Metal, Nonmetal, or Metalloid? Lab Background Elements have unique physical and chemical properties, which make them useful for specific purposes in our everyday world. All known elements can be classified as metals, nonmetals, or metalloids according to the substance’s specific physical and chemical properties. Physical properties are properties that can be observed without changing the identity of a substance, and chemical properties are properties that are observed while altering the identity of the substance involved. Metals and nonmetals are separated by the zigzag or stair-step line on the periodic table. Most elements are classified as metals, which are located from the center to the left side of the zigzag . Metals are elements that are usually silver-gray in color, with the exception of copper and gold. All metals are solid at room temperature except mercury, which is a liquid. Metals have a lustrous or shiny appearance and reflect light when polished. They can be bent or hammered flat (malleable), can be drawn into wire (ductile), are good conductors of heat and electricity, usually show reaction with acids, and generally have high melting points (many above 800 degrees C). Nonmetals are found to the right of the zigzag line on the periodic table. There are many fewer nonmetals than metals. Nonmetals are usually dull in appearance and do not reflect light. Many are brittle, and therefore cannot be hammered into sheets. Nonmetals are poor conductors of electricity and heat, show little or no reaction with acids, and generally have low melting points. At room temperature, nonmetals can exist as either solids or gases, with the exception of bromine, which is a liquid. Elements found along both sides of the zigzag line are called metalloids, with the exception of aluminum. Metalloids are elements that show properties of both metals and nonmetals. Metalloids are not good conductors of electricity; however, when mixed with small amounts of other elements, the conductivity of metalloids increases. Metal, Nonmetal, or Metalloid? Lab In this laboratory activity, a variety of physical and chemical properties of eight elements will be investigated, including color, luster, form, malleability, reaction with hydrochloric acid solution, reaction with cupric chloride solution, and electrical conductivity. The elements will then be classified as metals, nonmetals, or metalloids. It is important to note that although elements can be categorized and generalizations can be made, each element has its own unique properties. Thus there are many exceptions to the rules for classifying elements. Materials Elements, two small pieces (or a few crystals) of each: Aluminum Carbon Copper CuCl2, 0.1 M, 5 mL Iodine Magnesium Silicon Equipment Beral-type pipets, 2 Hammer or other hard, solid object Nail Pencil or pen Periodic table Zinc Sulfur HCl, 1 M, 5 mL Piece of white paper Spatula or forceps Test tubes, 8 Test tube rack Conductivity apparatus Safety Precautions Perform this lab activity in a well-ventilated laboratory. Iodine is toxic by ingestion and inhalation; it is corrosive to the skin, eyes, and the respiratory tract; avoid inhalation of iodine vapors by keeping the iodine bottle covered throughout the lab. Hydrochloric acids solution is corrosive to eyes and skin. Cupric chloride solution is toxic if ingested. Avoid contact of all chemicals with eyes and all body tissues. Wear chemical splash goggles, chemical-resistant gloves, and a chemical-resistant apron. Wash hands thoroughly with soap and water before leaving the laboratory. Metal, Nonmetal, or Metalloid? Lab Procedure and Pre-Lab Preparation 1. Using a periodic table, determine the chemical symbol for each of the eight elements to be tested in this laboratory. Fill in the chemical symbol for each element on the data table. 2. Obtain one well plate. Place a small amount of each sample into the appropriate wells in your well plate. (Note: Use only the tip of the scoopula for obtaining your sample. Do not touch any of the elements with your hands.) See diagram below for sample locations. WELL PLATE: aluminum aluminum carbon carbon copper copper sulfur sulfur silicon silicon magnesium magnesium zinc zinc (empty) (empty) (empty) (empty) (empty) (empty) (empty) (empty) (empty) (empty) Part 1. Physical Properties 3. Observe and record the color of each element in the Data Table. Is the sample silver, gray, colored, etc. …? Be very specific in recording observations. 4. Observe and record the luster of each element in the Data Table. Is the sample lustrous and shiny, slightly shiny, dull? 5. Record any other physical properties that are observed about each element in the Data Table. Be specific in your observations. What form is the sample in? Is the sample crystalline, flaky, rough, smooth, flat and plate-like, rocky, in strips? Is there any odor or are any vapors given off? (Note: Avoid breathing any vapors directly. Instead of smelling a sample directly, waft the vapors from the sample toward your nose.) 6. COMPLETE ON THE CENTER LAB TABLE. YOU MAY SKIP THIS STEP AND GO BACK TO IT IF THE CENTER TABLE HAS A LAB GROUP ALREADY THERE. Determine whether each element is malleable or brittle. To do this, position a nail on the sample and gently tap the nail with a hard, solid object. A material is malleable if it flattens or bends without shattering. A sample is brittle if it shatters or cracks into pieces when struck. Record your results in the Data Table. Metal, Nonmetal, or Metalloid? Lab 7. When a conductivity tester is available, use it to test the conductivity of the seven samples. Touch both electrodes to the element being tested, being sure that the electrodes are not touching each other. If the bulb lights dimly, the sample is a weak electrical conductor. If the bulb fails to light, the material is a nonconductor of electricity. Record your results in the Data Table. (Caution: Avoid touching the electrodes with your hands—an electric shock may result.) Part 2. Chemical Properties 8. Determine the reactivity with acid of each sample by adding one pipetful (about 2-3 mL) of 1 M hydrochloric acid (HCl) to ONLY ONE WELL of each substance. (Note: Evidence for a chemical reaction may be the formation of gas bubbles and/or discoloration on the surface of the element. Some reactions may be slow to start—be patient.) 9. Observe each well for approximately 3-5 minutes and record results in the Data Table. 10. Determine the reactivity with cupric chloride solution of each sample by adding one pipetful (about 2-3 mL) of 0.1 M cupric chloride solution (CuCl2) to the REMAINING WELL for each substance. 11. Observe each well for approximately 3-5 minutes and record results in the Data Table. Disposal Pour the contents of your well plate into the waste container provided by your teacher. Use a wash bottle to rinse any solid residue from the wells. Thoroughly wash well plate. Metal, Nonmetal, or Metalloid? Lab Post-Lab Questions 1. Review the data gathered for the eight elements. Sort the eight elements into groups, based on similarities and differences in their physical and chemical properties. From the information provided in the background reading, classify each group as metals, nonmetals, or metalloids. DO NOT USE YOUR PERIODIC TABLE. USE YOUR DATA. Metals Metalloids Nonmetals __ 2. Are there any inconsistencies within the groups you made? Do any elements seem to have properties of both groups? Which? Explain. 3. Look at the location on the periodic table of each of the eight elements tested in this lab. How do the properties of these elements compare to their general position on the periodic table? Make generalizations about the position of the metals, nonmetals, and metalloids on the periodic table. 4. Predict the physical and chemical properties of the following elements which were not tested in this lab—selenium, calcium, and cobalt. 5. Putting it all together: Complete the table below. Metal, Nonmetal, or Metalloid? Lab Metals General Location on Periodic Table Luster (Shininess) Malleability (Ability to be dented) Conductivity (Ability to conduct electricity) Color Nonmetals Metalloids