The Mole Notesheets Name_______________________________ Period______Date_____________________ 7.1, 7.3 7.1 Chemical Measurement: 1. Counting units: pair = _______ dozen = _______ score = _______ gross = _______ ream = _______ mole = _________________________ 2. A mole is the ________________ of a substance. It is based on the number of atoms of an element equal to the number of atoms in exactly 12.0g of _____________________. 3. The number of particles in a mole is called ________________________ ____________________. 4. The value of Avogadro’s constant is ___________________________________________________. 5. Atomic mass: mass of one atom of an element measured in amu (atomic mass units). Ex #1) H = 1 amu O = _______amu C = _______amu 6. Formula mass: mass of all the atoms in a single molecule or formula unit of a compound. Ex #2) H2O = Ex #3) H2CO3 = 7. Molar Mass: mass of one mole of an element The units used are _________. Round all elements’ masses to the nearest whole number except _______ + _______. Ex #4) Elements: Cu = _______g/mol 1 mole Cu = ___________________atoms Cl = _______g/mol 1 mole Cl = ____________________atoms Ex #5) Covalent Compounds: H2O = _______g/mol 1 mole H2O = ______________________molecules H2CO3 = _______g/mol Ex #6) Ionic Compounds: NaCl = _______g/mol MgO = _______g/mol 8. Examples: N2 = _________g/mol 2N2 = _________g/mol = = 1 mole H2CO3 = ____________________molecules 1 mole NaCl = __________________formula units 1 mole MgO = __________________formula units _________________________molecules _________________________molecules 9. Practice: Calculate the molar mass of sucrose, C12H22O11. Avogadro’s Number 1 10. 1 mole = _________________________________ particles = molar mass 1 mole Ne = ________________________________________ = __________g 1 mole CO2 = ________________________________________ = __________g 1 mole CaF2 = ________________________________________ = __________g 11. The mole is the _________________ between calculations of # of particles, mass and volume of a gas. 12. Conversion Factors: 1 mole = 6.02 x 1023 particles (atoms, molecules or formula units) 1 mole = molar mass (grams) from the periodic table May be used in a problem in one of two ways depending on the given units. 6.02x1023 1 mole or 23 1 mole 6.02x10 X grams 1 mole or 1 mole X grams Ex #1) Given 11.2 g of NaCl, how many moles does this represent? 1 mole NaCl 11.2 g NaCl .191 mol NaCl *3 significant digits because 11.2 is 3 58.5 g NaCl Ex #2) Given 2.50 moles of NaCl, how many grams does this represent? Ex #3) How many particles are in 2.00 moles of H2O? How many atoms is this? Ex #4) How many moles of CaCO3 are 8.74 x 1023 formula units? Multistep Problems: 2 Ex #1) How many particles of copper are in 56.3 g of copper? 1mole Cu 56.3 g Cu 63.5 g Cu 6.02 x 1023 atoms Cu 23 = 5.34 x 10 atoms Cu 1mole Cu We use atoms because copper is an element. There are 3 significant digits because 56.3 has 3. Ex #2) Given 7.2 x 1023 atoms of calcium, how many grams of calcium is this? Ex #3) How many sugar particles of sugar (C12H22O11) are in 250g of sugar? Moles & Gases: Molar Volume: 1 mole of any gas at Standard Temperature and Pressure (STP = 0oC and 1 atm) has a volume of 22.4dm3 or __________L Ex #1) How many particles of CO2 gas are in a 1.0L flask at STP? 1 mole CO2 1.0 L CO2 22.4 L CO2 6.02 x 1023 molecules CO2 22 = 2.7 x 10 molecules CO2 1 mole CO2 Ex #2) How many atoms of radon gas are contained in a 6500. dm3 basement room at STP? Ex #3) If a room has a volume of 4000. L, how many moles of air is this at STP? 7.3 % Composition, Empirical & Molecular Formulas: 3 % Composition: The mass of each element in a compound compared to the entire __________ of the compound x by 100%. This can be calculated experimentally from the grams of each element in a compound, or the expected % can be calculated by using the molar masses of the elements in the compound compared to the molar mass of the compound. Ex #1) What is the % hydrogen in water? Use the molar masses when not provided the lab data. %H= 2.0 g H x 100% = 11% 18 g H20 %O= The numbers should add up to 100% unless significant digits prevent it. Ex #2) Find the % composition of a compound that contains 2.30 g of sodium, 1.60 g of oxygen, and 0.100 g of hydrogen. Ex #3) A sample of an unknown compound with a mass of 0.562 g has the following % composition: 13.0 % carbon, 2.20 % hydrogen, and 84.5 % fluorine. When this compound is decomposed into its elements, what mass of each element should be recovered? Empirical Formula: A formula that gives the simplest _____________-number ratio of the atoms of the elements in the compound. Molecular Formula: Gives the _____________ number of atoms of each element in a molecular compound. The molecular formula may be the same as the empirical formula. H20 Ex #1) Hydrogen peroxide = _______________ molecular formula = _______________ empirical formula (a ____: ____ ratio) Ex #2) glucose = C6H12O6 molecular formula = _______________ empirical formula (a___: ___:___ ratio) 4 Ex #3) Find the empirical formula of the compound if you have 80.g of carbon and 20.g of hydrogen. Ex #4) An unknown compound is analyzed. It’s composition was determined to be 51.85% carbon, 8.64% hydrogen and 39.51% oxygen. Find the empirical formula of the compound. Ex #5) Find the molecular formula of ribose (molecular mass = 150 g/mol). It has a chemical composition that is 40.0% carbon, 6.67% hydrogen and 53.3% oxygen. Assume a 100 g sample. Hint: First find the empirical formula: 5