaction of 2 elements (a redox process) to form a compound. Eg. S + O2 N2 Mg + Decomposition These are __________ reactions of synthesis. When a simple binary compound is decomposed the elements result. _______ energy is often used to decompose the compound. Eg. H2O Ag2O More complex decompositions (by heat) include compounds decomposing into “simpler” compounds. In general: 1. 2. 3. Eg. base metal oxide + water acid containing oxygen non-metal oxide + water salt containing oxygen metal oxide + non-metal oxide Ca(OH)2 H2CO3 Na2CO3 1 Chemistry 11 Single Replacement This is when an ________ reacts with a ____________. Such reactions are redox in nature (more on that in Chemistry 12). In that compound there must be an element similar in some way to the reacting element but _______________ The more reactive element _________ the less reactive element. The activity of a given element is most easily predicted with a standard reduction potential table (which is used in Chemistry 12), or by looking at the following ___________________: METALS NON-METALS Decreasing activity Lithium Potassium Calcium Sodium Magnesium Aluminum Zinc Chromium Iron Nickel Tin Lead Hydrogen Copper Silver Mercury Platinum Gold Eg. Fluorine Chlorine Bromine Iodine Cl2 + KBr Zn + CuSO4 Fe + NaNO3 2 Chemistry 11 Double Replacement These reactions begin with 2 ____________ _____________ and produce 2 ___________ ______________. They typically occur when reactants are acids, bases or salts. Often a formation of a __________ will result. Such reactions usually occur in _________ solutions. Prediction of products: simply ________ the __________ ions of the two reactants. Eg. AgNO3 + NaCl HCl + NaOH Refer to the solubility chart in your data booklet. NOTE that a ______ solubility compound means that it will be a ________ in water (insoluble in water). In contrast a _________ compound will exist as an _________ solution. If the compound is ________ in water, that means that it can separate (or _________) into its aqueous ions. If the compound is _________ in water, it __________ ___________ into its respective ions. A net-ionic equation shows the ________ reaction that is occurring. Certain ions are not included because they do not officially participate in the reaction (such ions are known as ______________ ______). Combustion Any reaction that involves _______________ as a reactant is considered to be a combustion. Substantial amounts of ____________ are usually produced as well. This includes burning of metals in air or oxygen, as well as combustion of ___________ (organic compounds made of hydrogen and carbon). In general, combustion of hydrocarbons produces __________ and _______. This is true whether or not oxygen is present in the hydrocarbon. Hydrocarbons that contain halogens, nitrogen or sulphur usually form oxides of the elements as well. These are difficult to predict, although in the case of nitrogen, NO or NO2 would always be a reasonable guess. Some examples are found below: Li + O2 C4H10 + O2 C5H12S + O2 3