MRHS Chemistry Y. Varma-Kumar Name: ________________________________________________ Date: _____________ Pd: __________ Day: ________ VEGIUM LAB Average Atomic Mass Objectives Determine the weight of each isotope of the fictitious element VEGIUM. Determine the relative abundances of the isotopes of vegium. Calculate from experimental data the atomic mass of vegium. Introduction Isotopes are atoms of the same atomic number having different masses due to different numbers of neutrons. The atomic mass of an element is a weighted average, taking into account both the mass and relative abundance of each isotope of that element as it occurs in nature. The relative abundances and masses of small atomic particles are measured in the laboratory by an instrument called a mass spectrometer. The mass spectrometer separates particles by mass and measures the mass and relative abundance of each type of particle it studies. From these data a weighted average is calculated to determine the atomic mass of the element. Purpose In this lab you will carry out experiments and perform the necessary calculations to determine the atomic mass of vegium. Three isotopes of vegium have been observed in nature: beans, peas, and black-eyed peas. These isotopes are different varieties of vegium having different masses. Unlike real isotopes, the individual isotopic particles (beans, peas, and blackeyed peas) differ slightly in mass, so you will determine the average mass of each type of isotopic particle. Then you will determine the relative abundance of each isotope, and use this data along with the isotopic masses to calculate the weighted average mass, or atomic mass, of vegium. Materials & Equipment a sample of vegium electronic balance weighing boat (to act as a weighing dish) Experimental Procedure Carry out the following steps and record your results in your data table. Show all calculations neatly on a separate sheet of paper. Report all numbers to four significant figures. 1. Weigh all the beans, then all the peas, then all the blackeye peas. Record your data. 2. Count all the beans, then all the peas, then all the black-eye peas. Record your data. 1 Title 3. Divide the total mass of each isotope by the number of each isotope to get the average mass of each isotope. Note: In all rows except the average mass in the table, the numbers in the "total" column can be obtained by adding the numbers across each row. Step 3 is an exception because it does not take into account the fact that there are different numbers of each type of particle. Rather than adding across, calculate this number using the same method you used to calculate the other numbers in step 3. 4. Divide the number of each isotope by the total number of atoms, and multiply by 100 to get the percent abundance of each isotope. 5. Divide the percent abundance from step 4 by 100 to get the relative abundance of each isotope. 6. Multiply the relative abundance from step 5 by the average mass of each isotope to get the relative weight of each isotope. 7. Add the relative weights to get the average mass of all particles in vegium, the atomic mass. 8. Return your first sample of vegium in its ziploc bag. Obtain a second sample of vegium and do the experiments to determine its atomic mass. Data Table (a part of your Results section) Beans Trial Trial 1 2 Peas Trial Trial 1 2 B.E. Peas Trial Trial 1 2 Total Trial Trial 1 2 Mass of Each Isotope Number of each Isotope Average mass of each “atom” Percent Abundance Relative Abundance Relative Weight Atomic Mass Trial 1: ________________ Atomic Mass Trial 2: ________________ 2 Title Analysis Questions: Use your experimental data and your knowledge of atomic structure and isotopes to answer the following questions: 1. Which of your data (in the table) can be measured and which had to be calculated? 2. What is the difference between percent abundance and relative abundance? 3. What is the result when you total the individual percent abundances? The individual relative abundances? 4. What is the difference between the average mass you calculated in step 3 and the relative weight you calculated in step 6? 5. Can atomic masses be calculated the way the total for row 3 was calculated? Explain why your results using this method would or would not be the same as those you obtained by using step 7. 6. Explain any differences between the atomic masses of your two samples of vegium. Explain why the differences would be smaller if larger samples were used. 7. In what ways does this lab succeed in imitating “real-life” isotope calculations? In what ways does it do a poor job at simulating real-life? 8. Compare your results for the atomic mass of vegium to the class results. Explain why the calculated atomic masses might vary. 9. Identify two possible sources of experimental error and explain which data were most impacted and how. 10. Identify two possible sources of human error and explain data which were most impacted and how. 11. Explain why the atomic mass of an element reported on the periodic table is a weighted average based on relative abundance instead of a straight average not accounting for the abundance of each isotope. 12. The beanium isotope of vegium is naturally radioactive and decays with a half-life of 33.8 seconds. Starting with one thousand atoms, calculate the number of beanium atoms that are present every 33.8 seconds for 304.2 seconds. (304.2 seconds is 9 half-lives.) Use a graphing program to create a table of time(s) and number of beanium isotopes for this time period. 13. Use a computer graphing program to graph the decay of the beanium isotope where the number of atoms of beanium remaining depends on the time elapsed. 14. If the actual average atomic mass of Vegium is 0.2050 g, determine percent error. 3 Title