PHY 335 Exam II Name ________________________ Instructions: Place your name on all of the pages. Do all of your work in this booklet. Do not tear off any sheets. Show all of your steps in the problems for full credit. Be clear and neat in your work. Any illegible work, or scribbling in the margins, will not be graded. Put a box around your answers when appropriate.. If you need more space, you may use the back of a page and write On back of page # in the problem space or the attached blank sheets. No other scratch paper is allowed. Try to answer as many problems as possible. Provide as much information as possible. Show sufficient work or rationale for full credit. Remember that some problems may require less work than brute force methods. If you are stuck, or running out of time, indicate as completely as possible, the methods and steps you would take to tackle the problem. Also, indicate any relevant information that you would use. Do not spend too much time on one problem. Pace yourself. Pay attention to the point distribution. Not all problems have the same weight. Be careful to note units and use an appropriate number of significant digits. Page Pts 1 22 2 18 3 18 4 12 Total 70 Score Constants h 6.626 10 34 Js, 1.055 1034 Js , a0 0.5292 1010 m, me 9.11 1031 kg, mp 1.67 1027 kg, 1eV 1.6 1019 J ________________________________________________________________________ Bonus: a. Who introduced the concept of matter waves? ______________________________ b. Enter the quantum numbers (n,l,m) for hydrogenic probability densities shown on the right. ___ ___ ___ ___ ___ ___ PHY 335 Exam II Name ________________________ 1. (12 pts) Evaluate the following: a. Simplify to standard form: b. Simplify: (1 i )3 (1 i ) 2 2i 3 4i c. Put in exact standard form without trigonometric functions: 6e3 i /4 . 2 d. Evaluate: , for ( x, t ) 5e2t i (3 x 5t ) 2. (6 pts) Let k 3 . Find the phase and group velocities. 3. (4 pts) It takes 4.0 eV to excite an electron in a one dimensional box from the ground state to the first excited state. What is the length of the box in nm? PHY 335 Exam II Name ________________________ 4. (6 pts) A molecule of mass 2.0 1024 kg is moving along at a speed of 100 10 m/sec. The molecule is localized in space and is described by a traveling wave packet solution to the Schrödinger wave equation centered around x 0 at t 0 and moving in the positive x direction. a. What is the minimum uncertainty Δx in the determination of its position? b. What is the de Broglie wavelength of this molecule? 5. (12 pts) Suppose a particle in a box has an initial wavefunction given by 3 x ( x, 0) A sin , 0 x 4. 4 a. What must A be for the wavefunction to be normalized? b. What is the initial probability density at x 2? c. What is the probability that the particle is initially in the interval [2,3]? d. What is the energy of the particle? [Leave in terms of , , and m.] e. What is ( x,5), i.e., what is the wave function at t 5? PHY 335 Exam II Name ________________________ 6. (9 pts) Consider the quantum harmonic oscillator. a. Write the one dimensional time independent Schrödinger equation for ( x) for the quantum harmonic oscillator. b. Sketch the potential energy V ( x ) and wavefunction 3 ( x) for the quantum harmonic oscillator. c. What is the energy E3 associated with 3 ( x)? 7. (9 pts) The z-component of the angular momentum operator takes the form LZ i x y . x y a. Calculate [ Lz , y] for ( x, y, z ). b. Let 322 (r , , ) be a hydrogen wave function. Complete the following eigenvalue problems for this wave function using the appropriate quantum numbers: i. Lz 322 ii. L2 322 iii. H 322 PHY 335 Exam II Name ________________________ 8. (12 pts) A free electron of kinetic energy 2.5 eV is traveling in a straight line to the right. It approaches a region of constant potential of +2.6 eV. a. What are the wave number k1 (in m-1)and wavelength 1 (in m) of the electron in the free region on the left? b. Does the electron propagate as a wave in the region on the right or does its wavefunction decrease exponentially? ________________________ c. If it propagates, what is the wave number k2 (in m-1) of the electron in this region on the right? If it decays away exponentially, what is the decay constant α in the expression e x ? d. Does the electron undergo any reflection at x 0? Explain in one or two sentences.