Section 2.6—Chemical Reactions Objectives: •Define the components of a chemical reaction •Convert word equations to formula equations •Define and predict products for double replacement and neutralization reactions Chemical Reactions When substances react, bonds are broken, atoms are rearranged, and bond are re-formed to create new compounds. 2 H2 + O2 2 H2O O O Watch as 2 H2 and 1 O2 undergo a chemical reaction Chemical Reactions Bonds and atoms are rearranged to form new compounds. 2 H2 + O2 2 H2O O O The substances in the end are different from those in the beginning. Bonds are broken and re-formed between different atoms Chemical Reactions In chemistry, the “sentence” (showing the starting materials and the final products of a chemical reaction) is called a chemical equation. Examples of Chemical Equations Word equation: magnesium metal is reacted with aqueous hydrochloric acid to produce aqueous magnesium chloride and hydrogen gas Formula equation: Mg (s) + 2 HCl (aq) MgCl2 (aq) + H2 (g) Visualization H Cl Mg Cl H Cl Mg Cl H H Parts of a Chemical Equation The starting materials for the reaction—each compound is separated by a “+” Formed in the reaction Products Reactants NaCl (aq) + AgNO3 (aq) AgCl(s) + NaNO3 (aq) States of matter Arrow s = solid l = liquid g = gas aq = aqueous (dissolved in water) Read as: Yields Produces Forms Makes etc. Writing Chemical Equations You must write each chemical formula correctly first! (Recall how to write formulas from names - Section 2.2) “and”, “is mixed with” or “reacts with” = + “yield”, “produces” and “forms” = Then after they are written, chemical equations have to be balanced – we’ll do that in Sec. 2.7! Let’s Practice #1 Example: Write the word equation into symbol form Aluminum metal is reacted with hydrochloric acid to form aluminum chloride and hydrogen gas Let’s Practice #1 Example: Write the word equation into symbol form Aluminum metal is reacted with hydrochloric acid to form aluminum chloride and hydrogen gas Al + HCl AlCl3 + H2 Let’s Practice #2 Example: Write the word equation into symbol form Copper (II) nitrate and sodium hydroxide form copper (II) hydroxide and sodium nitrate Let’s Practice #2 Example: Write the word equation into symbol form Copper (II) nitrate and sodium hydroxide form copper (II) hydroxide and sodium nitrate Cu(NO3)2 + NaOH Cu(OH)2 + NaNO3 Double Replacement Reactions The cations from two compounds replace each other. NaCl + AgNO3 AgCl + NaNO3 Two ionic compounds switch ions Double Replacement Reactions The general format of a double replacement reaction: A X B Z A Z B X Products of a Double Replacement 1 Combine the cation of the first reactant with the anion of the second reactant CaCl2 + AgNO3 Products of a Double Replacement 2 Combine the cation of the second reactant with the anion of the first reactant CaCl2 + AgNO3 Products of a Double Replacement Remember to write cations first … 3 & balance charges with subscripts when writing formulas Remember NOT the change the subscripts that are part of any polyatomic ion! CaCl2 CaCl2 + AgNO3 + AgNO3 Ca(NO3)2 + AgCl Neutralization Reactions Neutralization reactions are double replacement reactions where one cation is “H” and one anion is “OH” and water is formed. General format of a neutralization reaction: H X ACID B O BASE H B X IONIC COMPOUND O H H WATER Products of a Neutralization Reaction Combine the cation of the first reactant (the 1 acid) with the anion of the second reactant (the base). This gives you the water. H2SO4 + NaOH Products of a Neutralization Reaction 2 Combine the cation of the second reactant with the anion of the first reactant. This gives you an ionic compound. H2SO4 + NaOH Products of a Neutralization Reaction 3 Remember to write cations first … & balance charges with subscripts when writing formulas Only leave subscripts that are in the original compound there if they are a part of a polyatomic ion! H2 SO4 H2 SO4 + Na OH + Na OH Na2SO4 + HOH You can write the water as “HOH” when you combine the cation & anion or you can change it to “H2O” Let’s Practice #3 Example: Write the products for this reaction Sr(OH)2 + HBr Let’s Practice #3 Example: Write the products for this reaction Sr(OH)2 + HBr SrBr2 + HOH Let’s Practice #4 Example: Write the products for this reaction HCl + Ca(OH)2 Let’s Practice #4 Example: Write the products for this reaction HCl + Ca(OH)2 CaCl2 + HOH