SPECIALIST FLUIDS 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION, REVISION NUMBER AND DATE Product Name : LCP MEK MIP BLACK INK Product Code : D/MIP/***/** Revision No : D Date : 10/01 2. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS (nl - not listed in CHIP) Chemical Name Methyl Ethyl Ketone Isopropyl Alcohol Solvent based Dye % 35 – 55 35 – 55 < 20 CAS Number EEC No Hazard Symbol Risk Phrases 78-93-3 67-63-0 - 201-159-0 200-661-7 - Flame, St Andrews Cross Flame & St Andrews Cross St Andrews Cross R11, 36, 66, 67 R11, 36, 67 R10, 41 R10 = Flammable; R11 = Highly Flammable; R36 = Irritating to eyes; R41 = Risk of serious damage to the eyes; R66 = Repeated exposure may cause skin dryness or cracking; R67 = vapours may cause drowsiness and dizziness. The remaining ingredients, do not present a health hazard within the meaning of the EC/ CHIP2 regulations. 3. HAZARDOUS IDENTIFICATION Classification (CHIP) : Highly flammable and Irritant Main Health Hazards : Not expected to present any hazards to health under normal conditions of anticipated use. 4. FIRST AID Inhalation : Move casualty to fresh air immediately. If there is respiratory distress, give oxygen and seek medical attention. Skin Contact : Wash affected area with soap and water Eye Contact : Rinse immediately with copious amounts of water. If redness or soreness persists, seek medical advice. Ingestion : DO NOT induce vomiting. Encourage the casualty to drink water to dilute stomach. Avoid alcoholic drinks as this will enhance toxic effects. Seek medical advice. 5. FIRE FIGHTING MEASURES Flammability : Highly Flammable Combustion products : Combustion vapours may be toxic. Hazardous polymerisation will not occur. Extinguishing media : Use dry powder, especially near electrical equipment. Carbon dioxide or alcohol resistant foams or water spray may also be used. water spray may be used to keep containers cool near fire. Do not use : Water Jet. 6. ACCIDENTAL RELEASE MEASURE Do not allow to enter drains. Shut off all sources of ignition and wear protective clothing. Mop or soak up small spills onto paper. Absorb large spills with inert material such as sand and remove to a safe place for disposal. Flush contaminated area with plenty of water. Dispose of in accordance with Local Authority Regulations. 7. HANDLING AND STORAGE Handling : Usual precautionary measures when handling chemicals are to be taken. Avoid contact with skin and eyes and avoid inhaling vapour. Open and handle bottle with care. Take measures against static discharge. Fire Prevention : Avoid heat and all sources of ignition. Storage : To be stored in a flameproof cabinet away form all sources of ignition. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Respiratory protection : Keep work area well ventilated. Eye and Skin protection : Wear safety glasses and gloves if splashing is likely. File : MSDS 375 Page 1 of 2 SPECIALIST FLUIDS 8. EXPOSURE CONTROLS / PERSONAL PROTECTION (Continued) OCCUPATIONAL EXPOSURE LIMITS : Substance listed in EH40/-- Long term (8 Hrs) ppm mg/m³ Short term (10 min) ppm mg/m³ Methyl Ethyl Ketone Iso Propyl Alcohol 200 400 300 500 9. PHYSICAL AND CHEMICAL PROPERTIES 600 999 899 1250 (n.d.a = No data available) Form : Colour liquid. Flashpoint : ~ 1.0°C Vapour Pressure : ~52 mm Hg @ 20°C Solubility in Water : Slightly soluble in water Autoignition Point : 427°C pH : Not applicable Boiling Point : ~ 83°C Melting Point : ~ -84°C Vapour Density : ~ 2.1 Density : ~ 0.85 gm/cm³ Explosive Limits: Lower : 1.9 % Upper : 12 % 10. STABILITY AND REACTIVITY Chemical reactivity : None known. Decomposition products : Combustion vapours may be toxic. Hazardous polymerisation will not occur. May form oxides of carbon in a fire. Materials / conditions to avoid : Avoid all sources of heat and ignition. 11. TOXICOLOGICAL INFORMATION Methyl Ethyl Ketone: LD50 : Acute / oral / rat: 3400mg/kg LD50 : Acute / dermal / rabbit: 13.000mg/kg Frequent or prolonged skin contact may cause dermatitis 12. ECOLOGICAL INFORMATION Readily biodegradable; No evidence of Bio-accumulation or tainting of seafood Methyl Ethyl Ketone: Non hazardous to living resources – LC50/96hr >1000mg/l Iso Propyl Alcohol: EC50/24h/Daphnia = > 1000mg/l; LC50/96h/Fathead minnow = 9600mg/l 13. DISPOSAL CONSIDERATIONS Consult Local Authority for regulations regarding waste disposal 14. TRANSPORT REGULATIONS Proper shipping name : Printing Ink Flammable UN Number : UN1210 IMDG code : Page 3272-1 ICAO/IATA class : 3 Marine Pollutant : Packing group : II IMDG class : 3.2 RID/ADR : ADR Classification Code : F1 Hazard warning sign : Highly flammable 15. REGULATORY INFORMATION CHIP labelling - Symbol : Flame & St Andrew's Cross Hazard : Highly Flammable Contains : Methyl Ethyl Ketone & Irritant Other suggested labelling : Risk Phrases : R11, 36, 41, 66, 67 Safety phrases : S16, 23, 25, 33 R11 = Highly Flammable; R36 = Irritating to eyes; R41 = Risk of serious damage to the eyes; R66 = Repeated exposure may cause skin dryness or cracking; R67 = vapours may cause drowsiness and dizziness S16 = Keep away form sources of ignition- no smoking; S23 = Do not breath vapour; S25 = Avoid contact with eyes; S33 = Take precautionary measures against static discharge 16. OTHER INFORMATION This safety data sheet has been updated to comply with CHIP regulations. The information is based solely on the data provided by the suppliers of the materials used and/or recognised technical sources, not on the mixture itself and is believed to be correct as of this date. No warranty is expressed or implied regarding the accuracy of the data. Elink sa/nv File : MSDS 375 Rue des Mayeurs 25 a 4280 HANNUT Page 2 of 2