Chapter 2: The Chemistry of Life ATOMS Are the smallest particles of an element that has all the properties of that element They are the building blocks of matter They are made up of smaller particles: protons, neutrons and electronsarranged in a specific way. Atoms continued… MOST STABLE (unlikely to react) when outermost energy level is completely filled Energy Levels- have a set maximum # of electrons Ion= atom that has lost or gained electrons Lose electrons= become positive ions Gain electrons= negative ions Elements- a substance that cannot be broken down by chemical processes into simpler substances*Protons are positively charged *Neutrons have no electrical charge *Electrons are negatively charged and are located along the outside Isotopes Different element They number of neutrons, but same have the same proton and electron number! Compound two or more elements bonded together Ex. H2O, NaCl Compounds that contain CARBON and HYDROGEN together are termed, ORGANIC compounds Chemical Bonds Are the attractions that hold 2 or more atoms together to form a compound. Whenever a chemical bond is formed or broken, energy is either absorbed or released Ionic Bonds the chemical bond formed from the attractive force between ions with opposite charges = NO ELECTRICAL CHARGE (electrons are lost by one element & gained by another) 2. Covalent Bonds bonds in which electrons are NOT gained or lost, but shared. Co Ex. cooperative (sharing) Water, carbohydrates, lipids, proteins and nucleic acids all have covalent bonds TYPES of Covalent BONDS SINGLE- 2 electrons shared DOUBLE- 4 electrons shared TRIPLE- 6 electrons shared Types of bonds The units formed by covalent bonds are called molecules—most are made of atoms from different elements Some are not Ex. N2, O2 Polar Molecules Atoms do not share electrons equally There is a slightly negative end and a slightly positive end Ex. Water is POLAR Van der Waals Forces Intermolecular forces of attraction Weaker forces than ionic or covalent bonds Gecko Do example on page 39 section Assessment 2-1 #s 1-6 2-2 Properties of Water Solutions: a uniform mixture of two or more substances Water solutions are important because all of life’s chemical processes occur in solution Uniform- mixed evenly so parts cannot be distinguished 2 Components (parts) Solvent- dissolving substance found in greatest amount Solute- Dissolved substance Water = The Universal Solvent Why? Because of polarity- dissolves polar molecules, ionic compounds 2 Properties of water besides having hydrogen bonds (which are weak chemical attractions between hydrogen and other atoms) 1. Cohesion- “sticking together”: causes surface tension- a filmlike boundary forms on the surface of water Adhesion: attraction of molecules of different substances 2. Expansion- water expands as it freezes Ice has a lower density than liquid water Ice floats on water D= m/v D>1= sink D<1= float Acids, Bases and Salts When ionic compounds are placed in water forming a solution, the compound breaks apart and releases ions. Acid- A compound that releases Hydrogen Ions (H+) in water Base- A compound that produces Hydroxide ions (OH-) when dissolved in water Salt- Compounds that yield ions other than hydrogen or hydroxide ions when in solution, are called salts pH SCALE pH scale is the standard measurement of the concentration of hydrogen ions (H+) present in a solution p= “power H= hydrogen ion concentration pH scale ranges from 0 to 14 NEUTRAL ACIDS 0 BASES 7 14 2- 3 Carbon Compounds Carbon has 4 valence electrons. Can bind with many elements and to each other. Organic Chemistry is the study of carbon and hydrogen compounds. Most abundant elements in our body : Don’t CHNO: carbon, Hydrogen, nitrogen and oxygen Macromolecules: large molecules are formed by a process called polymeriazation Monomers + monomers + monomers= polymers Four groups of organic compounds found in living things: 1. Carbohydrates: sugars starches and cellulose—living things use carbs as main energy source and structural purposes Sugars: mono, di and polysaccacharide Animals use glycogen Plants use starch 2. lipids: fats, oils and waxes—Can be used to store energy, they are important parts of membranes and waterproof coverings. 3. nucleic acids: store and transmit hereditary or genetic information--made of monomers called nucleotides 3 PARTS!! 2 Kinds DNA Deoxyribonucleic acid RNA: ribonucleic acid 4. Proteins: made up of smaller units called amino acids (Amino because has an NH2 on one end and a –COOH on the other) Very important: Protein Synthesis in cells Functions: Defense(antibodies), movement(actin/myosin), Transport (hemoglobin), hair and nails (keratin) 2-4 Chemical Reactions and Enzymes Chemical Reactions: a process that changes one set of chemicals into another set of chemicals They always involve the breaking of bond in the reactants and the formation of new bonds in the products Example ( Label the reactants and products) CO2 + H2 O H2CO3 Energy in Reactions Energy is released or absorbed whenever chemical bonds form or are broken Chemical reactions that release energy often occur spontaneously. Chemical reactions that absorb energy will not occur without a source of energy. Energy Releasing 2H2 + O2 2H2O Energy Absorbing 2H2O 2H2 + O2 Energy Releasing (Exothermic) Activation Energy- the energy needed to get a reaction started Energy Absorbing (Endothermic) Catalyst: is a substance that speeds up the rate of a chemical reaction- they work by LOWERING the activation energy ENZYMES are protein catalysts Enzyme - Substrate Complex Substrate= reactant, substance to be changed Active site= where the substrate attaches