Chemistry I: Matter & Energy Review Define the following terms: 1. Energy - The capacity to do work or produce light 2. Kinetic energy – Energy of Motion 3. Potential energy – Stored energy of position 4. Exothermic – Release of heat 5. Endothermic – Absorption of heat 6. Conservation - The fact that mass and energy cannot be created or destroyed 7. Temperature – Average kinetic energy of the molecules 8. Hypothesis – An assertion subject to verification or proof as a premise from which a conclusion is drawn 9. Variable - A factor that could affect the results of an experiment 10. Theory - A well-tested explanation of observations 11. Law - statement or mathematical expression that reliably describes a behavior of the natural world 12. Conclusion - A proposed explanation of observations 13. Conservation of mass – The fact that matter cannot be destroyed in a chemical reaction 14. Precision – The closeness of a measurement to other measurements 15. Accuracy – The closeness of a measurement to the true value 16. Chemistry – The study of matter and changes that occur in matter 17. Chemical property – A characteristic of a substance that cannot be observed without chemically changing the identity of the substance 18. Physical property – A characteristic of a substance that can be observed without changing the identity of the substance 19. Chemical change – A change in which one or more new products with new properties is produced 20. Physical change – A change in which the same substance remains before and after the change 21. Solid – State of matter that has both a definite shape and volume 22. Liquid – State of matter that has a definite volume but no definite shape 23. Gas – State of matter with no definite shape or volume 24. Homogeneous – Uniform 25. Heterogeneous – Not uniform 26. Quantitative – A measurement that involves a number 27. Qualitative – A measurement that describes a characteristic of a substance that is not a number Short Answer: Describe the energy change involved when an egg cooks. Energy is absorbed by the raw egg. The absorbed energy is stored as chemical energy in the cooked egg. Explain the difference in an endothermic process and an exothermic process. An endothermic process absorbs energy, and an exothermic process releases energy Explain how energy is conserved when a piece of paper burns. The total energy contained in the bonds of the paper and oxygen equals the total energy contained in the bonds of the ashes and gases produced and the heat energy released Use pouring hot chocolate into a cold cup to explain the difference in heat and temperature. The hot chocolate has a higher average kinetic energy of its particles because it has a higher temperature. The energy that is transferred from the particles in the hot chocolate to the particles of the cup is heat Explain how to change from Kelvin to degrees Celsius. Kelvin units are the same size as degrees Celsius. The zero point on the Kelvin scale is 273 units below that on the Celsius scale, so to change from Kelvin to degrees Celsius, subtract 273 from the Kelvin temperature Why should a scientist record all observations, even those that appear insignificant? Many important discoveries are made through mistakes or by accident. If seemingly insignificant observations are not recorded, such discoveries cannot be reproduced What are the first steps scientists take to analyze the cause of a disease? Scientists must first observe the symptoms of the disease. Then they form a hypothesis and design an experiment with a control and variables to test their hypothesis about the probable cause of the disease Explain what is meant by a scientific method. A scientific method is a logical, systematic approach to problem solving. The exact steps followed might vary from problem to problem What is the purpose of a control in an experiment? Answers might include that controls eliminate error due to unforeseen variations in the system, serve as a comparison or baseline for other data, and increase confidence in collected data Explain why pictures of atoms and molecules are models. The pictures represent the atoms and molecules and are consistent with what we know about their behavior. They are not true representations because atoms and molecules are not hard, colored sphere Differentiate between a theory and a law. A theory is a broad generalization based on observations, data, and reasoning, that is used to explain a phenomenon. A law is a mathematical expression or statement that describes the behavior of some part of the natural world The mass of a 3.45-g piece of aluminum was measured several times. The measured masses were 2.67 g, 2.59 g, 2.60 g, and 2.64 g. Use these results to explain the difference between accuracy and precision. Because the masses were close to each other, they were precise. Because they were not close to the accepted value of the mass, they were not accurate The specific heat of iron is 0.449 J/(g K), and that of aluminum is 0.897 J/(g K). Explain how you know which metal will absorb and release more energy under the same temperature change. Assume samples of equal mass. Because the specific heat of aluminum is greater than that of iron, aluminum will absorb and release more energy Explain why the number 62.605 x 106 is not in correct scientific notation. What is the correct scientific notation for this number? The first part of the number should be a number between one and ten. The correct form is 6.2605 107 A 10.0 g sample of cadmium absorbed 43 J of energy as it was heated. The initial temperature was 285 K. What was the final temperature of the metal if the specific heat of cadmium is 0.232 J/(g K)? final temperature = initial temperature + T = 285 K + 14 K = 299 K The specific heat of tin is 0.228 J/(g K). A sample of tin absorbs 92 J as it is heated from 271 K to 295 K. What is the mass of the sample? The specific heat of carbon is 0.709 J/(g K). How much energy is absorbed if a 7.34 g sample is heated until its temperature increases by 12 K? q = T m cp= 12 K 7.34 g 0.709 J/(g K) = 62 J If a 12.6 g sample of a material is heated from 181 K to 199 K, 46 J of energy is absorbed. What is the specific heat of the material? When water boils, steam forms. When vinegar and baking soda combine, carbon dioxide gas is released. Which change is physical, and which is chemical? How do you know? In both changes, a gas is produced. However, water boiling is a physical change because no new products are produced; steam is still water. In the chemical change, a new product–carbon dioxide–is formed State which one of the following observations is quantitative and explain why it is. a. The liquid turns blue litmus paper red. b. The liquid boils at 100°C. c. The liquid tastes bitter. d. The liquid is cloudy. Answer b is quantitative because it involves a measured quantity. The other choices involve properties that are not quantitatively measured Explain the difference between a pure substance and a homogeneous mixture. Use an example in your explanation A homogeneous mixture can be separated by physical means, whereas a pure substance cannot. For example, salt can be removed from a salt-water mixture by evaporating the water, but to separate water into hydrogen and oxygen requires chemical means Name three different ways that mixtures can be separated. Any logical physical means of separation can be accepted. Answers might include filtration, distillation, decanting, sorting, evaporation, or use of a sieve