Cycad Products Material Safety Data Sheets (MSDS) Cycad Blackgold MATERIAL SAFETY DATA SHEET Revision of January 18, 2014 I. Product Identification Trade Name: Cycad Blackgold Optical Pitch Grades: soft, medium, medium-hard, hard, and extra-hard Manufactured by: Cycad Products 763 Dora Celeste Drive Las Vegas, New Mexico 87701 Emergency Telephone: (505) 425-9505 Bus Hours Dr. Ronald Clark (505) 425-9475 Home Dr. Ronald Clark If Dr. Clark is not available II. Hazardous Ingredients Common Name Chemical Name CAS Number Per Cent Petroleum pitch Asphalt 8052-42-4 20-60% Components not precisely identified are either proprietary or non-hazardous. All components appear on the EPA TSCA inventory. Values are not product specifications. III. Physical Data Boiling Point: NA Melting Point: 65-80 C. Specific Gravity: 1.1 Vapor Pressure: NA Vapor Density: NA Solubility: insoluble in water, soluble in hydrocarbons Percent Volatiles: none Appearance and odor: Black, odorless cold IV. Fire and Explosion Data Flash Point: est > 400 F Extinguishing Media: dry chemical, foam, steam, water fog, or carbon dioxide Special fire fighting procedures: Optical Pitch is never found in tonnage lots, so fires would only involve relatively small amounts of material. If fire occurs in can, cover the can with the lid to put out the fire. Treat as an oil fire. If possible, do not use water as water causes spreading of the burning pitch. If only water is available, use gross amounts which will solidify the pitch. Unusual fire and explosion hazards: none V. Health Hazard Data Inhalation of fumes Acute: Upper respiratory tract (nose and throat) irritation. Skin Contact Acute: Prolonged contact may cause mild irritation. Contact with hot material will cause thermal burns. Eye Contact Acute: Fumes from heated material will cause irritation. Exposure Limits Asphalt fume OSHA PEL none established ACGIH TLV 5 mg/M3 NIOSH 5 mg/M3 Carcinogenicity Asphalt NTP listed no IARC listed yes OSHA regulated no Emergency First Aid Procedures Inhalation: Remove individual to fresh air. If irritation persists, seek medical attention. Skin: Cool hot material with ice or cold water. Do not remove pitch immediately, Cover with petroleum jelly and remove when softened. Seek medical attention for burns. A bucket of cold water should be kept nearby whenever melted pitch is handled. Eyes: Flush with running water for at least 15 minutes. Seek medical attention. VI. Reactivity Data Stability (conditions to avoid): Stable Incompatibility: Strong oxidizing agents Hazardous decomposition products: Combustion yields the usual hydrocarbon combustion products. Hazardous polymerization: will not occur VII. Spill or Leak Procedures Action to take for spills: If molten, let cool to a solid, then shovel into waste receptacle. Avoid inhalation of fumes. Waste Disposal Method: Dispose in accordance with federal, state, and local regulations, Primary disposal is in a municipal or industrial landfill. Combustion in an approved incinerator is acceptable. VIII. Special Protection Information Ventilation: Use a hood or other well-ventilated area when heating to avoid fume inhalation. Respiration: Use an approved organic vapor respirator with a particulate pre-filter if fumes exceed 5 mg/M3. Protective Clothing: Wear insulating covering when working with molten material. Eye Protection: Wear safety glasses or safety shield when working with molten material. IX. Special Precautions and Other Information 1. Never add water or other low boiling material to melted pitch. 2. Optical pitch is usually dispensed as a liquid at 200-400 F. The chief hazard in handling pitch is the danger of burns from splashes or spills. Protective clothing, including safety glasses, should always be used when hot pitch is being handled. 3. In use, optical pitch may become contaminated with hazardous materials from the surfaces being worked. If so, dispose of the pitch as appropriate for the surface materials. 4. Laps can usually be formed from melted pitch at 260F, and at this temperature essentially no fumes or vapor will form. We recommend casting below 275F. 5. Cycad Blackgold Optical Pitch is petroleum pitch modified by blending with natural resins long known to be non-toxic. None of these materials is considered hazardous except that, with regard to the asphalt component, our petroleum pitch supplier has indicated in their MSDS that " There are no studies to indicate that asphalt causes cancer or respiratory damage in man. This petroleum based product contains a small amount of polycyclic aromatic hydrocarbons which have been known to cause cancer and respiratory damage in laboratory animals." Asphalt is commonly found in such everyday materials as road tar, roofing tar, roofing paper, and sealing compounds. Notice All information, recommendations, and suggestions appearing herein concerning this product are based upon data obtained from our suppliers and/or recognized technical sources and are believed to be accurate, however, Cycad Products makes no warranty, representation or guarantee as to the accuracy, sufficiency, or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity, and suitability of their own use, handling, and disposal of the product. Since actual use by others is beyond our control, no warranty, express or implied is made by Cycad Products as the effects of such use, the results to be obtained, or the safety and toxicity of the product, nor does Cycad Products assume any liability arising out of the use by others of the products referred herein. The data in this Material Safety Data Sheet relate only to the specific material designated herein and do not relate to use in combination with any other material or in any process. Cycad Cleargold MATERIAL SAFETY DATA SHEET Revision of February 3, 2000 I. Product Identification Trade Name: Cycad Cleargold Optical Pitch Grades: soft, medium, medium-hard, and hard Manufactured by: Cycad Products 763 Dora Celeste Drive Las Vegas, New Mexico 87701 Emergency Telephone: (505) 425-9505 Bus Hours Dr. Ronald Clark (505) 425-9475 Home Dr. Ronald Clark If Dr. Clark is not available (505) 425-6378 Mr. Wayne Proell II. Hazardous Ingredients Common Name Chemical Name CAS Number Per Cent None. The principle component is rosin (CAS No. 8050-09-7) Components not precisely identified are either proprietary or non-hazardous. All components appear on the EPA TSCA inventory. Values are not product specifications. III. Physical Data Boiling Point NA Melting Point 65-80 C Specific Gravity: 1.1 Vapor Pressure: NA Vapor Density: NA Solubility: insoluble in water, soluble in hydrocarbons Percent Volatiles: none Appearance and odor: Clear, honey-colored solid IV. Fire and Explosion Data Flash Point: est > 400 Extinguishing Media: dry chemical, foam, steam, water fog, or carbon dioxide Special fire fighting procedures: Optical Pitch is never found in tonnage lots, so fires would only involve relatively small amounts of material. If fire occurs in can, cover the can with the lid to put out the fire. Treat as an oil fire. If possible, do not use water as water causes spreading of the burning pitch. If only water is available, use gross amounts, which will solidify the pitch. Unusual fire and explosion hazards: none V. Health Hazard Data Inhalation of fumes Acute: Upper respiratory tract (nose and throat) irritation. Skin Contact Acute: Prolonged contact may cause mild irritation. Contact with hot material will cause thermal burns. Eye Contact Acute: Fumes from heated material will cause irritation. Exposure Limits Rosin OSHA PEL none established ACGIH TLV 10 mg/M Emergency First Aid Procedures: Inhalation: Remove individual to fresh air. If irritation persists seek medical attention. Skin: Cool hot material with ice or cold water. Do not remove pitch immediately, Cover with petroleum jelly and remove when softened. Seek medical attention for burns. A bucket of cold water should be kept nearby whenever melted pitch is handled. Eyes: Flush with running water for at least 15 minutes. Seek medical attention. VI. Reactivity Data Stability (conditions to avoid): Stable Incompatibility: Strong oxidizing agents Hazardous decomposition products: Combustion yields the usual hydrocarbon combustion products. Hazardous polymerization: will not occur VII. Spill or Leak Procedures Action to take for spills: If molten, let cool to a solid, then shovel into waste receptacle. Avoid inhalation of fumes. Waste Disposal Method: Dispose in accordance with federal, state, and local regulations, Primary disposal is in a municipal or industrial landfill. Combustion in an approved incinerator would be acceptable. VIII. Special Protection Information Ventilation: Use a hood or other well-ventilated area when heating to avoid fume inhalation Respiration: Use an approved organic vapor respirator with a particulate pre-filter if fumes exceed 5 mg/M3 Protective Clothing: Wear insulating covering when working with molten material. Eye Protection: Wear safety glasses or safety shield when working with molten material. IX. Special Precautions and Other Information Never add water or other low boiling material to melted pitch. Optical pitch is usually dispensed as a liquid at 200-400 F. The chief hazard in handling pitch is the danger of burns from splashes or spills. Protective clothing, including safety glasses, should always be used when hot pitch is being handled. In use, optical pitch may become contaminated with hazardous materials from the surfaces being worked. If so, dispose of the pitch as appropriate for the surface materials. Laps can usually be formed from melted pitch at 260 F, and at this temperature essentially no fumes or vapors will form. We recommend casting below 275 F if at all possible. Cycad Cleargold Optical Pitch is rosin pitch modified by blending with materials believed to be non-toxic. As with any industrial chemical product, it should be handled with good industrial hygiene and safety practices. Notice All information, recommendations, and suggestions appearing herein concerning this product are based upon data obtained from our suppliers and/or recognized technical sources and are believed to be accurate, However, Cycad Products makes no warranty, representation or guarantee as to the accuracy, sufficiency, or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity, and suitability of his own use, handling, and disposal of the product. Since actual use by others is beyond our control, no warranty, express or implied is made by Cycad Products as the effects of such use, the results to be obtained, or the safety and toxicity of the product, nor does Cycad Products assume any liability arising out of the use by others of the products referred herein. The data in this Material Safety Data Sheet relate only to the specific material designated herein and do not relate to use in combination with any other material or in any process. ________________________________________________________________________ Cycad Blocker MATERIAL SAFETY DATA SHEET Revision of February 3, 2000 I. Product Identification Trade Name: Cycad Blocker Cycad Blocking Pitch Manufactured by: Cycad Products 763 Dora Celeste Drive Las Vegas, New Mexico 87701 Emergency Telephone: (505) 425-9505 Bus Hours Dr. Ronald Clark (505) 425-9475 Home Dr. Ronald Clark If Dr. Clark is not available (505) 425-6378 Mr. Wayne Proell II. Hazardous Ingredients Common Name Chemical Name CAS Number Per Cent None III. Physical Data Boiling Point: NA Melting Point: 65-80 C. Specific Gravity: 1.1-1.2 Vapor Pressure:NA Vapor Density: NA Solubility: insoluble in water, soluble in hydrocarbons Percent Volatiles: none Appearance and odor: Brownish gold, odorless, cold IV. Fire and Explosion Data Flash Point: est > 400 F Extinguishing Media: dry chemical, foam, steam, water fog, or carbon dioxide Special fire fighting procedures: Optical Pitch is never found in tonnage lots, so fires would only involve relatively small amounts of material. Treat as an oil fire. If possible, do not use water as water causes spreading of the burning pitch. If only water is available, use gross amounts which will solidify the pitch. Unusual fire and explosion hazards: none V. Health Hazard Data Inhalation of fumes Acute: Upper respiratory tract (nose and throat) irritation. Skin Contact Acute: Contact with hot material will cause thermal burns. Eye Contact Acute: Fumes from heated material will cause irritation from rosin. Exposure Limits None established. We recommend 10 mg/M3 for dust and 5 mg/M3 for fumes Carcinogenicity Not listed Emergency First Aid Procedures Inhalation: Remove individual to fresh air. If irritation persists, seek medical attention. Skin: Cool hot material with ice or cold water. Do not remove pitch immediately. Cover affected area with Furacin soluble dressing. Material will flake off as the burn heals. Seek medical attention for severe burns. A bucket of cold water should be kept nearby whenever melted pitch is handled. Eyes: Flush with running water for at least 15 minutes. Seek medical attention. VI. Reactivity Data Stability (conditions to avoid): Stable Incompatibility: Strong oxidizing agents Hazardous decomposition products: Combustion yields the usual organic combustion products. Hazardous polymerization: will not occur VII. Spill or Leak Procedures Action to take for spills: If molten, let cool to a solid, then shovel into waste receptacle. Avoid inhalation of fumes. Waste Disposal Method: Dispose in accordance with federal, state, and local regulations, Primary disposal is in a municipal or industrial landfill. Combustion in an approved incinerator would be acceptable. VIII. Special Protection Information Ventilation: Use a hood or other well ventilated area when heating to avoid fume inhalation Respiration: Use an approved organic vapor respirator with a particulate prefilter if fumes exceed 5 mg/M3. Protective Clothing: Wear insulating covering when working with molten material. Eye Protection: Wear safety glasses or safety shield when working with molten material. IX. Special Precautions and Other Information 1. Never add water or other low boiling material to melted pitch. 2. The chief hazard in handling pitch is the danger of burns from splashes or spills. Protective clothing, including safety glasses, should always be used when hot pitch is being handled. 3. In use, optical pitch may become contaminated with hazardous materials from the surfaces being worked. If so, dispose of the pitch as appropriate for the surface materials. 4. Cycad Blocking Pitch is primarily a blend of natural materials long known to be non- toxic. None of these materials is considered hazardous under normal conditions. Fumes can be avoided by keeping the temperature of the pitch below 275oF. Notice We have been informed of no health effects caused by Cycad blocking pitch other than thermal burns. All information, recommendations, and suggestions appearing herein concerning this product are based upon data obtained from our suppliers and/or recognized technical sources and are believed to be accurate, However, Cycad Products makes no warranty, representation or guarantee as to the accuracy, sufficiency, or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity, and suitability of their own use, handling, and disposal of the product. Since actual use by others is beyond our control, no warranty, express or implied is made by Cycad Products as the effects of such use, the results to be obtained, or the safety and toxicity of the product, nor does Cycad Products assume any liability arising out of the use by others of the products referred herein. The data in this Material Safety Data Sheet relate only to the specific material designated herein and do not relate to use in combination with any other material or in any process. ________________________________________________________________________ Cycad Optical Pitch MATERIAL SAFETY DATA SHEET Revision of May 5, 1999 I. Product Identification Trade Name: Cycad Optical Pitch Grades: soft, medium, medium-hard, hard, and extra-hard Manufactured by: Cycad Products 763 Dora Celeste Drive Las Vegas, New Mexico 87701 Emergency Telephone: (505) 425-9505 Bus Hours Dr. Ronald Clark (505) 425-9475 Home Dr. Ronald Clark If Dr. Clark is not available (505) 425-6378 Mr. Wayne Proell II. Hazardous Ingredients Common Name Chemical Name CAS Number Per Cent Petroleum pitch Asphalt 8052-42-4 20-60% Components not precisely identified are either proprietary or non-hazardous. All components appear on the EPA TSCA inventory. Values are not product specifications. III. Physical Data Boiling Point: NA Melting Point: 65-800 C. Specific Gravity: 1.1 Vapor Pressure: NA Vapor Density: NA Solubility: insoluble in water, soluble in hydrocarbons Percent Volatiles: none Appearance and odor: Black, odorless when cold IV. Fire and Explosion Data Flash Point: Est > 4000 C. Extinguishing Media: dry chemical, foam, steam, water fog, or carbon dioxide Special fire fighting procedures: Optical Pitch is never found in tonnage lots, so fires would only involve relatively small amounts of material. If fire occurs in can, cover the can with the lid to put out the fire. Treat as an oil fire. If possible, do not use water as water causes spreading of the burning pitch. If only water is available, use gross amounts, which will solidify the pitch. Unusual fire and explosion hazards: none V. Health Hazard Data Inhalation of fumes Acute: Upper respiratory tract (nose and throat) irritation. May cause nausea or dizziness. Skin Contact Acute: Prolonged contact may cause dermatitis. Contact with hot material will cause thermal burns. Eye Contact Acute: Fumes from heated material will cause irritation. Exposure Limits Asphalt fume OSHA PEL none established ACGIH TLV 5 mg/M3 NIOSH 5 mg/M3 Carcinogenicity Asphalt NTP listed no IARC listed yes OSHA regulated no Emergency First Aid Procedures Inhalation: Remove individual to fresh air. If irritation persists, seek medical attention. Skin: Cool hot material with ice or cold water. Do not remove pitch immediately, Cover with petroleum jelly and remove when softened. Seek medical attention for burns. A bucket of cold water should be kept nearby whenever melted pitch is handled. Eyes: Flush with running water for at least 15 minutes. Seek medical attention. VI. Reactivity Data Stability (conditions to avoid): Stable Incompatibility: Strong oxidizing agents Hazardous decomposition products: Combustion yields the usual hydrocarbon combustion products. Hazardous polymerization: will not occur VII. Spill or Leak Procedures Action to take for spills: If molten, let cool to a solid, then shovel into waste receptacle. Avoid inhalation of fumes. Waste Disposal Method: Dispose in accordance with federal, state, and local regulations, Primary disposal is in a municipal or industrial landfill. Combustion in an approved incinerator would be acceptable. VIII. Special Protection Information Ventilation: Use a hood or other well-ventilated area when heating to avoid fume inhalation Respiration: Use an approved organic vapor respirator with a particulate pre-filter if fumes exceed 5 mg/M3 Protective Clothing: Wear insulating covering when working with molten material. Eye Protection: Wear safety glasses or safety shield when working with molten material. IX. Special Precautions and Other Information 1. Never add water or other low boiling material to melted pitch. 2. Optical pitch is usually dispensed as a liquid at 200 - 4000 F. The chief hazard in handling pitch is the danger of burns from splashes or spills. Protective clothing, including safety glasses, should always be used when hot pitch is being handled. 3. In use, optical pitch may become contaminated with hazardous materials from the surfaces being worked. If so, dispose of the pitch as appropriate for the surface materials. 4. Cycad Optical Pitch is petroleum pitch modified by blending with natural resins long known to be non-toxic. None of these materials is considered hazardous except that, with regard to the asphalt component, our petroleum pitch supplier has indicated that "There are no studies to indicate that asphalt causes cancer or respiratory damage to man. This petroleum-based product contains a small amount of polycyclic aromatic hydrocarbons which have been shown to cause cancer and respiratory damage in laboratory animals." Notice In the 48 years that Cycad Optical Pitch has been marketed, we have been informed of no health effects caused by the pitch other than thermal burns. All information, recommendations, and suggestions appearing herein concerning this product are based upon data obtained from our suppliers and/or recognized technical sources and are believed to be accurate. However, Cycad Products makes no warranty, representation or guarantee as to the accuracy, sufficiency, or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity, and suitability for his own use, handling, and disposal of the product. Since actual use by others is beyond our control, no warranty, express or implied is made by Cycad Products as to the effects of such use, the results to be obtained, or the safety and toxicity of the product, nor does Cycad Products assume any liability arising out of the use by others of the products referred herein. The data in this Material Safety Data Sheet relate only to the specific material designated herein and do not relate to use in combination with any other material or in any process.