Honors Chemistry Name ___________________________________ Chapter 16: Acids and Bases Worksheet I Date _____/_____/_____ Period _____ 1. Name the following binary acids: a. HCl hydrochloric acid b. HF hydrofluoric acid c. H2S hydrosulfuric acid d. HCN hydrocyanic acid 2. Name the following oxyacids: a. H2SO4 sulfuric acid b. H3PO4 phosphoric acid c. HC2H3O2 acetic acid d. HNO3 nitric acid e. H2SO3 sulfurous acid f. HNO2 nitrous acid g. HClO4 perchloric acid h. HClO hypochlorous acid 3. Write formulas for the following acids: a. Perbromic acid HBrO4 b. Chlorous acid HClO2 c. Phosphoric acid H3PO4 d. Hypochlorous acid HClO 4. What is the difference between monoprotic, diprotic, and triprotic acids and give 2 examples of each. Monoprotic acids are acids with 1 H+1 or 1 H3O+1 ion/molecule. (HCl, HF) Diprotic acids are acids with 2 H+1 or 2 H3O+1 ions/molecule. (H2SO4, H2S, H2CO3) Triprotic acids are acids with 3 H+1 or 3 H3O+1 ions/molecule. (H3PO4, H3AsO4) 5. Write the equation showing the 2-step ionization of sulfuric acid in dilute aqueous solution. Step 1) H2SO4 + H2O Step 2) HSO4-1 + Net eq) H3O+1 + HSO4-1 H2O H3O+1 + SO4-2 H2SO4 + 2 H2O 2 H3O+1 + SO4-2 6. Explain why HCl(aq) which is monoprotic is a stronger acid than H3PO4(aq), which is triprotic. HCl(aq) ionizes nearly 100% while H3PO4 has a low % ionization, meaning that there are more hydronium ions in solution with the solution of HCl than with the phosphoric acid solution. 7. Write the formula equation, total ionic equation, and net ionic equation for the reaction between Ca(OH)2(s) and HCl(aq). Ca(OH)2(s) + 2 HCl(aq) CaCl2(aq) + 2 H2O() Ca(OH)2(s) + 2 H+1(aq) + 2 Cl-1(aq) Ca+2(aq) + 2 Cl-1(aq) + 2 H2O() H+1(aq) + (OH)-1(aq) H2O() 8. Name the following bases: a. NaOH Sodium hydroxide b. Ca(OH)2 Calcium hydroxide c. Li(OH) Lithium hydroxide d. Al(OH)3 Aluminum hydroxide e. Mg(OH)2 Magnesium hydroxide 9. Explain why Mg(OH)2 is weaker than NaOH, even though it contains more hydroxide ions per molecule. If saturated solutions of both compounds were made, the sodium hydroxide solution will end up with a lot more moles of hydroxide ions because it “completely” dissociates. Even though magnesium hydroxide has more hydroxide ions in the ionic form, it does not completely dissociate when dissolved in water and therefore does not produce as many moles of hydroxide ions in solution as sodium hydroxide. 10. Dilute HCl(aq) and KOH(aq) are mixed in chemically equivalent quantities. Write the following: a. Formula equation for the reaction: HCl(aq) + KOH(aq) H2O() + KCl(aq) b. overall ionic equation: H+1(aq) + Cl-1(aq) + K+1 (aq) + (OH) -1(aq) H2O() + K+1(aq) + Cl-1(aq) c. net ionic equation: H+1(aq) + (OH) -1(aq) H2O() 11. What is a conjugate base? The species that remains after a Bronsted-Lowry acid has given up a proton. 12. What is a conjugate acid? The species that is formed after the Bronsted-Lowry base gains a proton. 13. Determine the conjugate acid for each: CA H2O H3O+1 HCO3-1 H2CO3 -1 OH H2O -1 H2PO4 H3PO4 -1 ClO4 HClO4 -1 SH H2S HSO4-1 H2SO4 F-1 SO4-2 PO4-3 Cl-1 CH3COO-1 CN-1 NH3 14. Determine the conjugate base for each: CB H2O HCO3-1 OH-1 H3PO4 HBrO2 H2S HSO4-1 OH-1 CO3-2 O-2 H2PO4-1 BrO2-1 HS-1 SO4-2 CA HF HSO4-1 HPO4-2 HCl CH3COOH HCN NH4+1 CB HF HSO4-1 HPO4-2 HCl CH3COOH HOCN NH3 F-1 SO4-2 PO4-3 Cl-1 CH3COO-1 OCN-1 NH2-1 Use the table below to identify the proton donor (Bronsted-Lowry acid), identify the proton acceptor (Bronsted-Lowry base). Use arrows to show the conjugate acid-base pairs and circle the arrow showing the correct direction of the proton transfer reaction. 15. a. CH3COOH(aq) + H2O() H3O+1(aq) + CH3COO-1(aq) Acid Base CA CB b. HCl(aq) Acid + c. NH3(g) Acid + d. HCO3-1(aq) Base NH3(g) Base H2O() Base + NH4+1(aq) CA H2O() Acid NH2-1 (aq) CB Cl-1(aq) CB + + H2CO3(aq) CA H3O+1(aq) CA + OH-1(aq) CB 16. What is the term used to refer to any substance that can be an acid or a base? amphoteric What are two examples of such a substance? 1. Water H2O 2. Ammonia NH3 17. Complete the matching section below testing your general knowledge on acids & bases A = Acid B = Base S = Salt A / B = Acids & Bases A / S = Acids & Salts B / S = Bases & Salts A / B / S = Acids, Bases & Salts B Has the Hydroxide ion (OH-) as its only anion. A Ionizes in water to produce hydronium ions. S Does not contain a H+ or OH- ion. A Tastes sour (examples are vinegar and citrus fruits). AB Can change the color of indicators. B Feels slippery (example being soaps). S CaCO3 is an example (chalk). B Dissociates in water to produce hydroxide ions. B Has a pH > (greater than) 7. A Has a pH < (less than) 7. B Is a proton (H+) acceptor. A Is a proton (H+) donor. A Is an electron pair acceptor. B Is an electron pair donor. ABS Can be corrosive. 18. What is the product of all Neutralization reaction between aqueous acids and bases? Water is always produced in neutralization reactions. 19. What is the product of all acid anhydrides and basic anhydrides? Acid anhydrides (nonmetal oxide) produce an acid when re-hydrated. Basic anhydrides (metal oxide) produce a base when re-hydrated. 20. Show that carbon dioxide is an acid anhydride of carbonic acid. CO2(g) 21. + H2O() H2CO3(aq) Show that magnesium oxide is a basic anhydride of magnesium hydroxide. MgO(s) + H2O() Mg(OH)2(s) 22. Complete the following neutralization reactions, making certain the balance the end product. a. 3 HNO3(aq) + Al(OH)3(s) b. 2 H3PO4(aq) + 3 Mg(OH)2(s) c. 2 HCl(aq) + Ca(OH)2(aq) 3 HOH() 2 HOH() + Al(NO3)3(aq) 6 HOH() + + CaCl2(aq) Mg3(PO4)2(s)