Nuclear Chemistry Worksheet Name______________________________________ Date____________ Block____ Most nuclear reactions involve changes in the number of protons and/or neutrons in the nucleus of an atom. These changes are called transmutations because an atom of one element is changed into an atom of a different element. During these changes, nuclear particles may be absorbed and/or emitted along with a release of energy. There are four types of nuclear reactions: 1) natural radioactive decay: transmutations occur by natural radioactivity (the ability of a nucleus to emit a nuclear particle and energy without external stimulation); 2) artificial transmutation: transmutations occur by nuclear disintegration caused by external stimulation as a scientist bombards a nucleus with a particle (the addition of another nuclear particle makes the nucleus unstable); 3) fission: certain nuclei having a large mass are bombarded with special particles that cause the nuclei to split into two nuclei each having a smaller mass; 4) fusion: nuclei of light elements are combined to form heavier nuclei. Nuclear reactions are written using symbols in the maX notation. The symbols for the major nuclear particles involved in nuclear reactions are given below. Alpha particle 4 Proton 1 Neutron 1 Electron 0 Positron 0 Gamma ray 0 He (an alpha particle is a helium nucleus) 2 1 H (the most common hydrogen nucleus is a proton) n 0 e or 1 e or 0 -1 0 -1 0 1 (also called a beta particle) The table below contains information about nuclear reactions involving the emission of radiation. Type of Reaction Alpha emission () Beta emission () Positron emission (+) Gamma emission Electron capture (EC) Radiation (Particle) 4 2 He or -1e 0 or 1e 0 0 0 or -1e 0 0 -1 0 1 0 -1 NUCLEAR CHANGES Effect on the Effect on the Atomic Number Atomic Mass decrease by 2 decrease by 4 increase by 1 no change decrease by 1 no change no change no change decrease by 1 no change GHS Honors Chemistry Nuclear Chemistry Worksheet Nuclear reactions that involve bombardment of nuclei vary in their products. For example: 9 Be + 4 14 7 4 2 4 N + 27 13 Al 45 21 He 2 1 1 + Sc + He 1 H n 0 12 6 C + 17 8 1 0 O + 26 13 n 1 1 Al + 42 19 K + H 2 1 4 2 H He In nuclear equations, the total number of positive charges (represented by the atomic numbers) of the reactants (substances on the left of the reaction arrow) equals the total number of positive charges of the products (substances on the right of the reaction arrow). The total mass of the reactants must also equal the total mass of the products. For example: A uranium-238 atom decays by emitting an alpha particle to form a thorium-234 atom. 238 234 4 92U 90 Th + 2 He Another example: Potassium-40 decays to calcium-40 by beta emission. 40 40 0 19K 20Ca + -1β In both examples, the total mass on the left equals the total mass on the right. The total number of positive charges on the left equal the total number of positive charges on the right. Write out or complete the following nuclear reactions. 1) Technetium-99 (9943 Tc) decays by beta emission to form ruthenium-99 (9944 Ru). 2) Phosphorus-32 decays by beta emission to form sulfur-32. 3) Francium-212 (21287 Fr) decays by alpha emission. GHS Honors Chemistry Nuclear Chemistry Worksheet 4) Fluorine-18 decays to oxygen-18 by positron emission. 5) Sodium-24 decays by beta emission. 6) Krypton-76 absorbs a beta particle to form bromine-76. 7) Aluminum-27 absorbs an alpha particle to form phosphorus-30 and emits a neutron. 8) Nitrogen-14 absorbs an alpha particle to form oxygen-17 and emits a proton. 9) When neptunium-239 decays, plutonium-239 is formed and a particle is emitted. (Be sure to include the correct particle in the equation.) 10) A particular atom absorbs a neutron to form uranium-236. No particle is emitted. Complete the following nuclear equations: 11) ________ 12) ________ + 13) 239 93 14) 4 15) 1 Np 239 0 4 2 94 e + 14 He 12 -1 7 6 N C + 1 0 n Pu + _________ 2 He + _________ 240 0 n + __________ 236 94 Pu + 92 1 U GHS Honors Chemistry 0 n + 1 0 n Nuclear Chemistry Worksheet 16) 13 7 N _________ + 1 17) ______ + 1 18) ______ + 19) 226 88 20) 18 21) 49 22) 239 94 23) 7 24) 3 25) 14 26) 9 27) 14 28) 26 29) 59 30) 208 84 9 24 Ra F Cr 7 1 H + 2 n 6 3 3 1 H + _________ + Li 1 C 14 4 2 27 Co + Po 7 222 0 -1 +1 2 86 He Rn e e 241 95 1 Am + 1 H + He + ___________ 12 He 1 He 4 + 0 2 1 + 0 n N + _________ He N + Mg + 2 4 H _________ 4 2 12 4 e C + _______ + Be + 7 0 12 +1 Pu + _________ Li + 4 H _______ 3 6 1 0 n 0 2 1 H 6 C + _________ _________ ________ 0 + + 0 +1 ________ + ________ + 4 2 +1 He GHS Honors Chemistry e e 0 +1 e 1 0