Certificate in Chemistry (iGCSE) Scheme of Work Year 9 Feb 2012 The Reactivity Series and Extraction of Metals This work is a review of work done in Yr 8 allowing students to plan practical work. Lesson Lesson 1 The Reactivity Series Learning Outcomes Activities Assessment Safety Other emphasis understand that metals can be arranged in a reactivity series based on the reactions of the metals and their compounds: potassium, sodium, lithium, calcium, magnesium, aluminium, zinc, iron, copper, silver and gold Starter - ask pupils to work in pairs and put a set of given metals into a reactivity series. Review – use Reactivity Series in e science. How has this order been worked out? Which reactions can we use to test it? Focus on Metal + Water Metal + Acid Displacement reactions in solution and with metal oxides. Write general equations for these reactions. Activity – consider which reactions could be used to test which parts of the Reactivity Series. Use their prior knowledge for this. Consider things such as copper water pipes, Thermit reaction etc. Plan a series of reactions suitable to test the series. Try to let students have as much ownership as possible but also advise them which reactions will need to be demonstrated by a teacher. Students complete their plan for homework. Certificate in Chemistry (iGCSE) Scheme of Work Year 9 The Reactivity Series and Extraction of Metals Lesson Learning Outcomes Activities Starter – review ideas from last lesson about which metals can be reacted with water. Lesson 2 Reactions of Metals with water describe how reactions with water and dilute acids can be used to deduce the following order of reactivity: potassium, sodium, lithium, calcium, magnesium, zinc, iron and copper Demo – Li, Na and K with cold water Feb 2012 Assessment Safety Homework – Write balanced equations for all the reactions they have seen in this lesson. Grp 1 metals with water, use pea size amounts of metal and safety screen. Ca with water will be very exothermic, warn students not to burn themselves . Students write full and clear observations Students set up Mg in water and leave with a bung until next lesson. Students carry out Ca in water and test for hydrogen. Demo Mg with steam, consider the reactivity of zinc in the light of this – very slow in cold water but will react with steam to produce ZnO and H2 Plenary – place these metals in a reactivity Series based on these reactions. Predict the reactivity of Fe and Cu from their prior knowledge ( common sense!) Other emphasis Certificate in Chemistry (iGCSE) Scheme of Work Year 9 Feb 2012 The Reactivity Series and Extraction of Metals Lesson Lesson 3 Learning Outcomes Reactions Of Metals Acids describe how reactions with water and dilute acids can be used to deduce the following order of reactivity: potassium, sodium, lithium, calcium, magnesium, zinc, iron and copper Activities Assessment Starter – check on reaction of Write balanced Mg and water. Test for any equations hydrogen produced. Review Reactivity series as a result of this reaction. Metals with Acid Student react Ca, Mg, Zn and Cu in 1.0 moldm-3 HCl. Test for hydrogen NB Zn must be started as early as possible in the lesson and left with a bung in to stand any chance of producing H2. It may be prudent to have one set up earlier to demo if students have no reaction. Write word equations for the reactions seen Plenary - Review reactivity Series after these experiments. Risk Assessment Other emphasis Take care to control Ca very carefully. Teacher must keep Ca container at front and distribute one granule per student, directly into their test tube of acid. Certificate in Chemistry (iGCSE) Scheme of Work Year 9 Feb 2012 The Reactivity Series and Extraction of Metals Lesson Learning Outcomes Deduce the position of a metal within the Displacement reactivity series using displacement reactions Reactions of between metals and their oxides, and Metals between metals and their salts in aqueous solutions Lesson 4 Activities Assessment Risk Assessment Other emphasis Starter – Student predict the results of reactions between Cu/AgNO3 and Hg/AgNO3. H/W question sheet. Demonstrate these reactions to pupils and write word equations. Pupil practical – Displacement reactions, Mg, Zn, Fe, and Cu with copper sulfate, Zinc sulfate and magnesium sulfate to be carried out in test tubes with pieces of metal foil or ribbon. Pupils record results. Write word and balanced equations Plenary – review Certificate in Chemistry (iGCSE) Scheme of Work Year 9 Feb 2012 The Reactivity Series and Extraction of Metals Lesson Lesson 5 Learning Outcomes Metals And Metals oxides Deduce the position of a metal within the reactivity series using displacement reactions between metals and their oxides, and between metals and their salts in aqueous solutions understand oxidation and reduction as the addition and removal of oxygen respectively understand the terms redox, oxidising agent, reducing agent Activities Assessment Safety Starter – Pupils carry out RSC Expt 31, see work sheet. Students write word and balanced equations for the reactions that occur Introduce Redox ideas and apply them to these reactions Define the terms in terms of loss and gain of oxygen. Demo Thermite reaction, get pupils to predict results and identify oxidising and reducing agents. Plenary N/a Other emphasis V interactive periodic table A Playing the elements song. Certificate in Chemistry (iGCSE) Scheme of Work Year 9 Feb 2012 The Reactivity Series and Extraction of Metals Lesson Lesson 6 Review of reactivity and extraction Learning Outcomes understand that metals can be arranged in a reactivity series based on the reactions of the metals and their compounds: potassium, sodium, lithium, calcium, magnesium, aluminium, zinc, iron, copper, silver and gold explain how the methods of extraction of the metals in this section are related to their positions in the reactivity series. Activities Assessment Risk Assessment Other emphasis Starter – Review of Reactivity work Students produce a table for reactivity of all four reactions as above. Extraction of Metals Consider reactivity related to extraction of metals. Show position of carbon in the reactivity series. Construct a timeline showing how discovery of the metal relates to reactivity. Plenary – predict the results of reactions based on the reactivity series. Certificate in Chemistry (iGCSE) Scheme of Work Year 9 Feb 2012 The Reactivity Series and Extraction of Metals Lesson Learning Outcomes Lesson 7 Extracting metals explain how the methods of extraction of the metals in this section are related to their positions in the reactivity series Activities Assessment Safety Other emphasis Starter – see teacher notes CuO Practical - extracting metal from metal oxides – worksheet available PbO in fume cupboard Review word and balanced equations Acid is irritant Care with bunsens Plenary DART activity , see power point H/w sheet on extraction of metals Tech notes Pg 39 teachers guide Certificate in Chemistry (iGCSE) Scheme of Work Year 9 Feb 2012 The Reactivity Series and Extraction of Metals Lesson Lesson 8 Extracting Iron Learning Outcomes Activities describe and explain the main reactions involved in the extraction of iron from iron ore (haematite), using coke, limestone and air in a blast furnace The Blast Furnace Assessment Starter – Redox activity Pg 40 teachers guide Iron oxide + carbon monoxide = Iron + carbon dioxide Which is oxidised and which is reduced? MAIN Review Oxidation and reduction, use iron oxide + carbon reaction from earlier practical as redox example. RSC video on blast furnace Pupils copy blast furnace diagram neatly with labels from book p. 154. Include notes on blast furnace, e.g. three raw materials needed, production of slag etc. – See also power point in GCSE folder Blast furnace equations Go through equations and recap balancing. Get pupils to balance the equations Plenary: Pupils balance equation and identify REDOX: Copper oxide + carbon → Copper + carbon dioxide Make a flow chart of the processes in a blast furnace EXTENSION Introduce the Shelton website Learn the chemical reactions in the Blast Furnace Safety Other emphasis Certificate in Chemistry (iGCSE) Scheme of Work Year 9 Feb 2012 The Reactivity Series and Extraction of Metals Lesson Lesson 9 Properties of iron and steels Learning Objectives The properties of pig iron and how this limits its usefulness. That iron can be alloyed to make it more useful. understand that a metal can be described as a giant structure of positive ions surrounded by a sea of delocalised electrons Most students should be able to: • List the properties of iron produced from the blast furnace. • Explain why steels are produced. Some students should also be able to: • Explain why alloying changes the properties of a pure metal in terms of its structure. • Give examples of different types of steels, their chemical content and how their differ.properties Activities Starter - get pupils to list as many properties of iron as they can and link them to uses. The Structure of metals – explain and draw a diagram - positive metal ions with a sea of delocalised electrons. E science animation How do the structures of steels affect their hardness? – W/S Notes on alloys, table on properties of alloys Plenary – true/false activity, red and green cards – see teachers notes From 9E Properties of Metals / Non metals Assessment Uses of Steels Homework sheet Risk Assessment Other emphasis Certificate in Chemistry (iGCSE) Scheme of Work Year 9 Feb 2012 The Reactivity Series and Extraction of Metals Lesson Lesson 10 Rusting Learning Outcomes Activities Assessment Risk Assessment Starter – Complete worksheet Revise for test next lesson describe the conditions Demonstrate - test tubes under which iron rusts with reactions of iron with air describe how the rusting of iron may be prevented by grease, oil, paint, plastic and galvanising understand the sacrificial protection of iron in terms of the reactivity series. and water and iron wool with air etc. Discuss what conditions are needed for rusting. Pupils complete worksheet. Methods of preventing rusting – in small groups students find ways to prevent rusting and how they work. Each group reports back to whole class. Introduce sacrificial protection, showing test tube with iron and zinc. Make notes on rusting and protection from rusting Plenary - Other emphasis Certificate in Chemistry (iGCSE) Scheme of Work Year 9 Feb 2012 The Reactivity Series and Extraction of Metals Lesson Learning Outcomes Activities Assessment Lesson 11 Test Risk Assessment Other emphasis