Module 2 Module 2 Inquiry question: What happens in chemical reactions? Students: conduct practical investigations to observe and measure the quantitative relationships of chemical reactions, including but not limited to: o masses of solids and/or liquids in chemical reactions o volumes of gases in chemical reactions (ACSCH046) relate stoichiometry to the law of conservation of mass in chemical reactions by investigating: o balancing chemical equations (ACSCH039) o solving problems regarding mass changes in chemical reactions (ACSCH046) Practical investigations are an essential part of chemistry and involve changes in the quantity of a chemical present. You are expected to be able to propose methods to measure changes in the quantity of a substance that might occur during a chemical reaction. You could be expected to measure the change in the mass of a substance as a result of a chemical reaction. For example, if a strip of magnesium ribbon was brunt in oxygen to form magnesium oxide, you could measure the change in mass of the solid substance, and work out what mass was added to the material. You could also be expected to measure volumes of gas produced in the reaction using things like a syringe or a balloon. For example, hydrogen is produced when metals react with acid, and can be captured using a balloon. When asked to propose how an experiment to measure mass or volume could be done, remember to think in practical terms: choose a method that is straightforward and achievable in a basic laboratory. It is a chemical change in which one or more substances are destroyed and one or more new substances are created. BEFORE AFTER H2 gas H2O liquid and O2 gas Reactants Products Reactants: Substances that are destroyed by the chemical change (bonds break). Products: Substances created by the chemical change (new bonds form). The arrow () is read as “yields”. (s) = solid (l) = liquid (g) = gas (aq) = aqueous solution (the substance is dissolved in H2O) “+” separates two or more reactants or products “” yield sign separates reactants from products 1) Evolution of light or heat. 2) Temperature change (increase or decrease) to the surroundings. 3) Formation of a gas (bubbling or an 4) Color change (due to the odor) other than boiling. formation of a new substance). 5) Formation of a precipitate (a new solid forms) from the reaction of two aqueous solutions. WORD EQUATIONS Statements that indicate the reactants and products in a chemical reaction. Ex. Iron (s) + chlorine (g) iron (III) chloride (s) This is read as: “Solid iron and chlorine gas react (combine) to produce solid iron (III) chloride” A skeleton equation uses chemical formulas rather than words to identify the reactants and products of a chemical reaction. The word equation Iron (s) + chlorine (g) iron (III) chloride (s) The skeleton equation Fe(s) + Cl2(g) FeCl3 (s) A skeleton equation is not yet “balanced” by coefficients! 6 Na (s) + Fe2O3 (s) 3 Na2O (s) + 2 Fe (s) The numbers preceding the chemical formulae are coefficients. They are used to balance the reaction. The numbers within the chemical formulae are subscripts. You can read the above balanced reaction as: “6 atoms of solid sodium plus 1 formula unit of solid iron (III) oxide yields 3 formula units of solid sodium oxide and 2 atoms of solid iron” or… “6 moles of solid sodium plus 1 mole of solid iron (III) oxide yields 3 moles of solid sodium oxide plus 2 moles of solid iron” Chemical reactions can never be read in terms of grams, only in terms of particles or groups of particles (moles). The Law of Conservation of Mass states that mass cannot be created or destroyed by chemical reactions or physical transformations. This means that the total mass of the products in a chemical reaction are exactly the same as the total mass of the reactions – matter can not be produced from nothing! A consequence of the Law of Conservation of Mass is that all chemical equations must be balanced, that is, you must show the same number of each type of atom on each side of the reaction arrow. In order for a chemical equation to be balances and correct: 1. All reactants and products must be included 2. The chemical formula for each chemical species must be correct 3. The physical state at the room temperature and pressure must be included 4. The number of each type of atom must be the same on each side of the reaction arrow. CONSERVATION OF MASS During a chemical reaction, atoms are neither created nor destroyed (Conservation of Mass). Hydrogen and oxygen gas react to form water: H2 (g) + O2 (g) H2O (l) H2 (g) + O2 (g) H2O (l) What is wrong with this equation above? Doesn’t it appear that one oxygen atom “went missing”? According to conservation of mass, the proper way to write this reaction is: 2H2 (g) + 1O2 (g) 2H2O (l) The red coefficients represent the # of molecules (or the # of moles) of each reactant or product. For example, the balances chemical equation for the reaction between magnesium metal and oxygen gas to produce magnesium oxide is as follows: As an additional note, you will need to know these polyatomic ions moving forward: 2Ca3(PO4)2 + 6 SiO2 + 10C 6 CaSiO3 + P4 +10CO Atom Ca P O Si C # Atoms on Left Side # Atoms on Right Side __H2 + __ O2 __H2O Balancing is about finding the right coefficients! 1) You can change the coefficients, but NEVER the subscripts! __H2 + __ O2 __H2O Off Limits! 2) The coefficients must reduced to represent the lowest possible numbers. 4H2 + 2 O2 4H2O 3) It is OK to use fraction coefficients, but you must get rid of them in the end (multiply through by denominator). H2 + ½ O2 H2O 4) Do a final balance check for each element! 2H2 + O2 2H2O 1) K + Br KBr 2) HgO Hg + O2 3) Na + H2O NaOH + H2 4) CaO + H2O Ca(OH)2 5) Al + HCl AlCl3 + H2 Page 206 from Pearson has the practical write up and students refer to worksheet 2.1 from skills and assessment workbook for questions.