Material Safety Data Sheet
ROYALSIL HI-PURITY AMEO
1: SUBSTANCE AND SUPPLIER INFORMATION
Trade Name:
ROYALSIL -HI-PURITY-AMEO
Supplier:
ROYALSIL Inc.
25 Lancelot Lane
Mount Laurel, NJ 08054
Phone Number:
856-866-0038
Use of the Substance/Preparation Function: For industrial & Research use as a
Coupling agent
Cross linking agents
Surface modifier
US: CHEMTREC emergency number:
800-424-9300
Canada: CANUTEC Emergency number: 613-996-6666
2: COMPOSITION INFORMATION ON COMPONENTS
Chemical Name:
3-Aminopropyltriethoxysilane
Alternative name:
3-(Triethoxysilyl)-1-propylamine
Formula:
C9H23NO3Si
Minor impurities:
Not determined
CAS Number:
919-30-2
EINECS Number:
2130484
Pre-registration No.: 05-2114534454-51-0000
Other Information:
The material is classified as hazardous under OSHA regulations.
3: HAZARDS INFORMATION
Form: Liquid
Color: Colorless to yellowish Odor: Amine like
EMERGENCY OVERVIEW:
Corrosive – Combustible liquid and vapor.
Harmful if swallowed. Causes severe skin and eye burns.
Target organ(s): Nerves. Liver
POTENTIAL HEALTH HAZARDS:
EYE CONTACT: Corrosive. May cause burns resulting in permanent damage.
SKIN CONTACT: Corrosive. May cause burns resulting in permanent damage.
INHALATION: May cause irritations of the respiratory tract.
INGESTION: Harmful if swallowed.
Corrosive and may cause severe and permanent damage to mouth, throat and stomach.
HMIS RATING:
NFPA RATING
HEALTH:
3
HEALTH:
3
FLAMMABILITY:
2
FLAMMABILITY: 2
PHYSICAL HAZARD:
1
REACTIVITY:
1
For additional information on toxicity, please refer to Section 11
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Material Safety Data Sheet
ROYALSIL HI-PURITY AMEO
4: SAFETY INFORMATION AND FIRST AID MEASURES
General Advice: Take off all contaminated clothing immediately.
Skin Contact: Wash off immediately with plenty of water. Consult a physician.
Dermal contact: In case of skin contact, flush with copious amounts of water for at least 15 minutes.
Remove contaminated clothing and shoes. If irritation persists or other symptoms are
observed, seek medical attention.
Eye contact: With eye held open, thoroughly flush with copious amounts of water for at least 15
minutes while protecting unharmed eye if only one eye is affected.
To assure adequate flushing, separate eyelids with fingers. Call a physician. If possible
bring affected person for immediate further treatment to an ophthalmic hospital or
ophthalmologist. Continue rinsing eye or eyes until arrival at ophthalmic hospital or
ophthalmologist.
Inhalation:
If aerosol or mists are formed:
Possible discomfort: Severe irritation of mucous lining (nose, throat, eyes) coughing,
sneezing, flow of tears. Take affected person out into the fresh air. If not breathing give
artificial respiration. If breathing is difficult, keep patient half sitting with upper body
raised. Give oxygen if available. Call a physician immediately.
Oral Exposure: If swallowed, wash out mouth with water provided person is conscious. Call physician. Do
not induce vomiting.
Ingestion:
Do not induce vomiting.
Only when patient is fully conscious:
Have the mouth rinsed with water.
Have patient drink plenty of water in small sips.
Notify ambulance immediately (keyword: Chemical burn)
5: FIRE & FLAMMABIITY INFORMATION:
Conditions of flammability:
Under fire conditions, material may decompose to form
flammable and/or explosive mixtures in air.
Flash point:
208.40F – 98.00C: Closed Cup Method
199.00F – 93.00C: DIN 51758 Method
Explosion limits:
Lower: 0.8%
Upper: 4.5%
Auto ignition temperature:
N/A
Flammability:
N/A
Extinguishing Media:
Suitable: Carbon dioxide, dry chemical powder, or appropriate
foam. Unsuitable: Do not use water.
Fire Fighting:
Protective equipment. Wear self-contained positive pressure breathing
apparatus (MSHA/NIOSH approved or equivalent) and full protective
clothing to prevent contact with skin and eyes.
Specific Hazard(s):
Emits toxic fumes under fire conditions. Combustible.
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Material Safety Data Sheet
ROYALSIL HI-PURITY AMEO
6: ACCIDENTAL RELEASE INFORMATION:
Procedure to be followed in case of leak or spill: Evacuate Area.
Procedures of personal precautions: Wear self contained breathing apparatus, chemical safety goggles,
Rubber boots and heavy rubber gloves.
Methods for cleaning up: Cover and soak up with absorbent material with dry lime, sand, silica gel, acid
binder, saw dust or soda ash. Pick up, and place in a marked sealable container and hold for waste
disposal in accordance with existing federal, provincial, state and local regulations. Ventilate area and
wash spill site after material pick up is complete.
Environmental Precautions: Obey relevant local, state, provincial and federal laws and regulations. Do
not contaminate any lakes, streams, rivers or other water bodies or groundwater or soils.
7: STORAGE AND HANDLING INFORMATION:
Shelf Life:
When stored under recommended conditions the product will be viable for 1 year after
the drum is opened. It is recommended to use a Drierite System or similar device if you
cannot purge with Nitrogen every time you open the drum.
Handling:
User exposure: Do not breath vapor. Avoid contact with eyes, skin and on
clothing. Avoid prolonged or repeated exposure.
Storage:
Suitable: Keep container tightly closed. Store in a cool dry place. Handle and store
under nitrogen. Keep containers tightly closed in a cool, well ventilated place. Protect
from all forms of moisture. Residual vapors might explode on ignition. Do not apply heat,
cut, drill or weld on or near this container for any reason at any time.
Special requirements: Moisture sensitive. Handle and store under inert gas.
8: PERSONAL PROTECTION & EXPOSURE CONTROLS:
Engineering controls: Use only in a chemical fume hood. Safety shower and eye bath.
Personal protective equipment:
Respiratory: Government approved respirator that meets OSHA 1910.134 and ANSI Z88.2 or applicable
federal or provincial or state requirements must be followed when ever workplace conditions warrant
respirator use. NIOSH’s “Respirator Decision Logic” may be useful in determining the suitability of various
types of respirators. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU). Where risk assessment shows air-purifying respirators are
appropriate use a full face respirator with multi-purpose combination (US) or type ABEK (EN 14387)
respirator cartridges as a backup to engineering controls. If respirator is the sole means of protection, use
full face supplied air respirator.
Hand:
Compatible chemical-resistant gloves.
Eye:
Chemical safety goggles. Face shield (8 inch minimum)
Skin:
Protective clothing.
General hygiene measures: Wash contaminated clothing before reuse. Discard contaminated shoes. Wash
thoroughly after handling. Avoid contact with eyes and skin. Do not inhale gases/vapors/aerosols. Do not
eat, drink or smoke while handling.
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Material Safety Data Sheet
ROYALSIL HI-PURITY AMEO
9: PHYSICAL & CHEMICAL INFORMATION:
Molecular Formula
C9H23NO3Si
Molecular Weight
221.37 AMU
Viscosity 250C
2 CST
BP/BP Range
213-2160C
Flash Point
1080C
Color & Appearance
Colorless transparent liquid
Density 25/250C
1.045
Refractive Index
1.423 {250C]
Melting Point
N/A
Freezing Point
N/A
Vapor Pressure
<10 mmHg @ 100 C
Vapor Density
7.7 g/l
Saturated Vapor Conc. N/A
Specific Gravity/Density 0.949 g/cm3
Flash Point
208.40F or 980C Method: Cleveland Open Cup
Explosion Limits Lower 0.8%
Explosion Limits Upper 4.5%
Refractive Index
1.423
pH
11.3 (500 g/l) @ 20 0C
10: REACTIVITY & STABILITY
Conditions of Instability:
May decompose on exposure to moist air or water.
Conditions of avoid:
Protect from moisture
Materials to avoid:
Strong oxidizing agents. Water and acids react with material to liberate
ethanol. Heat or reaction may ignite vapors of alcohol, oxidizing agents or acids.
Hazardous decomposition products: Thermal decomposition may produce carbon monoxide, carbon
dioxide, nitrogen oxide and silicon oxide.
Hazardous Polymerization – Will not occur
11: TOXICOLOGICAL INFORMATION
Route of Exposure
Skin contact:
Skin absorption:
Eye contact:
Inhalation:
Causes burns.
May be harmful if absorbed through the skin.
Causes burns.
Material is extremely destructive to the tissue of the mucous membranes
and upper respiratory tract. May be harmful if inhaled
Ingestion:
May be harmful if swallowed
Target Organ(s) or System(s): Nerves. Liver. Kidney.
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Material Safety Data Sheet
ROYALSIL HI-PURITY AMEO
Signs and Symptoms of Exposure: Material is extremely destructive to the tissue of the mucous
membranes and upper respitory tract, eyes and skin.
Inhalation may result in spasm, inflammation and edema of the larynx and bronchi, chemical
pneumontis and pulmonary edema.
Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness
of breath, headache, nausea and vomiting.
TOXICITY DATA:
Oral Rat: 1780 mg/kg LD 50
Oral Mouse: 4000 mg/kg LD 50
Product Acute Dermal Toxicity: 4,000 mg/kg (RETECS)
Remarks: Behavioral: Excitement. Lungs, Thorax or
Respiration: Emphysema.
Blood: Changes in Leukocytes (WBC) count.
Intraperitoneal Mouse: 260 MG/KG LD 50
Skin Rabbit:
260 MG/KG LD50
Oral Mammal: 4000 mg/kg LD 50
IRRATATION DATA:
Skin Rabbit:
0.1 mg 24 Hour Remarks: Open irritation test.
5.0 mg 24 Hour Remarks: Severe Irritation Effect.
Eyes Rabbit: 100 mg Remarks: Mild Irritation Effect
0.75 mg 24 Hours Remarks: Severe Irritation Effect.
12: ENVIRONMENTAL & ECOLOGICAL INFORMATION
GENERAL: Take care to prevent chemicals from entering the ground, water courses or drainage systems.
13: DISPOSAL INFORMATION
Appropriate method of disposal of substance or preparation: Contact a licensed professional waste
disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and
burn in a chemical incinerator equipped with an afterburner and scrubber.
Empty containers must be handled with care due to product residue. DO NOT HEAT OR CUT THE EMPTY
CONTAINER WITH ELECTRIC OR GAS TORCH. Observe all federal, state, and local environmental
regulations
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Material Safety Data Sheet
ROYALSIL HI-PURITY AMEO
14: TRANSPORT INFORMATION
DOT Road / Rail Shipment Information: (49 CFR 172.101)
Proper Shipping Name: CORROSIVE LIQUID, BASIC, ORGANIC N.O.S.
Hazard Technical Name: GAMMA-AMINOPROPYLTRIETHOXYSILANE or 3-AMINOPROPYLTRIETHOXYSILANE
Hazard Class: 8
UN/NA Number: UN3267
Packing Group: II
Hazard Label(s): CORROSIVE LIQUID, Basic, Organic, N.O.S.
Ocean – Sea Transport: (IMDG Code)
Proper Shipping Name: CORROSIVE LIQUID, BASIC, ORGANIC N.O.S.
Hazard Technical Name: GAMMA-AMINOPROPYLTRIETHOXYSILANE or 3-AMINOPROPYLTRIETHOXYSILANE
Hazard Class: 8
UN/NA Number: UN3267
Packing Group: II
Hazard Label(s): CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.
Marine Pollutant: Not Applicable.
Air Shipment: (ICAO-TI/IATA-DGR)
Proper Shipping Name: CORROSIVE LIQUID, BASIC, ORGANIC N.O.S.
Hazard Technical Name: GAMMA-AMINOPROPYLTRIETHOXYSILANE or 3-AMINOPROPYLTRIETHOXYSILANE
Hazard Class: 8
UN/NA Number: UN3267
Packing Group: II
Hazard Label(s): CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.
Loading Instructions/Remarks
IATA-C
ERG-Code 8L
IATA-P
ERG-Code 8L
IMDG
Clear of living quarters
IMDG
Keep separate from acids
15: REGULATORY INFORMATION
US Federal Regulations:
OSHA
If listed below, chemical specific standards apply to the product components:
 None listed.
Clean Air Act Section (112)
If listed below, components present at or above the de minimus level are hazardous air pollutants:
 None listed.
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Material Safety Data Sheet
ROYALSIL HI-PURITY AMEO
CERCLA Reportable Quantities
If listed below, a reportable quantity (RQ) applies to the product based on the % of the named
component:
 None listed.
SARA Title III Section 311/312 Hazard Categories
The Product meets the criteria only for the listed hazard classes:
 Acute health hazard.
 Fire hazard.
SARA Title III Section 313 Hazard Categories
If listed below, components are subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendments and reauthorization Act of 1986 and 40 CFR Part 372
 None Listed.
Toxic Substances Control Act (TSCA)
If listed below, non-proprietary substances are subject to export notification under Section 12 (b) of TSCA:
 None Listed.
State Regulations
The listing requirements of the Right to Know (RTK) legislation varies by state. All information for NJ, PA,
MA and other states can be derived from the listing of hazardous and non-hazardous components in
section 2 and 15 of this MSDS.
California Proposition 65
A warning under the California Drinking Water Act is required if listed below:
 None Listed.
International Chemical Inventory Status
Unless otherwise noted, this product is in compliance with the inventory listing of the countries shown
below. For information on listing for countries not shown, contact Royalsil Inc. management.
 Europe (ENIECS/ELINCS)
Listed Registered
 USA (TSCA)
Listed Registered
 Canada (DSL)
Listed Registered
 Australia (AICS)
Listed Registered
 JAPAN (MITI)
Listed Registered
 Korea (TCCL)
Listed Registered
 Philippines (PICCS)
Listed Registered
 China
Listed Registered
EU DIRECTIVES CLASSIFICATIONS
Symbol of Danger: C
Indication of Danger: Corrosive
R: 22 34
Risk Statements: Harmful if swallowed. Causes burns.
S: 26 36/37/39 45
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Material Safety Data Sheet
ROYALSIL HI-PURITY AMEO
Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice. Wear suitable protective coating, gloves, and eye/face protection. In case of an accident or if you
feel unwell, seek medical advice immediately. (Show the label when possible)
US CLASSIFICATION AND LABLE TEXT:
Indication of Danger: Corrosive
Risk Statements: Harmful if swallowed. Causes burns.
Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice. Wear suitable protective coating, gloves, and eye/face protection. In case of an accident or if you
feel unwell, seek medical advice immediately. (Show the label when possible)
US Statements: Target organ(s): Nerves. Liver.
CANADA REGULATORY INFORMATION:
WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR,
and the MSDS and contains all information required by CPR.
DSL: Yes
NDSL: NO
16 – ADDITIONAL INFORMATION
It must be recognized that the physical and chemical properties of any product may not be fully understood and
that new, possible hazardous products may arise from reactions between chemicals.
The information provided in this Material Safety Data Sheet is based on present knowledge and shall not
constitute a guarantee for any specific product features and shall not establish a legally valid contractual
relationship. It is correct to the best of ROYALSIL Inc. knowledge, information and belief at the date of its
publication.
DISCLAIMER: This chemical is to be used exclusively for R & D and Industrial use only unless elsewhere
specified as such. Not for drug, household or other uses.
WARRANTY: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as guidance for safe handling, use, processing, storage, transportation, disposal and
release and is not to be considered a warranty or quality specification.
The information relates only to the specific material designated and may not be valid for such materials
used in combination with any other materials or in any process, unless specified by text.
The reseller, ROYALSIL Inc., shall not, under any and all conditions, be held liable for any damage
resulting from handling or from contact with the above mentioned product.
Last Modified: 11-24-10
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