Lesson: Radioactive Decay & Dating Prentice Hall Conceptual Physics Chapter 39, Atomic and Nuclear Physics Section 39.2 Radioactive Decay Section 39.4 Radioactive Isotopes Section 39.5 Radioactive Half-Life Support provided by: Context of Lesson The purpose of this lesson is to provide students with a basic understanding of radioactive decay and its application—radiometric dating, in this instance—in the earth sciences. The activity can be used to teach observation skills, data collection, interpretation of graphs, organization of data, analyzing and mathematical skills, and making evidence based conclusions. This lesson will build on the students’ study of atoms in sections 39.2, 39.4, and 39.5 of Prentice Hall Conceptual Physics. The lesson will be taught over the course of one class period, and the knowledge gained in this lesson will lay the foundation for understanding scientists’ use of physics chemistry to study rocks, fossils, and the dating (or “aging”) of them. Main Goals/Objectives Students will be able to: Explain radioactivity, including the concepts of isotopes, radioactive decay, and half-lives. Collect, analyze, and interpret data, read graphs, and report results. General Alignment to Standards Mathematics State Goal 8. Use algebraic and analytical methods to identify and describe patterns and relationships in data, solve problems and predict results. D. Use algebraic concepts and procedures to represent and solve problems. ILS 8.D.4 Formulate and solve linear and quadratic equations and linear inequalities algebraically and investigate nonlinear inequalities using graphs, tables, calculators and computers. Science State Goal 11. Understand the processes of scientific inquiry and technological design to investigate questions, conduct experiments and solve problems. A. Know and apply the concepts, principles and processes of scientific inquiry. 1 ILS 11.A.4c Collect, organize and analyze data accurately and precisely. Science State Goal 12. Understand the fundamental concepts, principles and interconnections of the life, physical and earth/space sciences. E. Know and apply concepts that describe the features and processes of the Earth and its resources. ILS 12.E.4b Describe how rock sequences and fossil remains are used to interpret the age and changes in the Earth. Teacher Lab Preparation In addition to having a clock (with a second hand) for the entire class and one calculator per group, 48 small cards (each about 2x2 inches) are required. They may be cut from cardboard or construction paper, preferably with a different color on opposite sides, and each card or button should be marked with "U-235" on one colored side and "Pb-207" on the opposite side. Materials For each group of 5 or 6 students: Watch or clock that keeps time (seconds required). Materials from the Harris Educational Loan Program: o 300 Million Years Ago in Illinois Experience Box, or o Fossil Plants of Illinois Exhibit Case One calculator for each group. 48 small cards (each about 2x2 inches) for each group. The cards may be cut from cardboard or construction paper, preferably with a different color on opposite sides, each marked with "U-235" all on one colored side and "Pb-207" on the opposite side. Copies of the Understanding Radioactive Decay and Ages of Rocks & the Fossils in Them activity sheets; 1 copy of each activity sheet per student (NOTE: Blank activity sheets are provided at the end of the lesson). Transparency of Uranium-235 decay series (attached) to project to the class. Optional if students are not graphing Uranium-235 atoms over time: transparencies of graphs (attached). Optional but recommended: Internet access to view Dr. Meenakshi Wadhwa’s video on radioactivity and radiometic dating at http://www.fieldmuseum.org/evolvingplanet/precambrian_15.asp. Lesson Introduction This lesson should follow a discussion of subatomic particles and atoms, as presented in sections 39.2, 39.4, and 39.5 of Prentice Hall Conceptual Physics textbook. 2 Introduce students to the concepts of radiation and radioactivity: radioactive atoms emit radiation because their nuclei are unstable—a process called radioactive decay. As indicated in Section 39.4 of the textbook, unstable radioactive atoms (called radioisotopes) undergo radioactive decay until they form stable non-radioactive atoms, often of a different element. For example, uranium-235 is an unstable radioisotope that has 92 protons and 143 neutrons in the nucleus of each atom. As a result of radioactive decay, it emits several particles, ending up with 82 protons and 125 neutrons. This is a stable condition, and there are no more changes in the atomic nucleus. A nucleus with that number of protons is called lead (Pb). The protons (82) and neutrons (125) total 207. This particular form of lead is called lead-207. Uranium-235 is the parent radioisotope of lead-207, which is the daughter radioisotope. Explain that radioactive decay rates are measured in half-lives. A half-life is the time required for one-half of a radioisotope’s nuclei to decay into its products. For example, the half-life of strontium-90 is 29 years. If you had 10.0g of strontium-90 today, 29 years from now you would have 5.0g left. The half-life of uranium-235 is 704 million (that’s 704,000,000!) years. In other words, during 704 million years, half the U-235 atoms that existed at the beginning of that time will decay to lead-207. Some half lives are several billion years long, and others are as short as a ten-thousandth of a second. Explain to your students that the “decay” presented in this activity is greatly simplified from the actual decay of uranium-235. Uranium-235 does not become lead-207 in a single step, but rather changes into a radioactive daughter isotope, thorium-231. The thorium then decays into another radioisotope, which then decays into another radioisotope, etc. The entire process is called a decay series and is shown in the attached diagram (figure 2). You may use this diagram to show the atoms involved as the uranium decays into lead. For more advanced discussion, you may use figure 2 as you explain the emission of alpha particles and beta particles from the nucleus. Nuclei of radioactive atoms are unstable and they are unstable because there are either too many protons or too many neutrons in the nucleus. An atom can change the ratio of protons to neutrons by ejecting an alpha particle (2 protons and 2 neutrons) from the nucleus. This is called alpha decay. Also, an atom may change the ratio of protons to neutrons when a neutron changes into a proton with the simultaneous ejection of an electron from the nucleus. This is called beta decay. In the uranium-235 decay series, there are alpha and beta emissions. Because of the constant decay rates associated with radioactive atoms, they can be used to determine the ages of rocks or fossils that contain the atoms. Many rocks contain small amounts of unstable radioisotopes. When the amounts of parent and daughter radioisotopes can be accurately measured, and when the half-life rate is known, the ratio can be used to determine the age of the rock or fossil. 3 Some students may wonder how scientists know that there is no daughter nucleus in the original mineral when it is first formed. You may point out that scientists don’t just examine one mineral and they don’t measure the amount of just two isotopes. To accurately determine the age of the rock, they must look at stable isotopes of daughter isotopes that were formed with the original radioactive material. Then they must look at the isotope ratios in other minerals. Finally, all of the data are compiled and analyzed to determine the age of the minerals. Uranium-235 is only one isotope that is used to date rocks and minerals. Table 1 lists common parent isotopes (and their half-lives) used for radiometric dating. You might want to copy this and hand it out or project it on a screen for your class. These concepts can be reviewed by watching the video that features Dr. Meenakshi Wadhwa at http://www.fieldmuseum.org/evolvingplanet/precambrian_15.asp You may want to show this video in parts, stopping after a short section to explain what is going on and to let the information sink in. After you show the video in sections, you might want to repeat it so that students see the segment uninterrupted. Note to Teacher This is not a traditional cookbook lab and lacks a written procedure that the students can follow. This may be extremely frustrating for most students. You need to support and monitor their inquiry without directing it. Resist the temptation to tell them the answers; rather, answer their questions with a guiding question. Some students have been taught that the increments along graph axes must be constant and unbroken. These students will have questions when they first see the logarithmic scale on the fraction of uranium-235 remaining versus age of the rock graph. You may have to help students understand the construction of this graph. Lesson Modifications Instead of 4-6 students per group, this activity could be done using 2 or 3 students per lab group. Of course, this would require additional sets of 48 cards. If you can find enough index cards, stock paper, or thick white construction paper, you can cut (or, students can cut if you have enough scissors) the cards and then have students carefully make the symbols on each side of the card. At the end of the activity, collect the cards to reuse them for another class or for the following year. A color indicator should be used so that students know when a card is representing a stable atom, 207Pb, and when it is representing a radioactive atom, 235U. You should tell students that stable atoms do not change, and that their 207Pb cards should not be turned back—those cards should be left alone. Choose a color that you think best represents an unstable particle, perhaps red, and a color that you think best represents stability, perhaps blue. Use these colors to write the 235U and 207Pb symbols, respectively. Emphasize that one color is to be turned over and one color must not be touched. 4 Many students pick up the concept of half-life quickly, and shortening the time interval of the card turning would keep these students engaged. Also, shortening the time intervals would leave more time for graphing, answering questions, and discussion. To greatly shorten the activity, use 48-second time intervals instead of 2-minute time intervals. During the first 48-second interval, have students flip the cards every 2 seconds. During the next 48-second interval, flip the cards every 4 seconds. In the third 48-second interval, flip the cards every 8 seconds, and in the fourth and final interval, flip the cards every 16 seconds. An alternative to having lab groups time the card turning would be to have one official timer (which could be you). The timer would announce when to flip cards and when the time interval is complete. This type of organization further reduces the activity time and allows the teacher more control in the case of mistakes. The teacher can check student progress at the end of each interval, walking among the lab groups and checking the status of the cards while students are completing their data tables. Activity – Part 1 (Understanding Radioactive Decay) Uranium-235 (also written as U-235) is found in many rocks. Unless the rock is heated to a very high temperature, both the U-235 and its daughter lead-207 (also written as Pb207) remain in the rock. A scientist can compare the proportion of U-235 atoms to the Pb-207 atoms produced from it and determine the age of the rock. The following activity will demonstrate the technique of radioactive dating! Divide the class into groups consisting of 4 to 6 students. Each group receives 48 small pieces of paper (about 2x2 inches), with U-235 written on one side and Pb-207 written on the other side. Also distribute the Understanding Radioactive Decay activity sheets (one sheet per student). Each group should place each marked piece of paper so that "U-235" is showing. This represents uranium-235, which emits a series of particles from the nucleus as it decays to Pb-207. When each team is ready with the 48 pieces all showing "U-235", a timed twominute interval should start. During the first two minute interval, each team turns over one piece of paper every 5 seconds. After the first two minutes, 24 of the U-235 pieces, or half, will have been turned over to now show Pb-207. This represents one "half-life" of U-235; the half-life is the time for half the nuclei to change from the parent U-235 to the daughter Pb-207. A second two-minute interval begins. During the second interval, the team should turn over half of the U-235 that was left after the first interval. To do so, students will have to turn over one piece of paper every 10 seconds. Emphasize that the rate of change from U235 to Pb-207 changes from the first interval, but the overall result is the same: after the two minutes, half of the U-235 pieces will have been turned over to show Pb-207. This represents the second half-life. 5 There are now 12 pieces of paper with “U-235” showing. Continue through a third twominute interval, turning over one piece of the remaining U-235 every 20 seconds. After two minutes, groups will end with 6 U-235. Finally, continue with a fourth two-minute interval, turning over one piece of the remaining U-235 every 40 seconds. After two minutes, groups will end with 3 U-235. After all the timed intervals have occurred, the task now for each team is to determine how many timed half-lives the set of pieces they are looking at has experienced. Ask students to record this information in the appropriate column on the activity sheet. NOTE: The number of half-lives equals the number of timed intervals. The half life of U-235 is 704 million years. Based on the proportion of U-235 to Pb-207 present after the 4 timed intervals (i.e., half-lives), ask each team to determine how many million years are represented by the proportion of U-235 and Pb-207 present. Ask students to record this information in the appropriate column on the activity sheet. NOTE: The age equals the number of half-lives multiplied by 704 million years. 6 Understanding Radioactive Decay Name ______________________________ Period _____ Partners ________________________________________________________________ Procedure: 1) Place each marked piece of paper so that "U-235" is showing. Uranium-235 emits a series of particles from the nucleus as it decays to Pb-207. Time 1: Start a timed two-minute interval and turn over one piece of paper every 5 seconds. Only turn cards that show “U-235” and leave the cards that show “Pb-207” untouched on the table. After the interval, record the number of “U-235” and “Pb-207” cards showing and note the number of half-lives that just occurred in the “Time 1” line of the data table. (You may change the time interval to 48 seconds. If so, cross out “twominutes” and write “48-seconds” in its place. If you do this, you will be turning over a piece of paper every 2 seconds. Then, cross out “5 seconds” and write “2 seconds” instead.) After the first two minutes, 24 of the U-235 pieces, or half, will have been turned over to now show Pb207. This represents one "half-life" of U-235; the half-life is the time for half the nuclei to change from the parent U-235 to the daughter Pb-207. 2) Time 2: Begin a second two-minute interval. During the second interval, turn over one piece of “U-235” paper every 10 seconds. Only turn cards that show “U-235” and leave the cards that show “Pb-207” untouched on the table. After the interval, record the number of “U-235” and “Pb-207” cards showing and note the number of half-lives that just occurred in the “Time 2” line of the data table. (Again, you may change the time interval to 48 seconds, if you have done so for the last interval. If so, cross out “twominutes” and write “48-seconds” in its place. If you do this, you will be turning over a piece of paper every 4 seconds. Then, cross out “10 seconds” and write “4 seconds” instead.) Emphasize that the rate of change from U-235 to Pb-207 changes from the first interval, but the overall result is the same: after the second two-minute interval, half of the 24 U-235 pieces will have been turned over to now show a total of 12 U-235 cards and 36 Pb-207 cards. This represents the second half-life. 3) Time 3: Continue through a third two-minute interval, turning over one piece of the remaining U-235 every 20 seconds. Only turn cards that show “U-235” and leave the cards that show “Pb-207” untouched on the table. After the interval, record the number of “U-235” and “Pb-207” cards showing and note the number of half-lives that just occurred in the “Time 3” line of the data table. (Again, you may change the time interval to 48 seconds, if you have done so for the previous two intervals. If so, cross out “two- 7 minutes” and write “48-seconds” in its place. If you do this, you will be turning over a piece of paper every 8 seconds. Then, cross out “20 seconds” and write “8 seconds” instead.) After two minutes, groups will end with 6 U-235 cards and 42 Pb-207 cards. This represents half-life number three. 4) Continue with a fourth two-minute interval, turning over one piece of the remaining U235 every 40 seconds. Only turn cards that show “U-235” and leave the cards that show “Pb-207” untouched on the table. After the interval, record the number of “U-235” and “Pb-207” cards showing and note the number of half-lives that just occurred in the “Time 4” line of the data table. (For this last interval, you may change the time to 48 seconds, if you have done so for the previous three intervals. If so, cross out “two-minutes” and write “48-seconds” in its place. If you do this, you will be turning over a piece of paper every 16 seconds. Then, cross out “40 seconds” and write “16 seconds” instead.) After two minutes, groups will end with 3 U-235 and 45 Pb-207; this represents the fourth half-life. 5) Now, based on the number of half-lives, determine the age of the sample. For each timed interval, the age equals the number of half-lives multiplied by 704 million years. 6) (Optional) Make two graphs of your data. On one graph place the number of uranium235 cards on the y-axis and the time elapsed when the cards were counted on the x-axis. For the second graph, use a calculator to determine the base-ten logarithm (“log function”) of the number of uranium-235 cards left. Then graph log (card number) on the y-axis and the time elapsed when the cards were counted on the x-axis. 8 Table - Decay of U-235 to Pb-207 Time elapsed (seconds) Time 0 Number of Number of “U-235” “Pb-207” Cards Cards Age (=No. of Half-Lives x 704 million years) 0 0 0 24 1 704 million years 0 48 Time 1 Number of Half-Lives 120 (or 48) 24 Time 2 240 (or 96) 12 36 2 1408 million years (=1.408 billion years) Time 3 360 (144) 6 42 3 2112 million years (=2.112 billion years) Time 4 480 (or 192) 3 45 4 2816 million years (=2.816 billion years) 9 Activity – Part 2 (Ages of Rocks & the Fossils in Them) Begin the second part of the activity by displaying the 300 Million Years Ago in Chicago Experience Box or the Fossil Plants of Illinois Exhibit Case from The Field Museum’s Harris Educational Loan Program. Explain that the fossils are found in rocks. Once taken to a laboratory and removed, they provide clues to help scientists understand the history of life on Earth, but key to this understanding is knowing the age of fossils. The fossils in the boxes/cases are from Illinois—just 60 miles southwest of Chicago—and they are 300 million years old! But how do scientists determine the ages of fossils? The following activity will demonstrate the dating of fossil-bearing rocks! Distribute the Ages of Rocks & the Fossils in Them activity sheet to students. The block diagram represents a section of the earth. Now… 1) Explain that, in the rocks depicted in the diagram, the ratio of U-235 to Pb207 atoms in the pegmatite is 1:1. Using the same reasoning about proportions as in Part 1 above, ask students to determine how old the pegmatite and the granite are. Remember, the half-life of U-235 is 704 million years. Ask students to write the age of the pegmatite beside the names of the rocks in the list below the diagram. The pegmatite is 704 million years old (i.e., it formed 704,000,000 years ago). 2) By plotting the half-life on a type of scale known as a logarithmic scale, it is possible for students to find the ages of rocks based on the ratios of U-235 to Pb-207 atoms. Such a graph is especially helpful for ratios of parent isotope to daughter isotope that represent less than one half life. This scale (“Figure 4. Half life of U-235”) can be found on the last page of this lesson. Present the following example to the students: If geochemical analyses determine that the volcanic ash that is in the siltstone has a ratio of U-235:Pb-207 of 47:3, find its age. To find its age using the logarithmic scale… STEP 1: 47 + 3 = 50; STEP 2: 47 / 50 = 0.94 = 94% STEP 3: Use the logarithmic scale to find the age. The ash in the siltstone is 70 million years old. 3) The U-235:Pb-207 ratio in the granite is 1:3, and the U-235:Pb-207 ratio in the basalt is 7:3. Using the steps outlined directly above, find the ages of the 10 granite and the basalt. Ask students to write the age of the siltstone, granite, and basalt beside the names of the rocks in the list below the diagram. The basalt is 350 million years old. STEP 1: 7 + 3 = 10; STEP 2: 7 / 10 = 0.70 = 70% STEP 3: Use the logarithmic scale to find the age. The granite is 1400 million years old. STEP 1: 1 + 3 = 4; STEP 2: 1 / 4 = 0.25 = 25% STEP 3: Use the logarithmic scale to find the age. 11 Ages of Rocks & the Fossils in Them Name ______________________________ Period _____ Partners ________________________________________________________________ Procedure: 1) In the rocks depicted in the diagram below, the ratio of U-235 to Pb-207 atoms in the pegmatite is 1:1. Determine how old the pegmatite and the granite are. Remember, the half-life of U-235 is 704 million years. Write the age of the pegmatite in the blank beside the name of the rock in the list below the diagram. The pegmatite is 704 million years old (i.e., it formed 704,000,000 years ago). 2) By plotting the half-life on a type of scale known as a logarithmic scale, it is possible to find the ages of rocks based on the ratios of U-235 to Pb-207 atoms. For example… If geochemical analyses determine that the volcanic ash that is in the siltstone has a ratio of U-235:Pb-207 of 47:3, you can use the scale to find the age… STEP 1: 47 + 3 = 50; STEP 2: 47 / 50 = 0.94 = 94% STEP 3: Use the logarithmic scale to find the age. ANSWER: The ash in the siltstone is 70 million years old. 3) The U-235:Pb-207 ratio in the granite is 1:3, and the U-235:Pb-207 ratio in the basalt is 7:3. Using the same steps in #2 above, find the ages of the granite and the basalt and write their ages in the blanks below. The basalt is 350 million years old: STEP 1: 7 + 3 = 10; STEP 2: 7 / 10 = 0.70 = 70% STEP 3: Use the logarithmic scale to find the age. The granite is 1400 million years old: STEP 1: 1 + 3 = 4; STEP 2: 1 / 4 = 0.25 = 25% STEP 3: Use the logarithmic scale to find the age. 12 FOSSIL OCCURRENCES: Bacteria remains are found in the slate. Fossils of trilobites (ancient relatives of insects) are found in the limestone. Dinosaur bones are found in the siltstone. ROCK UNIT Most Recent Rock Formed: Siltstone RADIOMETRIC AGE 70 Million Years Ago Basalt 350 Million Years Ago Limestone Pegmatite 704 Million Years Ago Sandstone Slate Oldest Rock: Granite 1400 Million Years Ago 13 Questions 1) Based on the available radiometric ages, can you determine the possible age of the rock unit that has the bacteria? What is it? Why can't you say exactly what the age of the rock is? The slate that contains the bacteria is between 704 million years and 1400 million years old, because the pegmatite is 704 million years old and the granite is 1400 million years old. The slate itself has not been radiometrically dated, so can only be bracketed between the ages of the granite and the pegmatite. 2) Can you determine the possible age of the rock unit that has trilobites? What is it? Why can't you say exactly what the age of the rock is? The limestone with the trilobites overlies the pegmatite; it underlies the basalt. Therefore, limestone must be younger than 704 million years (the age of the pegmatite) and older than 350 million years (the age of the basalt). The limestone itself is not radiometrically dated, so can only be bracketed between the ages of the granite and the pegmatite. 3) What is the age of the rock that contains the dinosaur fossils? Why can you be more precise about the age of this rock than you could about the ages of the rock that has the trilobites and the rock that contains fossilized bacteria? The dinosaur fossils are definitely younger than 350 million years because the siltstone formed on top of the basalt. But we can be more precise and say that the dinosaur remains are approximately 70 million years old because they are found in shale and siltstone that contain volcanic ash, which was radiometrically dated at 70 million years. Any dinosaur found below the volcanic ash may be a little older than 70 million years, and any found above may be a little younger than 70 million years. The age of the dinosaur fossils can be determined more closely than those of the bacteria and trilobites because the rock unit that contains the dinosaur is radiometrically dated, whereas that of the other fossils could not. 4) From your first graph (U-235 atoms (cards) on the y-axis and time on the x-axis), is there a relationship between the rate of decay and the number of U-235 atoms left? How will the radioactivity change over time? As the number of cards decreases, the rate of decay decreases proportionally. For example, when the number of cards decreases by one-half, the rate of decay decreases by one-half. (This is an example of a first-order reaction and students may review this again later in the unit on reaction rates.) The radioactivity will decrease just as the rate of 14 decay decreases. That is, fewer particles and less energy will be emitted over time as the sample decays. 5) What is the shape of the graph with log (U-235 atoms (cards)) on the y-axis versus time on the x-axis? This is a linear graph. It is an identifying characteristic of a first order reaction. 15 16 Table 1 Primary Parent and Daughter Isotopes Used to Determine the Ages of Rocks and Minerals Parent Isotope (Radioactive) 40 K 87 Rb 147 Sm 176 Lu 187 Re 232 Th 235 U 238 U Daughter Isotope (Stable) 40 Ar 87 Sr 143 Nd 176 Hf 187 Os 208 Pb 207 Pb 206 Pb Half-life (Millions of Years) 1 250 48 800 106 000 35 900 43 000 14 000 704 4 470 From Dalrymple, G. Brent, The Age of the Earth, Stanford University Press, 1991 17 18 19 Understanding Radioactive Decay Name ______________________________ Period _____ Partners ________________________________________________________________ Procedure: 1) Place each marked piece of paper so that "U-235" is showing. Uranium-235 emits a series of particles from the nucleus as it decays to Pb-207. Time 1: Start a timed two-minute interval and turn over one piece of paper every 5 seconds. Only turn cards that show “U-235” and leave the cards that show “Pb-207” untouched on the table. After the interval, record the number of “U-235” and “Pb-207” cards showing and note the number of half-lives that just occurred in the “Time 1” line of the data table. (You may change the time interval to 48 seconds. If so, cross out “twominutes” and write “48-seconds” in its place. If you do this, you will be turning over a piece of paper every 2 seconds. Then, cross out “5 seconds” and write “2 seconds” instead.) 2) Time 2: Begin a second two-minute interval. During the second interval, turn over one piece of “U-235” paper every 10 seconds. Only turn cards that show “U-235” and leave the cards that show “Pb-207” untouched on the table. After the interval, record the number of “U-235” and “Pb-207” cards showing and note the number of half-lives that just occurred in the “Time 2” line of the data table. (Again, you may change the time interval to 48 seconds, if you have done so for the last interval. If so, cross out “twominutes” and write “48-seconds” in its place. If you do this, you will be turning over a piece of paper every 4 seconds. Then, cross out “10 seconds” and write “4 seconds” instead.) 3) Time 3: Continue through a third two-minute interval, turning over one piece of the remaining U-235 every 20 seconds. Only turn cards that show “U-235” and leave the cards that show “Pb-207” untouched on the table. After the interval, record the number of “U-235” and “Pb-207” cards showing and note the number of half-lives that just occurred in the “Time 3” line of the data table. (Again, you may change the time interval to 48 seconds, if you have done so for the previous two intervals. If so, cross out “twominutes” and write “48-seconds” in its place. If you do this, you will be turning over a piece of paper every 8 seconds. Then, cross out “20 seconds” and write “8 seconds” instead.) 20 4) Continue with a fourth two-minute interval, turning over one piece of the remaining U235 every 40 seconds. Only turn cards that show “U-235” and leave the cards that show “Pb-207” untouched on the table. After the interval, record the number of “U-235” and “Pb-207” cards showing and note the number of half-lives that just occurred in the “Time 4” line of the data table. (For this last interval, you may change the time to 48 seconds, if you have done so for the previous three intervals. If so, cross out “two-minutes” and write “48-seconds” in its place. If you do this, you will be turning over a piece of paper every 16 seconds. Then, cross out “40 seconds” and write “16 seconds” instead.) 5) Now, based on the number of half-lives, determine the age of the sample. 6) (Optional) Make two graphs of your data. On one graph place the number of uranium235 cards on the y-axis and the time elapsed when the cards were counted on the x-axis. For the second graph, use a calculator to determine the base-ten logarithm (“log function”) of the number of uranium-235 cards left. Then graph log (card number) on the y-axis and the time elapsed when the cards were counted on the x-axis. 21 Table - Decay of U-235 to Pb-207 Time elapsed (seconds) Number of Number of “U-235” “Pb-207” Cards Cards Time 0 48 Time 1 24 0 Time 2 Time 3 Time 4 22 Number of Half-Lives Age (=No. of Half-Lives x 704 million years) 0 0 Ages of Rocks & the Fossils in Them Name ______________________________ Period _____ Partners ________________________________________________________________ Procedure: 1) In the rocks depicted in the diagram below, the ratio of U-235 to Pb-207 atoms in the pegmatite is 1:1. Determine how old the pegmatite and the granite are. Remember, the half-life of U-235 is 704 million years. Write the age of the pegmatite in the blank beside the name of the rock in the list below the diagram. 2) By plotting the half-life on a type of scale known as a logarithmic scale, it is possible to find the ages of rocks based on the ratios of U-235 to Pb-207 atoms. For example… If geochemical analyses determine that the volcanic ash that is in the siltstone has a ratio of U-235:Pb-207 of 47:3, you can use the scale to find the age… STEP 1: 47 + 3 = 50; STEP 2: 47 / 50 = 0.94 = 94% STEP 3: Use the logarithmic scale to find the age. ANSWER: The ash in the siltstone is 70 million years old. 3) The U-235:Pb-207 ratio in the granite is 1:3, and the U-235:Pb-207 ratio in the basalt is 7:3. Using the same steps in #2 above, find the ages of the granite and the basalt and write their ages in the blanks below. 23 FOSSIL OCCURRENCES: Bacteria remains are found in the slate. Fossils of trilobites (ancient relatives of insects) are found in the limestone. Dinosaur bones are found in the siltstone. ROCK UNIT Most Recent Rock Formed: Siltstone RADIOMETRIC AGE __________ Basalt __________ Limestone Pegmatite __________ Sandstone Slate Oldest Rock: Granite __________ 24 Questions 1) Based on the available radiometric ages, can you determine the possible age of the rock unit that has the bacteria? What is it? Why can't you say exactly what the age of the rock is? 2) Can you determine the possible age of the rock unit that has trilobites? What is it? Why can't you say exactly what the age of the rock is? 3) What is the age of the rock that contains the dinosaur fossils? Why can you be more precise about the age of this rock than you could about the ages of the rock that has the trilobites and the rock that contains fossilized bacteria? 4) From your first graph (U-235 atoms (cards) on the y-axis and time on the x-axis), is there a relationship between the rate of decay and the number of U-235 atoms left? How will the radioactivity change over time? 5) What is the shape of the graph with log (U-235 atoms (cards)) on the y-axis versus time on the x-axis? 25 Figure 1 26 Figure 2 27 Table 1 Primary Parent and Daughter Isotopes Used to Determine the Ages of Rocks and Minerals Parent Isotope (Radioactive) 40 K 87 Rb 147 Sm 176 Lu 187 Re 232 Th 235 U 238 U Daughter Isotope (Stable) 40 Ar 87 Sr 143 Nd 176 Hf 187 Os 208 Pb 207 Pb 206 Pb Half-life (Millions of Years) 1 250 48 800 106 000 35 900 43 000 14 000 704 4 470 From Dalrymple, G. Brent, The Age of the Earth, Stanford University Press, 1991 28 29 30