ISOPROPANOL Page 1 of 4 Date of Issue: 25/06/03 24 HOUR EMERGENCY RESPONSE - CHEMCALL - 0800 243 622 NATIONAL POISON CENTRE 0800 764 766 TMK Packers Ltd PO Box 258031 Greenmount Auckland NZ Phone: 09 2733753 For all orders and inquiries Phone: 09 2733753 MATERIAL SAFETY DATA SHEET IDENTIFICATION PRODUCT NAME: Isopropanol Other names: Manufacturers Code: Use: Pack sizes: Isopropyl alcohol BISOPR Industrial solvent 20L, 200L, bulk U.N. Number Dangerous Goods Class Subsidiary Risk Packing Group Hazchem Code Poisons Schedule 1219 3 None II 2[Y]E S4 Physical Description/Properties (Typical Values) Appearance: Clear, colourless, mobile liquid with sweet odour Boiling Point/Range (ºC): 82.4 Vapour Pressure (mmHg @20ºC): 33 Specific Gravity (g/ml @20ºC): 0.786 Flash Point (ºC): 17 Flammability Limits(%): (LEL) 2.0 – (UEL) 12.0 Solubility in Water: Completely miscible Other Properties Percent Volatiles: 100% Ingredients Chemical Name: CAS Number: Proportion: Isopropanol 67-63-0 100% HEALTH HAZARD INFORMATION Health Effects Acute: Swallowed: Isopropanol is not classified under the poisons schedule, however the product may cause discomfort on swallowing. It is suggested that the product is not used in any other manner than the intended use, as listed in this Material Safety Data Sheet. Eye: Liquid and vapour may cause moderate eye irritation. 1 ISOPROPANOL Page 2 of 4 Date of Issue: 25/06/03 Skin: Contact may cause mild irritation. Prolonged or repeated exposure may cause defatting and drying of the skin resulting in irritant contact dermatitis. Inhaled: Vapour concentrations are irritating to nose and throat resulting in possible headaches, dizziness, lack of coordination, nausea, and possibly loss of consciousness. Chronic: Repeated or prolonged contact may cause irritant contact dermatitis. First Aid Swallowed: For advice, contact the National Poisons Centre (0800 764 766), or a doctor immediately. If swallowed, do not induce vomiting. Give a glass of water. Begin artificial respiration if the victim is not breathing. Use mouth to nose rather than mouth to mouth. Obtain medical attention. Skin: If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. For advice, contact the National Poisons Centre (0800 764 766) or a doctor immediately. Eye: Hold eyelids apart and flush the eye continuously with running water. Continue flushing until advised to stop by the National Poisons Centre, or for at least 15 minutes. Inhaled: Move the victim to fresh air immediately. Begin artificial respiration if breathing has stopped. First Aid Facilities: Provide eye baths and safety showers close to areas where splashing may occur. Advice to Doctor Treat symptomatically. PRECAUTIONS FOR USE Exposure Standards: The time-weighted average (TWA) for this product is 400ppm, where TWA indicates the concentration of exposure over an eight-hour day, for a five-day working week. The short-term exposure limit (STEL) is 500ppm, where the STEL should not be exceeded in an eight-hour working day. Engineering Controls: Keep away from sources of ignition. Take precautionary measures against static discharges. Provide sufficient ventilation to control exposure levels below the exposure standards. Use local exhaust ventilation at sources of air contamination such as open process equipment. Dangerous concentrations may exist in areas with poor ventilation such as confined spaces. ISOPROPANOL Page 3 of 4 Date of Issue: 25/06/03 Personal Protection: Wear chemical goggles or face shield. Wear chemical resistant gloves. Respiratory protection should be used if there is a risk of exposure to high vapour concentrations. Respirators should comply with AS1716 or an equivalent approved by a state/territory authority. Wear protective clothing as necessary to avoid skin contact. Flammability: Isopropanol is a highly flammable liquid. Vapour may form explosive mixtures with air. Avoid heat and all ignition sources. Use only in well ventilated areas. Flameproof equipment is necessary in any area where product is being used. Product transfer and storage equipment must be earthed. Prevent build-up of flammable vapours. Consult AS1940 for further information on safe storage and handling of flammable liquids. Handle in accordance with state or territory regulations for flammable liquids. SAFE HANDLING INFORMATION Storage and Transport Store in cool well ventilated area away from heat and ignition sources. Containers should always be kept closed in storage and properly labelled. Avoid contact with oxidising agents and mineral acids. Many plastics may be unsuitable as storage and handling materials store only in original or approved containers. This product is classified under the Hazardous Substances and New Organisms Act. Spills and Disposal For major spills, dam and recover. Extinguish all ignition sources. Prevent entry into drainage systems, sewers and waterways. Collect with inert absorbent material such as sand or earth. Ensure waste disposal conforms to local waste disposal regulations. Empty containers retain vapour and product residue and may, therefore, present explosive and, or irritant vapour hazards. Drain containers and allow to dry with ventilation to remove liquid and vapour. Observe all safeguards on label and in this MSDS until container is cleaned, reconditioned or destroyed. Fire/Explosion Hazard Highly flammable liquid. Vapours may form explosive mixtures with air. Use water sprays to cool fire exposed surfaces and any adjacent storage vessels. Shut of source of product if safe to do so. Remove sources of reignition. Use water fog to extinguish, or in the absence of water fog, a fine spray may be used. Wear a breathing apparatus when attending fire hazard. OTHER INFORMATION Chronic toxicology: Persons with pre-existing liver impairment, skin and respiratory disorders may be at an increased risk from exposure. Concurrent absorption of this product in combination with ethanol and some drugs may cause adverse health effects. ENVIRONMENTAL INFORMATION As this product is regarded as harmful to the environment, it is recommended that extreme caution be taken to avoid discharge to waterways, grasslands, and areas with local fauna and flora. While it is not established how this product affects biological organisms, it is recommended that this product be used only in accordance with this MSDS and the container is disposed in accordance with local regulations. ISOPROPANOL Page 4 of 4 Date of Issue: 25/06/03 CONTACT POINT ASCC (NZ) Pty Ltd PO Box 8340 Symonds Street Auckland NZ Emergency Contact: CHEMCALL: 0800 243 622 For all order and inquiries: 0800 754 767 The information sourced for the preparation of this document was correct and complete at the time of writing to the best of the writer’s knowledge. The document represents the commitment to the company’s responsibilities surrounding the supply of this product, undertaken in good faith. This document should be taken as a safety guide for the product and its recommended uses but is in no way an absolute authority. Please consult the relevant legislation and regulations governing the use and storage of this type of product. For further information, please contact ASCC (NZ) Pty Ltd.