Topic # 6.6 GPS: 7b Properties & Nomenclature of Acids & Bases Date: _____/_____/_____ Part I: General Properties of Acids & Bases acids and bases are found in many _________ items, like _____, _______, and ________. acids give _____ ______ their ____ flavor, and ____ ______ their ____ flavor bases are found in both ____ and powerful ______, like soap and ______, and also in many ________, such as Tums acids and bases have distinct _________ that distinguish them: Acid Properties Base Properties aqueous solutions have a _____ flavor aqueous solutions have a _______ flavor change the color of indicators to ____ change the color of indicators to _____ react with ______ to form ___ gas aqueous solutions feel ________ are considered “________” are considered “________” some can be __________ can cause ______ ____ by dissolving ______ named using _____ nomenclature named using _____ ____ like always Properties of Both Acids and Bases acids react with bases to form a salt (a metal + a halogen) and water both produce electrolytes in aqueous solutions (extent depends on polarity) Part II: Definitions of Acids & Bases there are two distinct __________ that describe the sort of _________ that can be called acids and bases: Arrhenius and Brønsted-Lowry Arrhenius Acids & Bases the general Arrhenius acid and base definition depends on what _____ a compound makes in _______ solution: Arrhenius Acids Arrhenius Bases produce ________ ions (___) produce ________ ions (___) ex: ex: this definition is the most ________, meaning relatively ____ substances can be considered Arrhenius acids or bases because of the _____ they must make in order to ____ the definition. Brønsted-Lowry Acids & Bases the general Brønsted-Lowry acid and base definition depends on whether the compound can be considered a ______ _____ or a ______ ________: Brønsted-Lowry Acids Brønsted-Lowry Bases ______ protons (in the form of ___) _______ protons (usually have a ____. charge) ex: ex: to ______ a proton means to produce an ___ ion in aqueous solution, so a BrønstedLowry acid is essentially defined the _____ way as an Arrhenius acid the ability to ______ a proton is the ability to gain __ or _____ H+ ions and form a new, _______ compound, so a Brønsted-Lowry base is, by definition, ________ from an Arrhenius base. This means that all B-L bases must have a _____. charge. this definition is the _____ exclusive, meaning _____ substances can be considered B-L acids or bases because there are less _____ a compound must ____ in order to fit the definition. Part III: Acid & Base Strength the ________ of an Arrhenius acid or base depends _____ on the _______ of ___________/ ____________ the acid or base undergoes in other words, the higher the _________ of the acid or base, the ________ it is Part IV: Acid Nomenclature acids are distinguished from _____ substances by the presence of one or more _______ ions (H+) or hydrogen atoms at the ________ of the formula. to _____ an acid correctly, you must know the _____ of acid it is. There are ___ types of acids: Binary Acids and Oxyacids binary acid = an acid consisting of only __ elements. One of the elements is always ________, and the other is usually a ________ or other _________. to name a binary acid, follow this procedure: (HCl as an example) 1. use the prefix “______-” hydro__________ 2. name the _______ the H is bonded to chlorine 3. take the ______ off the element name hydrochlor4. add the ______ “-___” to the element name hydrochloric 5. add the separate word “_____” to the end hydrochloric acid try naming/formulating these binary acids: HBr = ________________________ hydrofluoric acid = __________ HI = ________________________ hydroxic acid = __________ H2S = ________________________ hydroselenic acid = __________ oxyacid = an acid consisting of __ or ____ elements. One of the elements is always ________, and the other 2 or more come from a __________ ____ (PAI). to name a oxyacid, follow this procedure: (H2CO3 as an example) 1. name the ____ the H is bonded to carbonate 2. take the ______ off the PAI name carbon3. add a suffix to the PAI name—if the PAI ends in: a. “-____,” use the suffix “-____” b. “-____,” use the suffix “-___” carbonic 4. add the separate word “_____” to the end carbonic acid try naming/formulating these oxyacids: HNO3 = ______________________ permanganic acid = __________ H2SO4 = ______________________ chloric acid = __________ H2SO3 = ______________________ chlorous acid = __________ HBrO = _______________________ phosphoric acid = __________ Some Common Industrial Acids Topic # 6.6 GPS: 7b Date: _____/_____/_____ The properties of acids make them important chemicals both in the laboratory and in industry. Sulfuric acid, nitric acid, phosphoric acid, hydrochloric acid, and acetic acid are all common industrial acids. Sulfuric Acid Sulfuric acid is the most commonly produced industrial chemical in the world. More than 47 million tons of it are made each year in the United States alone. Sulfuric acid is used in large quantities in petroleum refining and metallurgy as well as in the manufacture of fertilizer. It is also essential to a vast number of industrial processes, including the production of metals, paper, paint, dyes, detergents, and many chemical raw materials. Sulfuric acid is the acid used in automobile batteries. Because it attracts water, concentrated sulfuric acid is an effective dehydration (waterremoving) agent. It can be used to remove water from gases with which it does not react. Sugar and certain other organic compounds are also dehydrated by sulfuric acid. Skin contains organic compounds that are attacked by concentrated sulfuric acid, which can cause serious burns. Nitric Acid Pure nitric acid is a volatile, unstable liquid rarely used in industry or laboratories. Dissolving the acid in water provides stability. Nitric acid stains proteins yellow. The feather in this picture was stained by nitric acid. The acid has a suffocating odor, stains skin, and can cause serious burns. It is used in making explosives, many of which are nitrogen containing compounds. It is also used to make rubber, plastics, dyes, and pharmaceuticals. Initially, nitric acid solutions are colorless; however, upon standing, they gradually become yellow because of slight decomposition to brown nitrogen dioxide gas. Phosphoric Acid Phosphorus, along with nitrogen and potassium, is an essential element for plants and animals. The bulk of phosphoric acid produced each year is used directly for manufacturing fertilizers and animal feed. Dilute phosphoric acid has a pleasant but sour taste and is not toxic. It is used as a flavoring agent in beverages and as a cleaning agent for dairy equipment. Phosphoric acid is also important in the manufacture of detergents and ceramics. Hydrochloric Acid The stomach produces HCl to aid in digestion. Industrially, hydrochloric acid is important for “pickling” iron and steel. Pickling is the immersion of metals in acid solutions to remove surface impurities. This acid is also used in industry as a general cleaning agent, in food processing, in the activation of oil wells, in the recovery of magnesium from sea water, and in the production of other chemicals. A dilute solution of hydrochloric acid, commonly referred to as muriatic acid, may be found in hardware stores. It is used to maintain the correct acidity in swimming pools and for general cleaning of masonry. Acetic Acid Concentrated acetic acid is a clear, colorless, pungent-smelling liquid known as glacial acetic acid. This name derives from the fact that pure acetic acid has a freezing point of only 17°C. It can form crystals in a cold room. The fermentation of certain plants produces vinegars containing acetic acid. White vinegar contains 4–8% acetic acid. Acetic acid is important industrially in synthesizing chemicals used in the manufacture of plastics. It is a raw material in the production of food supplements—for example, lysine, an essential amino acid. Acetic acid is also used as a fungicide.