New Mexico Bureauof Mines and Mineral Open File ReportNo. OF-272 Resources HYDROCARBON S.OURCE-ROCK ANAYLYSES, TRUE OIL COMPANYNO. 21 MEDINA WELL, COLFAX COUNTY, NEW MEXICO By Core Laboratories, Inc. and Cehvron U.S.A., Inc. 1987 1601 S T E M M O M FREEWAY.80X 47541.DALLAS.TEXAS 1 5 2 4 1 ~ 1 1 4 ~ 8 3 1 8 2 1 0 CORE LABORATORIES, INC. May 17,1983 Geochemical Services M r . S. R.Jacobson C h e v r o nU S A C e n t r a lR e g i o n P. 0. B o x 599 D e n v e r , CO 80201 Subject:TotalOrganicCarbonand Rock-Eva1Pyrolysi:: Well: T r u eO iCl o m p a n y No. 27 Medina Chevron Job Nos.: P-4079-1 CMEN-1120 O u rJ o b No.: 83075 DearMr.Jacobson: '3 . T h ef o l l o w i n gr e p o r ct o n t a i n st h ea n a l y t i c arl e s u l t so f 30 sampl?s in t h e i n t e r v a l 3620 t o 9000 f e ef tr o m t hT e r uO eC il ompany No. 21 Medina, N . M . A lol r g a n i cc a r b o na n dR o c k - E v a 1P y r o l y s i sd a t ai s C o l f a xC o u n t y , p r e s e n t e d in T a b l e 2. T h eo r i g i n a lp y r o l y s i sp y r o g r a m sh a v eb e e nr e t u r n e da sr e q u e s t e c ' . T h a n ky o uf o rt h eo p p o r t u n i t yt ob eo fs e r v i c et oC h e v r o nU S A . h a v ea n yq u e s t i o n so r if wemaybeoffurtherassistance,pleasedonot hesitatetocallus. Sincerely, CORELABORATORIES, R o b e r tB l a k e Supervisor GeochemicalServices RB,PJS:kn INC. Paul J. Swetland Manager GeochemicalServices If y o u * F I L E NO. 8 3 0 7 5 True O li Company No. 21Medina ROCK-€VAL PYROLYS Depth (FT) 3620- 3880 4120- 4130 4290- 4310 4870- 4920 5130- 5170 5200- 5210 5.4 0 0 - 5 4 3 0 5 5 6 0 5- 6 4 0 5 8 2 0 -5 8 5 0 6 1 3 0 -6 2 7 0 6350- 6400 6480- 6500 6600- 6650 6800- 6850 7020- 7100 7130- 7200 7230- 7260 7420- 7490 7650- 7680 7840- 7860 7950- 7980 8 0 1 0 -8 0 8 0 8 1 6 0 -8 1 8 0 8 2 3 0 -8 2 5 0 8 3 1 0 -8 3 5 0 8 4 1 0 -8 4 5 0 qgnn8 7 7 0 -8 8 0 0 8880- 8940 8 9 6 0 - 9000 ~~ ~~ TOC (wt%) 0.53 0.57 0.98 1.01 0.72 0.75 0.83 1.07 1.61 1.76 1.13 0.77 0.89 0.87 0.84 0.97 1.oo 0.92 1.07 1.62 9.55 2.01 3.41 1.44 4.89 5.62 4.71 2.12 1. 8 8 2.59 s1 0.06 0.02 0.15 0.16 0.08 0.05 0.04 0.04 0.32 0.13 0.09 0.05 0.08 0.03 0.04 0.04 0.03 0.03 0.06 0.04 0.43 0.04 0.06 0.01 0.08 0.08 0.07 0.04 0.03 0.03 Organic Carbon TOC = Total HydrogenIndex OxygenIndex = 'l/TOC = '3/TOC Mg/Gm R o c k 53 52 0.73 0.41 0.06 0.09 0.08 0.20 0.68 0.24 0.07 - - 0.09 6.51 0.16 0.52 - 1.20 1.09 1.19 - 0.47 0.56 0.53 0.35 0.35 0.40 0.46 0.47 0.32 0.29 0.26 0.30 0.29 0.27 0.35 0.35 0.42 0.36 0.42 0.27 0.56 0.51 0.44 0.46 0.41 0.38 0.33 0.34 0.31 0.34 Hydrogen Index - 74.5 40.6 8.3 12.0 9.6 18.7 42.2 13.6 6.2 - 5.6 68.2 8.0 15.2 - 24.5 19.4 ?5.3 - Oxygen Index 88.7 98.2 54.1 34.7 48.6 53.3 55.4 43.9 19.9 16.5 23.0 39.0 32.6 3 1 .O 41.7 36.1 42.0 39.1 39.3 16.7 5.9 25.4 12.9 31.9 8.4 6.8 7.0 16.0 16.5 13.1 O i l o r Gas Potential Shows 0.06 0.02 0.88 0.57 0.14 0.14 0.12 0.24 1.00 0.37 0.16 0.05 0.08 0.03 0.04 0.04 0.03 0.03 0.06 0.13 6.94 0.20 0.58 0.01 1.28 1.17 1.26 .O. 0 4 0.03 0.03 0.06 0.02 0.15 0.16 0.08 0.05 0.04 0.04 0.32 0.13 0.09 0.05 0.08 0.03 0.04 0.04 0.03 0.03 0.06 0.04 0.43 0.04 0.06 0.01 0.08 0.08 0.07 0.04 0.03 0.03 O li o r Gas Shows = S1 O li o r Gas P o t e n t i a l = S1 + S2 S. Trans Ratio = 1 - s1+s2 Trans Ratio - - 0.17 0.28 0.57 0.36 0.33 0.17 0.32 0.35 0.56 - - TMAX (Deg C; ; ' " 442 449 449 455 444 432 452 449 4 54 - - - - 0.31 0.06 0.20 0.10 482 4 88 510 481 0.06 0.07 0.06 492 490 499 - - - - - T R U E OIL CO. a 2 1 M E D I N A SEC. 25 - COLFAX CO., 24N - 16E NEW MEXICO HYDROCARBON GENERATION ZONES BlOSlUDK NO. 1116 % KEROGEN TYPES T I ! 1 , ! BIOSTRATIGRAPHIC STUDYNO. 1176 PALYNOLOGY REPORT Location True OilCo. 821 Medina Sec. 25-24N-16E Colfax County, New Mexico Problem Cuttings samples submitted by Steve Phillips for determination of maturity (TAI-V~)and microscopic organic analysis (MOA) indices. Note: '3 For discussioninthisreporr,thesamplesare grouped mainly by Tmax values, the interval 36206400 has Tmax values in the oil generating range, the interval 6480-7770 had insufficient 52 values duringpyrolysistomeasure Tmax andth?third interva1"from- 7840-8800 has Tmax values in the gascond. generative range. Specimens of Lycospora sp. were used or co-rsidered in making TAI determinations. The restricted range of this palynomorph is Devonian, Miss. and Penn., thus corroborating to gome extent the stratigraphy as given. They were first noted in sample 8, (55605640) and were generally evident TD. to Sample 33 (8310-8320) was very good for determination of vitrinite reflectance. The vitrinite plug for sample 28 (8770-8800) seemed noticeably cleanof caving material. Also the TAI slide for this sample hadasmall TAI spreadindicatingahomogeneoua sample. The TAI slideforsample 30 (8960-9000) contained two groups of TAI indices, the 3.8-3.9 (drygas)groupwasinterpretedasreworkm?d,the less mature group 3.6-3.7 waa interpreted as probably being in place and corroborated by v!.trinite reflectance. '3 -1- Results Data Sample P4079-1 (3620-3880) 2 3 (4610-4670) 31 P4079-4 5 6 7 8 9 10 11 (4120-4130) (4290-4310) (4870-4920) (5130-5170) (5200-5210) (5400-5430) (5560-5640) (5820-5850) (6130-6270) (6350-6400) Kerogen Types (MOA) TOC 1 111 11 10 30 60 0 0 10 60 0 20 50 0 40 30 0 0 050 0 0 0 0 0 20 20 10 10 10 10 30 30 30 50 50 30 30 30 50 60 60 60 60 30 30 30 30 30 20 20 IV - Organic Yield (m1./10 grams.) .53 .57 .98 1.01 .72 ;75 .83 1.07 1.61 1.76 1.13 .6 .5 1.0 .6 .6 .5 1 .o .5 1.0 .5 .6 .8 Maturity ‘3 Tmax sample 3,442OC oil generative zone. samples 4-7, 9-11, 444O-455OC oil gen. zone. sample 8, 432OC immature. Note: Tmax value is not substantiated by TAI and therefore should not be used. - VO sample 31, .83 (=TAI 2.8-2.9) oil gen. zone. sample 4, 1.2 (=TAI 3.2) early gas-cond. gen. zone. Note: sample 4 has a higher Vo reading than might be expected from adjacent interval, could be measuring reworked vitrinite. sample 11, 1.31 (-TAI 3.3-3.4) gas-cond. gen. zone. TAIsample 1, 2.9 (=V, .go) oil gen. zone. oil gen. zone. .90-1.1) 2.9-3.1 (=Vo sample 31, oil 2.9-3.0 .90-1.0) gen. zone. (=Vo sample 8, Amount (of oraanics) W t 5: TOC samples 1-3, .53-.98 fair (.5-1.0). samples 5-7, .72-.83 fair (.5-1.0). samples 4, 8-11, 1.01-1.76 good (1.0-2.0) Organic yield, see above. -2- ~ J ,/ ,> Sample P4079-12 13 14 15 16 17 34 18 19 32 1 (6480-6500) (6600-6650) (6800-6850) (7020-7100) (7130-7200) (7230-7260) (7240-7250) (7420-7490) (7650-7680) (7740-7770) 0 0 0 0 0 0 0 0 0 0 Kerogen Types (MOA) 11 IV 111 20 30 50 60 30 10 60 30 10 10 60 30 10 60 30 10 60 30 50 30 20 60 30 10 10 60 30 60 30 10 TOC .77 .89 .a7 ..97 a4 1.oo .92 1.97 Organic Yield (m1./10 grams.) 1.0 .6 1.0 .8 .5 .5 1 .o 1.0 1.0 1.6 Maturity insufficient Tmax S-2 "3 - VO sample 16, 1.41 (=TAI 3.4-3.5) gas-cond. gen. zone. sample 19, 1.56 (=TAI 3.5-3.6) gas-cond. gen. zone. sample 32, 1.41 (=TAI 3.4-3.5) gas-cond. gen. zone. TAI sample 13, 3.3-3.5 (=V0 1.3-1.5) gas-cond. gen. zone. sample 18, 3.5-3.6 (=Vo 1.5-1.7) gas-cond. gen. zone. sample 19, 3.3-3.6 (=Vo 1.3-1.7) gas-cond. gen. zone. Amount (of organics) wtX TOC samples12-16, 18, .77-.97fair(.5-1.0). samples 17, 19, 1.0-1.7 good (1.0-2.0). Organic yield, see above. '3 -3- ;/ $9 Sample P4079-20 21 22 23 24 25 33 26 35 27 28 29 30 Maturity Tmax j: "0 TAI TOC - Kerogen Types (MOA) 1 11 IV 111 (7840-7860) 0 10 60 30 (7950-7980) 0 10 60 30 (8010-8080) 10 60 0 30 (8160-8180) 30 0 50 20 (8230-8250) 050 20 30 (8310-8350) 0 30 40 30 (8310-8320) (8410-8450) 30 0 50 20 (8430-8450) 0 30 50 30 (8500-8560) 0 20 50 30 (8770-8800) 0 20 50 30 (8880-8940) 20 30 050 (8960-9000) 20 30 50 0 Organic Yield (m1./10 grams.) 1.62 9.55 2.01 3.41 1.44 4.89 5.62 4.71 2.12 1.88 2.59 .1 2.2 1.6 2.0 2.0 2.0 1.2 1.5 1.5 .2 .07 .3 .2 $gOL samples 20, 21, 23, 25, 26 and 27, 4810 O C Cas cond. gen. zone. sample 22, 510OC. Post mature. Note: This value is out of context with adjacent hasalso sample values. This highera maturity index (TAI 3.7-3.8=V0 2.0-2.7) which is actually not inconsistant with the Tmax of 510oC but the thermal gradient as indicated by adjacent samples doesn't accommodate these maturity values. The most likely reason for higher indices in this sample is thata perhaps larger amount of redeposited material waspremnt in this interval. sample sample sample sample sample 33, 1.39 35, 1.61 28, 1.53 29,1.67 30, 1.75 3.3-3.4) gas-cond. gen. 3.5-3.x) gas-cond. gen. 3.5-3.6) gas-cond. gen. 3.5-3.6) gas-cond. gen. (=TAI 3.6-3.7) gas-cond. gen. (=TAI (PTAI (=TAI (=TAI zone. zone. zone. zone. zone. 1.5-2.0) gas-cond. gen. zone. sample 28, 3.5-3.6 (4, sample 30, 3.6-3.7 (=Vo 1.7-2.0) gas-cond. gen. zone. Amount (of organics) samples 20, 24, and 29, 1.44-1.88 good (1.0-2.0). samples 21, 22, 23, 25, 26, 27, 28, and 30, 2.01-9.55 very good (2.0-10.0). Organic yield, see above. J. D. SAXTON 6/9/83 JDS:mm Attachments: Computer drafted chart Fig. 1 Core Lab Report 83075 -4- rrsL e . - , .,. .,a. ..