Material Safety Data Sheet
ROYALSIL HI-PURITY AMMO
1: SUBSTANCE AND SUPPLIER INFORMATION
Trade Name:
ROYALSIL -HI-PURITY AMMO
Supplier:
ROYALSIL Inc.
25 Lancelot Lane
Mount Laurel, NJ 08054
Phone Number:
856-866-0038
Use of the Substance/Preparation Function: For industrial & Research use as a
Coupling agent
Cross linking agents
Surface modifier
US: CHEMTREC emergency number:
800-424-9300
Canada: CANUTEC Emergency number:
613-996-6666
2: COMPOSITION INFORMATION ON COMPONENTS
Chemical Name:
3-Aminopropyltrimethoxysilane
Alternative name:
3-(Trimethoxysilyl)-propylamine
Formula:
C6H17NO3Si
Minor impurities:
Not determined
CAS Number:
13822-56-5
Other Information:
The material is classified as hazardous under OSHA regulations.
3: HAZARDS INFORMATION
Form: Liquid
Color: Colorless to yellowish Odor: Amine like
EMERGENCY OVERVIEW:
Corrosive – Combustible liquid and vapor.
Harmful if swallowed. Causes severe skin and eye burns.
Target organ(s): Nerves. Liver
POTENTIAL HEALTH HAZARDS:
EYE CONTACT: Causes eye irritation.
SKIN CONTACT: Causes skin irritation.
INHALATION: No hazard expected. Do not inhale.
INGESTION: No hazard expected. Do not swallow.
Corrosive and may cause severe and permanent damage to mouth, throat and stomach.
HMIS RATING:
HEALTH: 3
FLAMMABILITY:
2
PHYSICAL HAZARD: 1
Chronic Health Hazard: This material generates methanol on hydrolysis. Methanol is harmful if inhaled or
absorbed through the skin. Causes damage to the liver, kidney and nervous system. Causes eye, skin, nose and
throat irritation. May be fatal or cause blindness if swallowed. Cannot be made non poisonous.
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Material Safety Data Sheet
ROYALSIL HI-PURITY AMMO
4: SAFETY INFORMATION AND FIRST AID MEASURES
General Advice: Take off all contaminated clothing immediately.
Skin Contact: Wash off immediately with plenty of water. Consult a physician in event of permanent
irritation.
Dermal contact: In case of skin contact, flush with copious amounts of water for at least 15 minutes.
Remove contaminated clothing and shoes. If irritation persists or other symptoms are
observed, seek medical attention.
Eye contact: With eye lid held open, thoroughly flush with copious amounts of water for at least 10
minutes while protecting unharmed eye if only one eye is affected.
To assure adequate flushing, separate eyelids with fingers. Call a physician. If possible
bring affected person for immediate further treatment to an ophthalmic hospital or
ophthalmologist. Continue rinsing eye or eyes until arrival at ophthalmic hospital or
ophthalmologist.
Inhalation:
If aerosol or mists are formed: Take affected person out into the fresh air. In case of
persistent discomfort then call a physician immediately.
Oral Exposure: If swallowed, wash out mouth with water provided person is conscious. Call physician. Do
not induce vomiting.
Ingestion:
Have the mouth rinsed with water. Call a physician immediately.
NOTES TO PYSICIAN: If required, therapy or irritative effect.
After absorbing larger amounts of substance: Liberation of reaction products (Methanol)
can lead to symptoms of poisoning. Daze, dizziness, nausea, colicky abdominal pain,
respiratory disturbance. Symptoms upon increasing intoxication: Dystopia, loss of
eyesight.
Treatment: Immediate gastric lavage. Antidote treatment, correction of acid-base balance.
Detection of substance (methanol) possible in blood. Antidote treatment: ethanol.
5: FIRE & FLAMMABIITY INFORMATION:
Conditions of flammability:
Under fire conditions, material may decompose to form
flammable and/or explosive mixtures in air.
Flash point:
208.40F – 98.00C: Closed Cup Method
194.00F – 90.00C: DIN 51758 Method
Explosion limits:
Lower: Not Determined Upper: Not determined.
Auto ignition temperature:
295.00C Method: DIN 51 794
Flammability:
N/A
Extinguishing Media:
Suitable: Foam water spray, or CO2 dry powder.
Fire Fighting:
Protective equipment. Hazardous fumes in fire, specific to product:
Nitrogen Oxide (NOx) as in any fire, wear self contained positive pressure
breathing apparatus. (MSHA/NIOSH approved or equivalent) and full
protective gear.
Specific Hazard(s):
Emits toxic fumes under fire conditions.
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Material Safety Data Sheet
ROYALSIL HI-PURITY AMMO
6: ACCIDENTAL RELEASE INFORMATION:
Procedures of personal precautions: Use personal protective equipment.
Methods for cleaning up: Soak up with absorbent material (E.G. sand, silica gel, acid binder, universal
binder, saw dust). Pick up, and place in a marked sealable container and hold for waste disposal in
compliance with existing federal, provincial, state and local regulations. Ventilate area and wash spill site
after material pick up is complete.
Environmental Precautions: Obey relevant local, state, provincial and federal laws and regulations. Do
not contaminate any lakes, streams, rivers or other water bodies or groundwater or soils. Do not allow
entrance in soil, stretches of water or drainage systems.
7: STORAGE AND HANDLING INFORMATION:
Shelf Life:
When stored under recommended conditions the product will be viable for 1 year after
the drum is opened. It is recommended to use a Drierite System or similar device if you
cannot purge with Nitrogen every time you open the drum.
Handling:
Safe handling advice during application or processing is to provide good ventilation or
extraction.
Advice on protection against fire and explosion. Keep away from sources of ignition.
Positively no smoking.
Storage:
Suitable: Keep container tightly closed. Store in a cool, dry, well ventilated place. Handle
and store under nitrogen. Protect from all forms of moisture. Residual vapors might
explode on ignition. Do not apply heat, cut, drill or weld on or near this container for any
reason at any time.
Special requirements: Moisture sensitive. Handle and store under inert gas.
8: PERSONAL PROTECTION & EXPOSURE CONTROLS:
Engineering controls: Safety shower and eye bath. Provide good ventilation and extraction.
Personal protective equipment:
Respiratory: In case of dust/vapors/aerosols being formed or if the limit values like TLV are exceeded then
use respiratory equipment with suitable filter or wear a self contained respiratory apparatus.
Government approved respirator that meets OSHA 1910.134 and ANSI Z88.2 or applicable federal or
provincial or state requirements must be followed when ever workplace conditions warrant respirator
use. NIOSH’s “Respirator Decision Logic” may be useful in determining the suitability of various types of
respirators.
Use respirators and components tested and approved under appropriate government standards such as
NIOSH (US) or CEN (EU). Where risk assessment shows air-purifying respirators are appropriate use a full
face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a
backup to engineering controls. If respirator is the sole means of protection, use full face supplied air
respirator.
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Material Safety Data Sheet
ROYALSIL HI-PURITY AMMO
Hand:
Compatible chemical-resistant gloves.
Glove material: Butyl rubber or equivalent
Material Thickness: 0.5 mm
Break Through Time: = 480 minutes
Glove material: Fluorinated rubber (Viton) or equivalent
Material Thickness: 0.4 mm
Break Through Time: = 480 minutes
Selection of protective gloves to meet the requirements of specific workplaces.
Suitability for specific workplaces should be clarified with protective glove manufacturers.
The information is based on reference from the literature. Remember that the useful time of day of a
chemical protection glove may be much shorter than the permeation time determined according to EN
374 due to the many different influential factors involve (e.g. temperature).
Eye:
Close fitting chemical safety goggles.
Skin & Body protection: A safety shower and eye wash fountain should be readily available. TO identify
additional Personal Protective Equipment (PPE) requirements, it is recommended that a hazard
assessment in accordance with OSHA PPE standard (29CFR1910.132) be conducted before using this
product.
General hygiene measures: Wash contaminated clothing before reuse. Discard contaminated shoes. Wash
thoroughly after handling. Avoid contact with eyes and skin. Do not inhale gases/vapors/aerosols. Do not
eat, drink or smoke while handling.
9: PHYSICAL & CHEMICAL INFORMATION:
Molecular Formula
C9H23NO3Si
Molecular Weight
221.37 AMU
Viscosity 250C
2 CST
BP/BP Range
1940C (1013 hPa) Method DIN 51751
Flash Point
900C
Color & Appearance
Colorless transparent liquid
Density 25/250C
1.045
Refractive Index
1.423 {250C]
Melting Point
N/A
Freezing Point
N/A
Vapor Pressure
Not Determined
Vapor Density
Not Determined
Saturated Vapor Conc. N/A
Specific Gravity/Density 0.949 g/cm3
Flash Point
208.40F or 980C Method: Cleveland Open Cup
Explosion Limits Lower Not Determined
Explosion Limits Upper Not Determined
pH
> 9.0 @ 20 0C
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Material Safety Data Sheet
ROYALSIL HI-PURITY AMMO
10: REACTIVITY & STABILITY
Conditions of Instability:
May decompose on exposure to moist air or water.
Conditions of avoid:
Protect from moisture
Materials to avoid:
Strong oxidizing agents. Water and acids react with material to liberate
ethanol. Heat or reaction may ignite vapors of alcohol, oxidizing agents or acids.
Hazardous decomposition products: Produces methanol in the event of hydrolysis
Hazardous Polymerization – Exothermic reaction with: acids.
11: TOXICOLOGICAL INFORMATION
Route of Exposure
Skin contact:
Causes irritation.
Skin absorption:
May be harmful if absorbed through the skin.
Eye contact:
Causes irritation.
Inhalation:
Material is an irritant.
Ingestion:
May be harmful if swallowed
Target Organ(s) or System(s): Nerves. Liver. Kidney.
Signs and Symptoms of Exposure: See section 8 of this MSDS.
TOXICITY DATA:
Oral Rat: 2000 mg/kg LD 50
Product Acute Dermal Toxicity: 2,000 mg/kg LD50 Rabbit
Skin Sensitization:
guinea pig – non sensitizing
Oral Toxicity: Ingestion of methanol releasing compounds may result in delayed damage to optic
nerves, causing permanent blindness, and if untreated may cause other potentially fatal toxic
effects. There are much reported warnings in the literature on methanol.
12: ENVIRONMENTAL & ECOLOGICAL INFORMATION
GENERAL: Take care to prevent chemicals from entering the ground, water courses or drainage systems.
13: DISPOSAL INFORMATION
Appropriate method of disposal of substance or preparation: Contact a licensed professional waste
disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and
burn in a chemical incinerator equipped with an afterburner and scrubber.
Empty containers must be handled with care due to product residue. DO NOT HEAT OR CUT THE EMPTY
CONTAINER WITH ELECTRIC OR GAS TORCH. Observe all federal, state, and local environmental
regulations.
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Material Safety Data Sheet
ROYALSIL HI-PURITY AMMO
14: TRANSPORT INFORMATION
DOT Road / Rail Shipment Information: (49 CFR 172.101)
Hazard Technical Name: GAMMA-AMINOPROPYLTRIMETHOXYSILANE or 3-AMINOPROPYLTRIMETHOXYSILANE
Hazard Class: Combustible Liquid
UN/NA Number: UN1993
Packing Group: III
Loading Instructions/Remarks
IATA-C
Not classified as dangerous in the meaning of transport regulations.
IATA-P
Not classified as dangerous in the meaning of transport regulations.
IMDG
Not classified as dangerous in the meaning of transport regulations.
IATA-C & IATA-P & IMDG: USA: OBSERVE RQ
15: REGULATORY INFORMATION
US Federal Regulations:
OSHA
If listed below, chemical specific standards apply to the product components:
 None listed.
Clean Air Act Section (112)
If listed below, components present at or above the de minimus level are hazardous air pollutants:
 None listed.
CERCLA Reportable Quantities
If listed below, a reportable quantity (RQ) applies to the product based on the % of the named
component:
 None listed.
SARA Title III Section 311/312 Hazard Categories
The Product meets the criteria only for the listed hazard classes:
 Acute health hazard.
SARA Title III Section 313 Hazard Categories
If listed below, components are subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendments and reauthorization Act of 1986 and 40 CFR Part 372
 None Listed.
Toxic Substances Control Act (TSCA)
If listed below, non-proprietary substances are subject to export notification under Section 12 (b) of TSCA:
 None Listed.
State Regulations
The listing requirements of the Right to Know (RTK) legislation varies by state. All information for NJ, PA,
MA and other states can be derived from the listing of hazardous and non-hazardous components in
section 2 and 15 of this MSDS.
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Material Safety Data Sheet
ROYALSIL HI-PURITY AMMO
California Proposition 65
A warning under the California Drinking Water Act is required if listed below: None Listed.
International Chemical Inventory Status:
Unless otherwise noted, this product is in compliance with the inventory listing of the countries shown
below. For information on listing for countries not shown, contact Royalsil Inc. management.
 Europe (ENIECS/ELINCS)
Listed Registered
 USA (TSCA)
Listed Registered
 Canada (DSL)
Listed Registered
 Australia (AICS)
Listed Registered
 JAPAN (MITI)
Listed Registered
 Korea (TCCL)
Listed Registered
 Philippines (PICCS)
Not Listed Registered
 China
Not Listed Registered
16 – ADDITIONAL INFORMATION
HMIS Rating:
HEALTH:
3
FLAMMABILITY
2
PHYSICAL HAZARD
1
Further Information:
It must be recognized that the physical and chemical properties of any product may not be fully understood and
that new, possible hazardous products may arise from reactions between chemicals.
The information provided in this Material Safety Data Sheet is based on present knowledge and shall not
constitute a guarantee for any specific product features and shall not establish a legally valid contractual
relationship. It is correct to the best of ROYALSIL Inc. knowledge, information and belief at the date of its
publication.
DISCLAIMER: This chemical is to be used exclusively for R & D and Industrial use only unless elsewhere
specified as such. Not for drug, household or other uses.
WARRANTY: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as guidance for safe handling, use, processing, storage, transportation, disposal and
release and is not to be considered a warranty or quality specification.
The information relates only to the specific material designated and may not be valid for such materials
used in combination with any other materials or in any process, unless specified by text.
The reseller, ROYALSIL Inc., shall not, under any and all conditions, be held liable for any damage
resulting from handling or from contact with the above mentioned product.
Last Modified: 11-24-10
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