Atomic Model Notes What is a scientific model and how is it used? Link 1 Scientific Models http://en.wikipedia.org/wiki/Scientific_modelling An idea expressed by: writing, drawing, physical, replicas, animations. . . Can be: used to make predictions Predictions are: tested by experiments Can be modified: when predictions are incorrect 600 2.1 big light 540 2.3 long light Making A Scientific Model: The Black Box Experiment In this experiment, you will make a model of the unseen parts inside of a black box. Making a scientific model involves 4 processes: 1. Forming ideas (the model) about something that is observed. 2. Making predictions using the model. 3. Testing the predictions with experiments using the model. 4. Correcting or modifying the model according to information learned in the experiments. The black box that you will use to help you develop the skill to make a model is made of cardboard. It has metal rods running through the box. Inside of the box there are objects, which may be similar to washers. All of the black boxes are set up the same inside. Your lab team will get two black boxes. You are not allowed to look in the box, but you can tilt it and use your sense of touch and hearing and use a magnet to develop a model of what you think it looks like inside the box. Draw your model of the inside of the box. Next, develop predictions of what you think will happen if you were to pull the rods out of the box. Test your predictions by using one of the black boxes. Modify your model if your predictions are not accurate. Test your new model using the second box. Make a final model of the inside of the black box. Parts of the Atom Link 2 Parts of the Atom http://www.chem4kids.com/files/atom_structure.html 1. Protons Found: in the nucleus Has: a positive charge Has: a mass of one atomic mass unit Number of: protons is equal to the atomic number Number of: protons determines the identity of an element Link 3 Interactive Periodic Table Link http://www.dayah.com/periodic/ 2. Neutrons Found: in the nucleus No charge Mass: equal to one atomic mass unit The number of: Neutrons = atomic mass - protons An element may have atoms with different numbers of: neutrons. These are called xs. C-12, and C-14 are isotopes of carbon. The average of the isotopes leads to the decimal in the atomic mass Link 4 Isotopes http://www.chem4kids.com/files/atom_isotopes.html 3. Electrons Found: outside the nucleus in the electron cloud Have: a negative charge Have: such a small mass it is considered zero Protons Electron Nucleus Neutrons Electron cloud Link 5 Proton, Neutron, and Electron Numbers http://education.jlab.org/qa/pen_number.html In a neutral atom: # of electrons = # of protons If the atom has a charge: it is because the atom has gained or lost electrons Charged atoms are called: ions Sodium tends to lose 1 electron so its charge becomes: +1 11 P+ 12 N 11 E- Neutral Sodium 11 P+ 12 N 10 E- Na less 1 Electron Oxygen tends to gain 2 electrons so its charge becomes: negative 8 P+ 8N Neutral Oxygen 8 E- 8 P+ 8N 10 E- O plus 2 Electrons Charges on some of the Atoms +2 +3 +4 -3 Electrons can move: to higher energy levels when energy is added to the atom Pathways: electrons take are not just special -2 -1 Link 6 Parts of the Atomhttp://education.jlab.org/atomtour/index.html Link 7 The Changing Atomic Model http://www.absorblearning.com/chemistry/demo/units/LR301.html Spectroscopy The study of the: spectra of light emitted by elements and compounds It is used to: identify substances because each element has unique fingerprint of light The “spectral fingerprint” is made of peaks: on a graph of different Intensity +1 wavelengths 400 500 Wavelength (nm) 600 700 0 How Spectroscopy Happens (Why we study this with the atomic model) Energy: is added to the atom electrons jump out to the excited state This causes: the electron to jump out to the excited state Immediately: the electron goes back to the ground state Resulting in: light being emitted Link 8 Spectroscopy https://science.howstuffworks.com/laser-analysis2.htm Unique Spectra of Light Emitted Energy Excited State E E Ground State E E E E Fluorine E E E E Figure 1. Flame Test Lab When energy is added to atoms the electrons move to a higher energy level. The electrons then move back releasing the energy. This may be in the form of visible light. Every element gives off a unique color (wavelength) of light. These colors can be used to identify unknown substances by comparing them to known elements. In this lab you will use flame test to observe and record the colors of 7 known elements. On another lab day you will be given the same elements marked as unknowns. In 7 tiny test tubes place about 1 cm of solution, which contain the metals: strontium, calcium, copper, lithium, barium, sodium, and potassium. Use a sheet of paper to mark the names of the elements and place this in front of your test tube rack. To test the elements dip a nichrome wire into a solution and then place the tip of the wire into a burner flame. You may have to repeat this several times to get a good observation of the color. Fill a small test tube about 1/3 full of hydrochloric acid to clean the nichrome wire in between each test by dipping the wire into the acid and then placing it in the flame until most of the color is gone. After testing all elements, you may make mixtures and test these to see if you can detect individual colors. On a following day you will get the 7 elements again marked as unknowns 1-7. You will also get a mixture containing 2 unknown elements. You can use your observations from day one to help identify the unknowns. In the next lab you will exam elements for their spectral graph fingerprint. This can be used in your analysis section of your lab report. In your pre-lab make a table containing the following columns: Number of unknown, name of element(s), detailed color description, and a column to be filled with the color(s) you observed. You will turn the completed table in as a follow up to the lab. The table should have a figure number and caption that describes the lab and information in the table. Spectroscopy Lab In this lab, you will learn how to use a spectroscope to observe the chemical fingerprint of various elements and compounds. A spectroscope breaks down light into its different wavelengths (Figure1). In comparison in the flame test lab you used eyesight alone and were only able to see the colors blended together. Figure 1. The diagram shows a bright-line spectrum as seen through our laboratory spectroscope. A scale on the bottom allows you to measure the wavelength of the lines. The intensity of the lines can be estimated on a relative 1-10 scale by looking at their brightness. Use the hand-held spectroscopes and the Loggerpro spectral analysis probes to observe the given elements and compounds set out in the room. For each sample lights where you do not use Loggerpro record the type of bulb, the colors you see, their wavelength and their brightness in relationship to each other on a 1-10 scale. (Add a table like the one below to your pre-lab) When you use Loggerpro you have to change the y-axis to intensity. You do this by clicking on Experiment (next to File) and then Change Units/Spectrometer 1/Select Spectrometer Mode and click Intensity. Aim the fiber optic cable at the light source and the collect button. When you get a good graph click stop. Change the y units to get tall peaks shown on the graph and then take a screen shot of the graph including the axis and name the screenshot with the correct element or compound name. One of these spectral finger print graphs can be used in your analysis section of your flame test lab report to show what a spectra finger print looks like. Color of Line Relative Intensity (10 being the brightest) Wavelength Elements and Compounds Element • Any substance that: cannot be broken down further by a chemical reaction • Examples: Nihonium Compound • Two or more: elements chemically combined • Compounds can be: broken down by chemical means, but not physical • Compounds do not: retain the properties of their elements • They have set: ratios of their elements • Formulas show: H2O • Examples: • Compounds are: pure substances, mixtures are not Link 9 Animated Elements and Compounds http://www.chem.purdue.edu/gchelp/atoms/elements.html Is usually found in the form of… Matter Mixtures Which is usually made of… Compounds Elements Which can be broken down into… Chemical Bonding • The outer shell of electrons are the electrons: electrons involved in bonding. They are known as valence electrons 1 2 Number of Valence Electrons 3 4 5 6 7 8 (2) • Valence electrons are represented: by dot diagrams Na Mg Al C Link 10 Dot Diagrams http://hyperphysics.phy-astr.gsu.edu/hbase/pertab/perlewis.html The Octet Rule: Atoms are most stable when they have: 8 electrons in their outer shell They will gain: lose, or share electrons to get to the octet rule. The exception is if it only has the first energy level, which only needs: 2 electrons to be stable How many electrons will sodium gain or lose to achieve the octet rule: 1l How many electrons will barium gain or lose to achieve the octet rule: 2l How many electrons will chlorine gain or lose to achieve the octet rule: 1g How many electrons will nitrogen gain or lose to achieve the octet rule: 3g How many electrons will neon gain or lose to achieve the octet rule: 0 Atomic model test 1 will go up to this point Ionic Bonds Atoms: Link 11 Ionic Bonds https://en.wikipedia.org/wiki/Ionic_bonding Link 12 Charges and Ionic Bonds Video https://share.vidyard.com/watch/1oiuPx7U9gaRzEY5QprGec The charged atoms are called: ions The attraction is between: the opposite charges Type of bond between: a metal and non-metal E E E E E E E E E E E E E Sodium Chlorine E E E E E E E E E E E E E E E Naming Ionic Compounds Link 13 Naming Rules http://science.widener.edu/svb/pset/nomen_b.html Rules for ionic compounds made of two elements; a metal and a nonmetal. 1. Name the: metal first 2. Name the: non-metal second 3. Drop the last syllable of the: non-metal and add “ide” 4. If the metal can form more than one charge (transition elements) indicate the charge with: a roman numeral Compound containing Br and Li: Lithium bromide Compound containing N2 and Ca3: Calcium nitroide Compound containing Mg and O: Magnesium oxide Compound containing Fe+3 and S: Iron III sulide Finding Formulas for Ionic Compounds The elements in these compounds have: charges because they gain or lose electrons Examples Na+1, Mg+2, Cl-1, N-3 The overall charge of the compound: has to equal zero Examples: Sodium nitride (Na+1 N-3): Na3N Barium fluoride (Ba+2 F-1 ): BaF2 Link 14 Ionic Formula https://chem.libretexts.org/Bookshelves/Introductory_Chemistry/Map%3A_Introductory_Chemistry_(Tro)/05%3A_Molecules_and_Compounds/5.05%3A_ Writing_Formulas_for_Ionic_Compounds Drawing Dot Diagrams of Ionic Bonds 1st. Find the: formula of the compound 2nd. Draw the dot diagram by placing the metal to the: left, nonmetal to the right 3rd. Electrons that transfer are shown as: X’s 4th. If there is more than one atom in the formula: stack the atoms 5th. Include the: charge of each atom Example: Sodium chloride +1 Na X -1 Example: Magnesium fluoride (you may have to copy paste parts) Mg +2 X -1 X -1 F F Covalent Bonds Link 15 Scroll to Covalent Bonds http://www.visionlearning.com/library/module_viewer.php?mid=55 Atoms: share electrons to become more stable by fulfilling the octet rule Atoms share: pairs of electrons Covalent bonds occur between: nonmetals Compounds are: referred to as molecules Link 16 Covalent Bonds https://www.thoughtco.com/definition-of-covalent-bond-604414 E E E E F E E E E E E E E E E F E E C E E E E F E E E E E E E E E E E E E E E E E E F E E E E Naming Covalent Compounds Link 17 Naming Covalent Compounds https://cpanhd.sitehost.iu.edu/C101webnotes/chemicalnomenclature/bimolcmpds.html Name the element furthest: left (first except hydrogen) (in same family; name the lower first). Drop the last syllable of the 2nd element: and add “ide” Add prefixes to the element to indicate: the numbers in the formula 1 is: mono, 2 is di, 3 is tri, 4 is tetra, 5 is penta, 6 is hexa Never use: mono on the first element Examples: CO2: Carbon Dioxide CO: Carbon monoxide N2H6: Dinitrogen Hexahydride Finding the Formulas for Covalent Compounds Look at: the prefixes Silicon tetrachloride SiCl4 Covalent Dot Diagrams 1st. Find the: formula of the compound 2nd. Place the element symbols: symmetrically around a center atom 3rd. Calculate the number of bonds: for each atom using the octet rule 4th. Complete the octet rule: around each atom Sulfur Dichloride has 20 dots because: the number of valence electrons for two chlorines and one sulfur S Covalent Bonding Lab Covalent bonds occur when atoms share electrons to become more stable by fulfilling the Octet Rule. The smallest group of covalently bonded atoms for a compound is referred to as a molecule. For example H2O is the molecule that makes up water. In this lab you will make models of molecules of various covalent compounds. When you get your molecular model kit you must first use your periodic chart and what you know about the octet rule to decide what color ball will represent each of the following elements: carbon, hydrogen (you will need a lot), oxygen, chlorine, bromine, and nitrogen. When you have decided you will then draw the dot diagram for carbon tetrahydride (methane). When you have your dot diagram correct you can build your model of the molecule. When you have that model correct you will then draw the dot diagram for dicarbon hexahydride. When you have your dot diagram correct you can build your model of the molecule. Continue the same process for: dihydrogen monoxide, dicarbon tetrahydride, Cl2, O2, nitrogen trihydride (ammonia gas), and carbon dioxide. Ionic or Covalent Compound Lab Ionic or covalent compounds often differ in the following ways: Ionic compounds may have harder crystals than covalent compounds. They may dissolve better in water. Ionic compounds when dissolved in solution may conduct electricity better and they may higher melting points than covalent compounds. In this lab you will get four compounds and you will rank them from 0-5 for each category underlined above with the goal of determining if the compounds are ionic or covalent. In your pre-lab you should make a data table to keep track of your rankings of the four compounds (A-D) for each category. Do not touch the chemicals with your fingers. If a chemical come in contact with your wash it off immediately. Use the microspactula or scoopula to move the chemicals around. Use a microspatula to try and crush a few crystals of each on the aluminum tray provided. Place a few crystals of each on a microscope slide and set this on a hot plate set on low to check for relative melting points. If it turns brown and smokes that is a chemical reaction not melting. You should stop if that happens. Place a few crystals of one of the compounds in a 100 ml beaker containing 20 ml of water to see if it dissolves. If it does try some more to test to see how soluble it is. Next test the solution with the probes of a voltmeter to see how well it conducts electricity. Repeat the tests for each compound. Use a preponderance of evidence to determine if the compound was ionic or covalent. Formation of the Atom and the Big Bang Just before the Big Bang The big bang occurred about 14 billion years ago The "inflationary universe" model assumes that before the big bang the universe had an extremely concentrated, unstable form of energy, but no matter The Big Bang Link 18 The Big Bang Theory http://science.nasa.gov/astrophysics/focus-areas/what-powered-the-big-bang/ Energy changed into matter during the big bang One second after the big bang protons, neutrons, and electrons had formed By three minutes after the big bang hydrogen the first element had formed Less than a billion years after the big bang Stars form as hydrogen comes together by the force of gravity In stars hydrogen forms helium through the nuclear reaction fusion which produces the light and heat given off by stars Billions of years later, as stars go super nova the tremendous pressure and heat caused the helium to fuse together to form all of the other elements in the universe These elements eventually came together by the force of gravity to form the planets Elements Fused Together Evidence that the Big Bang Occurred The universe is still expanding today as a result of the big bang There is background radiation every where in the universe left over from the big bang What we can determine by looking at the stars Link 19 Examining Spectral Fingerprints https://imagine.gsfc.nasa.gov/features/yba/M31_velocity/spectrum/spectra_info.html The primary cause of star color is the temperature of the stars Cooler stars radiate most of their energy in the red and infrared region of the electromagnetic spectrum and thus appear red Hotter stars emit in the yellow part of the spectrum The hottest stars emit mostly at blue and ultra-violet wavelengths, making them appear blue or white Which stars are the coolest? Hottest? Why is our sun yellow? Using Spectral Analysis to Find Composition of Stars Link 20 Composition of the Sun http://www.space.com/17170-what-is-the-sun-made-of.html Scientists break light from stars into its spectral fingerprint to determine the composition of the elements in the star Spectral Fingerprint of the Sun Our Solar System Link 21 Solar System Facts http://earthsky.org/space/ten-things-you-may-not-know-about-the-solar-system The solar system and earth formed about 4.5 billion years ago It formed as elements and compounds from previous supernovas came back together by the force of gravity Earth is the right distance for life because water can exist in the 3 phases; solid, liquid, and gas making the earth’s water cycle possible