Nuclear notation and Binding energy Contents: •Atomic notation •Isotopes •Whiteboard •Binding Energy •AMU •Making an atom •Calculating binding energy •Whiteboards •The curve of binding energy and the strong nuclear force (or why there is a limit to the periodic table) Atomic notation A Z 12 6 X C X = Symbol (C, Au) A = Atomic Mass Number = #nucleons (Protons + Neutrons) Z = Atomic Number = #protons Carbon A = 12, Z = 6. #neutrons? TOC Isotopes 12 6 14 6 C C Carbon 12 has 6 Neutrons Carbon 14 has 8 Neutrons Carbon 14 is an isotope of Carbon Chemically the same Nuclear-lly different (it’s unstable) TOC Whiteboards: Atomic Notation 1|2|3|4|5 TOC What is the Atomic notation for tritium? (tritium is an isotope of Hydrogen with 2 neutrons) Hydrogen has a Z = 1, A = 1 p + 2 n = 3 3/1 H W 10 protons, 12 neutrons. What is its atomic notation? Z = 10, A = 10 + 12 = 22, element 10 is Ne 22/10 Ne W How many neutrons in U 235? (235 = A) (1) U is element 92 235 - 92 = 143 neutrons 143 W How many neutrons in Pb 208? (208 = A) (1) Pb is element 82 208 - 82 = 126 neutrons 126 W How many neutrons in Kr 78? (1) Kr is element 36 78 - 36 = 42 neutrons 42 W Binding energy - the energy to take an atom apart Unified Mass Units: (u) C 12 (neutral atom) = 12.0000000 u (defined) 1 u = 1.6605 x 10-27 kg = 931.5 MeV Electron = .00054858 u (not useful) Proton = 1.007276 u (not useful) H (neutral atom) = 1.007825 u (very useful) Neutron = 1.008665 u (very useful) TOC Binding energy - the energy to take an atom apart H (neutral atom) = 1.007825 u (very useful) Neutron = 1.008665 u (very useful) 1 u = 931.5 MeV To take an atom apart: C 12 can be taken apart into: 6 H atoms: 6(1.007825 u) (i.e. 6 p + 6 e) 6 Neutrons: 6(1.008665 u) Total “taken apart” mass = 6(1.007825 u) + 6(1.008665 u) Total “taken apart” mass = 12.09894 u Mass “defect” = 12.09894 u - 12.000000 u = .09894 u .09894 u - Represents energy needed to take atom apart Binding energy = (.09894 u)(931.5 MeV/u) = 92.16 MeV TOC Binding energy - the energy to take an atom apart H (neutral atom) = 1.007825 u (very useful) Neutron = 1.008665 u (very useful) 1 u = 931.5 MeV Binding energy in general 1. Look neutral atom mass in Appendix F (p 1064) 2. Break atom into H and n 3. Subtract neutral atom mass from taken apart mass 4. Multiply mass defect by 931.5 Mev/u TOC Whiteboards: Binding Energy 1|2|3 TOC What is the binding energy for Nitrogen 13? (Z = 7) N 13 mass = 13.005738 u H = 1.007825 u Neutron = 1.008665 u 1 u = 931.5 MeV Atom mass = 13.005738 7H + 6n = 7(1.007825 u) +6(1.008665 u) = 13.106765 u Binding energy = (13.106765 - 13.005738)931.5 MeV/u = 94.11 MeV 94.11 MeV W What is the binding energy for Carbon 14? (Z = 6) C 14 mass = 14.003242 u H = 1.007825 u Neutron = 1.008665 u 1 u = 931.5 MeV Atom mass = 14.003242 6H + 8n = 6(1.007825 u) +8(1.008665 u) = 14.11627 u Binding energy = (14.11627 - 14.003242)931.5 MeV/u = 105.3 MeV Binding energy per nucleon: C 12: 92.16/12 = 7.68 MeV/nucleon C 14: 105.3/14 = 7.52 MeV/nucleon (less) 105.3 MeV W What is the binding energy for Carbon 10? (Z = 6) C 10 mass = 10.231610 u H = 1.007825 u Neutron = 1.008665 u 1 u = 931.5 MeV Atom mass = 10.231610 6H + 4n = 6(1.007825 u) +4(1.008665 u) = 10.08161 u Binding energy = (10.08161 - 10.23161)931.5 MeV/u = -139.7 MeV (Carbon 10 does not exist) -139.7 W The curve of binding energy Binding energy per nucleon Going to more tightly bound releases energy Fission - splitting nuclei Fusion - joining nuclei Most tightly bound Fission releases energy Fusion releases energy TOC Nuclear Stability Coulombic force tries to tear apart nucleus Strong Nuclear force holds it together (force between nucleons) n p p p n p n Strong Nuclear is very short range As nucleus gets bigger •Strong nuclear gets weaker •Coulombic gets stronger Neutrons add strong force, don’t repel Trend with heavier elements At some point neutrons don’t cut it The crazy man at UMn TOC