7.6 Metals, Nonmetals, & Metalloids We have looked at properties of individual atoms (IE, EA, radius). Only the ________________ ___________________ exist as individual atoms in nature. Review properties of metals & nonmetals (Table 7.3, p. 264) Ge is a ________________ , Sn is a ________________ even though they are in the same group. How can you explain this difference? Metallic character ________________ down a group and ________________ across a period. Metals All metals are solid except for ________________ ; Cs and Ga melt just above room T Metals tend to have ________________ ionization energies and tend to form ________________ relatively easily. Since metals lose e- in reactions, they are ________________ . First ionization energy is the best indicator whether an element behaves as a metal or a nonmetal. Sn forms either a 2+ or 4+ ion. Why? Soluble metallic oxides react with water to form hydroxides: Na2O(s) + H2O CaO(s) + H2O Metallic oxides react with acid to produce a salt and water: NiO(s) + HNO3 p. 267 SE (a) Would you expect scandium oxide to me a solid, liquid, or gas at room T? (b) Write the net ionic equation for scandium oxide reacting with nitric acid: When the name of an acid has no prefix and ends in –ic (like sulfuric acid), the formula is H+ + the –ate ion (H+ combines with SO42- to make H2SO4). PE: copper(II) oxide and sulfuric acid Nonmetals ________________ , ________________ , or gas at room T. Melting points tend to be ________________ than metals. Nonmetals tend to ________________ e- to fill the outer p sublevel when they react with metals. Compounds of nonmetals tend to be __________________________ substances that are ________________ , ________________ , or ________________ with low ________________ ________________ . Nonmetallic oxides react with water to produce an acid CO2 + H2O This is why carbonate beverages are acidic and is one factor in acid rain. SO2 and SO3 produced from burning fuels are also responsible for acid rain. P4O10 + H2O Nonmetallic oxides react with bases to produce a salt and water CO2 + NaOH A compound, XCl3, has a melting point of -112oC. Would you expect the compound to me molecular or ionic? If you were told that X is either scandium or phosphorus, which do you think is the more likely choice? Write net ionic equations: SeO2 (s) + H2O SeO2(s) + NaOH(aq) P4O6(s) + H2O Read Metalloids on page 268 7.7 Trends for Group 1A and Group 2A Metals Read Group 1A: The Alkali Metals on page 269 Alkali metals combine directly with most nonmetals. When hydrogen combines with a metal, it forms the hydride ion (H-) Na + H2 K+S Alkali metals react with water to produce a metallic hydroxide (base) and hydrogen Li + H2O (this is an __________________________ reaction) Why are alkali metals stored in oil or kerosene? Write the balanced equations and net ionic equations for cesium metal reacting with (a) Cl2 (b) H2O (c) H2