Nuclear Reactions Many atoms contain nuclei that are unstable, and so easily decay An unstable nucleus is described as being radioactive, and will decay releasing radiation Each nucleus has its own rate of radioactive decay Symbols of particles common in nuclear equations Particle Electron Symbol Neutron Alpha particle 4 2 He Beta particle Summary of Alpha particles, Beta Particles and Gamma rays Property Nature of radiation Alpha 4 2 He nuclei Beta Beta particle Charge Mass +2 4 amu -1 0 Gamma High energy radiation 0 0 Isotopes The different isotopes of a given element have the same atomic number but different mass numbers since they have different numbers of neutrons. The chemical properties of the different isotopes of an element are identical, but they will often have great differences in nuclear stability Nuclear Notation Sometimes you will see C-14 written. This means the isotopes of carbon with mass number 14 (instead of normal 12). Types of Emissions and Balancing Nuclear Reactions When a nuclide decays, it will form a nuclide of lower energy, and the excess energy will be emitted as radiation. This radiation can be emitted in different forms, of which 3 are discussed below. When balancing a nuclear reaction, the total A and Z values must remain the same in reactants and products. A Z Re ac tan ts A Z Pr oducts 1 Alpha Particles and Decay Involves the loss of one alpha particle, which is identical to a Helium nucleus ( 24 He ) Example 1: Note that the total mass numbers and atomic numbers on both sides are equal Mass number total Atomic number total Left of the equation Right of the equation 234 = 4+ 230 92 = 2 + 90 Beta Particles and Decay Occurs when an isotope emits an electron, called a beta particle. Example 2: Mass number total Atomic number total Left of the equation Right of the equation 233 = 0+ 233 92 = -1 + 93 Gamma Rays and Emission Accompanies alpha or beta emission, Gamma rays have neither mass nor charge. Generally, gamma rays are not shown when writing nuclear reactions. Artificial Transmutation In artificial transmutation, the nucleus does not spontaneously decompose but decomposes when it is bombarded by a neutron or another nucleus. The process of artificial transmutation can be used to produce atoms with a specific number of protons and neutrons. The particles used must be travelling at very high speeds in order to overcome the electrostatic repulsion between them and the target nucleus. The high speed of the particles is produced in particle accelerators, which use magnetic and electric fields. You will not be able to predict the products of these reactions because different particles may be produced in artificial transmutation. You can predict the unknown if you are given enough information. Example 4: What element is produced during bombardment of a chlorine-35 nucleus with a neutron to produce a proton? 35 17 Unknown: Element X would be S-35 (mass # 35, atomic #16) Cl + 01 n Equation: A B X + 11 p 2 Fission Nuclear fission is a very important process for energy production today. Nuclear fission occurs when a nucleus absorbs a neutron and splits into two smaller nuclei and several neutrons. The produced neutrons collide with other fissionable nuclei, causing a chain reaction. Nuclear fission reactions release a tremendous amount of energy and are used in nuclear reactors today. Example 15: Identify the unknown in the equation for the nuclear fission of uranium235 (notice that in this equation there are three neutrons produced so the total mass of all of the neutrons produced will be 3) 235 92 A 1 U 01 n 87 35 Br B X 3 0 n Mass number 235 +1 = 87 + A + 3 Atomic number 92 +0 = 35 + B + 0 The unknown element is Lanthanum. 3