科目名 Course Title
Physico-chemical Properties of High Temperature Materials [耐熱材料学 E]
講義題目 Subtitle
責任教員
Instructor
黒川 一哉 [Kazuya KUROKAWA] (大学院工学研究院附属エネルギー・マテリアル融合領域
研究センター)
担当教員 Other
Instructors
開講年度 Year
2013
時間割番号 Course Number (E3)
092078 (36009)
開講学期 Semester
２学期
単位数
2
Number of Credits
補足事項 Other Information
キーワード Key Words
High Temperature Materials, Point Defect in Oxide, Transport Property of Oxide, Oxidation Mechanism
授業の目標 Course Objectives
The development of alloys is usually aimed at improving oxidation resistance, as well as improving mechanical
properties. In this course, to acquire basic knowledge of thermodynamics and kinetics in the reactions of metals
and alloys with gaseous environments at high temperatures is aimed. In particular, oxidation mechanism of metals
and alloys is discussed on the basis of fundamental parameters of oxides such as point defect structures and
transport properties of oxide scales. The final goal of this course is to acquire basic skills which can be utilized to
analyze oxidation mechanism of metals and alloys and design new oxidation-resistant materials.
到達目標 Course Goals
授業計画 Course Schedule
1. Outline of High Temperature Materials
1-1. Mechanical and physical properties
1-2. Chemical properties
1-3. Recent and future high temperature materials
2. Reaction Path
2-1. Metal-oxygen phase diagrams
2-2. Reaction path in oxidation
3. Defect Structures of Oxides
3-1. Point defects in oxides
3-2. Negative and positive semiconductors
3-3. Formation of point defects
3-4. Oxide doping
4. Transport mechanism in Oxide Scales
4-1. Diffusion of cations and anions in oxide scales
4-2. Marker measurement
5. Oxidation of Metals and Alloys
5-1. Basic thermodynamics
5-2. Oxidation kinetics
5-3. Wagner theory of oxidation
5-4. Actual oxidation process
6. Recent Topics
Reading of papers dealing with recent topics on high temperature materials
準備学習（予習・復習）等の内容と分量 Homework
成績評価の基準と方法 Grading System
based on the results of reports and final examination
テキスト・教科書 Textbooks
handouts are provided at each lecture.
講義指定図書 Reading List
参照ホームページ Websites
研究室のホームページ Website of Laboratory
備考 Additional Information
basic thermodynamics