Name: Ionic Bonding Year 11 Science Ruawai College 2014 Ions and Ionic Compounds Ions are atoms that have gained or lost electrons. Ions that lose electrons form positive ions. Ions that gain electrons form negative ions. Sodium loses an electron to achieve a full shell. Chlorine gains an electron to achieve a full shell. But the electrons do not just come and go from nowhere. Electrons are transferred from one atom to another when ions are formed. The electron that sodium loses is the same electron that chlorine gains. When this happens a strong bond is formed between the two atoms – an ionic bond. A strong ionic bond forms between the positive sodium ion and the negative chloride ion. This strong bond holds the two ions in a regular arrangement. Above is a 2D model of the salt sodium chloride. For every positive sodium ion there is a negative chloride ion. Sodium chloride is made up of Na+ and Cl- in a ratio of 1:1. We write sodium chloride as NaCl. NaCl is the formula for sodium chloride. Above is a 3D model of sodium chloride showing the lattice arrangement. Key Questions: Above is a diagram of magnesium oxide being formed when electrons are transferred from one atom to another atom. 1. How many electrons are being transferred from the magnesium atom to the oxygen atom? 2. What does the magnesium atom change into when it loses two electrons? 3. What does the oxygen atom change into when it gains two electrons? 4. What forms between the two ions when electrons are transferred from one to the other? 5. What is the chemical formula of magnesium oxide? 6. Draw a 2D model of magnesium oxide? . A 3D model of Lithium chloride is shown above. 7. What is ratio of lithium ions to chloride ions? 8. What is the formula of lithium chloride? A 3D model of Potassium chloride is shown above. 9. What is ratio of potassium ions to chloride ions? 10. What is the formula of potassium chloride? Exercises: Above is a diagram of magnesium chloride being formed when electrons are transferred from one atom to two other atoms. 11. How many electrons are being transferred from the magnesium atom to each chloride atom? 12. What does the magnesium atom change into when it loses two electrons? 13. What do the chlorine atoms change into when they gain an electron? 14. What forms between the magnesium ion and the two chloride ions when electrons are transferred? 15. The chemical formula of magnesium chloride is MgCl2. What does the 2 indicate? 16. The ratio of magnesium ions to chloride ions is 1:2. Why is the ratio 1:2? Chemical Formulas and Names of Ionic Compounds The diagrams below show some models of ionic compounds. a. Sodium chloride Chemical formula: NaCl b. Calcium chloride Chemical formula: CaCl2 c. Aluminium oxide Chemical formula: Al2O3 Key Questions: 1. What are the names of the elements found in the compounds above: a. b. c. 2. How does the name of the elements in each compound differ from that of the free elements. 3. How many sodium ions are there in the sodium chloride sample shown above? How many chloride ions? What is the ratio between the two? 4. How many calcium ions are there in the calcium chloride sample shown above? How many chloride ions? What is the ratio between the two? 5. How many aluminium ions are there in the aluminium oxide sample shown above? How many oxide ions? What is the ratio between the two? 6. What is the relationship between the chemical formula for the compounds above and the ratio of the ions between them? 7. What is the charge on the sodium ion? What is the charge on the chloride ion? 8. What is the charge on the calcium ion? What is the charge on the chloride ion? What is the charge on the oxide ion? 10. All samples of sodium chloride have a ratio of one sodium ion for one chloride ion. What must be true of the total charge for any sample of sodium chloride? 11. All samples of calcium chloride have a ratio of one calcium ion for two chloride ions. What must be true of the total charge for any sample of calcium chloride? 12. All samples of aluminium oxide have a ratio of two aluminiums for three oxide ions. What must be true of the total charge for any sample of aluminium oxide? 13 From the pattern seen in the last three questions, what is the rule for the total charge for a compound? Exercise: 14. Write the name of the compound above. 15. Write the chemical formula of the compound above. Ionic Charges Some ions are listed in the table below: Group 1 2 13 15 16 17 Charge +1 +2 +3 -3 -2 -1 Oxide O2Sulfide S2- Fluoride FChloride Cl- Lithium Nitride + Li N3Sodium Magnesium Aluminium Phosphide Na+ Mg2+ Al3+ P3Potassium Calcium + K Ca2+ Key Question 16. What patterns do you notice about the charges on the ions and their position on the periodic table. Exercise 17. Write the correct chemical formula for each of the following compounds. a. Compound Lithium chloride b. Potassium chloride c. Sodium fluoride d. Calcium oxide e. Magnesium sulfide f. Magnesium chloride g. Calcium chloride h. Aluminium chloride i. Aluminium fluoride j. Aluminium oxide Formula Name: Ionic Bonding Year 11 Science Ruawai College 2014 Ions and Ionic Compounds Ions are atoms that have gained or lost electrons. Ions that lose electrons form positive ions. Ions that gain electrons form negative ions. Sodium loses an electron to achieve a full shell. Chlorine gains an electron to achieve a full shell. But the electrons do not just come and go from nowhere. Electrons are transferred from one atom to another when ions are formed. The electron that sodium loses is the same electron that chlorine gains. When this happens a strong bond is formed between the two atoms – an ionic bond. A strong ionic bond forms between the positive sodium ion and the negative chloride ion. This strong bond holds the two ions in a regular arrangement. Above is a 2D model of the salt sodium chloride. For every positive sodium ion there is a negative chloride ion. Sodium chloride is made up of Na+ and Cl- in a ratio of 1:1. We write sodium chloride as NaCl. NaCl is the formula for sodium chloride. Above is a 3D model of sodium chloride showing the lattice arrangement. Key Questions: Above is a diagram of magnesium oxide being formed when electrons are transferred from one atom to another. 1. How many electrons are being transferred from the magnesium atom to the oxygen atom? 2 2. What does the magnesium atom change into when it loses two electrons? Magnesium ion Mg2+ 3. What does the oxygen atom change into when it gains two electrons? Oxide ion O2What forms between the two ions when electrons are transferred from one to the other? Ionic bond What is the chemical formula of magnesium oxide? MgO Draw a 2D model of magnesium oxide? 4. 5. 6. . A 3D model of Lithium chloride is shown above. 7. 8. What is ratio of lithium ions to chloride ions? 1:1 What is the formula of lithium chloride? LiCl A 3D model of Potassium chloride is shown above. 9. 10. What is ratio of potassium ions to chloride ions? 1:1 What is the formula of potassium chloride? KCl Exercises: Above is a diagram of magnesium chloride being formed when electrons are transferred from one atom to two other atoms. 11. 12. 13. 14. 15. How many electrons are being transferred from the magnesium atom to each chloride atom? One electron to each chloride ion What does the magnesium atom change into when it loses two electrons? Magnesium ion Mg2+ What do the chlorine atoms change into when they gain an electron? Chloride ion ClWhat forms between the magnesium ion and the two chloride ions when electrons are transferred? Ionic bond The chemical formula of magnesium chloride is MgCl2. What does the 2 indicate? There are two chloride ions for every magnesium ion 16. The ratio of magnesium ions to chloride ions is 1:2. Why is the ratio 1:2? Two negative chlorides are needed to balance out the charge on the one positive magnesium ion Chemical Formulas and Names of Ionic Compounds The diagrams below show some models of ionic compounds. a. Sodium chloride Chemical formula: NaCl b. Calcium chloride Chemical formula: CaCl2 c. Aluminium oxide Chemical formula: Al2O3 Key Questions: 1. What are the names of the elements found in the compounds above: a. sodium and chlorine b. calcium and chlorine c. aluminium and oxygen 2. How does the name of the elements in each compound differ from that of the free elements. Metal name stays the same Non-metal name ending changes from -ine to -ide 3. How many sodium ions are there in the sodium chloride sample shown above? 9 How many chloride ions? 9 What is the ratio between the two? 1:1 4. How many calcium ions are there in the calcium chloride sample shown above? 5 How many chloride ions? 10 What is the ratio between the two? 1:2 5. How many aluminium ions are there in the aluminium oxide sample shown above? 4 How many oxide ions? 6 What is the ratio between the two? 2:3 6. What is the relationship between the chemical formula for the compounds above and the ratio of the ions between them? Chemical formula shows the ratio of ions 7. What is the charge on the sodium ion? +1 What is the charge on the chloride ion? -1 8. What is the charge on the calcium ion? +2 What is the charge on the chloride ion? -1 What is the charge on the oxide ion? -2 10. All samples of sodium chloride have a ratio of one sodium ion for one chloride ion. What must be true of the total charge for any sample of sodium chloride? Neutral / No charge 11. All samples of calcium chloride have a ratio of one calcium ion for two chloride ions. What must be true of the total charge for any sample of calcium chloride? Neutral / No charge 12. All samples of aluminium oxide have a ratio of two aluminiums for three oxide ions. What must be true of the total charge for any sample of aluminium oxide? Neutral / No charge 13 From the pattern seen in the last three questions, what is the rule for the total charge for a compound? All ionic compounds are neutral, they have no charge Exercise: 14. Write the name of the compound above. Barium iodide 15. Write the chemical formula of the compound above. BaI2 Ionic Charges Some ions are listed in the table below: Group 1 2 13 15 16 17 Charge +1 +2 +3 -3 -2 -1 Oxide O2Sulfide S2- Fluoride FChloride Cl- Lithium Nitride + Li N3Sodium Magnesium Aluminium Phosphide Na+ Mg2+ Al3+ P3Potassium Calcium + K Ca2+ Key Question 16. What patterns do you notice about the charges on the ions and their position on the periodic table. All ions in a group have the same charge Exercise 17. Write the correct chemical formula for each of the following compounds. a. Compound Lithium chloride Formula LiCl b. Potassium chloride KCl c. Sodium fluoride NaF d. Calcium oxide CaO e. Magnesium sulfide MgS f. Magnesium chloride MgCl2 g. Calcium chloride CaCl2 h. Aluminium chloride AlCl3 i. Aluminium fluoride AlF3 j. Aluminium oxide Al2O3