AP Chem Ch 21 and 22 Practice Quiz (Nuclear and Organic Chemistry) 1. In the following nuclear equation, identify the missing product: 43 1 20Ca + α _____ + 1H a) 46 22Ti b) 46 21Sc c) 44 22Ti d) 42 18Ar 2. An unstable isotope of rhenium, 191Re, has a half-life of 9.8 minutes and is a beta producer. What is the other product of the reaction? a) 191Os b) 191W c) 192Pt d) 190W e) 190Os 3. The nuclide 232 90Th is radioactive. When one of these atoms decays, a series of α and β - particle emissions occurs, taking the atom through may transformations to end up as an atom of 20882Pb how many α particles are emitted in converting 232 90Th into 20882Pb? a) 6 b) 8 c) 2 d) 214 e) 4 4. In the following fission reaction, identify the other product: 235 1 139 1 92U + 0n 53I + 2 0n+ ______ a) 8939Y b) 9539Y c) 9542Mo d) 9442Mo e) 9440Zr 5. Electron capture transforms 4019K into what nuclide? a) 4020Ca b) 4018Ar c) 42He d) 4019Ke) 3920Ca 6. Which of the following processes increase the atomic number by 1? a) gamma-ray production b) electron capture c) beta-particle production d) positron production e) alpha-particle production 7. The rate constant for the beta decay of thorium-234 is 2.88 x 10-2/day. What is the half-life of this nuclide? a) 53.1 days b) 1.22 days c) 0.693 days d) 24.1 days e) 101 days 8. Which of the following balanced equations is labeled incorrectly? a) fission: 20983Bi + 42He 21185At + 210n b) fusion: 21H + 21H 31H + 11H c) bombardment: 23994Pu + 10n 24095Am 0-1e d) beta production: 23992U 23993Np + 0-1e e) all are correctly labeled 9. The nuclide 127N is unstable. What type o f radioactive decay would be expected? a) βb) β+ c) σ d) α e) 10n 10. The number of a certain radioactive nuclide present in a sample decays from 1.00 x 10 3 to 2.50 x 102 in ten minutes. What is the half-life of this radioactive species? a) 10 minutes b) 5 minutes c) 20 minutes d) 2.5 minutes 3) not enough information given 11. The half-life of 90Sr is 28 years. How long will it take for a given sample of 90Sr to be 90.% decomposed? a) 9 half-lives b) 4.3 years c) 93 years d) 5.7 x 10-3 years e) none of these 12. If a tree dies and the trunk remains undisturbed for 13,750 years, what percentage of original 14C is still present? (half-life of 14C is 5730 years) a) 5.20% b) 19.0% c) 2.20% d) 45.0% 13. Calculate the change in energy in kJ/mol for the transmutation of radium from the given molar masses: 226 4 222 + 88Ra 2He 86Rn g/mol 226.0254 4.0026 222.0176 a) -5.2 kJ/mol b) -1.6 kJ/mol c) -4.7 x 1014 kJ/mol d) -4.7 x 108 kJ/mol e) +1.6 x 108 kJ/mol 14. Name the following compound. 15. What is the name of this compound? How many isomers does it have? 16. Name the functional group in this compound. 17. What is the name of this compound? 18. Name the functional group in this compound. 19. What is the name of this compound? 20. What is the name of this compound? 21. What is the name of this compound? 22. Name the functional groups in this compound. 23. Name the functional group in this compound. 24. What functional group is present in the following molecule? . 25. Is the following molecule an example of cis or trans isomerism? 26. Is the following molecule a chiral molecule? 27. Optical isomers a) have superimposable mirror images b) have non-superimposable mirror images c) are said to be chiral d) a and c e) b and c 28. A student gave a molecule the following name: 3-methyl-4-isopropylpentane However, the teacher pointed out that, although the molecule could be correctly drawn from this name, the name violates the IUPAC rules. What is the correct (IUPAC) name of the molecule? a) 4-isoproply-3-methylpentane b) 2-isopropyl-3-methylpentane c) 1,1,2,3-tetramethylpentane d) 2,3,4-trimethylhexane e) 3,4-dimethylheptane 29. Which of the following pairs is incorrect? a) ethane – C2H6 b) hexane – C6H14 c) decane – C10H22 d) heptane – C7H16 e) nonane – C9H18 30. Which of the following pairs is incorrect? a) –CH3 – methyl b) –CH2CH2CH3 – isopropyl c) –CH2CH3 – ethyl d) –CH2CH2CH3 – propyl e) –CH2CH2CH2CH3 – butyl 31. Substances with the same molecular formula but with different structures are known as: a) polymers b) esters c) isomers d) isotopes 32. Which of the following types of compounds lacks and sp 2-hybridized carbon center? a) aldehydes b) ketones c) alcohols d) alkenes e) benzene 33. Consider the molecule trans-2-butene. Which statement is true? a) The molecule has two π bonds b) There is free rotation around every bond in the molecule. c) Cis-2-butene is its structural isomer d) Carbon #2 exhibits sp2 hybridization e) none of the above Answers 1. (b) 2. (a) 3. (a) 4. (b) 5. (b) 6. (c) 7. (d) 8. (a) 9. (b) 10. (b) 11. (c) 12. (b) 13. (d) 14. 3-ethylpentane 15. butane; two 16. carboxylic acid 17. 1-ethyl-2-methylcyclohexane 18. ester 19. 3-ethyl-4,5-dipropyloctane 20. 4,6-diethyl-5,5-dipropyl-4,6,7-trimethydecane 21. 4-ethyl-3,5-dimethylheptane 22. carboxylic acid and amine 23. ether 24. ketone 25. trans 26. yes, 4 different groups attached to the carbon 27. (e) 28. (d) 29. (e) 30. (b) 31. (c) 32. (c) 33. (d)