Instructor’s Notes for Assignment #93: The Photon Game Steve Sogo, Laguna Beach High School ssogo@lbusd.org Overview: This game is designed to help students understand the nature of quantum energy states within an atom and their correlation to the production of discrete photons. In the game, students work in pairs, using an energy well to simulate the quantum leaps made by electrons in excited atoms. Colored pencils are used to record the colors of photons produced, based on the energy difference between the initial and final quantum states of the electron. Why do this activity? In my teaching, I found that students enjoyed looking at atomic spectra, but their conceptual understanding of how/why the various colors were produced was always disappointing. This game enhances conceptual understanding in a user-friendly, enjoyable activity. Cooperation between student pairs is required for “victory”. Materials: One practice game board per student One version C game board and one version D game board per pair Set of colored pencils (Red, Orange, Yellow, Green, Blue, Violet, Black/Gray) needed for each pair of students Calculators may be required Powerpoint slide show used by the instructor Note: To obtain electronic copies of this lab, including instructor’s notes with color photos, please Google “Steve Sogo Haiku”, which should take you to the “Chemistry with Mr. Sogo” Haiku page. From here, click on the “ChemEd 2015” link displayed in the lower right corner of the Haiku page (see picture below). This link will take you to a site where you will find downloadable editable documents (MS Word format) including both student pages and instructor’s notes. The instructor’s notes will provide links to relevant Youtube instructional videos from the ACR92651 channel. Assignment #93a: The Photon Game!!! Key Concepts: 1. You will work with a partner in this game. Each of you will need to start with a game board that represents the quantum energy levels in a particular atom (see next page for example!). 2. You will need a ¾” disk to represent an electron. In this game, the electron will be jumping between various energy levels within each atom. 3. Take a look at the gameboard on the next page and notice that there are energy values written on the board. Based on these energy values, try to complete the sentences below: In any atom, the lowest energy level is labeled as n = ___. This corresponds to the innermost shell of the atom. As n increases, energy approaches _____ kJ/mol. This means that an outer shell is at a relatively high / low energy level compared to an inner shell. If an electron ever reaches the energy level of zero kJ/mole, the electron has _____________ from the pull of the atom’s nucleus. 4. For an electron to climb higher in the energy well, it must ABSORB energy. This results in an increase in POTENTIAL energy. Sources of energy in the PHOTON GAME include: Bunsen burner The Sun! Energy-carrying photons (infrared, visible, and ultraviolet) 5. If an electron FALLS DOWN in the energy well, it will create a PHOTON of a particular color. This is a conversion of potential energy to light energy! The energy table shown on each game board specifies the particular photon ENERGIES that are associated with various COLORS. Ex: This drop of ____ kJ/mol will create a _________ colored photon. 6. Your instructor has a set of powerpoint slides which will specify possible changes for the electron’s position on the game board. For example, a slide may say “jump to level 4”. Alternatively, the slide may say something like “gain up to 500 kJ/mole of energy”. You must move your electron within the energy well to follow the changes that the slides specify. e- -600 kJ/mol -820 kJ/mol Fi g Color ur Orange e Yellow 3 Green 7. When your team has successfully produced ALL the colors of the rainbow (as well as ALL the “colors” that lie above and below the visible spectrum, you are a WINNER in the photon game! Your prize is a pair of photon-viewing glasses (one pair per person). kJ/mole 191-210 211-230 231-250 #93b: The Photon Game! Version P (for Practice) 0 kJ/mol n=5 -100 kJ/mol n=4 -250 kJ/mol -430 kJ/mol n=3 -650 kJ/mol n=2 A PHOTON is produced only when an electron FALLS within the energy well. An electron must reside on one of the indicated levels (or on the 0 kJ “freedom” level. When an electron jumps from one level to another, it is called a QUANTUM LEAP. Scoreboard -910 kJ/mol As you create photons, shade in the boxes here with appropriate colors!!!! n=1 Photon Color Energy (kJ/mol) Infrared <170 Red 170-190 Orange 191-210 Yellow 211-230 Green 231-250 Blue 251-270 Violet 271-300 UV-A 301-370 UV-B 371-420 UV-C 421-1200 #93c: The Photon Game! Version C 0 kJ/mol n=6 -20 kJ/mol n=5 -80 kJ/mol n=4 -170 kJ/mol -280 kJ/mol A PHOTON is produced only when an electron FALLS within the energy well. An electron must reside on one of the indicated levels (or on the 0 kJ “freedom” level. When an electron jumps from one level to another, it is called a QUANTUM LEAP. n=3 -460 kJ/mol n=2 -800 kJ/mol As you create photons, shade in the boxes here with appropriate colors!!!! n=1 Scoreboard Photon Color Energy (kJ/mol) Infrared <170 Red 170-190 Orange 191-210 Yellow 211-230 Green 231-250 Blue 251-270 Violet 271-300 UV-A 301-370 UV-B 371-420 UV-C 421-1200 #93d: The Photon Game! Version D 0 kJ/mol -20 kJ/mol n=6 n=5 -60 kJ/mol n=4 -120 kJ/mol n=3 -310 kJ/mol A PHOTON is produced only when an electron FALLS within the energy well. An electron must reside on one of the indicated levels (or on the 0 kJ “freedom” level. When an electron jumps from one level to another, it is called a QUANTUM LEAP. -530 kJ/mol n=2 Scoreboard -1030 kJ/mol As you create photons, shade in the boxes here with appropriate colors!!!! n=1 Photon Color Energy (kJ/mol) Infrared <170 Red 170-190 Orange 191-210 Yellow 211-230 Green 231-250 Blue 251-270 Violet 271-300 UV-A 301-370 UV-B 371-420 UV-C 421-1200 Assignment #94: The Photon Game Questions 1. A particular atom (such as a helium atom) can emit only certain colors of photons. In other words, helium atoms might be able to make R, Y, and V photons, but not O, G, or B photons. What is your explanation for why helium atoms can only emit particular colors of photons? 2. You probably know that ultraviolet “rays” can be damaging to your skin (and eyes). Why do you suppose UV light is so damaging to skin and eyes? 3. Label each of the following statements as TRUE or FALSE. Explain your reasoning in each case! Photons can never be created or destroyed An atom in its GROUND STATE cannot emit a photon Photons can go through glass Photons carry energy Photons can be created only after an atom has GAINED energy 4. Describe the conditions under which each of the following can be a photon producer. Note: a photon producer is different from a photon reflector. Consider invisible photons (IR and UV). . . a) The sun b) A light bulb c) A TV remote control d) A glow in the dark Frisbee e) A hedgehog 5. In order to remember the relative energies of the various colors of the rainbow, an acronym known as ROY G BIV is sometimes employed. Fill in the spaces in the table below. Abbreviation Color name Wavelength Energy (high vs. low) Long Low Short High R O Y G B I Indigo V 6. Add in the “color” that belongs before R and the “color” that belongs after V in the table shown above. 𝐸𝑛 = − Assignment #95: The Colors of the Rainbow An introduction to the Balmer Series of photons 1312 𝑘𝐽/𝑚𝑜𝑙 𝑛2 1. Use the Bohr Model equation shown above to calculate energy values for the first 8 shells of a hydrogen atom. Energy 8 -20.5 kJ/mole E4 = E3 = E2 = Increasing Energy Shell # E5 = 7 6 5 4 3 E1 = 2 1 Energy well for a hydrogen atom 2. Using the energy values that you calculated above, find the COLORS of photons produced from the following electron transitions that could occur within a hydrogen atom: Transition Potential Energy Loss Photon color emitted 31 1166 kJ/mole Ultraviolet (UV-C) 63 42 3. The visible spectrum of a hydrogen atom consists of only four bright lines. The photons emitted are red, teal green, and two closely spaced violet lines. Determine the electron transitions that result in these 4 colors and explain why no other visible colors can be emitted. Violet (1) Violet (2) Green (Teal) Red 62 292 kJ/mol Explanation: