Danfoss Negative List of Chemicals March 2014 Danfoss’ Negative List bans or restricts the use of chemical substances in Danfoss’ products and production processes and by Danfoss’ suppliers, contractors and tenants. The Negative List is valid for the entire Danfoss Group including but not limited to Power Solutions and Climate & Energy. This Negative List has been generated on the basis of the European Chemical legislation but the bans and restrictions are applicable worldwide. Only stricter local legislation than the European chemical legislation overrules this list. This Negative List shall be complied with throughout the entire Danfoss Group and by all tenants, suppliers and contractors working on Danfoss premises or supplying parts and materials to Danfoss. Requirements for suppliers and contractors Suppliers and subcontractors to Danfoss are required to comply with the Negative List and shall on request be able to document the type and amount of any hazardous substances present in materials, subassemblies or components and used in processes. Suppliers must proactively inform Danfoss about the presence of Candidate List substances above a concentration of 0.1 w/w %. Suppliers and subcontractors must not supply products, components or materials to Danfoss containing banned substances listed on the Negative List. Suppliers and subcontractors must not use any chemicals listed on the Negative List in processes manufacturing parts for Danfoss. If new substances are put on the Negative List, all suppliers and subcontractors must ensure that the new substance is removed from products delivered to Danfoss within a time period not exceeding one year. Requirements for tenants and their suppliers Contractors, tenants or their suppliers working on Danfoss’ owned property must not bring substances listed on the Negative List onto Danfoss premises. Keep up to date with changes to the Negative List All suppliers, subcontractors, contractors, tenants or their suppliers working on Danfoss’ owned property are responsible for keeping themselves updated with the current version of the Negative List. The Danfoss Negative List in force at any given time is available on HERE. All suppliers, subcontractors, contractors and tenants shall register themselves on the above webpage as recipient of updates to the Danfoss Negative List and remain registered for the term of the co-operation. Danfoss Negative List of Chemicals Metals (see also REACH Annex XIV in this document) CAS no. 1 7440-38-2 All, e.g.: 7784-40-9 15606-95-8 7440-43-9 Substance 2 Arsenic All Arsenic compounds (e.g. below) Lead hydrogen arsenate Triethyl arsenate Cadmium All All Cadmium compounds 7738-94-5; 13530-682; 1333-82-0; 778900-6; 7778-50-9; Chromium 6+ compounds 7789-12-0; 10588-019; 7439-92-1 All, e.g.: 77-58-7 1067-33-0 1118-46-3 15546-11-9 26401-86-5 26636-01-1 56-35-9 7440-28-0 All, e.g.: 563-68-8 7446-18-6 7791-12-0 March 2014 Occurrence 4 Legislation 5 E, T Pb and Cu alloys, metal adhesives, soft solders, electronics and pigments Annex XVII. See also Annex XIV C, E Stabilizers in polymers like PVC, Used in pigments in paints and plastics, present also in electronics. In soldering materials Annex XVII RoHS C, E Chromium pigments, chromated surfaces, corrosion inhibitors. Annex XIV RoHS T, N, E Lead as an element in metals and alloys, lead compounds (stabilizers), pigment, corrosion inhibitor N, E In lamps, electric switches, luminescent materials Lead 7758-97-6; 12656-858; 7784-40-9;1344Lead compounds 37-2 7439-97-6 Mercury All Risk 3 All Mercury compounds All Organotin (Mono-, di-, and trialkyl and -aryl tin compounds) (e.g. below) dibutyltin dilaurate (DBTL) dibutyltin diacetate butyltin trichloride (MBTC) e.g.dibutyltin bis(metylmaleate) octyltin tris(isooctyl mercaptoacetate) dimetyltin bis(isooctyl mercaptoacetate) bis(tributyltin)oxide (TBTO) Thallium All Thallium compounds (e.g. below) thallium acetate thallium sulphate thallium chloride E T, E Danish reg. no. 856/2009; RoHS Packaging dir. See also Annex XIV Danish reg. no. 627/2003; RoHS In plasticizers and metals Annex XVII Biocide in wood Candidate List Max allowable concentration 6 Comments/exemptions 7 Arsenic is prohibited as a salt/compound but not as a metallic element in an alloy. 0.01% Cd in PVC (recovered PVC: 0.1%). Cd in soldering materials (brazing fillers) max. 0.01%. In paint on products 0.1% Restricted in electronic and electric parts (Exemption: Electrical contacts). Also restricted in packaging as pollution Lead is prohibited as a salt/compound and not as a metallic element in an alloy in non-electrical equipment. 0,1% DK: See exemptions in the regulation Semiconductors, thermometers and optical Danfoss instruments, photometdecision rical cells, in solutions and as catalyst Page 2 Danfoss Negative List of Chemicals Lubricants and additives, degreasing agents, corrosion inhibitors8 (see also REACH Annex XIV in this document) CAS no. 1 Risk 3 Occurrence 4 Legislation 5 Max allowable concentration 6 C Corrosion protection, pH stabilizer TRGS 611; 615 0.2% All Substance 2 All Amines (secondary) which facilitate the formation of nitrosamines (e.g. below) diethanolamine Formaldehyde All Formaldehyde releasing substances (e.g. below) 2-Bromo-2-nitro-1,3-propanediole (bronopol) Trihydroxymethylnitromethane 4-(2-Nitrobutyl)-morpholine 4,4´-Dimethyleoxazolidine Methylene-bis-morpholine/Bis-morpholinomethane All Isothiazolones A Biocide in lubricants All All Mercaptobenzothiazoles A Biocide in lubricants All, e.g.: 50-32-8 All Mineral oil with PAH (e.g. below) benzo-(a)-pyrene (as a PAH) DMSO extract as a measuring method for PAH Morpholine All Morpholine releasing substances All Nitrite All Nonylphenols (e.g. below) 4-nonylphenol nonylphenol 4-nonylphenol branched All Nonylphenol ethoxylates C C Base oils C Biocide in lubricants C Corrosion protection E, R Surface active agents Annex XVII Tall oil distillates which contains adipinic acid A Extreme pressure additive Danfoss decision All, e.g.: 111-42-2 50-00-0 All, e.g.: 52-51-7 126-11-4 2224-44-4 5100-87-4 5625-90-1 110-91-8 All All All, e.g.: 104-40-5 25154-52-3 84852-15-3 All March 2014 0.005% free formaldehyde C, A Comments/exemptions 7 See also Formaldehyde in general below. Biocide in lubricants Danfoss decision 0.2% New products must not contain these substances New products must not contain these substances. A maximum allowable concentration cannot be set. 0.005% (50 ppm) Benz(a)pyren 3% DMSO extract for the base oil 0.002% (20ppm) nitrite New products must not contain these substances. A maximum allowable concentration cannot be set Only prohibited in lubricants and degreasing agents All use according to Annex XVII is banned. See also nonylphenol below Page 3 Danfoss Negative List of Chemicals Impregnation and dye (see also REACH Annex XIV in this document) CAS no. 1 Substance 2 All All Azo Dye Risk 3 C, E 8001-58-9 Creosote All All All, e.g.: 1330-78-5 78-30-8 78-32-0 All Cresylphosphates All Dicresylphosphates All Tricresylphosphates (TCP) (e.g. below) Tricresylphosphate (all isomers including ortho) Tri(ortho)cresylphosphate Tricresylphosphate (all isomers except ortho) 624-49-7 Dimethyl fumarate (T), E T, E E A Occurrence 4 In dyes for textiles etc., packaging materials In wood preservatives, packaging materials Legislation 5 Max allowable concentration 6 Annex XVII 0.003% (30ppm) Comments/exemptions 7 Stokholm Conv. Plasticizer additives in nitrocellulose, PVC, flame Danfoss deciretardant, additive in oils, sion acrylate lacquers, varnishes. Ortho-TCP: 0.5%. The sum of Meta- and Para-TCP: 5%. The substance is normally used as an additive to silica gel sold in small packs. The packs release Annex XVII DMFu during transport of entry 61 products in order to avoid mold, mostly in furniture, textiles and footwear Banned in EU in 2009 Green House gases (see also REACH Annex XIV in this document) CAS no. 1 Substance 2 All, e.g.: All HFC (Hydrofluorocarbons) (e.g. below) 811-97-2 R-134a 75-37-6 431-89-0 R-152a R-227a 74-83-9 Methylbromide All All PFC (Perfluorocarbons) 2551-62-4 SF6 (Sulfurhexafluoride) Risk 3 E March 2014 Occurrence 4 Legislation 5 In heat pumps, refrigeration and air-conditioning and sprays (EU 842/2006) In spray containers for testing print boards shall follow the local phase out Kyoto schedule. In Denmark this Protocol particular use is allowed until further notice (DK reg. 552/2002) Kyoto; EU no. 2037/2000 For PFC: also in fire extinguisher and equipment. Danish reg. no. 552/2002 and EU no. 2034/2000 Max allowable concentration 6 Comments/exemptions 7 In Denmark: Only fillings larger than 10 kg in refrigeration systems, heat pumps and air conditioning systems and fillings larger than 50 kg in ventilation plants are prohibited. (Reg. 552). Outside DK HFC is not prohibited but there are like in Denmark regulations for containment, recovery, certification, reporting, labeling Use are not allowed after December 31- 2005 Kyoto Protocol Page 4 Danfoss Negative List of Chemicals Ozone depleting substances (see also REACH Annex XIV in this document) CAS no. 1 353-59-3 75-63-8 124-73-2 All, e.g.: 75-69-4 75-71-8 75-72-9 76-13-1 76-14-2 76-15-3 All, e.g.: 75-45-6 75-68-3 Substance 2 Bromochlorodifluoromethane (R-1211) Bromotrifluoromethane (R-1301) 1,2-dibromotrafluoroethane (R-2402) All CFC (Chlorofluorocarbons) (e.g. below) Trichlorofluoromethane (R-11) Dichlorodifluoromethane (R-12) Chlorotrifluoromethane (R-13) 1,1,2-Trichlorotrifluoroethane (R-113) Dichlorotetrafluoroethane (R-114) Monochloropentafluoroethane (R-115) All HCFC (Hydrochlorofluorocarbons) (e.g. below) Monochlorodifluoromethane (R-22 ) Monochlorodifluoroethane (R-142b) 1717-00-6 Dichlorofluoroethane (R-141b) Risk 3 Occurrence 4 Legislation 5 Montreal Protocol O, E In cleaning agents, refrigerants, propellants in aerosol spray, blowing agents for making foam and in air-condition system. Max allowable concentration 6 EPA Ozone Layer protection Comments/exemptions 7 Until December 31st, 2014 reclaimed hydrochloroflourocarbons may be used for the maintenance or servicing of existing refrigeration, air-conditioning and heat pump equipment, provided that the container is labeled with an indication that the substance has been reclaimed and with information on the batch number and name and address of the reclamation facility (Article 11 item 3) Solvents, aromatic and chlorinated (see also REACH Annex XIV in this document) CAS no. 1 71-43-2 56-23-5 108-90-7 75-09-2 127-18-4 12002-48-1; 120-82-1 71-55-6; 79-00-5 79-01-6 Substance 2 Benzene Carbontetrachloride Chlorobenzene Methylenechloride Tetrachloroethylene ("PER") Trichlorobenzene Trichloroethane (1,1,1-) Trichloroethylene ("TRI") Risk 3 C, E O , C, E Occurrence 4 Legislation 5 Max allowable concentration 6 Comments/exemptions 7 Except in gasoline Annex XVII Solvent, degreasing agent C,E Danfoss decision Annex XVII Danish 243/2002 Except in thermo bulbs for fire-extinguishing equipment Monomers and Plasticizers (see also REACH Annex XIV in this document) CAS no. 1 107-13-1 106-99-0 75-01-4 March 2014 Substance 2 Acrylonitrile Butadiene (1,3 -) Vinylchloride Risk 3 Occurrence 4 Monomer in ABS and other copolymers Monomer in PVC and other copolymers Legislation 5 Danfoss decision Max allowable concentration 6 Comments/exemptions 7 The plasticizers are mentioned in the group called "REACH Annex XIV" Page 5 Danfoss Negative List of Chemicals Flame retardants (see also REACH Annex XIV in this document) CAS no. 1 32536-52-0 32534-81-9 All, e.g.: 36355-01-8; 2785807-7; 13654-09-6 All, e.g.: 40088-47-9; 3253481-9; 36483-60-0; 68928-80-3; 3253652-0; 63936-56-1; 1163-19-5 Substance 2 Octabromodiphenylethers Pentabromodiphenylethers Risk 3 Occurrence 4 Legislation 5 Max allowable concentration 6 Comments/exemptions 7 EU 2003/11 Polybrominated biphenyls (PBB) E, R In electronic and electrical parts, in plastics and polymers etc. RoHS Iee also A RCA Rnnel eSS Polybrominated diphenylethers (PBDE) Persistent Organic Pollutants (POP) (see also REACH Annex XIV in this document) CAS no. 1 All, e.g.: 309-00-2 57-74-9 50-29-3 All 60-57-1 All 115-29-7 72-20-8 76-44-8 118-74-1 2385-85-5 1336-36-3 87-86-5 Substance 2 All POP (e.g. below) Aldrin Chlordan DDT Dibenzofuranes Dieldrin Dioxins Endosulfan Endrin Heptachlor Hexachlorobenzene Mirex PCB Pentachlorophenol Risk 3 All PFOS (Perfluoro octylsulfonates) E All 8001-35-2 75635-23-3 PFOA (Perfluorooctanoic acids) Toxaphene Trifluralin E March 2014 Occurrence 4 Legislation 5 Insecticide Stockholm Convention Max allowable concentration 6 Comments/exemptions 7 C, E E All use is banned, except in wood treatment C, E C, E In fire extinguishing equipment, surface treatment Surface treatment Pesticide Annex XVII 0.005% in preparations; 0.1% in articles Annex XVII Stockholm Convention Page 6 Danfoss Negative List of Chemicals Nonylphenols (see also REACH Annex XIV in this document) CAS no. 1 All, e.g.: 104-40-5 25154-52-3 84852-15-3 All Substance 2 All Nonylphenols (e.g. below) 4-nonylphenol Nonylphenol 4-nonylphenol branched Nonylphenolethoxylate Risk 3 Occurrence 4 Legislation 5 Max allowable concentration 6 Comments/exemptions 7 E, R In cleaning agents Annex XVII Occurrence 4 Paper products, cleaners, disinfectants, textile materials intended for skin contact Legislation 5 Max allowable concentration 6 Comments/exemptions 7 Danfoss decision 0.15% Restricted in its own, in preparations or released from materials. See also lubricants See also lubricants Formaldehyde (see also REACH Annex XIV in this document) CAS no. 1 Substance 2 Risk 3 50-00-0 Formaldehyde A, C, E Asbestos (see also REACH Annex XIV in this document) CAS no. 1 77536-66-4 12172-73-5 77536-67-5 12001-29-5 12001-28-4 Substance 2 Actinolite Amosite Anthophyllite Chrysotile Crocidolite 77536-68-6 Tremolite Risk 3 C Occurrence 4 Legislation 5 Max allowable concentration 6 EU Directive In insulating material in on Marketing buildings and in products. and use of Severe precautions certain should be taken in refurdangerous bishing asbestos contain- substances and ing buildings preparations (asbestos) Comments/exemptions 7 All use is banned. E.g. Insulating material. In production of articles such as gaskets, brake linings etc. Mineral wool fibers (see also REACH Annex XIV in this document) CAS no. 1 Substance 2 Risk 3 Manmade mineral fibers with proven C effects All C Aluminosilicate, Refractory Ceramic Fibres Zirconia Aluminosilicate, Refractory Ceramic Fibres March 2014 Occurrence 4 Legislation 5 Danish gorking nvironment Ruthorities Max allowable concentration 6 Comments/exemptions 7 Insulating materials in buildings are exempted Applies to work processes where there is a risk of exposure to respirable fibers Candidate List Page 7 Danfoss Negative List of Chemicals Radioactive substances CAS no. 1 Substance 2 Risk 3 All Radioactive substances C Occurrence 4 Legislation 5 Max allowable concentration 6 Comments/exemptions 7 ldNo thresho PAH (Poly Aromatic Hydrocarbons) (see also REACH Annex XIV in this document) CAS no. 1 All, e.g.: 50-32-8 53-70-3 56-55-3 191-24-2 192-97-2 193-39-5 205-82-3 205-99-2 207-08-9 218-01-9 Substance 2 All PAH (e.g. below) Benzo(a)pyrene Dibenzo(a,h)anthracene Benzo(a)anthracene Benzo(ghi)perylene Benzo(e)pyrene Indeno(1,2,3-cd)pyrene Benzo(j)fluoranthene Benzo(b)fluoranthene Benzo(k)fluoranthene Chrysene Risk 3 Occurrence 4 Legislation 5 Max allowable concentration 6 Comments/exemptions 7 0.0001% (1ppm) C, E Softening oils in rubber compounds/chemicals and as pollutants in many materials Annex XVII Sum of all PAH: 0.001% (10ppm) In rubber compounds/chemicals See also "Lubricants" The following substances are prohibited if they are not documented to be conflict-free. Conflict minerals CAS no. 1 Substance 2 Several Conflict minerals from DR Congo or adjoining countries. The minerals include gold, tin, tantalum and tungsten or their derivatives. March 2014 Risk 3 Legislation 5 Wall Street Reform and Consumer Protection Act. Section 1502 Comments/exemptions 7 Suppliers are required to supply materials to Danfoss that are DRC Conflict-Free. DRC includes the countries of Democratic Republic of Congo, Republic of Congo, Central Africa Republic, South Sudan, Zambia, Angola, Tanzania, Burundi, Rwanda and Uganda. Suppliers are required to adopt policies and management systems with respect to conflict minerals and to require their suppliers to adopt similar policies and systems. Page 8 Danfoss Negative List of Chemicals REACH (Annex XIV) CAS no. 1 Substance 2 Risk 3 Occurrence 4 Sunset date Latest application date 7738-94-5, 13530-68-2 Acids generated from chromium trioxide and their oligomers. Names of the acids and their oligomers: Chromic acid, Dichromic acid, Oligomers of chromic acid and dichromic acid. C 21-09-2017 7789-09-5 Ammonium dichromate C, M 1333-82-0 Chromium trioxide C and R 7789-00-6 Potassium chromate C and M 7778-50-9 Potassium dichromate C, M and 7775-11-3 Sodium chromate C, M and R 7789-12-0, 10588-01-9 Sodium dichromate C, M and R Acids generated from chromium trioxide and their oligomers are mainly used in metal finishing, such as electroplating (e.g. hard chrome and decorative plating), conversion coatings and brightening. It is also used as a fixing agent in waterborne wood preservatives. Minor uses are e.g. in the manufacture of pigments and paints, in catalyst and detergent manufacture, and as an oxidizing agent. Ammonium dichromate is mainly used as an oxidizing agent. Other known uses are in the manufacture of photosensitive screens and as mordant in the manufacture of textiles. Minor uses seem to comprise metal treatment and laboratory analytical agent Chromium trioxide is mainly used in metal finishing, such as electroplating (e.g. hard chrome and decorative plating), conversion coatings and brightening. It is also used as a fixing agent in waterborne wood preservatives. Minor uses are e.g. in the manufacture of pigments and paints, in catalyst and detergent manufacture, and as an oxidizing agent. Potassium chromate is used as a corrosion inhibitor for treatment and coating of metals, for manufacture of reagents, chemicals and textiles, as a coloring agent in ceramics, in the manufacture of pigments/inks and in the laboratory as analytical agent. Potassium dichromate is used for chrome metal manufacturing and as corrosion inhibitor for treatment and coating of metals. It is further used as textile mordant, as laboratory analytical agent, for cleaning of laboratory glassware, in the manufacture of other reagents and as oxidizing agent in photolithography. Sodium chromate is mainly used as an intermediate in the manufacture of other chromium compounds as well as a laboratory analytical agent, but this use is limited. Other potential uses are mentioned in the literature but whether they occur in the EU is not clear. This substance is an important reagent for the production of a wide range of chemicals. It is aso used in metal finishing process, leather tanning and in some ceramics / glasses. This substance is very unlikely to be present in articles above 0.1% except in some coloured glazes and glasses. The latter are more likely to be found in craft / specialised articles than general purpose ceramics and glasses. Trichlororethylene is mainly used as intermediate in the manufacture of chlorinated and fluorinated organic compounds. Other uses are for cleaning and degreasing of metal parts or as solvent in adhesives. 79-01-6 March 2014 Trichloroethylene C Comments/exemptions 7 21-03-2016 Always check for the latest Annex XIV updates on the ECHA homepage. Some of these substances are also present on Annex XVII. 21-09-2017 21-03-2016 21-09-2017 21-03-2016 21-09-2017 21-03-2016 21-09-2017 21-03-2016 21-09-2017 21-03-2016 21-09-2017 21-03-2016 21-04-2016 21-10-2014 Substitution of Annex XIV substances shall be initiated as soon as possible – preferably at the point where the substance was added to the Candidate List. Always check for the latest Annex XIV updates on the ECHA homepage. Some of these substances are also present on Annex XVII. Substitution of Annex XIV substances shall be initiated as soon as possible – preferably at the point where the substance was added to the Candidate List. Page 9 Danfoss Negative List of Chemicals REACH (Annex XIV) 3194-55-6, 25637-99-4, 134237-50-6, 134237-51-7, 134237-52-8 121-14-2 115-96-8 1303-28-2 Hexabromocyclododecane (HBCDD), alpha-hexabromocyclododecane, beta-hexabromocyclododecane, gamma-hexabromocyclododecane PBT 2,4 – Dinitrotoluene (2,4-DNT) Tris(2-chloroethyl)phosphate (TCEP) Diarsenic pentaoxide C R C 1344-37-2 Lead sulfochromate yellow (C.I. Pigment Yellow 34) Diarsenic trioxide Lead chromate C, R Lead chromate molybdate sulphate red (C.I. Pigment Red 104) Benzyl butyl phthalate (BBP) Bis(2-ethylhexyl) phthalate (DEHP) Dibutyl phthalate (DBP) Diisobutyl phthalate (DIBP) 5-tert-butyl-2,4,6-trinitro-m-xylene (Musk xylene) 4,4’-Diaminodiphenylmethane (MDA) 1327-53-3 7758-97-6 12656-85-8 85-68-7 117-81-7 84-74-2 84-69-5 81-15-2 101-77-9 Flame retardant 21-08-2015 21-02-2014 For the production of toluene diisocyanate. Plasticizer with flame-retarding properties The substance is very unlikely to be present in articles above 0.1% except for old optical glass Used in paint for rubber, plastic and in varnishing products. 21-08-2015 21-08-2015 21-02-2014 21-02-2014 21-05-2015 21-11-2013 21-05-2015 21-11-2013 21-05-2015 21-11-2013 21-05-2015 21-11-2013 C, R In lead alloys, glass, electronics In pigments and dyes in industrial and maritime paint products or varnish Used in paint for rubber, plastic and in varnishing products. 21-05-2015 21-11-2013 R R R R vPvB Plasticizer in PVC Plasticizer in PVC Plasticizer and additive in adhesives or printing inks Plasticizer Perfume, fragrance 21-02-2015 21-02-2015 21-02-2015 21-02-2015 21-08-2013 21-08-2013 21-08-2013 21-08-2013 21-08-2014 21-02-2013 C A hardener used in the production of rubber, plastics, adhesives. Not 21-08-2014 likely to be present above 0.1% in a supplied article. 21-02-2013 C C, R The substances on the Candidate List are not prohibited unless also mentioned on Annex XIV or XVII, but if the concentration is above 0.1%, information must be provided to the recipient of the chemical or article. Please always check for the latest update on the ECHA homepage. REACH Candidate List (sorted by inclusion date and then by substance name) CAS no. 1 1306-23-6 84-75-3 573-58-0 Risk 3 C R C Occurrence 4 Pigment for ceramics and glass and in photo electronic applications such as solar cells. This phthalate is used as a plasticizer for PVC Direct Red 28 is a benzidine-based dyes Date of inclusion 16-12-2013 16-12-2013 16-12-2013 C Direct Black 38 is a benzidine-based dye 16-12-2013 96-45-7 301-04-2 Substance 2 Cadmium sulphide Dihexyl phthalate Disodium 3,3'-[[1,1'-biphenyl]-4,4'-diylbis(azo)]bis(4aminonaphthalene-1-sulphonate) (C.I. Direct Red 28) Disodium 4-amino-3-[[4'-[(2,4-diaminophenyl)azo][1,1'-biphenyl]-4yl]azo] -5-hydroxy-6-(phenylazo)naphthalene-2,7-disulphonate (C.I. Direct Black 38) Imidazolidine-2-thione; (2-imidazoline-2-thiol) Lead di(acetate) R R 16-12-2013 16-12-2013 25155-23-1 - Trixylyl phosphate 4-Nonylphenol, branched and linear, ethoxylated R E, R This substance is used as a vulcanisation agent and in the production of tyres and general rubber goods This substance may be found in paints and coatings, fillers and plasters, as an intermediate and as a laboratory reagent Flame retardant Cleaning agents 1937-37-7 March 2014 16-12-2013 20-06-2013 Page 10 Danfoss Negative List of Chemicals REACH Candidate List (sorted by inclusion date and then by substance name) CAS no. 1 3825-26-1 7440-43-9 Substance 2 Ammonium pentadecafluorooctanoate (APFO) Cadmium Risk 3 R C 1306-19-0 Cadmium oxide C 131-18-0 335-67-1 69011-06-9 84777-06-0 Dipentyl phthalate (DPP) Pentadecafluorooctanoic acid (PFOA) [Phthalato(2-)]dioxotrilead 1,2-Benzenedicarboxylic acid, dipentylester, branched and linear R R R R 629-14-1 1,2-Diethoxyethane R 106-94-5 1-bromopropane (n-propyl bromide) R 143860-04-2 - 3-ethyl-2-methyl-2-(3-methylbutyl)-1,3-oxazolidine 4-(1,1,3,3-tetramethylbutyl)phenol, ethoxylated <i>[covering welldefined substances and UVCB substances, polymers and homologues]</i> R E 838-88-0 101-80-4 4,4'-methylenedi-o-toluidine 4,4'-oxydianiline and its salts C C;M 60-09-3 4-Aminoazobenzene C 95-80-7 4-methyl-m-phenylenediamine (toluene-2,4-diamine) C - E 120-71-8 51404-69-4 4-Nonylphenol, branched and linear <i>[substances with a linear and/or branched alkyl chain with a carbon number of 9 covalently bound in position 4 to phenol, covering also UVCB- and well-defined substances which include any of the individual isomers or a combination thereof]</i> 6-methoxy-m-toluidine (p-cresidine) Acetic acid, lead salt, basic 92-67-1 Biphenyl-4-ylamine C March 2014 C R Occurrence 4 Cleaning agents Nickel- cadmium batteries, Pigments for plastics, Low melting alloys, Electroplating, Solder, Semiconductors, Stabilizers in PVC Nickel- cadmium batteries, Pigments for plastics, Low melting alloys, Electroplating, Solder, Semiconductors, Stabilizers in PVC Plasticiser Cleaning agents Stabiliser used in production of pvc products This phthalate may be used as a plasticiser for plastic materials. It was not registered for the 2010 deadline and thus is thought to be in low usage in the EEA. However, it may be present in imported plastic articles. This substance is a glycol ether and belongs to the glyme family of chemicals and is expected to have similar applications; monoglyme, diglyme and triglyme are also included on the Candidate List. Globally, common uses for glycol ethers are as a solvent in formulations such as paints, inks and cleaning fluids. They may be used in fabric cleaning compounds such as dry powder carpet cleaner, in stain removers, in mildew removers, oven cleaners and multi-purpose detergents. Non-solvent uses for glycol ethers include hydraulic and brake fluids, anti-icing agents and as chemical intermediates. This substance was not registered for the 2010 deadline and is thus thought to be in low usage in the EEA. This substance has been registered for REACH. According to the dissemination portal, it is used as an industrial solvent, surface cleaner and degreasing agent. Used in electronics industry for cleaning circuit boards. The chemical’s proposed use is in high-solids polyurethane coatings as a reactive This is part of the alkyl phenol ethoxylate group of substances used in detergents, inks, etc and have been voluntarily removed from the market by many companies. One concern is endocrine effects from environmental release. Found in printed papers, especially glossy printing from outside Europe. Degradation product of 'alkyl phenol ethoxylates' that may themselves be polymers (higher ethoxylates) and no-longer polymer (lower level of ethoxylation). Also found in some oil additives. Can also be residual on imported textiles. This substance is used as an intermediate in the production of elastomers, dyes and colourants. Production of polymers such as polyimides for uses in wiring, printed circuits, and other high temperature applications. Residues may remain in articles of this nature. Also known as aniline yellow, CI 11000 or under many other common historical names. This chemical was implicated in the 1980s vegetable oil poisoning incident when added to industrial oil that was put into the food market. It is used in many industrial dying activities, markers and in some ink-jet printers. Used mainly as an intermediate, but also may appear as residue in polyurethane foams from polymer production This is part of the alkyl phenol ethoxylate group of substances used in detergents, inks, etc and have been voluntarily removed from the market by many companies. One concern is endocrine effects from environmental release. Found in printed papers, especially glossy printing from outside Europe. Degradation product of 'alkyl phenol ethoxylates' that may themselves be polymers (higher ethoxylates) and no-longer polymer (lower level of ethoxylation). Also found in some oil additives. Can also be residual on imported textiles. Used in dying of textiles and leather goods. Lead acetate is used in dying and pigmentation aid for textiles, hair products, paints etc. Use in Europe restricted under regulations on use of lead, but may be found in imported products, especially painted ornamental goods Starting chemical for many azo dyes and will be a residue from production or may even form as a metabolite (breakdown product) from certain materials. Possible residue in textiles and coloured materials Date of inclusion 20-06-2013 20-06-2013 20-06-2013 20-06-2013 20-06-2013 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 Page 11 Danfoss Negative List of Chemicals REACH Candidate List (sorted by inclusion date and then by substance name) CAS no. 1 1163-19-5 Substance 2 Bis(pentabromophenyl) ether (decabromodiphenyl ether; DecaBDE) 85-42-7, 13149-003, 14166-21-3 123-77-3 Cyclohexane-1,2-dicarboxylic anhydride [1], cis-cyclohexane-1,2dicarboxylic anhydride [2], trans-cyclohexane-1,2-dicarboxylic anhydride [3] <i>[The individual cis- [2] and trans- [3] isomer substances and all possible combinations of the cis- and trans-isomers [1] are covered by this entry]</i> Diazene-1,2-dicarboxamide (C,C'-azodi(formamide)) 683-18-1 Dibutyltin dichloride (DBTC) Serious effects to human health R 64-67-5 605-50-5 Diethyl sulphate Diisopentylphthalate C;M R 77-78-1 Dimethyl sulphate C 88-85-7 Dinoseb (6-sec-butyl-2,4-dinitrophenol) R 12578-12-0 91031-62-8 110-00-9 Dioxobis(stearato)trilead Fatty acids, C16-18, lead salts Furan R R C 2058-94-8 Henicosafluoroundecanoic acid vPvB 376-06-7 Heptacosafluorotetradecanoic acid vPvB 25550-51-0, 1943860-9, 48122-14-1, 57110-29-9 Hexahydromethylphthalic anhydride [1], Hexahydro-4-methylphthalic anhydride [2], Hexahydro-1-methylphthalic anhydride [3], Hexahydro3-methylphthalic anhydride [4] <i>[The individual isomers [2], [3] and [4] (including their cis- and trans- stereo isomeric forms) and all possible combinations of the isomers [1] are covered by this entry]</i> Serious effects to human health March 2014 Risk 3 Occurrence 4 Date of inclusion PBT; vPvB One of a family of brominated fire retardants used in plastics and foams. These chemicals can leach out of 19-12-2012 plastics, especially during recycling activities and are functionally very persistent and environmental groups are concerned at build up in sea water. Serious Used as hardeners for epoxy resins, intermediates for alkyds, plasticizers, insect repellents and rust inhibitors 19-12-2012 effects to human health This substance is used as a catalyst, in the production of electrical equipment and as an industrial blowing agent in the production of rubber and plastic products. It may also be used in adhesives, paints and coatings and consumer-use air fresheners. 19-12-2012 This substance is used as an additive in the production of tyres and other rubber products. It is also used as a stabiliser in PVC, for example in water pipes, PVC textile products and packing materials), as a catalyst in the production of polyurethanes and silicones. It may be present above 0.1% w/w in such (parts of) articles. Note that this substance is covered by Entries 20 and 30 of Annex XVII. Also used in parts of the World in timber preservation. Used mainly as a reagent in chemical synthesis. This phthalate is used as a plasticiser in plastic goods and may be present above 0.1% w/w in such articles. It is also used in the manufacture of propellants and explosives and as such may be found in ammunition and rifle powders above 0.1% w/w. Dimethyl sulfate is a strong methylating agent used to convert compounds such as phenols, amines, and thiols to the corresponding methyl derivatives. It is also used as a methylating or sulfating agent in the manufacture of methyl esters, ethers, and amines in dyes, drugs, perfumes, pesticides, phenol derivatives, fabric softeners, polyurethane- based adhesives, and other organic chemicals. Dimethyl sulfate is also used as a solvent for the separation of mineral oils, for the analysis of auto fluids, and with boron to stabilize liquid sulfur trioxide. It was formerly used as a chemical weapon. Miticide, herbicide (withdrawn from use). High temperature polymerization inhibitor for styrene, methylstyrene and other styrene analogues. Also used as organic intermediate Stabiliser used in production of pvc products Stabiliser used in production of pvc products, particularly construction products such as piping, cables, etc. Furan is used primarily as an intermediate in the synthesis and production of tetrahydrofuran, pyrrole, and thiophene. Furan is also used in the formation of lacquers, as a solvent for resins, and in the production of agricultural chemicals, stabilizers, and pharmaceuticals. Processing aids in the production of fluoropolymers and fluoroelastomers and in other surfactant uses / impurity Used as processing aids in the production of fluoropolymers and fluoroelastomers and in other surfactant uses / impurity Curing agent for epoxy resins, especially in the electric and electonics field 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 Page 12 Danfoss Negative List of Chemicals REACH Candidate List (sorted by inclusion date and then by substance name) CAS no. 1 13814-96-5 Substance 2 Lead bis(tetrafluoroborate) Risk 3 R 20837-86-9 10099-74-8 Lead cyanamidate Lead dinitrate R R 1317-36-8 Lead monoxide (lead oxide) R 12036-76-9 12060-00-3 12626-81-2 Lead oxide sulfate Lead titanium trioxide Lead titanium zirconium oxide R R R 625-45-6 75-56-9 Methoxyacetic acid Methyloxirane (Propylene oxide) R C;M 68-12-2 N,N-dimethylformamide R 79-16-3 776297-69-9 N-methylacetamide N-pentyl-isopentylphthalate R R 97-56-3 o-aminoazotoluene C 1314-41-6 Orange lead (lead tetroxide) R 95-53-4 o-Toluidine C 72629-94-8 Pentacosafluorotridecanoic acid vPvB 12065-90-6 Pentalead tetraoxide sulphate R 8012-00-8 68784-75-8 Pyrochlore, antimony lead yellow Silicic acid (H2Si2O5), barium salt (1:1), lead-doped [with lead (Pb) content above the applicable generic concentration limit for ’tolicity for reproduction’ Aepr. 1R (CLP) or category 1 (DID); the substance is a member of the group entry of lead compounds, with index number 082-001-00-6 in Regulation (EU) No 1272/2008] Silicic acid, lead salt Sulfurous acid, lead salt, dibasic 11120-22-2 62229-08-7 March 2014 Date of inclusion 19-12-2012 R R Occurrence 4 Used as a catalyst in production of linear polyesters, a curing agent for epoxy resins; in electroplating solutions for coating metals with lead, in manufacturing flame-retardants, for electrolytic generation of boron, and in preparations for glazing frits Pigment, lubricant additive Used in manufacture of explosives, weapons and ammunitions , intermediate in preoduction of pigments and a laboratory agent. Glass and crystal making, ceramics, lead-acid batteries, pigments and paints, vulcanisation of rubber, manufacture of cathode ray tubes, organic synthesis Used in lead batteries, pigments and paints, stabiliser for PVC Used in piezoelectric ceramics, pigments and paints This substance is used in the production of lead titanate zirconate, in electro-ceramic components and piezoceramics. It may be present in such articles above 0.1% w/w. Used in chemical synthesis, cleaning agent, metal finishing, cosmetics Intermediate in the production of polyether polyols and glycols for use in making polyurethane plastics and resins. Also used in the preparation of lubricants, surfactants, and oil demulsifiers. Used as a fumigant for dried fruits and treating wood for termite resistance. Also used in electron microscopy. DMF is used as a reagent and solvent in many industrial applications in the chemical industry. It is also used in the production and cleaning of polyurethane synthetic/artificial leather and some plastics. It may be used as a degreaser in the metal and electronic/electrical industry. Globally, it may be found in paints, varnishes, cleaning agents, pesticides and adhesives. Trace amounts may be found in finished plastic, leather and textile articles. Intermediate for chemical synthesis in the production of pharmaceuticals, pesticides and electronic materials Plasticiser for plastic products, adhesives, paints, etc. Not pre-registered, so use likely to be low or present as an impurity. Azo dye, may be used as a staining agent in biological sciences. Formerly used for coloring oils, fats, and waxes. Used in anti-corrosion coatings (red lead primer), also used in optical glass, ceramic glazes and enamel, to make piezofiles, and as a weak oxidizerin the chemical industry Intermediate in chemical synthesis of herbicides, rubber chemicals, dye and pigment intermediates, resin hardeners, fungicide intermediates, pharmacectical intermediates, and others Processing aids in the production of fluoropolymers and fluoroelastomers and in other surfactant uses / impurity. Laboratory chemical. Used in manufacture of explosives, weapons and ammunitions , intermediate in preoduction of pigments and a laboratory agent. Pigment in paints and enamels UV fluorescent tubes R R Stabiliser used in production of pvc products Stabiliser used in production of pvc products 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 19-12-2012 Page 13 Danfoss Negative List of Chemicals REACH Candidate List (sorted by inclusion date and then by substance name) CAS no. 1 78-00-2 Substance 2 Tetraethyllead Risk 3 R 12202-17-4 307-55-1 Tetralead trioxide sulphate Tricosafluorododecanoic acid R vPvB 1319-46-6 Trilead bis(carbonate)dihydroxide R 12141-20-7 2580-56-5 Trilead dioxide phosphonate [4-[[4-anilino-1-naphthyl][4(dimethylamino)phenyl]methylene]cyclohexa-2,5-dien-1-ylidene] dimethylammonium chloride (C.S. Basic Blue 26) [with ≥ 0.1% of Michler's ketone (EU No. 202-027-5) or Michler's base (EU No. 202-959-2)] R C 548-62-9 112-49-2 4-[4,4'-bis(dimethylamino) benzhydrylidene]cyclohexa-2,5-dien-1ylidene]dimethylammonium chloride (C.S. Basic eiolet 3) [with ≥ 0.1% of Michler's ketone (EU No. 202-027-5) or Michler's base (EU No. 202959-2)] 1,2-bis(2-methoxyethoxy)ethane (TEGDME; triglyme) 110-71-4 1,2-dimethoxyethane; ethylene glycol dimethyl ether (EGDME) R 2451-62-9 1,3,5-Tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione (TGIC) M 59653-74-6 1,3,5-tris[(2S and 2R)-2,3-epoxypropyl]-1,3,5-triazine-2,4,6-(1H,3H,5H)- M trione (β-TGIC) 561-41-1 4,4'-bis(dimethylamino)-4''-(methylamino)trityl alcohol [with ≥ 0.1% of C Michler's ketone (EU No. 202-027-5) or Michler's base (EU No. 202959-2)] 90-94-8 4,4'-bis(dimethylamino)benzophenone (Michler’s ketone) March 2014 Occurrence 4 Formerly used as an an antiknock additive in leaded petrol. It is still used as an additive in aviation fuel for piston engine-powered aircraft. Stabiliser used in production of pvc products. Processing aids in the production of fluoropolymers and fluoroelastomers and in other surfactant uses / impurity. Laboratory chemical. Pigment in paints and ceramic glazes. Catalyst in the preparation of polyesters from terephthalic acid and diols, curing agent for peroxides to form improved polyethylene wire insulation, pearlescent pigment, colorchanging component of temperature-sensitive inks, red-reflecting pigment in iridescent plastic sheets, smudge-resistant film on electrically sensitive recording sheets, lubricating grease component, component of ultraviolet light reflective paints to increase solar reflectivity, improved cool gun-propellant stabilizer which decomposes and forms a lubricating lead deposit, heat stabilizer for PVC polymers, component of weighted nylon-reinforced fish nets made from PVC fibers. Stabiliser used in production of pvc products. Colorant with uses that may include dyes and inks, including in ball point pens and printer cartridges, cosmetics such as soaps, dyeing of paper, card, plastic, wood, lacquers and coatings, analytical / R&D/diagnostic uses. Date of inclusion 19-12-2012 C Colorant with uses that may include dyes and inks, including in ball pens, cosmetics such as soaps, dyeing of paper, card, plastic, wood, lacquers and coatings, analytical / R&D/diagnostic uses. 18-06-2012 R Used as an industrial and process solvent. May also be used as a constituent within flexo gravure watersolvent based inks, lithographic plate developers and glass cleaning solvents. May be found in the electrolyte system of lithium batteries (including consumer batteries). Used as an industrial and process solvent. Also used as a constituent within flexo gravure water-solvent based inks, lithographic plate developers and glass cleaning solvents. May be found in the electrolyte system of lithium batteries (including consumer batteries) Epoxy compound. Used as hardener in resins and coatings. May be used in solder mask applications in production of printed circuit boards. Also used in weather resistant polyester-based powder coatings. May be found in electrical insulation materials, adhesives, laminated sheeting, silk-screen coatings, tools and stabilizers for plastics. Epoxy compound. Used as hardener in resins and coatings. May be used in solder mask applications in production of printed circuit boards. Also used in weather resistant polyester-based powder coatings. May be found in electrical insulation materials, adhesives, laminated sheeting, silk-screen coatings, tools and stabilizers for plastics. Mainly used as a dye in writing inks. May be referred to as Solvent Violet 8, although the Color Index and CAS registry numbers do not necessarily match. Solvent Violet 8 is used in inks (including ballpoint pens and printer cartridges) and dyes. It may be used to color a variety of materials such as soaps, oil and fat products, paper, wood, packaging, leather, candles, rubber. It may also be used in black dyes to color polyacrylonitrile materials. It may be used in R&R / analytical / diagnostic applications and as an anti-allergen and bactericide. Important intermediate in the manufacture of triphenylmethane dyes. May be used as a colouring agent in the paper and paper products sector. May be present in dyes and pigments as a photosensitizer. May be present as an impurity in other substances used as coloring agents. 18-06-2012 C 19-12-2012 19-12-2012 19-12-2012 19-12-2012 18-06-2012 18-06-2012 18-06-2012 18-06-2012 18-06-2012 18-06-2012 Page 14 Danfoss Negative List of Chemicals REACH Candidate List (sorted by inclusion date and then by substance name) CAS no. 1 1303-86-2 Substance 2 Diboron trioxide Risk 3 R 75-12-7 Formamide R 17570-76-2 Lead(II) bis(methanesulfonate) R 101-61-1 N,N,N',N'-tetramethyl-4,4'-methylenedianiline (Michler’s base) C 6786-83-0 107-06-2 α,α-Bis[4-(dimethylamino)phenyl]-4 (phenylamino)naphthalene-1C methanol (C.S. Iolvent Blue 4) [with ≥ 0.1% of Michler's ketone (EU No. 202-027-5) or Michler's base (EU No. 202-959-2)] 1,2-dichloroethane C 101-14-4 2,2'-dichloro-4,4'-methylenedianiline C 90-04-0 140-66-9 2-Methoxyaniline; o-Anisidine 4-(1,1,3,3-tetramethylbutyl)phenol C E 7778-39-4 Aluminosilicate Refractory Ceramic Fibres<br/><i> are fibres covered C by index number 650-017-00-8 in Annex VI, part 3, table 3.1 of Regulation (EU) No 1272/2008 of the EUropean Parliament and of the Council of 16 DEUember 2008 on classification, labelling and packaging of substances and mixtures, and fulfil the three following conditions: a) oxides of aluminium and silicon are the main components present (in the fibres) within variable concentration ranges b) fibres have a length weighted geometric mean diameter less two standard geometric errors of 6 or less micrometres (µm) c) alkaline oxide and alkali earth oxide (Na2O+K2O+CaO+MgO+BaO) content less or equal to 18% by weight</i> Arsenic acid C 111-96-6 Bis(2-methoxyethyl) ether R 117-82-8 Bis(2-methoxyethyl) phthalate R 7778-44-1 Calcium arsenate C March 2014 Occurrence 4 Wide range of registered uses including soldering and welding agents, protective chemicals, in wood stone, plaster, cement, ceramic and glass articles; inks, varnishes, paints, coatings, fertilizers, vehicle and machinery parts, batteries, leather and textiles, paper, plastic. An intermediate used in the manufacture of pharmaceuticals and vitamins. Also used as a solvent, and as a laboratory reagent. May also be used in the production of pyrimidines, in hydrogen cyanide production, as an intermediate for paper finishing and as a solvent for example in the production of synthetic leather and inks. Formamide may also be used to make triazoles as starting materials for crop protection (agrochemical) products. Main application is tin-lead electroplating on printed circuit boards. This application is in decline owing to the restrictions on lead in electrical products as regulated in the EU by RoHS (2011/65/EU). Chemical intermediate in the manufacture of dyes and pigments and in the manufacture of its hydrochloric salt. May be used as an R&D reagent. Colorant with uses that may include dyes and inks, including in ball pens, cosmetics such as soaps, fuels, dyeing of paper, card, plastic, wood, lacquers and coatings, analytical / R&D/diagnostic uses. May be found in Wind screen washing fluid. Mainly used for manufacture of other substances. Minor uses as solvent in the chemical and pharmacectical industry. Mainly used as curing agent in resins and in the production of polymer articles and also for manufacture of other substances. The substance may further be used in construction and arts. Mainly used in the manufacture of dyes for tattooing and coloration of paper, polymers and aluminum foil. Mainly used in the manufacture of polymer preparations and of ethoxylates. Further used as a component in adhesives, coatings, inks and rubber articles. Zirconia Aluminosilicate Refractory Ceramic Fibres are fibres covered by index number 650-017-00-8 in Annex VI, part 3, table 3.1 of Regulation (EU) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, and fulfil the three following conditions: Date of inclusion 18-06-2012 Mainly used to remove gas bubbles from ceramic glass melt and in the production of laminated printed circuit boards. Used primarily as a reaction solvent or process chemical in a wide variety of applications. Used also as solvent for battery electrolytes, and possibly in other products such as sealants, adhesives, fuels and automotive care products. No registration for this phthalate compound has been submitted to ECHA. Hence, the substance seems not to be manufactured in or imported to the EU in quantities above 1 t/y. Main uses in the past were as plasticizer in polymeric materials and paints, lacquers and varnishes, including printing inks Calcium arsenate is present in complex raw materials imported for manufacture of copper, lead and a range of precious metals. It appears mainly to be used as precipitating agent in copper smelting and to manufacture diarsenic trioxide. However, most of the substance seems to be disposed of as waste. 19-12-2011 18-06-2012 18-06-2012 18-06-2012 18-06-2012 19-12-2011 19-12-2011 19-12-2011 19-12-2011 19-12-2011 19-12-2011 19-12-2011 19-12-2011 Page 15 Danfoss Negative List of Chemicals REACH Candidate List (sorted by inclusion date and then by substance name) CAS no. 1 24613-89-6 Substance 2 Dichromium tris(chromate) Risk 3 C 25214-70-4 Formaldehyde, oligomeric reaction products with aniline C 13424-46-9 Lead diazide, Lead azide R, 6477-64-1 Lead dipicrate R 15245-44-0 Lead styphnate R 127-19-5 N,N-dimethylacetamide R 49663-84-5 77-09-8 Pentazinc chromate octahydroxide Phenolphthalein C C 11103-86-9 Potassium hydroxyoctaoxodizincatedichromate C 3687-31-8 Trilead diarsenate C and R 96-18-4 Zirconia Aluminosilicate Refractory Ceramic Fibres<br /><i> are fibres C covered by index number 650-017-00-8 in Annex VI, part 3, table 3.1 of Regulation (EU) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, and fulfil the three following conditions: a) oxides of aluminium, silicon and zirconium are the main components present (in the fibres) within variable concentration ranges b) fibres have a length weighted geometric mean diameter less two standard geometric errors of 6 or less micrometres (µm). c) alkaline oxide and alkali earth oxide (Na2O+K2O+CaO+MgO+BaO) content less or equal to 18% by weight</i> 1,2,3-Trichloropropane C and R 71888-89-6 68515-42-4 872-50-4 1,2-Benzenedicarboxylic acid, di-C6-8-branched alkyl esters, C7-rich R 1,2-Benzenedicarboxylic acid, di-C7-11-branched and linear alkyl esters R 1-Methyl-2-pyrrolidone R March 2014 Occurrence 4 Mainly used in mixtures for metal surface treatment in the aeronautic/aerospace, steel and aluminum coating sectors. Mainly used for manufacture of other substances. Minor uses are as hardener for epoxy resins, e.g. for the production of rolls, pipes and molds, and as well for adhesives. Mainly used as initiator or booster in detonators for both civilian and military uses and as initiator in pyrotechnic devices. No registration for this substance has been submitted to ECHA. Lead dipicrate is an explosive like lead diazide and lead styphnate. It may be used in low amounts in detonator mixtures together with the two other mentioned lead compounds. Mainly used as a primer for small calibre and rifle ammunition. Other common uses are in munition pyrotechnics, powder actuated devices and detonators for civilian use. Used as solvent, mainly in the manufacture of various substances and in the production of fibres for clothing and other applications. Also used as reagent, and in products such as industrial coatings, polyimide films, paint strippers and ink removers. Mainly used in coatings in the vehicle coating and aeronautic / aerospace sectors. Mainly used as laboratory agent (in pH indicator solutions), for the production of pH-indicator paper and in medicinal products. Mainly used in coatings in the aeronautic/ aerospace, steel and aluminum coil coating and vehicle coating sectors. Trilead diarsenate is present in complex raw materials imported for manufacture of copper, lead and a range of precious metals. The trilead diarsenate contained in the raw materials is in the metallurgical refinement process transformed to calcium arsenate and diarsenic trioxide. Whereas most of the calcium arsenate appears to be disposed of as waste the diarsenic trioxide is used further. Zirconia Aluminosilicate Refractory Ceramic Fibres are fibres covered by index number 650-017-00-8 in Annex VI, part 3, table 3.1 of Regulation (EU) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, and fulfil the three following conditions: Date of inclusion 19-12-2011 TCP is used as an industrial solvent, as a monomer and as an intermediate for the synthesis of chlorinated solvents, some cross-linking agents and chlorinated solvents. Historically it had uses in consumer products such as paint strippers but must no longer be supplied to the general public. This substance may be used as a plasticizer for PVC and some ink and coatings formulations. This substance may be used as a plasticizer for PVC. This substance is used as an intermediate and as an industrial solvent for surface treatment of textiles, resins and metal coated plastics or as a paint stripper. It is also used in the pharmacectical and agrochemical industries. 20-06-2011 19-12-2011 19-12-2011 19-12-2011 19-12-2011 19-12-2011 19-12-2011 19-12-2011 19-12-2011 19-12-2011 19-12-2011 20-06-2011 20-06-2011 20-06-2011 Page 16 Danfoss Negative List of Chemicals REACH Candidate List (sorted by inclusion date and then by substance name) CAS no. 1 111-15-9 Substance 2 2-Ethoxyethyl acetate Risk 3 R 302-01-2, 7803-57-8 Hydrazine C 02-06-7789 Strontium chromate C 110-80-5 2-Ethoxyethanol R 109-86-4 2-Methoxyethanol R 7738-94-5, 1353068-2 Acids generated from chromium trioxide and their oligomers. Names of the acids and their oligomers: Chromic acid, Dichromic acid, Oligomers of chromic acid and dichromic acid. C 1333-82-0 Chromium trioxide C and R 513-79-1 Cobalt(II) carbonate C and R 71-48-7 Cobalt(II) diacetate C and R 10141-05-6 Cobalt(II) dinitrate C and R 10124-43-3 Cobalt(II) sulphate C and R 7789-09-5 Ammonium dichromate C, M 10043-35-3, 1111350-1 Boric acid R 1303-96-4, 1330-43- Disodium tetraborate, anhydrous 4, 12179-04-3 R March 2014 Occurrence 4 This substance is used as a solvent in some industrial adhesives and coatings, including wood stains, paints and varnishes. As a substance its use is prohibited in cosmetic products and must not be supplied to the general public. Hydrazine is used as a foaming agent, as a precursor to polymerization catalysts and pharmaceuticals. Additionally, hydrazine is used in various rocket fuels and to prepare the gas precursors used in air bags. Hydrazine is also used as a corrosion inhibitor in steam plants. Strontium chromate pigment is used as an anti-corrosion ingredient for some paints. It has uses in coatings for the aerospace and vehicle sectors as well as in coil coating applications. 2-ethoxyethanol is mainly used as a chemical intermediate. Further minor uses are as a solvent or a laboratory chemical. 2-methoxyethanol is mainly used as a chemical intermediate. Further minor uses are as a solvent or a laboratory chemical. Acids generated from chromium trioxide and their oligomers are mainly used in metal finishing, such as electroplating (e.g. hard chrome and decorative plating), conversion coatings and brightening. It is also used as a fixing agent in waterborne wood preservatives. Minor uses are e.g. in the manufacture of pigments and paints, in catalyst and detergent manufacture, and as an oxidizing agent. Chromium trioxide is mainly used in metal finishing, such as electroplating (e.g. hard chrome and decorative plating), conversion coatings and brightening. It is also used as a fixing agent in waterborne wood preservatives. Minor uses are e.g. in the manufacture of pigments and paints, in catalyst and detergent manufacture, and as an oxidizing agent. Cobalt(II) carbonate is mainly used in the manufacture of catalysts. Minor uses may include as a feed additive, in the manufacture of other chemicals including pigments, and as an adhesive in ground coat frit. Cobalt(II) diacetate is mainly used in the manufacture of catalysts or as a catalyst. Minor uses may include the manufacture of other chemicals including pigments, surface treatments, in alloys, dyes, rubber adhesion, and as a feed additive. Date of inclusion 20-06-2011 Cobalt(II) dinitrate is mainly used in the manufacture of other chemicals including catalysts. Further applications may include surface treatment and in batteries. 15-12-2010 Cobalt(II) sulphate is mainly used in the manufacture of other chemicals including pigments and possibly catalysts, driers. Further applications comprise surface treatments (such as electroplating), corrosion prevention, decolorization (in glass, pottery), in batteries, animal food supplements and soil fertilizers 15-12-2010 Ammonium dichromate is mainly used as an oxidizing agent. Other known uses are in the manufacture of photosensitive screens and as mordant in the manufacture of textiles. Minor uses seem to comprise metal treatment and laboratory analytical agent Boric acid is widely used on account of its consistency-influencing, flame-retarding, antiseptic and preservative properties. It is a component of detergents and cleaners, adhesives, toys, industrial fluids, brake fluids, glass, ceramics, flame retardants, paints, disinfectants, cosmetics, food additives, fertilizers, insecticides and other products. It is also used in paper manufacture. Disodium tetraborate and tetraboron disodium heptaoxide form the same compounds in aqueous solutions. Uses include a multitude of applications, e.g. in detergents and cleaners, in glass and glass fibers, ceramics, industrial fluids, metallurgy, adhesives, flame retardants, personal care products, biocides, fertilizers. 18-06-2010 20-06-2011 20-06-2011 15-12-2010 15-12-2010 15-12-2010 15-12-2010 15-12-2010 15-12-2010 18-06-2010 18-06-2010 Page 17 Danfoss Negative List of Chemicals REACH Candidate List (sorted by inclusion date and then by substance name) CAS no. 1 7789-00-6 Substance 2 Potassium chromate Risk 3 C and M 7778-50-9 Potassium dichromate C, M and 03-11-7775 Sodium chromate C, M and R 12267-73-1 Tetraboron disodium heptaoxide, hydrate R 79-01-6 Trichloroethylene C 79-06-1 Acrylamide C and M 121-14-2 2,4-Dinitrotoluene C 90640-80-5 Anthracene oil PBT and vPvB 90640-81-6 Anthracene oil, anthracene paste PBT and vPvB 91995-15-2 Anthracene oil, anthracene paste, anthracene fraction Occurrence 4 Potassium chromate is used as a corrosion inhibitor for treatment and coating of metals, for manufacture of reagents, chemicals and textiles, as a coloring agent in ceramics, in the manufacture of pigments/inks and in the laboratory as analytical agent. Potassium dichromate is used for chrome metal manufacturing and as corrosion inhibitor for treatment and coating of metals. It is further used as textile mordant, as laboratory analytical agent, for cleaning of laboratory glassware, in the manufacture of other reagents and as oxidizing agent in photolithography. Sodium chromate is mainly used as an intermediate in the manufacture of other chromium compounds as well as a laboratory analytical agent, but this use is limited. Other potential uses are mentioned in the literature but whether they occur in the EU is not clear. Disodium tetraborate and tetraboron disodium heptaoxide form the same compounds in aqueous solutions. Uses include a multitude of applications, e.g. in detergents and cleaners, in glass and glass fibers, ceramics, industrial fluids, metallurgy, adhesives, flame retardants, personal care products, biocides, fertilizers. Trichlorethylene is mainly used as intermediate in the manufacture of chlorinated and fluorinated organic compounds. Other uses are for cleaning and degreasing of metal parts or as solvent in adhesives. Acrylamide is almost exclusively used for the synthesis of polyacrylamides, which are used in various applications, in particular in waste water treatment and paper processing. Minor uses of acrylamide comprise the preparation of polyacrylamide gels for research purposes and as a grouting agent in civil engineering 2,4-dinitrotoluene is used in the production of toluene diisocyanate, which is used for the manufacture of flexible polyurethane foams. The substance is also used as gelatinizingplasticizing agent for the manufacture of explosives. The listed anthracene oil based substances are mainly used in the manufacture of other substances such as anthracene and carbon black. They may also be used as reducing agents in blast furnaces, as components in bunker fuel, for impregnating, sealing and corrosion protection. They are present in pitch, tars, bitumens and will be found in finsihed goods such as electrodes, batteries, building sealants (tar based), road surfacing nd clay pigeons - Date of inclusion 18-06-2010 - 13-01-2010 - 13-01-2010 - 13-01-2010 18-06-2010 18-06-2010 18-06-2010 18-06-2010 30-03-2010 13-01-2010 13-01-2010 13-01-2010 PBT and vPvB 91995-17-4 Anthracene oil, anthracene paste,distn. lights PBT and vPvB 90640-82-7 Anthracene oil, anthracene-low PBT and vPvB March 2014 Page 18 Danfoss Negative List of Chemicals REACH Candidate List (sorted by inclusion date and then by substance name) CAS no. 1 84-69-5 Substance 2 Diisobutyl phthalate 7758-97-6 Lead chromate 12656-85-8 Lead chromate molybdate sulphate red (C.I. Pigment Red 104) Risk 3 R C and R C and R 1344-37-2 Lead sulfochromate yellow (C.I. Pigment Yellow 34) C and R 65996-93-2 Pitch, coal tar, high temp. C, PBT and vPvB 115-96-8 Tris(2-chloroethyl)phosphate R 101-77-9 4,4'- Diaminodiphenylmethane (MDA) C 81-15-2 5-tert-butyl-2,4,6-trinitro-m-xylene (musk xylene) 85535-84-8 120-12-7 March 2014 Occurrence 4 Diisobutyl phthalate is used as plasticiser for nitrocellulose, cellulose ether, polyacrylate and polyacetate dispersions, and as a gelling aid in combination with other plasticisers, which are widely used for plastics, lacquers, adhesives, explosive material and nail polish. Lead chromate is used for manufacturing pigments and dyes, and as a pigment or coating agent in industrial and maritime paint products or varnishes. Further potential uses may be ssociated with the formulation of detergents and bleaches, photosensitive materials, the manufacture of pyrotechnic powder or the embalming / restoring of art products. Lead chromate molybdate sulphate red (C.I. Pigment Red 104) is used as a colouring, painting and coating agent in sectors such as the rubber, plastic and paints, coatings and varnishes ndustries. Applications comprise the production of agricultural equipment, vehicles and aircraft as well as road and airstrip painting. Lead sulfochromate yellow (C.I. Pigment Yellow 34) is used as a colouring, painting and coating agent in sectors such as the rubber, plastic and paints, coatings and varnishes industries. Applications comprise the production of agricultural equipment, vehicles and aircraft as well as road and airstrip painting. The substance is further used for camouflage or ammunition marking in the defence area. Pitch, coal tar, high temp. is mainly used in the production of electrodes for industrial applications. Smaller volumes are dedicated to specific uses such as heavy duty corrosion protection, special purpose paving, and manufacture of other substances and the production of clay targets. Date of inclusion 13-01-2010 13-01-2010 13-01-2010 13-01-2010 13-01-2010 Tris(2-chloroethyl)phosphate is mainly used as an additive plasticiser and viscosity regulator with flameretarding properties for acrylic resins, polyurethane, polyvinyl chloride and other polymers. Other fields of application are adhesives, coatings, flame resistant paints and varnishes. The main industrial branches to use TCEP are the furniture, the textile and the building industry. Diaminodiphenylmethane (MDA) is used as a reagent in the manufacture of rubber, plastics, diisocyanates, dyes and adhesives. In this use it is normally substantially consumed by conversion to other chemials. Historically, there is some evidence of trace residual amounts in flexible rubber products where used as a curing agent. This substance is unlikely to be present above 0.1% in a supplied article. 13-01-2010 vPvB A fragrance which may be incorporated into complex fragrance mixtures. Although not manufactured in the EU it may be formulated into imported fragrance compositions. This substance is very unlikely to be present in any EU produced articles. BUT it may be found in fragrances in imported articles such as toilet blocks or candles. The concentration is unpredictable and may exceed 0.1%. 28-10-2008 Alkanes, C10-13, chloro (Short Chain Chlorinated Paraffins) PBT and vPvB Anthracene PBT SCCPs have had a variety of uses, including extreme pressure additives in metalworking fluids, flame retard28-10-2008 ants for rubbers and textiles, in leather processing and as a plasticiser in paints and sealing compounds. The major recent use has been in metal working fluids. These substances are very unlikely to be present in articles above 0.1%. Anthracene is normally a complex low concentration impurity or trace constituent in petroleum products. It 28-10-2008 has been found in some wood preservatives and fuels. This substance is very unlikely to feature in any supplied articles over 0.1%. Present in significant quantities in coal tar products and other coal distillates. 28-10-2008 Page 19 Danfoss Negative List of Chemicals REACH Candidate List (sorted by inclusion date and then by substance name) CAS no. 1 85-68-7 Substance 2 Benzyl butyl phthalate (BBP) Risk 3 R Occurrence 4 Mostly used as a plasticiser for PVC, commonly in floor tiles. Other uses include in food conveyor belts, and artificial leather. This substance may be present above 0.1% in the articles described above. Action required to investigate, particularly in the supply of replacement parts (tiles and conveyor belting). Date of inclusion 28-10-2008 117-81-7 Bis (2-ethylhexyl)phthalate (DEHP) R 28-10-2008 56-35-9 Bis(tributyltin)oxide (TBTO) PBT 7646-79-9 Cobalt dichloride C and R 1303-28-2 Diarsenic pentaoxide C 1327-53-3 Diarsenic trioxide C 84-74-2 Dibutyl phthalate (DBP) R 25637-99-4, 319455-6 (134237-50-6) (134237-51-7) (134237-52-8) 7784-40-9 Hexabromocyclododecane (HBCDD) and all major diastereoisomers identified: Alpha-hexabromocyclododecane Betahexabromocyclododecane Gamma-hexabromocyclododecane PBT Lead hydrogen arsenate C and R DEHP is widely used as a plasticizer for PVC (usually >> 1%). Plasticised PVC has a wide but diminishing use ranging from party clothing to gaskets, seals and medical devices. It should not be confused with UPVC, the plasticiser free version, which is used for rigid applications such as building products. DEHP is also used as a hydraulic fluid and as a dielectric fluid in liquid filled capacitors. DEHP may also be used in lightsticks. The wide range of uses and attractive price of this substance means that its use in plasticised PVC articles (especially those) described above is foreseeable. This makes it a priority for investigation in the fabric, tubing, adult and childrens toys, engineering, medical devices, electronics and electrical and novelty products sectors. This substance is a biocide with major use in external wood treatment and ship descaling. It is possible that this substance could be found in some imported timber products intended for outdoor use, in boats or in recovered timbers. The quantity used in the final treated article may vary and monitoring may be difficult. Possible concern for garden products including toys and play equipment. The most common use is for the detection of moisture, for example as a color indicator in drying agents such as silica gel. Paper impregnated with cobalt chloride, known as "cobalt chloride paper" has been used to detect the presence of water. This substance is very unlikely to be present above 0.1% in any article other than desiccants and laboratory test paper. Diarsenic pentoxide is used in the manufacture of arsenates, old or non-EU weed killer, metal adhesives and specialist insecticides, fungicides, and wood preservatives. Note that use of arsenic compounds is serverely restricted already. It has been used in glass manufacture but this is now very unlikely to occur. The substance is very unlikely to be present in articles above 0.1% except for some old optical glasses. This substance is used in lead alloys (especially in lead-acid batteries), glass (and, to a lesser extent, enamel) production and as a source of high-purity arsenic for use in the electronics industry. This substance has widespread historical use as a plasticiser. It was also used as an additive to adhesives or printing inks. Although responsible industry has been phasing out the use of this substance there are concerns that it is still widely used. When used as a plasticiser the amounts may be well above 0.1% in final products. This threshold is unlikely to be exceeded in any ink coated article. This substance should be regarded as priority for investigation of its presence in any soft plastics and adhesives. Any business sector dealing with these articles should be alert to this risk. This substance is a flame retardant for plastics and fibres. It is used to produce flame retarded polystyrene and to flame proof some clothing and furniture textiles. A narrow use profile but there is a significant possibility that flame resistant polystyrene (as pre formed packaging shapes) may contain this substance. These articles are widely used in the electronics and toy industries. An insecticide for food. It has been widely banned for many years. This substance is very unlikely to be present in articles above 0.1%. March 2014 28-10-2008 28-10-2008 28-10-2008 28-10-2008 28-10-2008 28-10-2008 28-10-2008 Page 20 Danfoss Negative List of Chemicals REACH Candidate List (sorted by inclusion date and then by substance name) CAS no. 1 7789-12-0, 1058801-9 Substance 2 Sodium dichromate Risk 3 C, M and R 15606-95-8 Triethyl arsenate C Occurrence 4 Date of inclusion This substance is an important reagent for the production of a wide range of chemicals. It is aso used in metal 28-10-2008 finishing process, leather tanning and in some ceramics / glasses. This substance is very unlikely to be present in articles above 0.1% except in some coloured glazes and glasses. The latter are more likely to be found in craft / specialised articles than general purpose ceramics and glasses. This substance is used in the manufacture of semiconductors and has been used in the production of wood 28-10-2008 preservatives. In both cases the final quantity of the compound in a finished article is expected to be less than 0.1%. Notes In general: Use of the substances mentioned above, are accepted for analytical purposes by skilled personnel in chemical laboratories. Exemptions to RoHS or other regulations are accepted. The RoHS-restrictions are on each homogeneous material in the product, which means that the limits do not apply to the weight of the finished product. The substances that are included in Annex XIV are still present on the Candidate List in this document. 1) CAS means "Chemical Abstract Service", an internationally accepted system for identifying chemical substances 6) Maximum allowable concentration 0.1% (w/w) if not otherwise stated. The maximum allowable concentra2) Name(s) of substances in the group tion for banned substances describes naturally occurring contaminations and not intentionally added sub3) Type of risk: A = allergenic; C = Cancerogenic; T = toxic; E = environmentally hazardous; M= Mutagenic; N = stances. neurotoxic; O = ozone depleting; R = reprotoxic; PBT = persistent, bio accumulative & toxic; vPvB = very persis7) Exemptions and general comments tent and very bio accumulative. 8) The substances mentioned in the group of lubricants and degreasing agents are only prohibited when they 4) Typical examples of where you find the substance(s). are used for this purpose, but the other substances outside this group are also prohibited in lubricants and 5) Reference is given to International conventions, EU legislation or national (DK) legislation. “Danfoss decision” degreasing agents. meaning: No reference to REACH, RoHS or other EU Legislation. March 2014 Page 21 Danfoss Negative List of Chemicals Relevant legislation English title (link to document in English) EU Regulation REACH EU Regulation REACH Annex XVII (including amendments) List of restriction table EU Regulation, REACH, Annex XVII, Entry 61 (Dimethylfumarate) Link to the Danish document EU Regulation, REACH Number 1907 1907 Year 2006 2006 412 2012 EU Regulation, REACH, Annex XIV (Recommendation for inclusion) EU Regulation, REACH, Candidate List EU Directive, RoHS The Stockholm Convention on POPs EU Regulation on Greenhouse gasses The Kyoto Protocol EU Regulation on ozone depletion The Montreal Protocol EU Regulation on Methylbromide EU Regulation on sulfonates perfluorooctane EU Directive on restrictions on the use of pentabromo- and octabromodiphenyl ether EU Directive on Packaging and packaging waste EU Directive on Marketing and use of certain dangerous substances and preparations (asbestos) Wall Street Reform and Consumer Protection Act. Section 1502.- Conflict Minerals EPA, Ozone Layer Protection Restrictions on N-nitrosamines (TRGS 611) Restrictions on N-nitrosamines (TRGS 615) March 2014 always check for latest update 65 EU Regulation on Greenhouse gasses Statutory order on Greenhouse gasses 842 552 EU Regulation on ozone depletion Danish regulation on ozone depletion 1005 243 EU Regulation on Methylbromide Danish regulation on Mercury EU Regulation on sulfonates perfluorooctane EU Directive on restrictions on the use of pentabromo- and octabromodiphenyl ether Danish regulation on lead EU Directive on Packaging and packaging waste - 2037 627 122 11 856 62 77 2011 2001 2006 2002 1997 2009 2002 1999 2007 2003 2006 2003 2009 1994 1999 2010 2007 2007 Page 22