Acids and Bases Word Bank Sour taste OH low pH Blue Litmus Paper -> Red -log[OH] Proton Acceptor Red Litmus Paper-> Blue good conductor Hydrogen Donator Slippery Bitter Taste pH < 7 -log[H3O] Hydrogen Acceptor pH > 7 Proton Donator H30 pH of 9 Acids Sour Taste pH < 7 Low pH -log[H3O] Hydrogen Donator H30 Proton donor Bases Slippery OH pH > 7 Proton Acceptor pH of 9 Hydrogen Acceptor -log[OH] Fill in the blank with the correct name. Bronsted-Lowry Definition is: The acid is the proton donor and the base is the proton acceptor. ( When water gains a proton it is called Hydronium and when it loses a proton it is called Hydroxide ) Lewis Definition is: The acid accepts an electron pair to form a covalent bond. The base donates an electron pair to form a covalent bond. Arrhenius Definition is: The acid releases H+ ions in (aq) solutions (HCl -> H+ + Cl) The base releases OH- ions in (aq) solutions ( NaOH -> Na+ + OH-). Also, acids and bases neutralize each other. Naming Binary and Tertiary Acids Name the given acids or write the chemical formula. ( ate = ic & ite = ous) 1) ____H3PO4____ = Phosphoric Acid 2) HF = ___Hydrofluoric Acid____ 3) Bromous Acid = ___HBrO2_____ 4) HNO3 = ______Nitric acid______ 5) _____H2CO3_____ = Carbonic Acid 6)HCl = _____Hydrochloric acid____ Acid-Base Reactions (in aqueous solutions) 1) HF + __H2O___ <------> H30 + F 2) HPO4 + H20 <------> H2PO4 + __OH__ 3) __NH3___ + H20 <-----> NH4 + OH 4) OH + HCN <-----> __H2O__ + CN Neutralization Reactions of Acids and Bases 1) HCl + NaOH <------> __NaCl__ + H20 2) HF + NAOH <----> __H2O__ + NaF 3) H2CO3 + __H2O__ <-------> HCO3 + H3O 4) H2O + __HCl__ <------> H30 + Cl pH/pOH and Hydronium/ Hydroxide Ion Concentrations ( round please) pH pOH [H3O] [OH] Acid or Base? 3 11 1 X 10^-3 1 X 10^-11 Acid 5 9 3.5 X10^-5 1 X 10^-9 Acid 6 8 1X 10^-6 1X 10^-8 Acid Titrations ( Fill in the Blank) The controlled ___addition___ and measurement of the amount of a solution of a known concentration required to react __completely____ with a measured amount of a solution of an _____unknown_____ concentration. Titration Problems 1) If 3 mL of 0.185mol/L of NaOH is used to neutralize HCl, what is the molarity of the acid solution. (0.185 mol/L) * ( 3.0 mL) = X * 80.0 .555 = x * 80.0 6.94 * 10^-3 = x 2) A teacher titrates a 10.00 mL sample of HBr with unknown molarity. The titration requires 10.05 mL of a 0.1726 M solution of NaOH. What is the molarity of the HBr solution? 10.05(0.1726)= 10(M) 1.73463/10=10M/10 M=0.1735 3)A flask is labeled 3.00M H2CO3. You decide to titrate a 15.00 mL sample with 1.85M NaOH. What volume of NaOh solution would you expect to use if the label is correct? H2CO3 + 2NaOH ----> Na2(CO3) + 2H2O 3.00 M = x Moles / 0.015 L = 0.045 moles 0.045 moles X (2 moles NaOH / 1 H2CO3) = 0.09 1.85 = 0.09 / x = 0.048mL x = 48.6 mL 4) An 8.00 ml sample of an H2SO4 is titrated with 40.5 ml of 0.150M KOH. What is concentration of the acid? H2SO4 + 2KOH ----> K2SO4 = 2H2O 0.150 M = x moles / 0.0405 L = 0.00607 0.00607 X (1 mol H2SO4 / 2 mol KOH) = 0.00303 mol 0.00303 / 0.008 = 0.379 M