Danfoss Negative List
of Chemicals
October 2013
Danfoss’ Negative List bans or restricts the use of chemical
substances in Danfoss’ products and production processes
and by Danfoss’ suppliers, contractors and tenants.
Suppliers and subcontractors must not use any chemicals
listed on the Negative List in processes manufacturing parts
for Danfoss.
This Negative List has been generated on the basis of the
European Chemical legislation but the bans and restrictions
are applicable worldwide. Only stricter local legislation than
the European chemical legislation overrules this list.
If new substances are put on the Negative List, all suppliers
and subcontractors must ensure that the new substance is
removed from products delivered to Danfoss within a time
period not exceeding one year.
This Negative List shall be complied with throughout the
entire Danfoss Group and by all tenants, suppliers and contractors working on Danfoss premises or supplying parts and
materials to Danfoss.
Requirements for tenants and their suppliers
Contractors, tenants or their suppliers working on Danfoss’
owned property must not bring substances listed on the
Negative List onto Danfoss premises.
Requirements for suppliers and contractors
Suppliers and subcontractors to Danfoss are required to
comply with the Negative List and shall on request be able
to document the type and amount of any hazardous substances present in materials, subassemblies or components
and used in processes. Suppliers must proactively inform
Danfoss about the presence of Candidate List substances
above a concentration of 0.1 w/w %.
Keep up to date with changes to the Negative List
All suppliers, subcontractors, contractors, tenants or their
suppliers working on Danfoss’ owned property are responsible for keeping themselves updated with the current version of the Negative List.
Suppliers and subcontractors must not supply products,
components or materials to Danfoss containing banned
substances listed on the Negative List.
The Danfoss Negative List in force at any given time is available on:
http://www.danfoss.com/AboutUs/Corporate+Citizenship/
NegativeList.htm.
All suppliers, subcontractors, contractors and tenants shall
register themselves on the above webpage as recipient of
updates to the Danfoss Negative List and remain registered
for the term of the co-operation.
Danfoss Negative List of Chemicals
Metals (see also REACH Annex XIV in this document)
CAS no. 1
7440-38-2
All, e.g.:
7784-40-9
15606-95-8
7440-43-9
Substance 2
Arsenic
All Arsenic compounds (e.g. below)

Lead hydrogen arsenate

Triethyl arsenate
Cadmium
All
All Cadmium compounds
7738-94-5; 13530-682; 1333-82-0; 778900-6; 7778-50-9;
Chromium 6+ compounds
7789-12-0; 10588-019;
7439-92-1
All, e.g.:
77-58-7
1067-33-0
1118-46-3
15546-11-9
26401-86-5
26636-01-1
56-35-9
7440-28-0
All, e.g.:
563-68-8
7446-18-6
7791-12-0
October 2013
Occurrence 4
Legislation 5
E, T
Pb and Cu alloys, metal
adhesives, soft solders,
electronics and pigments
Annex XVII. See
also Annex XIV
C, E
Stabilizers in polymers
like PVC, Used in pigments in paints and
plastics, present also in
electronics. In soldering
materials
Annex XVII
RoHS
C, E
Chromium pigments,
chromated surfaces,
corrosion inhibitors.
Annex XIV
RoHS
T, N, E
Lead as an element in
metals and alloys, lead
compounds (stabilizers),
pigment, corrosion inhibitor
N, E
In lamps, electric switches, luminescent materials
Lead
7758-97-6; 12656-858; 7784-40-9;1344Lead compounds
37-2
7439-97-6
Mercury
All
Risk 3
All Mercury compounds
All Organotin (Mono-, di-, and trialkyl and -aryl tin
compounds) (e.g. below)

dibutyltin dilaurate (DBTL)

dibutyltin diacetate

butyltin trichloride (MBTC)

e.g.dibutyltin bis(metylmaleate)

octyltin tris(isooctyl mercaptoacetate)

dimetyltin bis(isooctyl mercaptoacetate)

bis(tributyltin)oxide (TBTO)
Thallium
All Thallium compounds (e.g. below)

thallium acetate

thallium sulphate

thallium chloride
E
T, E
Danish reg. no.
856/2009;
RoHS
Packaging dir.
See also Annex
XIV
Danish reg. no.
627/2003;
RoHS
In plasticizers and metals
Annex XVII
Biocide in wood
Candidate List
Max allowable concentration 6
Comments/exemptions 7
Arsenic is prohibited as a salt/compound but not as a
metallic element in an alloy.
0.01% Cd in PVC (recovered PVC: 0.1%).
Cd in soldering materials (brazing fillers)
max. 0.01%. In paint on products 0.1%
Restricted in electronic
and electric parts (Exemption: Electrical
contacts). Also restricted in packaging as
pollution
Lead is prohibited as a
salt/compound and not as a
metallic element in an alloy in
non-electrical equipment.
0,1%
DK: See exemptions in the regulation
Semiconductors, thermometers and optical
Danfoss
instruments, photometdecision
rical cells, in solutions and
as catalyst
Page 2
Danfoss Negative List of Chemicals
Lubricants and additives, degreasing agents, corrosion inhibitors8 (see also REACH Annex XIV in this document)
CAS no. 1
Risk 3
Occurrence 4
Legislation 5
Max allowable concentration 6
C
Corrosion protection, pH
stabilizer
TRGS 611; 615
0.2%
All
Substance 2
All Amines (secondary) which facilitate the formation of nitrosamines (e.g. below)
 diethanolamine
Formaldehyde
All Formaldehyde releasing substances (e.g. below)
 2-Bromo-2-nitro-1,3-propanediole (bronopol)
 Trihydroxymethylnitromethane
 4-(2-Nitrobutyl)-morpholine
 4,4´-Dimethyleoxazolidine
 Methylene-bis-morpholine/Bis-morpholinomethane
All Isothiazolones
A
Biocide in lubricants
All
All Mercaptobenzothiazoles
A
Biocide in lubricants
All, e.g.:
50-32-8
All Mineral oil with PAH (e.g. below)
 benzo-(a)-pyrene (as a PAH)
 DMSO extract as a measuring method for PAH
Morpholine
All Morpholine releasing substances
All Nitrite
All Nonylphenols (e.g. below)
 4-nonylphenol
 nonylphenol
 4-nonylphenol branched
All Nonylphenol ethoxylates
C
C
Base oils
C
Biocide in lubricants
C
Corrosion protection
E, R
Surface active agents
Annex XVII
Tall oil distillates which contains adipinic acid
A
Extreme pressure additive
Danfoss decision
All, e.g.:
111-42-2
50-00-0
All, e.g.:
52-51-7
126-11-4
2224-44-4
5100-87-4
5625-90-1
110-91-8
All
All
All, e.g.:
104-40-5
25154-52-3
84852-15-3
All
October 2013
0.005% free formaldehyde
C, A
Comments/exemptions 7
See also Formaldehyde in general below.
Biocide in lubricants
Danfoss decision
0.2%
New products must not contain these substances
New products must not contain these substances. A maximum allowable concentration cannot be set.
0.005% (50 ppm) Benz(a)pyren
3% DMSO extract for the base oil
0.002% (20ppm) nitrite
New products must not contain these substances. A maximum allowable concentration cannot be set
Only prohibited in lubricants and degreasing agents
All use according to Annex XVII is banned. See also
nonylphenol below
Page 3
Danfoss Negative List of Chemicals
Impregnation and dye (see also REACH Annex XIV in this document)
CAS no. 1
Substance 2
All
All Azo Dye
Risk 3
C, E
8001-58-9
Creosote
All
All
All, e.g.:
1330-78-5
78-30-8
78-32-0
All Cresylphosphates
All Dicresylphosphates
All Tricresylphosphates (TCP) (e.g. below)
 Tricresylphosphate (all isomers including ortho)
 Tri(ortho)cresylphosphate
 Tricresylphosphate (all isomers except ortho)
624-49-7
Dimethyl fumarate
(T), E
T, E
E
A
Occurrence 4
In dyes for textiles etc.,
packaging materials
In wood preservatives,
packaging materials
Legislation 5
Max allowable concentration 6
Annex XVII
0.003% (30ppm)
Comments/exemptions 7
Stokholm Conv.
Plasticizer additives in
nitrocellulose, PVC, flame
Danfoss deciretardant, additive in oils,
sion
acrylate lacquers, varnishes.
Ortho-TCP: 0.5%. The sum of Meta- and
Para-TCP: 5%.
The substance is normally
used as an additive to
silica gel sold in small
packs. The packs release
Annex XVII
DMFu during transport of entry 61
products in order to avoid
mold, mostly in furniture,
textiles and footwear
Banned in EU in 2009
Green House gases (see also REACH Annex XIV in this document)
CAS no. 1
Substance 2
All, e.g.:
All HFC (Hydrofluorocarbons) (e.g. below)
811-97-2
 R-134a
75-37-6
431-89-0
 R-152a
 R-227a
74-83-9
Methylbromide
All
All PFC (Perfluorocarbons)
2551-62-4
SF6 (Sulfurhexafluoride)
Risk 3
E
October 2013
Occurrence 4
Legislation 5
In heat pumps, refrigeration and air-conditioning
and sprays (EU 842/2006)
In spray containers for
testing print boards shall
follow the local phase out Kyoto
schedule. In Denmark this Protocol
particular use is allowed
until further notice (DK
reg. 552/2002)
Kyoto; EU no.
2037/2000
For PFC: also in fire extinguisher and equipment.
Danish reg. no. 552/2002
and EU no. 2034/2000
Max allowable concentration 6
Comments/exemptions 7
In Denmark: Only fillings larger than 10 kg in refrigeration
systems, heat pumps and air conditioning systems and
fillings larger than 50 kg in ventilation plants are prohibited. (Reg. 552). Outside DK HFC is not prohibited but there
are like in Denmark regulations for containment, recovery,
certification, reporting, labeling
Use are not allowed after December 31- 2005
Kyoto
Protocol
Page 4
Danfoss Negative List of Chemicals
Ozone depleting substances (see also REACH Annex XIV in this document)
CAS no. 1
353-59-3
75-63-8
124-73-2
All, e.g.:
75-69-4
75-71-8
75-72-9
76-13-1
76-14-2
76-15-3
All, e.g.:
75-45-6
75-68-3
Substance 2
Bromochlorodifluoromethane (R-1211)
Bromotrifluoromethane (R-1301)
1,2-dibromotrafluoroethane (R-2402)
All CFC (Chlorofluorocarbons) (e.g. below)
 Trichlorofluoromethane (R-11)
 Dichlorodifluoromethane (R-12)
 Chlorotrifluoromethane (R-13)
 1,1,2-Trichlorotrifluoroethane (R-113)
 Dichlorotetrafluoroethane (R-114)
 Monochloropentafluoroethane (R-115)
All HCFC (Hydrochlorofluorocarbons) (e.g. below)
 Monochlorodifluoromethane (R-22 )
 Monochlorodifluoroethane (R-142b)
1717-00-6
 Dichlorofluoroethane (R-141b)
Risk 3
Occurrence 4
Legislation 5
Montreal
Protocol
O, E
In cleaning agents, refrigerants, propellants in
aerosol spray, blowing
agents for making foam
and in air-condition
system.
Max allowable concentration 6
EPA Ozone
Layer protection
Comments/exemptions 7
Until December 31st, 2014 reclaimed hydrochloroflourocarbons may be used for the maintenance or servicing of
existing refrigeration, air-conditioning and heat pump
equipment, provided that the container is labeled with an
indication that the substance has been reclaimed and with
information on the batch number and name and address
of the reclamation facility (Article 11 item 3)
Solvents, aromatic and chlorinated (see also REACH Annex XIV in this document)
CAS no. 1
71-43-2
56-23-5
108-90-7
75-09-2
127-18-4
12002-48-1; 120-82-1
71-55-6; 79-00-5
79-01-6
Substance 2
Benzene
Carbontetrachloride
Chlorobenzene
Methylenechloride
Tetrachloroethylene ("PER")
Trichlorobenzene
Trichloroethane (1,1,1-)
Trichloroethylene ("TRI")
Risk 3
C, E
O , C, E
Occurrence 4
Legislation 5
Max allowable concentration 6
Comments/exemptions 7
Except in gasoline
Annex XVII
Solvent, degreasing agent
C,E
Danfoss decision
Annex XVII
Danish
243/2002
Except in thermo bulbs for fire-extinguishing equipment
Monomers and Plasticizers (see also REACH Annex XIV in this document)
CAS no. 1
107-13-1
106-99-0
75-01-4
October 2013
Substance 2
Acrylonitrile
Butadiene (1,3 -)
Vinylchloride
Risk 3
Occurrence 4
Monomer in ABS and
other copolymers
Monomer in PVC and
other copolymers
Legislation 5
Danfoss decision
Max allowable concentration 6
Comments/exemptions 7
The plasticizers are mentioned in the group called "REACH
Annex XIV"
Page 5
Danfoss Negative List of Chemicals
Flame retardants (see also REACH Annex XIV in this document)
CAS no. 1
32536-52-0
32534-81-9
All, e.g.:
36355-01-8; 2785807-7; 13654-09-6
All, e.g.:
40088-47-9; 3253481-9; 36483-60-0;
68928-80-3; 3253652-0; 63936-56-1;
1163-19-5
Substance 2
Octabromodiphenylethers
Pentabromodiphenylethers
Risk 3
Occurrence 4
Legislation 5
Max allowable concentration 6
Comments/exemptions 7
EU 2003/11
Polybrominated biphenyls (PBB)
E, R
In electronic and electrical
parts, in plastics and
polymers etc.
RoHS
also REACH Annex XVII See
Polybrominated diphenylethers (PBDE)
Persistent Organic Pollutants (POP) (see also REACH Annex XIV in this document)
CAS no. 1
All, e.g.:
309-00-2
57-74-9
50-29-3
All
60-57-1
All
115-29-7
72-20-8
76-44-8
118-74-1
2385-85-5
1336-36-3
87-86-5
Substance 2
All POP (e.g. below)
 Aldrin
 Chlordan
 DDT
 Dibenzofuranes
 Dieldrin
 Dioxins
 Endosulfan
 Endrin
 Heptachlor
 Hexachlorobenzene
 Mirex
 PCB
 Pentachlorophenol
Risk 3
All
 PFOS (Perfluoro octylsulfonates)
E
All
8001-35-2
75635-23-3
 PFOA (Perfluorooctanoic acids)
 Toxaphene
 Trifluralin
E
October 2013
Occurrence 4
Legislation 5
Insecticide
Stockholm
Convention
Max allowable concentration 6
Comments/exemptions 7
C, E
E
All use is banned, except in wood treatment
C, E
C, E
In fire extinguishing
equipment, surface
treatment
Surface treatment
Pesticide
Annex XVII
0.005% in preparations; 0.1% in articles
Annex XVII
Stockholm
Convention
Page 6
Danfoss Negative List of Chemicals
Nonylphenols (see also REACH Annex XIV in this document)
CAS no. 1
All, e.g.:
104-40-5
25154-52-3
84852-15-3
All
Substance 2
All Nonylphenols (e.g. below)
 4-nonylphenol
 Nonylphenol
 4-nonylphenol branched
Nonylphenolethoxylate
Risk 3
Occurrence 4
Legislation 5
Max allowable concentration 6
Comments/exemptions 7
E, R
In cleaning agents
Annex XVII
Occurrence 4
Paper products, cleaners,
disinfectants, textile
materials intended for
skin contact
Legislation 5
Max allowable concentration 6
Comments/exemptions 7
Danfoss decision
0.15%
Restricted in its own, in preparations or released from
materials.
See also lubricants
See also lubricants
Formaldehyde (see also REACH Annex XIV in this document)
CAS no. 1
Substance 2
Risk 3
50-00-0
Formaldehyde
A, C, E
Asbestos (see also REACH Annex XIV in this document)
CAS no. 1
77536-66-4
12172-73-5
77536-67-5
12001-29-5
12001-28-4
Substance 2
Actinolite
Amosite
Anthophyllite
Chrysotile
Crocidolite
77536-68-6
Tremolite
Risk 3
C
Occurrence 4
Legislation 5
Max allowable concentration 6
EU Directive
In insulating material in
on Marketing
buildings and in products.
and use of
Severe precautions
certain
should be taken in refurdangerous
bishing asbestos contain- substances and
ing buildings
preparations
(asbestos)
Comments/exemptions 7
All use is banned. E.g. Insulating material. In production of
articles such as gaskets, brake linings etc.
Mineral wool fibers (see also REACH Annex XIV in this document)
CAS no. 1
Substance 2
Risk 3
Manmade mineral fibers with proven C effects
All
C
Aluminosilicate, Refractory Ceramic Fibres
Zirconia Aluminosilicate, Refractory Ceramic Fibres
October 2013
Occurrence 4
Legislation 5
Danish
Working
Environment
Authorities
Max allowable concentration 6
Comments/exemptions 7
Insulating materials in
buildings are exempted
Applies to work processes
where there is a risk of exposure
to respirable fibers
Candidate List
Page 7
Danfoss Negative List of Chemicals
Radioactive substances
CAS no. 1
Substance 2
Risk 3
All
Radioactive substances
C
Occurrence 4
Legislation 5
Max allowable concentration 6
Comments/exemptions 7
ldNo thresho
PAH (Poly Aromatic Hydrocarbons) (see also REACH Annex XIV in this document)
CAS no. 1
All, e.g.:
50-32-8
53-70-3
56-55-3
191-24-2
192-97-2
193-39-5
205-82-3
205-99-2
207-08-9
218-01-9
Substance 2
All PAH (e.g. below)
 Benzo(a)pyrene
 Dibenzo(a,h)anthracene
 Benzo(a)anthracene
 Benzo(ghi)perylene
 Benzo(e)pyrene
 Indeno(1,2,3-cd)pyrene
 Benzo(j)fluoranthene
 Benzo(b)fluoranthene
 Benzo(k)fluoranthene
Chrysene
Risk 3
Occurrence 4
Legislation 5
Max allowable concentration 6
Comments/exemptions 7
0.0001% (1ppm)
C, E
Softening oils in rubber
compounds/chemicals
and as pollutants in many
materials
Annex XVII
Sum of all PAH: 0.001% (10ppm)
In rubber compounds/chemicals
See also "Lubricants"
REACH (Annex XIV)
CAS no. 1
Substance 2
Risk 3
Occurrence 4
7738-94-5,
13530-68-2
Acids generated from chromium trioxide
and their oligomers. Names of the acids
and their oligomers: Chromic acid, Dichromic acid, Oligomers of chromic acid
and dichromic acid.
C
7789-09-5
Ammonium dichromate
C, M
Acids generated from chromium trioxide and their oligomers are
21-09-2017
mainly used in metal finishing, such as electroplating (e.g. hard
chrome and decorative plating), conversion coatings and brightening. It is also used as a fixing agent in waterborne wood preservatives. Minor uses are e.g. in the manufacture of pigments and paints,
in catalyst and detergent manufacture, and as an oxidizing agent.
Ammonium dichromate is mainly used as an oxidizing agent. Other
21-09-2017
known uses are in the manufacture of photosensitive screens and as
mordant in the manufacture of textiles. Minor uses seem to comprise metal treatment and laboratory analytical agent
October 2013
Sunset date Latest application date
21-03-2016
21-03-2016
Comments/exemptions 7
Always check for the latest Annex XIV
updates on the ECHA homepage. Some of
these substances are also present on Annex
XVII.
Substitution of Annex XIV substances shall
be initiated as soon as possible – preferably
at the point where the substance was
added to the Candidate List.
Page 8
Danfoss Negative List of Chemicals
REACH (Annex XIV)
1333-82-0
Chromium trioxide
C and
R
7789-00-6
Potassium chromate
C and
M
7778-50-9
Potassium dichromate
C, M
and
7775-11-3
Sodium chromate
C, M
and R
7789-12-0,
10588-01-9
Sodium dichromate
C, M
and R
79-01-6
Trichloroethylene
C
3194-55-6,
25637-99-4,
134237-50-6,
134237-51-7,
134237-52-8
121-14-2
115-96-8
1303-28-2
Hexabromocyclododecane (HBCDD),
alpha-hexabromocyclododecane,
beta-hexabromocyclododecane,
gamma-hexabromocyclododecane
PBT
2,4 – Dinitrotoluene (2,4-DNT)
Tris(2-chloroethyl)phosphate (TCEP)
Diarsenic pentaoxide
C
R
C
1344-37-2
Lead sulfochromate yellow (C.I. Pigment
Yellow 34)
Diarsenic trioxide
Lead chromate
C, R
Lead chromate molybdate sulphate red
(C.I. Pigment Red 104)
C, R
1327-53-3
7758-97-6
12656-85-8
October 2013
C
C, R
Chromium trioxide is mainly used in metal finishing, such as electroplating (e.g. hard chrome and decorative plating), conversion coatings and brightening. It is also used as a fixing agent in waterborne
wood preservatives. Minor uses are e.g. in the manufacture of
pigments and paints, in catalyst and detergent manufacture, and as
an oxidizing agent.
Potassium chromate is used as a corrosion inhibitor for treatment
and coating of metals, for manufacture of reagents, chemicals and
textiles, as a coloring agent in ceramics, in the manufacture of
pigments/inks and in the laboratory as analytical agent.
Potassium dichromate is used for chrome metal manufacturing and
as corrosion inhibitor for treatment and coating of metals. It is
further used as textile mordant, as laboratory analytical agent, for
cleaning of laboratory glassware, in the manufacture of other reagents and as oxidizing agent in photolithography.
Sodium chromate is mainly used as an intermediate in the manufacture of other chromium compounds as well as a laboratory analytical
agent, but this use is limited. Other potential uses are mentioned in
the literature but whether they occur in the EU is not clear.
This substance is an important reagent for the production of a wide
range of chemicals. It is aso used in metal finishing process, leather
tanning and in some ceramics / glasses.
This substance is very unlikely to be present in articles above 0.1%
except in some coloured glazes and glasses. The latter are more
likely to be found in craft / specialised articles than general purpose
ceramics and glasses.
Trichlororethylene is mainly used as intermediate in the manufacture of chlorinated and fluorinated organic compounds. Other uses
are for cleaning and degreasing of metal parts or as solvent in adhesives.
Flame retardant
21-09-2017
21-03-2016
21-09-2017
21-03-2016
21-09-2017
21-03-2016
21-09-2017
21-03-2016
21-09-2017
21-03-2016
21-04-2016
21-10-2014
21-08-2015
21-02-2014
For the production of toluene diisocyanate.
Plasticizer with flame-retarding properties
The substance is very unlikely to be present in articles above 0.1%
except for old optical glass
Used in paint for rubber, plastic and in varnishing products.
21-08-2015
21-08-2015
21-02-2014
21-02-2014
21-05-2015
21-11-2013
21-05-2015
21-11-2013
In lead alloys, glass, electronics
In pigments and dyes in industrial and maritime paint products or
varnish
Used in paint for rubber, plastic and in varnishing products.
21-05-2015
21-11-2013
21-05-2015
21-11-2013
21-05-2015
21-11-2013
Always check for the latest Annex XIV
updates on the ECHA homepage. Some of
these substances are also present on Annex
XVII.
Substitution of Annex XIV substances shall
be initiated as soon as possible – preferably
at the point where the substance was
added to the Candidate List.
Page 9
Danfoss Negative List of Chemicals
REACH (Annex XIV)
85-68-7
117-81-7
84-74-2
84-69-5
81-15-2
101-77-9
Benzyl butyl phthalate (BBP)
Bis(2-ethylhexyl) phthalate (DEHP)
Dibutyl phthalate (DBP)
Diisobutyl phthalate (DIBP)
5-tert-butyl-2,4,6-trinitro-m-xylene (Musk
xylene)
4,4’-Diaminodiphenylmethane (MDA)
R
R
R
R
vPvB
Plasticizer in PVC
Plasticizer in PVC
Plasticizer and additive in adhesives or printing inks
Plasticizer
Perfume, fragrance
21-02-2015
21-02-2015
21-02-2015
21-02-2015
21-08-2013
21-08-2013
21-08-2013
21-08-2013
21-08-2014
21-02-2013
C
A hardener used in the production of rubber, plastics, adhesives. Not
21-08-2014
likely to be present above 0.1% in a supplied article.
21-02-2013
The following substances are not forbidden, but Danfoss shall be informed about the presence in supplied products (chemicals and articles)
Conflict minerals
CAS no. 1
Substance 2
Several
Conflict minerals from DR Congo or similar states.
The minerals include gold, tin, tantalum and tungsten or their derivatives.
Risk 3
Legislation 5
Comments/exemptions 7
Wall Street Reform and Consumer Protection Act. Section 1502
The substances are not prohibited, but information must be provided to the recipient of the
chemical or article.
The substances on the Candidate List are not prohibited unless also mentioned on Annex XIV or XVII, but if the concentration is above 0.1%, information
must be provided to the recipient of the chemical or article. Please always check for the latest update on the ECHA homepage.
REACH Candidate List (sorted by inclusion date and then by substance name)
CAS no. 1
3825-26-1
7440-43-9
Substance 2
4-Nonylphenol, branched and linear, ethoxylated
Ammonium pentadecafluorooctanoate (APFO)
Cadmium
Risk 3
E, R
R
C
1306-19-0
Cadmium oxide
C
131-18-0
335-67-1
69011-06-9
84777-06-0
Dipentyl phthalate (DPP)
Pentadecafluorooctanoic acid (PFOA)
[Phthalato(2-)]dioxotrilead
1,2-Benzenedicarboxylic acid, dipentylester, branched and linear
R
R
R
R
October 2013
Occurrence 4
Cleaning agents
Cleaning agents
Nickel- cadmium batteries, Pigments for plastics, Low melting alloys, Electroplating, Solder, Semiconductors,
Stabilizers in PVC
Nickel- cadmium batteries, Pigments for plastics, Low melting alloys, Electroplating, Solder, Semiconductors,
Stabilizers in PVC
Plasticiser
Cleaning agents
Stabiliser used in production of pvc products
This phthalate may be used as a plasticiser for plastic materials. It was not registered for the 2010 deadline
and thus is thought to be in low usage in the EEA. However, it may be present in imported plastic articles.
Date of inclusion
20-06-2013
20-06-2013
20-06-2013
20-06-2013
20-06-2013
20-06-2013
19-12-2012
19-12-2012
Page 10
Danfoss Negative List of Chemicals
REACH Candidate List (sorted by inclusion date and then by substance name)
CAS no. 1
629-14-1
Substance 2
1,2-Diethoxyethane
106-94-5
1-bromopropane (n-propyl bromide)
143860-04-2
-
3-ethyl-2-methyl-2-(3-methylbutyl)-1,3-oxazolidine
4-(1,1,3,3-tetramethylbutyl)phenol, ethoxylated <i>[covering welldefined substances and UVCB substances, polymers and homologues]</i>
838-88-0
101-80-4
4,4'-methylenedi-o-toluidine
4,4'-oxydianiline and its salts
60-09-3
4-Aminoazobenzene
95-80-7
4-methyl-m-phenylenediamine (toluene-2,4-diamine)
-
120-71-8
51404-69-4
4-Nonylphenol, branched and linear <i>[substances with a linear
and/or branched alkyl chain with a carbon number of 9 covalently
bound in position 4 to phenol, covering also UVCB- and well-defined
substances which include any of the individual isomers or a combination thereof]</i>
6-methoxy-m-toluidine (p-cresidine)
Acetic acid, lead salt, basic
92-67-1
Biphenyl-4-ylamine
1163-19-5
Bis(pentabromophenyl) ether (decabromodiphenyl ether; DecaBDE)
85-42-7, 13149-003, 14166-21-3
Cyclohexane-1,2-dicarboxylic anhydride [1], cis-cyclohexane-1,2dicarboxylic anhydride [2], trans-cyclohexane-1,2-dicarboxylic anhydride [3] <i>[The individual cis- [2] and trans- [3] isomer substances
and all possible combinations of the cis- and trans-isomers [1] are
covered by this entry]</i>
October 2013
Risk 3
R
Occurrence 4
This substance is a glycol ether and belongs to the glyme family of chemicals and is expected to have similar
applications; monoglyme, diglyme and triglyme are also included on the Candidate List. Globally, common
uses for glycol ethers are as a solvent in formulations such as paints, inks and cleaning fluids. They may be
used in fabric cleaning compounds such as dry powder carpet cleaner, in stain removers, in mildew removers,
oven cleaners and multi-purpose detergents. Non-solvent uses for glycol ethers include hydraulic and brake
fluids, anti-icing agents and as chemical intermediates. This substance was not registered for the 2010 deadline and is thus thought to be in low usage in the EEA.
R
This substance has been registered for REACH. According to the dissemination portal, it is used as an industrial solvent, surface cleaner and degreasing agent. Used in electronics industry for cleaning circuit boards.
R
The chemical’s proposed use is in high-solids polyurethane coatings as a reactive
E
This is part of the alkyl phenol ethoxylate group of substances used in detergents, inks, etc and have been
voluntarily removed from the market by many companies. One concern is endocrine effects from environmental release. Found in printed papers, especially glossy printing from outside Europe. Degradation product of 'alkyl phenol ethoxylates' that may themselves be polymers (higher ethoxylates) and no-longer polymer (lower level of ethoxylation). Also found in some oil additives. Can also be residual on imported textiles.
C
This substance is used as an intermediate in the production of elastomers, dyes and colourants.
C;M
Production of polymers such as polyimides for uses in wiring, printed circuits, and other high temperature
applications. Residues may remain in articles of this nature.
C
Also known as aniline yellow, CI 11000 or under many other common historical names. This chemical was
implicated in the 1980s vegetable oil poisoning incident when added to industrial oil that was put into the
food market. It is used in many industrial dying activities, markers and in some ink-jet printers.
C
Used mainly as an intermediate, but also may appear as residue in polyurethane foams from polymer production
E
This is part of the alkyl phenol ethoxylate group of substances used in detergents, inks, etc and have been
voluntarily removed from the market by many companies. One concern is endocrine effects from environmental release. Found in printed papers, especially glossy printing from outside Europe. Degradation product of 'alkyl phenol ethoxylates' that may themselves be polymers (higher ethoxylates) and no-longer polymer (lower level of ethoxylation). Also found in some oil additives. Can also be residual on imported textiles.
C
Used in dying of textiles and leather goods.
R
Lead acetate is used in dying and pigmentation aid for textiles, hair products, paints etc. Use in Europe
restricted under regulations on use of lead, but may be found in imported products, especially painted
ornamental goods
C
Starting chemical for many azo dyes and will be a residue from production or may even form as a metabolite
(breakdown product) from certain materials. Possible residue in textiles and coloured materials
PBT; vPvB One of a family of brominated fire retardants used in plastics and foams. These chemicals can leach out of
plastics, especially during recycling activities and are functionally very persistent and environmental groups
are concerned at build up in sea water.
Serious
Used as hardeners for epoxy resins, intermediates for alkyds, plasticizers, insect repellents and rust inhibitors
effects to
human
health
Date of inclusion
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
Page 11
Danfoss Negative List of Chemicals
REACH Candidate List (sorted by inclusion date and then by substance name)
CAS no. 1
123-77-3
Substance 2
Diazene-1,2-dicarboxamide (C,C'-azodi(formamide))
683-18-1
Dibutyltin dichloride (DBTC)
Risk 3
Serious
effects to
human
health
R
64-67-5
605-50-5
Diethyl sulphate
Diisopentylphthalate
C;M
R
77-78-1
Dimethyl sulphate
C
88-85-7
Dinoseb (6-sec-butyl-2,4-dinitrophenol)
R
12578-12-0
91031-62-8
110-00-9
Dioxobis(stearato)trilead
Fatty acids, C16-18, lead salts
Furan
R
R
C
2058-94-8
Henicosafluoroundecanoic acid
vPvB
376-06-7
Heptacosafluorotetradecanoic acid
vPvB
25550-51-0, 1943860-9, 48122-14-1,
57110-29-9
Serious
effects to
human
health
13814-96-5
Hexahydromethylphthalic anhydride [1], Hexahydro-4-methylphthalic
anhydride [2], Hexahydro-1-methylphthalic anhydride [3], Hexahydro3-methylphthalic anhydride [4] <i>[The individual isomers [2], [3] and
[4] (including their cis- and trans- stereo isomeric forms) and all possible combinations of the isomers [1] are covered by this entry]</i>
Lead bis(tetrafluoroborate)
20837-86-9
10099-74-8
Lead cyanamidate
Lead dinitrate
R
R
1317-36-8
Lead monoxide (lead oxide)
R
12036-76-9
Lead oxide sulfate
R
October 2013
R
Occurrence 4
This substance is used as a catalyst, in the production of electrical equipment and as an industrial blowing
agent in the production of rubber and plastic products. It may also be used in adhesives, paints and coatings
and consumer-use air fresheners.
Date of inclusion
19-12-2012
This substance is used as an additive in the production of tyres and other rubber products. It is also used as a
stabiliser in PVC, for example in water pipes, PVC textile products and packing materials), as a catalyst in the
production of polyurethanes and silicones. It may be present above 0.1% w/w in such (parts of) articles. Note
that this substance is covered by Entries 20 and 30 of Annex XVII. Also used in parts of the World in timber
preservation.
Used mainly as a reagent in chemical synthesis.
This phthalate is used as a plasticiser in plastic goods and may be present above 0.1% w/w in such articles. It
is also used in the manufacture of propellants and explosives and as such may be found in ammunition and
rifle powders above 0.1% w/w.
Dimethyl sulfate is a strong methylating agent used to convert compounds such as phenols, amines, and
thiols to the corresponding methyl derivatives. It is also used as a methylating or sulfating agent in the manufacture of methyl esters, ethers, and amines in dyes, drugs, perfumes, pesticides, phenol derivatives, fabric
softeners, polyurethane- based adhesives, and other organic chemicals. Dimethyl sulfate is also used as a
solvent for the separation of mineral oils, for the analysis of auto fluids, and with boron to stabilize liquid
sulfur trioxide. It was formerly used as a chemical weapon.
Miticide, herbicide (withdrawn from use). High temperature polymerization inhibitor for styrene, methylstyrene and other styrene analogues. Also used as organic intermediate
Stabiliser used in production of pvc products
Stabiliser used in production of pvc products, particularly construction products such as piping, cables, etc.
Furan is used primarily as an intermediate in the synthesis and production of tetrahydrofuran, pyrrole, and
thiophene. Furan is also used in the formation of lacquers, as a solvent for resins, and in the production of
agricultural chemicals, stabilizers, and pharmaceuticals.
Processing aids in the production of fluoropolymers and fluoroelastomers and in other surfactant uses /
impurity
Used as processing aids in the production of fluoropolymers and fluoroelastomers and in other surfactant
uses / impurity
Curing agent for epoxy resins, especially in the electric and electonics field
19-12-2012
Used as a catalyst in production of linear polyesters, a curing agent for epoxy resins; in electroplating solutions for coating metals with lead, in manufacturing flame-retardants, for electrolytic generation of boron,
and in preparations for glazing frits
Pigment, lubricant additive
Used in manufacture of explosives, weapons and ammunitions , intermediate in preoduction of pigments and
a laboratory agent.
Glass and crystal making, ceramics, lead-acid batteries, pigments and paints, vulcanisation of rubber, manufacture of cathode ray tubes, organic synthesis
Used in lead batteries, pigments and paints, stabiliser for PVC
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
Page 12
Danfoss Negative List of Chemicals
REACH Candidate List (sorted by inclusion date and then by substance name)
CAS no. 1
12060-00-3
12626-81-2
Substance 2
Lead titanium trioxide
Lead titanium zirconium oxide
Risk 3
R
R
625-45-6
75-56-9
Methoxyacetic acid
Methyloxirane (Propylene oxide)
R
C;M
68-12-2
N,N-dimethylformamide
R
79-16-3
776297-69-9
N-methylacetamide
N-pentyl-isopentylphthalate
R
R
97-56-3
o-aminoazotoluene
C
1314-41-6
Orange lead (lead tetroxide)
R
95-53-4
o-Toluidine
C
72629-94-8
Pentacosafluorotridecanoic acid
vPvB
12065-90-6
Pentalead tetraoxide sulphate
R
8012-00-8
68784-75-8
R
R
11120-22-2
62229-08-7
78-00-2
Pyrochlore, antimony lead yellow
Silicic acid (H2Si2O5), barium salt (1:1), lead-doped
[with lead (Pb) content above the applicable generic concentration
limit for ’toxicity for reproduction’ Repr. 1A (CLP) or category 1 (DSD);
the substance is a member of the group entry of lead compounds, with
index number 082-001-00-6 in Regulation (EU) No 1272/2008]
Silicic acid, lead salt
Sulfurous acid, lead salt, dibasic
Tetraethyllead
12202-17-4
307-55-1
Tetralead trioxide sulphate
Tricosafluorododecanoic acid
R
vPvB
October 2013
R
R
R
Occurrence 4
Used in piezoelectric ceramics, pigments and paints
This substance is used in the production of lead titanate zirconate, in electro-ceramic components and piezoceramics. It may be present in such articles above 0.1% w/w.
Used in chemical synthesis, cleaning agent, metal finishing, cosmetics
Intermediate in the production of polyether polyols and glycols for use in making polyurethane plastics and
resins. Also used in the preparation of lubricants, surfactants, and oil demulsifiers. Used as a fumigant for
dried fruits and treating wood for termite resistance. Also used in electron microscopy.
DMF is used as a reagent and solvent in many industrial applications in the chemical industry. It is also used in
the production and cleaning of polyurethane synthetic/artificial leather and some plastics. It may be used as a
degreaser in the metal and electronic/electrical industry. Globally, it may be found in paints, varnishes,
cleaning agents, pesticides and adhesives. Trace amounts may be found in finished plastic, leather and textile
articles.
Intermediate for chemical synthesis in the production of pharmaceuticals, pesticides and electronic materials
Plasticiser for plastic products, adhesives, paints, etc. Not pre-registered, so use likely to be low or present as
an impurity.
Azo dye, may be used as a staining agent in biological sciences. Formerly used for coloring oils, fats, and
waxes.
Used in anti-corrosion coatings (red lead primer), also used in optical glass, ceramic glazes and enamel, to
make piezofiles, and as a weak oxidizerin the chemical industry
Intermediate in chemical synthesis of herbicides, rubber chemicals, dye and pigment intermediates, resin
hardeners, fungicide intermediates, pharmacectical intermediates, and others
Processing aids in the production of fluoropolymers and fluoroelastomers and in other surfactant uses /
impurity. Laboratory chemical.
Used in manufacture of explosives, weapons and ammunitions , intermediate in preoduction of pigments and
a laboratory agent.
Pigment in paints and enamels
UV fluorescent tubes
Date of inclusion
19-12-2012
19-12-2012
Stabiliser used in production of pvc products
Stabiliser used in production of pvc products
Formerly used as an an antiknock additive in leaded petrol. It is still used as an additive in aviation fuel for
piston engine-powered aircraft.
Stabiliser used in production of pvc products.
Processing aids in the production of fluoropolymers and fluoroelastomers and in other surfactant uses /
impurity. Laboratory chemical.
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
19-12-2012
Page 13
Danfoss Negative List of Chemicals
REACH Candidate List (sorted by inclusion date and then by substance name)
CAS no. 1
1319-46-6
Substance 2
Trilead bis(carbonate)dihydroxide
Risk 3
R
12141-20-7
2580-56-5
Trilead dioxide phosphonate
[4-[[4-anilino-1-naphthyl][4(dimethylamino)phenyl]methylene]cyclohexa-2,5-dien-1-ylidene]
dimethylammonium chloride (C.I. Basic Blue 26) [with ≥ 0.1% of Michler's ketone (EU No. 202-027-5) or Michler's base (EU No. 202-959-2)]
R
C
548-62-9
112-49-2
4-[4,4'-bis(dimethylamino) benzhydrylidene]cyclohexa-2,5-dien-1ylidene]dimethylammonium chloride (C.I. Basic Violet 3) [with ≥ 0.1%
of Michler's ketone (EU No. 202-027-5) or Michler's base (EU No. 202959-2)]
1,2-bis(2-methoxyethoxy)ethane (TEGDME; triglyme)
110-71-4
1,2-dimethoxyethane; ethylene glycol dimethyl ether (EGDME)
R
2451-62-9
1,3,5-Tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione (TGIC)
M
59653-74-6
1,3,5-tris[(2S and 2R)-2,3-epoxypropyl]-1,3,5-triazine-2,4,6-(1H,3H,5H)- M
trione (β-TGIC)
561-41-1
4,4'-bis(dimethylamino)-4''-(methylamino)trityl alcohol [with ≥ 0.1% of C
Michler's ketone (EU No. 202-027-5) or Michler's base (EU No. 202959-2)]
90-94-8
4,4'-bis(dimethylamino)benzophenone (Michler’s ketone)
C
1303-86-2
Diboron trioxide
R
October 2013
Occurrence 4
Pigment in paints and ceramic glazes. Catalyst in the preparation of polyesters from terephthalic acid and
diols, curing agent for peroxides to form improved polyethylene wire insulation, pearlescent pigment, colorchanging component of temperature-sensitive inks, red-reflecting pigment in iridescent plastic sheets,
smudge-resistant film on electrically sensitive recording sheets, lubricating grease component, component of
ultraviolet light reflective paints to increase solar reflectivity, improved cool gun-propellant stabilizer which
decomposes and forms a lubricating lead deposit, heat stabilizer for PVC polymers, component of weighted
nylon-reinforced fish nets made from PVC fibers.
Stabiliser used in production of pvc products.
Colorant with uses that may include dyes and inks, including in ball point pens and printer cartridges, cosmetics such as soaps, dyeing of paper, card, plastic, wood, lacquers and coatings, analytical / R&D/diagnostic
uses.
Date of inclusion
19-12-2012
C
Colorant with uses that may include dyes and inks, including in ball pens, cosmetics such as soaps, dyeing of
paper, card, plastic, wood, lacquers and coatings, analytical / R&D/diagnostic uses.
18-06-2012
R
Used as an industrial and process solvent. May also be used as a constituent within flexo gravure watersolvent based inks, lithographic plate developers and glass cleaning solvents. May be found in the electrolyte
system of lithium batteries (including consumer batteries).
Used as an industrial and process solvent. Also used as a constituent within flexo gravure water-solvent based
inks, lithographic plate developers and glass cleaning solvents. May be found in the electrolyte system of
lithium batteries (including consumer batteries)
Epoxy compound. Used as hardener in resins and coatings. May be used in solder mask applications in production of printed circuit boards. Also used in weather resistant polyester-based powder coatings. May be
found in electrical insulation materials, adhesives, laminated sheeting, silk-screen coatings, tools and stabilizers for plastics.
Epoxy compound. Used as hardener in resins and coatings. May be used in solder mask applications in production of printed circuit boards. Also used in weather resistant polyester-based powder coatings. May be
found in electrical insulation materials, adhesives, laminated sheeting, silk-screen coatings, tools and stabilizers for plastics.
Mainly used as a dye in writing inks. May be referred to as Solvent Violet 8, although the Color Index and CAS
registry numbers do not necessarily match. Solvent Violet 8 is used in inks (including ballpoint pens and
printer cartridges) and dyes. It may be used to color a variety of materials such as soaps, oil and fat products,
paper, wood, packaging, leather, candles, rubber. It may also be used in black dyes to color polyacrylonitrile
materials. It may be used in R&R / analytical / diagnostic applications and as an anti-allergen and bactericide.
Important intermediate in the manufacture of triphenylmethane dyes. May be used as a colouring agent in
the paper and paper products sector. May be present in dyes and pigments as a photosensitizer. May be
present as an impurity in other substances used as coloring agents.
Wide range of registered uses including soldering and welding agents, protective chemicals, in wood stone,
plaster, cement, ceramic and glass articles; inks, varnishes, paints, coatings, fertilizers, vehicle and machinery
parts, batteries, leather and textiles, paper, plastic.
18-06-2012
19-12-2012
18-06-2012
18-06-2012
18-06-2012
18-06-2012
18-06-2012
18-06-2012
18-06-2012
Page 14
Danfoss Negative List of Chemicals
REACH Candidate List (sorted by inclusion date and then by substance name)
CAS no. 1
75-12-7
Substance 2
Formamide
Risk 3
R
17570-76-2
Lead(II) bis(methanesulfonate)
R
101-61-1
N,N,N',N'-tetramethyl-4,4'-methylenedianiline (Michler’s base)
C
6786-83-0
107-06-2
α,α-Bis[4-(dimethylamino)phenyl]-4 (phenylamino)naphthalene-1C
methanol (C.I. Solvent Blue 4) [with ≥ 0.1% of Michler's ketone (EU No.
202-027-5) or Michler's base (EU No. 202-959-2)]
1,2-dichloroethane
C
101-14-4
2,2'-dichloro-4,4'-methylenedianiline
C
90-04-0
140-66-9
2-Methoxyaniline; o-Anisidine
4-(1,1,3,3-tetramethylbutyl)phenol
C
E
7778-39-4
Aluminosilicate Refractory Ceramic Fibres<br/><i> are fibres covered
C
by index number 650-017-00-8 in Annex VI, part 3, table 3.1 of Regulation (EU) No 1272/2008 of the EUropean Parliament and of the Council
of 16 DEUember 2008 on classification, labelling and packaging of
substances and mixtures, and fulfil the three following conditions: a)
oxides of aluminium and silicon are the main components present (in
the fibres) within variable concentration ranges b) fibres have a length
weighted geometric mean diameter less two standard geometric
errors of 6 or less micrometres (µm) c) alkaline oxide and alkali earth
oxide (Na2O+K2O+CaO+MgO+BaO) content less or equal to 18% by
weight</i>
Arsenic acid
C
111-96-6
Bis(2-methoxyethyl) ether
R
117-82-8
Bis(2-methoxyethyl) phthalate
R
7778-44-1
Calcium arsenate
C
24613-89-6
Dichromium tris(chromate)
C
October 2013
Occurrence 4
An intermediate used in the manufacture of pharmaceuticals and vitamins. Also used as a solvent, and as a
laboratory reagent. May also be used in the production of pyrimidines, in hydrogen cyanide production, as an
intermediate for paper finishing and as a solvent for example in the production of synthetic leather and inks.
Formamide may also be used to make triazoles as starting materials for crop protection (agrochemical)
products.
Main application is tin-lead electroplating on printed circuit boards. This application is in decline owing to the
restrictions on lead in electrical products as regulated in the EU by RoHS (2011/65/EU).
Chemical intermediate in the manufacture of dyes and pigments and in the manufacture of its hydrochloric
salt. May be used as an R&D reagent.
Colorant with uses that may include dyes and inks, including in ball pens, cosmetics such as soaps, fuels,
dyeing of paper, card, plastic, wood, lacquers and coatings, analytical / R&D/diagnostic uses. May be found in
Wind screen washing fluid.
Mainly used for manufacture of other substances. Minor uses as solvent in the chemical and pharmacectical
industry.
Mainly used as curing agent in resins and in the production of polymer articles and also for manufacture of
other substances. The substance may further be used in construction and arts.
Mainly used in the manufacture of dyes for tattooing and coloration of paper, polymers and aluminum foil.
Mainly used in the manufacture of polymer preparations and of ethoxylates. Further used as a component in
adhesives, coatings, inks and rubber articles.
Zirconia Aluminosilicate Refractory Ceramic Fibres are fibres covered by index number 650-017-00-8 in Annex
VI, part 3, table 3.1 of Regulation (EU) No 1272/2008 of the
European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of
substances and mixtures, and fulfil the three following conditions:
Date of inclusion
18-06-2012
Mainly used to remove gas bubbles from ceramic glass melt and in the production of laminated printed
circuit boards.
Used primarily as a reaction solvent or process chemical in a wide variety of applications. Used also as solvent
for battery electrolytes, and possibly in other products such as sealants, adhesives, fuels and automotive care
products.
No registration for this phthalate compound has been submitted to ECHA. Hence, the substance seems not to
be manufactured in or imported to the EU in quantities above 1 t/y. Main uses in the past were as plasticizer
in polymeric materials and paints, lacquers and varnishes, including printing inks
Calcium arsenate is present in complex raw materials imported for manufacture of copper, lead and a range
of precious metals. It appears mainly to be used as precipitating agent in copper smelting and to manufacture
diarsenic trioxide. However, most of the substance seems to be disposed of as waste.
Mainly used in mixtures for metal surface treatment in the aeronautic/aerospace, steel and aluminum coating sectors.
19-12-2011
18-06-2012
18-06-2012
18-06-2012
19-12-2011
19-12-2011
19-12-2011
19-12-2011
19-12-2011
19-12-2011
19-12-2011
19-12-2011
19-12-2011
Page 15
Danfoss Negative List of Chemicals
REACH Candidate List (sorted by inclusion date and then by substance name)
CAS no. 1
25214-70-4
Substance 2
Formaldehyde, oligomeric reaction products with aniline
Risk 3
C
13424-46-9
Lead diazide, Lead azide
R,
6477-64-1
Lead dipicrate
R
15245-44-0
Lead styphnate
R
127-19-5
N,N-dimethylacetamide
R
49663-84-5
77-09-8
Pentazinc chromate octahydroxide
Phenolphthalein
C
C
11103-86-9
Potassium hydroxyoctaoxodizincatedichromate
C
3687-31-8
Trilead diarsenate
C and R
96-18-4
Zirconia Aluminosilicate Refractory Ceramic Fibres<br /><i> are fibres C
covered by index number 650-017-00-8 in Annex VI, part 3, table 3.1 of
Regulation (EU) No 1272/2008 of the European Parliament and of the
Council of 16 December 2008 on classification, labelling and packaging
of substances and mixtures, and fulfil the three following conditions:
a) oxides of aluminium, silicon and zirconium are the main components present (in the fibres) within variable concentration ranges b)
fibres have a length weighted geometric mean diameter less two
standard geometric errors of 6 or less micrometres (µm). c) alkaline
oxide and alkali earth oxide (Na2O+K2O+CaO+MgO+BaO) content less
or equal to 18% by weight</i>
1,2,3-Trichloropropane
C and R
71888-89-6
68515-42-4
872-50-4
1,2-Benzenedicarboxylic acid, di-C6-8-branched alkyl esters, C7-rich
R
1,2-Benzenedicarboxylic acid, di-C7-11-branched and linear alkyl esters R
1-Methyl-2-pyrrolidone
R
111-15-9
2-Ethoxyethyl acetate
October 2013
R
Occurrence 4
Mainly used for manufacture of other substances. Minor uses are as hardener for epoxy resins, e.g. for the
production of rolls, pipes and molds, and as well for adhesives.
Mainly used as initiator or booster in detonators for both civilian and military uses and as initiator in pyrotechnic devices.
No registration for this substance has been submitted to ECHA. Lead dipicrate is an explosive like lead diazide
and lead styphnate. It may be used in low amounts in detonator mixtures together with the two other mentioned lead compounds.
Mainly used as a primer for small calibre and rifle ammunition. Other common uses are in munition pyrotechnics, powder actuated devices and detonators for civilian use.
Used as solvent, mainly in the manufacture of various substances and in the production of fibres for clothing
and other applications. Also used as reagent, and in products such as industrial coatings, polyimide films,
paint strippers and ink removers.
Mainly used in coatings in the vehicle coating and aeronautic / aerospace sectors.
Mainly used as laboratory agent (in pH indicator solutions), for the production of pH-indicator paper and in
medicinal products.
Mainly used in coatings in the aeronautic/ aerospace, steel and aluminum coil coating and vehicle coating
sectors.
Trilead diarsenate is present in complex raw materials imported for manufacture of copper, lead and a range
of precious metals. The trilead diarsenate contained in the raw materials is in the metallurgical refinement
process transformed to calcium arsenate and diarsenic trioxide. Whereas most of the calcium arsenate appears to be disposed of as waste the diarsenic trioxide is used further.
Zirconia Aluminosilicate Refractory Ceramic Fibres are fibres covered by index number 650-017-00-8 in Annex
VI, part 3, table 3.1 of Regulation (EU) No 1272/2008 of the
European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of
substances and mixtures, and fulfil the three following conditions:
Date of inclusion
19-12-2011
TCP is used as an industrial solvent, as a monomer and as an intermediate for the synthesis of chlorinated
solvents, some cross-linking agents and chlorinated solvents. Historically it had uses in consumer products
such as paint strippers but must no longer be supplied to the general public.
This substance may be used as a plasticizer for PVC and some ink and coatings formulations.
This substance may be used as a plasticizer for PVC.
This substance is used as an intermediate and as an industrial solvent for surface treatment of textiles, resins
and metal coated plastics or as a paint stripper. It is also used in the pharmacectical and agrochemical industries.
This substance is used as a solvent in some industrial adhesives and coatings, including wood stains, paints
and varnishes. As a substance its use is prohibited in cosmetic products and must not be supplied to the
general public.
20-06-2011
19-12-2011
19-12-2011
19-12-2011
19-12-2011
19-12-2011
19-12-2011
19-12-2011
19-12-2011
19-12-2011
20-06-2011
20-06-2011
20-06-2011
20-06-2011
Page 16
Danfoss Negative List of Chemicals
REACH Candidate List (sorted by inclusion date and then by substance name)
CAS no. 1
Substance 2
302-01-2, 7803-57-8 Hydrazine
Risk 3
C
02-06-7789
Strontium chromate
C
110-80-5
2-Ethoxyethanol
R
109-86-4
2-Methoxyethanol
R
7738-94-5, 1353068-2
Acids generated from chromium trioxide and their oligomers. Names
of the acids and their oligomers: Chromic acid, Dichromic acid, Oligomers of chromic acid and dichromic acid.
C
1333-82-0
Chromium trioxide
C and R
513-79-1
Cobalt(II) carbonate
C and R
71-48-7
Cobalt(II) diacetate
C and R
10141-05-6
Cobalt(II) dinitrate
C and R
10124-43-3
Cobalt(II) sulphate
C and R
7789-09-5
Ammonium dichromate
C, M
10043-35-3, 1111350-1
Boric acid
R
1303-96-4, 1330-43- Disodium tetraborate, anhydrous
4, 12179-04-3
R
7789-00-6
C and M
October 2013
Potassium chromate
Occurrence 4
Hydrazine is used as a foaming agent, as a precursor to polymerization catalysts and pharmaceuticals. Additionally, hydrazine is used in various rocket fuels and to prepare the gas precursors used in air bags. Hydrazine is also used as a corrosion inhibitor in steam plants.
Strontium chromate pigment is used as an anti-corrosion ingredient for some paints. It has uses in coatings
for the aerospace and vehicle sectors as well as in coil coating applications.
2-ethoxyethanol is mainly used as a chemical intermediate. Further minor uses are as a solvent or a laboratory chemical.
2-methoxyethanol is mainly used as a chemical intermediate. Further minor uses are as a solvent or a laboratory chemical.
Acids generated from chromium trioxide and their oligomers are mainly used in metal finishing, such as
electroplating (e.g. hard chrome and decorative plating), conversion coatings and brightening. It is also used
as a fixing agent in waterborne wood preservatives. Minor uses are e.g. in the manufacture of pigments and
paints, in catalyst and detergent manufacture, and as an oxidizing agent.
Chromium trioxide is mainly used in metal finishing, such as electroplating (e.g. hard chrome and decorative
plating), conversion coatings and brightening. It is also used as a fixing agent in waterborne wood preservatives. Minor uses are e.g. in the manufacture of pigments and paints, in catalyst and detergent manufacture,
and as an oxidizing agent.
Cobalt(II) carbonate is mainly used in the manufacture of catalysts. Minor uses may include as a feed additive,
in the manufacture of other chemicals including pigments, and as an adhesive in ground coat frit.
Cobalt(II) diacetate is mainly used in the manufacture of catalysts or as a catalyst. Minor uses may include the
manufacture of other chemicals including pigments, surface treatments, in alloys, dyes, rubber adhesion, and
as a feed additive.
Date of inclusion
20-06-2011
Cobalt(II) dinitrate is mainly used in the manufacture of other chemicals including catalysts. Further applications may include surface treatment and in batteries.
15-12-2010
Cobalt(II) sulphate is mainly used in the manufacture of other chemicals including pigments and possibly
catalysts, driers. Further applications comprise surface treatments (such as electroplating), corrosion prevention, decolorization (in glass, pottery), in batteries, animal food supplements and soil fertilizers
15-12-2010
Ammonium dichromate is mainly used as an oxidizing agent. Other known uses are in the manufacture of
photosensitive screens and as mordant in the manufacture of textiles. Minor uses seem to comprise metal
treatment and laboratory analytical agent
Boric acid is widely used on account of its consistency-influencing, flame-retarding, antiseptic and preservative properties. It is a component of detergents and cleaners, adhesives, toys, industrial fluids, brake fluids,
glass, ceramics, flame retardants, paints, disinfectants, cosmetics, food additives, fertilizers, insecticides and
other products. It is also used in paper manufacture.
Disodium tetraborate and tetraboron disodium heptaoxide form the same compounds in aqueous solutions.
Uses include a multitude of applications, e.g. in detergents and cleaners, in glass and glass fibers, ceramics,
industrial fluids, metallurgy, adhesives, flame retardants, personal care products, biocides, fertilizers.
Potassium chromate is used as a corrosion inhibitor for treatment and coating of metals, for manufacture of
reagents, chemicals and textiles, as a coloring agent in ceramics, in the manufacture of pigments/inks and in
the laboratory as analytical agent.
18-06-2010
20-06-2011
15-12-2010
15-12-2010
15-12-2010
15-12-2010
15-12-2010
15-12-2010
18-06-2010
18-06-2010
18-06-2010
Page 17
Danfoss Negative List of Chemicals
REACH Candidate List (sorted by inclusion date and then by substance name)
CAS no. 1
7778-50-9
Substance 2
Potassium dichromate
Risk 3
C, M and
03-11-7775
Sodium chromate
C, M and
R
12267-73-1
Tetraboron disodium heptaoxide, hydrate
R
79-01-6
Trichloroethylene
C
79-06-1
Acrylamide
C and M
121-14-2
2,4-Dinitrotoluene
C
90640-80-5
Anthracene oil
PBT and
vPvB
90640-81-6
Anthracene oil, anthracene paste
PBT and
vPvB
91995-15-2
Anthracene oil, anthracene paste, anthracene fraction
Occurrence 4
Potassium dichromate is used for chrome metal manufacturing and as corrosion inhibitor for treatment and
coating of metals. It is further used as textile mordant, as laboratory analytical agent, for cleaning of laboratory glassware, in the manufacture of other reagents and as oxidizing agent in photolithography.
Sodium chromate is mainly used as an intermediate in the manufacture of other chromium compounds as
well as a laboratory analytical agent, but this use is limited. Other potential uses are mentioned in the literature but whether they occur in the EU is not clear.
Disodium tetraborate and tetraboron disodium heptaoxide form the same compounds in aqueous solutions.
Uses include a multitude of applications, e.g. in detergents and cleaners, in glass and glass fibers, ceramics,
industrial fluids, metallurgy, adhesives, flame retardants, personal care products, biocides, fertilizers.
Trichlorethylene is mainly used as intermediate in the manufacture of chlorinated and fluorinated organic
compounds. Other uses are for cleaning and degreasing of metal parts or as solvent in adhesives.
Acrylamide is almost exclusively used for the synthesis of polyacrylamides, which are used in various applications, in particular in waste water treatment and paper processing. Minor uses of acrylamide comprise the
preparation of polyacrylamide gels for research purposes and as a grouting agent in civil engineering
2,4-dinitrotoluene is used in the production of toluene diisocyanate, which is used for the manufacture of
flexible polyurethane foams. The substance is also used as gelatinizingplasticizing agent for the manufacture of explosives.
The listed anthracene oil based substances are mainly used in the manufacture of other substances such as
anthracene and carbon black. They may also be used as reducing agents in blast furnaces, as components in
bunker fuel, for impregnating, sealing and corrosion protection. They are present in pitch, tars, bitumens and
will be found in finsihed goods such as electrodes, batteries, building sealants (tar based), road surfacing nd
clay pigeons
-
Date of inclusion
18-06-2010
-
13-01-2010
-
13-01-2010
-
13-01-2010
18-06-2010
18-06-2010
18-06-2010
30-03-2010
13-01-2010
13-01-2010
13-01-2010
PBT and
vPvB
91995-17-4
Anthracene oil, anthracene paste,distn. lights
PBT and
vPvB
90640-82-7
Anthracene oil, anthracene-low
PBT and
vPvB
84-69-5
Diisobutyl phthalate
R
13-01-2010
Diisobutyl phthalate is used as plasticiser for nitrocellulose, cellulose ether, polyacrylate and polyacetate
dispersions, and as a gelling aid in combination with other plasticisers,
which are widely used for plastics, lacquers, adhesives, explosive material and nail polish.
October 2013
Page 18
Danfoss Negative List of Chemicals
REACH Candidate List (sorted by inclusion date and then by substance name)
CAS no. 1
7758-97-6
Substance 2
Lead chromate
12656-85-8
Lead chromate molybdate sulphate red (C.I. Pigment Red 104)
Risk 3
C and R
C and R
1344-37-2
Lead sulfochromate yellow (C.I. Pigment Yellow 34)
C and R
Occurrence 4
Lead chromate is used for manufacturing pigments and dyes, and as a pigment or coating agent in industrial
and maritime paint products or varnishes. Further potential uses may
be ssociated with the formulation of detergents and bleaches, photosensitive materials, the manufacture of
pyrotechnic powder or the embalming / restoring of art products.
Lead chromate molybdate sulphate red (C.I. Pigment Red 104) is used as a colouring, painting and coating
agent in sectors such as the rubber, plastic and paints, coatings and
varnishes ndustries. Applications comprise the production of agricultural equipment, vehicles and aircraft as
well as road and airstrip painting.
Lead sulfochromate yellow (C.I. Pigment Yellow 34) is used as a colouring, painting and coating agent in
sectors such as the rubber, plastic and paints, coatings and varnishes
industries. Applications comprise the production of agricultural equipment, vehicles and aircraft as well as
road and airstrip painting. The substance is further used for camouflage or ammunition marking in the defence area.
Pitch, coal tar, high temp. is mainly used in the production of electrodes for industrial applications. Smaller
volumes are dedicated to specific uses such as heavy duty corrosion
protection, special purpose paving, and manufacture of other substances and the production of clay targets.
Date of inclusion
13-01-2010
Tris(2-chloroethyl)phosphate is mainly used as an additive plasticiser and viscosity regulator with flameretarding properties for acrylic resins, polyurethane, polyvinyl chloride and
other polymers. Other fields of application are adhesives, coatings, flame resistant paints and varnishes. The
main industrial branches to use TCEP are the furniture, the textile and the building industry.
Diaminodiphenylmethane (MDA) is used as a reagent in the manufacture of rubber, plastics, diisocyanates,
dyes and adhesives. In this use it is normally substantially consumed by conversion to other chemials. Historically, there is some evidence of trace residual amounts in flexible rubber products where used as a curing
agent. This substance is unlikely to be present above 0.1% in a supplied article.
13-01-2010
28-10-2008
13-01-2010
13-01-2010
65996-93-2
Pitch, coal tar, high temp.
C, PBT
and vPvB
115-96-8
Tris(2-chloroethyl)phosphate
R
101-77-9
4,4'- Diaminodiphenylmethane (MDA)
C
81-15-2
5-tert-butyl-2,4,6-trinitro-m-xylene (musk xylene)
vPvB
A fragrance which may be incorporated into complex fragrance mixtures. Although not manufactured in the
EU it may be formulated into imported fragrance compositions. This substance is very unlikely to be present
in any EU produced articles. BUT it may be found in fragrances in imported articles such as toilet blocks or
candles. The concentration is unpredictable and may exceed 0.1%.
85535-84-8
Alkanes, C10-13, chloro (Short Chain Chlorinated Paraffins)
PBT and
vPvB
120-12-7
Anthracene
PBT
85-68-7
Benzyl butyl phthalate (BBP)
R
SCCPs have had a variety of uses, including extreme pressure additives in metalworking fluids, flame retard28-10-2008
ants for rubbers and textiles, in leather processing and as a plasticiser in paints and sealing compounds. The
major recent use has been in metal working fluids. These substances are very unlikely to be present in articles
above 0.1%.
Anthracene is normally a complex low concentration impurity or trace constituent in petroleum products. It
28-10-2008
has been found in some wood preservatives and fuels. This substance is very unlikely to feature in any supplied articles over 0.1%. Present in significant quantities in coal tar products and other coal distillates.
Mostly used as a plasticiser for PVC, commonly in floor tiles. Other uses include in food conveyor belts, and
28-10-2008
artificial leather. This substance may be present above 0.1% in the articles described above. Action required
to investigate, particularly in the supply of replacement parts (tiles and conveyor belting).
October 2013
13-01-2010
28-10-2008
Page 19
Danfoss Negative List of Chemicals
REACH Candidate List (sorted by inclusion date and then by substance name)
CAS no. 1
117-81-7
Substance 2
Bis (2-ethylhexyl)phthalate (DEHP)
Risk 3
R
56-35-9
Bis(tributyltin)oxide (TBTO)
PBT
7646-79-9
Cobalt dichloride
C and R
1303-28-2
Diarsenic pentaoxide
C
1327-53-3
Diarsenic trioxide
C
84-74-2
Dibutyl phthalate (DBP)
R
25637-99-4, 319455-6 (134237-50-6)
(134237-51-7)
(134237-52-8)
7784-40-9
Hexabromocyclododecane (HBCDD) and all major diastereoisomers
identified: Alpha-hexabromocyclododecane Betahexabromocyclododecane Gamma-hexabromocyclododecane
PBT
Lead hydrogen arsenate
C and R
7789-12-0, 1058801-9
Sodium dichromate
C, M and
R
October 2013
Occurrence 4
DEHP is widely used as a plasticizer for PVC (usually >> 1%). Plasticised PVC has a wide but diminishing use
ranging from party clothing to gaskets, seals and medical devices. It should not be confused with UPVC, the
plasticiser free version, which is used for rigid applications such as building products. DEHP is also used as a
hydraulic fluid and as a dielectric fluid in liquid filled capacitors. DEHP may also be used in lightsticks. The
wide range of uses and attractive price of this substance means that its use in plasticised PVC articles (especially those) described above is foreseeable. This makes it a priority for investigation in the fabric, tubing,
adult and childrens toys, engineering, medical devices, electronics and electrical and novelty products sectors.
This substance is a biocide with major use in external wood treatment and ship descaling. It is possible that
this substance could be found in some imported timber products
intended for outdoor use, in boats or in recovered timbers. The quantity used in the final treated article may
vary and monitoring may be difficult. Possible concern for garden products including toys and play equipment.
The most common use is for the detection of moisture, for example as a color indicator in drying agents such
as silica gel. Paper impregnated with cobalt chloride, known as "cobalt chloride paper" has been used to
detect the presence of water. This substance is very unlikely to be present above 0.1% in any article other
than desiccants and laboratory test paper.
Diarsenic pentoxide is used in the manufacture of arsenates, old or non-EU weed killer, metal adhesives and
specialist insecticides, fungicides, and wood preservatives. Note that
use of arsenic compounds is serverely restricted already. It has been used in glass manufacture but this is
now very unlikely to occur. The substance is very unlikely to be present in articles above 0.1% except for
some old optical glasses.
This substance is used in lead alloys (especially in lead-acid batteries), glass (and, to a lesser extent, enamel)
production and as a source of high-purity arsenic for use in the
electronics industry.
This substance has widespread historical use as a plasticiser. It was also used as an additive to adhesives or
printing inks. Although responsible industry has been phasing out
the use of this substance there are concerns that it is still widely used. When used as a plasticiser the
amounts may be well above 0.1% in final products. This threshold is unlikely to be exceeded in any ink coated
article. This substance should be regarded as priority for investigation of its presence in any soft plastics and
adhesives. Any business sector dealing with these articles should be alert to this risk.
This substance is a flame retardant for plastics and fibres. It is used to produce flame retarded polystyrene
and to flame proof some clothing and furniture textiles. A narrow use
profile but there is a significant possibility that flame resistant polystyrene (as pre formed packaging shapes)
may contain this substance. These articles are widely used in the electronics and toy industries.
An insecticide for food. It has been widely banned for many years. This substance is very unlikely to be present in articles above 0.1%.
This substance is an important reagent for the production of a wide range of chemicals. It is aso used in metal
finishing process, leather tanning and in some ceramics / glasses.
This substance is very unlikely to be present in articles above 0.1% except in some coloured glazes and glasses. The latter are more likely to be found in craft / specialised articles than general purpose ceramics and
glasses.
Date of inclusion
28-10-2008
28-10-2008
28-10-2008
28-10-2008
28-10-2008
28-10-2008
28-10-2008
28-10-2008
28-10-2008
Page 20
Danfoss Negative List of Chemicals
REACH Candidate List (sorted by inclusion date and then by substance name)
CAS no. 1
15606-95-8
Substance 2
Triethyl arsenate
Risk 3
C
Occurrence 4
This substance is used in the manufacture of semiconductors and has been used in the production of wood
preservatives. In both cases the final quantity of the compound in a
finished article is expected to be less than 0.1%.
Date of inclusion
28-10-2008
Notes
In general: Use of the substances mentioned above, are accepted for analytical purposes by skilled personnel in chemical laboratories. Exemptions to RoHS or other regulations are accepted. The RoHS-restrictions are on each homogeneous material in the product, which means that the limits do not apply to the weight of the finished product. The substances that are included in Annex XIV are still present on the Candidate List in this document.
1) CAS means "Chemical Abstract Service", an internationally accepted system for identifying chemical substances
6) Maximum allowable concentration 0.1% (w/w) if not otherwise stated. The maximum allowable concentra2) Name(s) of substances in the group
tion for banned substances describes naturally occurring contaminations and not intentionally added sub3) Type of risk: A = allergenic; C = Cancerogenic; T = toxic; E = environmentally hazardous; M= Mutagenic; N =
stances.
neurotoxic; O = ozone depleting; R = reprotoxic; PBT = persistent, bio accumulative & toxic; vPvB = very persis7) Exemptions and general comments
tent and very bio accumulative.
8) The substances mentioned in the group of lubricants and degreasing agents are only prohibited when they
4) Typical examples of where you find the substance(s).
are used for this purpose, but the other substances outside this group are also prohibited in lubricants and
5) Reference is given to International conventions, EU legislation or national (DK) legislation. “Danfoss decision”
degreasing agents.
meaning: No reference to REACH, RoHS or other EU Legislation.
Relevant legislation
English title (link to document in English)
Link to the Danish document
Number
Year
EU Regulation REACH
EU Regulation, REACH
1907
2006
1907
2006
412
2012
EU Regulation REACH Annex XVII (including amendments)
List of restriction table
EU Regulation, REACH, Annex XVII, Entry 61 (Dimethylfumarate)
EU Regulation, REACH, Annex XIV (Recommendation for inclusion)
always check for
latest update
EU Regulation, REACH, Candidate List
EU Directive, RoHS
65
The Stockholm Convention on POPs
EU Regulation on Greenhouse gasses
The Kyoto Protocol
October 2013
2011
2001
EU Regulation on Greenhouse gasses
842
2006
Statutory order on Greenhouse gasses
552
2002
1997
Page 21
Danfoss Negative List of Chemicals
Relevant legislation
English title (link to document in English)
Link to the Danish document
Number
Year
EU Regulation on ozone depletion
EU Regulation on ozone depletion
1005
2009
Danish regulation on ozone depletion
243
2002
The Montreal Protocol
EU Regulation on Methylbromide
1999
EU Regulation on Methylbromide
2037
2007
Danish regulation on Mercury
627
2003
EU Regulation on sulfonates perfluorooctane
EU Regulation on sulfonates perfluorooctane
122
2006
EU Directive on restrictions on the use of pentabromo- and octabromodiphenyl ether
EU Directive on restrictions on the use of pentabromo- and octabromodiphenyl ether
11
2003
Danish regulation on lead
856
2009
EU Directive on Packaging and packaging waste
EU Directive on Packaging and packaging waste
62
1994
EU Directive on Marketing and use of certain dangerous substances and preparations
(asbestos)
Wall Street Reform and Consumer Protection Act. Section 1502.- Conflict Minerals
-
77
1999
2010
EPA, Ozone Layer Protection
Restrictions on N-nitrosamines (TRGS 611)
2007
Restrictions on N-nitrosamines (TRGS 615)
2007
October 2013
Page 22