Sr4 33 /61_ U5 a

advertisement
Sr4 33
o
U5 a
i
/61_
Fourth Progress Repor t
PRIMING-COAT REDUCTIONS FOR PAINTING N W DSURFACE S
A Joint Project o f
Northwestern Paint and. Varnish Production Clu b
Minnesota chapter of the International Associa tion of Master Painters and Decorator s
Paint, Oil and Varnish Club of the Twin Citie s
of the Twin Citie s
Retail
m4!!emi e -Ae .r,w rir
with the assistance o f
Forest Products Laboratory, Forest Service ,
U .S . Department of Agricultur e
By F . L . Brown e
For the St . Paul Test Fence Comm tte .
W . J . Philippbar, Chairman
- 'L . P . Warren
T . J . MacMahon
S . O . Sorenso n
J . M . Olse n
Peter Gydese n
M. H . Sim e
F . L . Browne
;
•
PRIMING-COAT REDUCTIONS FOR PAINTIN G
NEW WOOD SURFACE S
By
F . L . Browne
for the Test Fence Committee-
The principal object of this study is to discove r
the optimum priming-coat reduction in applying common hous e
paints to softwoods and to determine whether the primin g
coat should be reduced differently according to the natur e
of the softwood painted . The experiments were described i n
detail in a first progress report published in American Pain t
and Varnish Manufacturers Association, Scientific Section ,
Circular 404 ; 596 (1031) . A second progress report appeare d
in Federation of Paint and Varnish Production Clubs, Official
Digest No . 121, 1068 (1932) and a third report in America n
Paint and Varnish Manufacturers Association, Scientifi c
Section, Circular 445, 454 (1933) : Oil,Paint and Drug
Reporter 124, 68 (Nov . 16, 1933) ; Paint, Oil and Chemica l
Review 95, 67 (Nov . 2, 1933) .
•
Four woods and three paints were used in th e
experiments on priming-coat reduction . The woods were Norwa y
pine, northern white pine, western red cedar, and redwood .
The paints were white linseed oil house paints that differe d
only in the nature of the pigments ; in one the pigment wa s
entirely basic carbonate white lead, in the second the pigmen t
contained 60 percent by weight basic carbonate white lead ,
30 percent lead-free zinc oxide, and 10 percent magnesiu m
silicate, and the pigment of the third contained 60 percen t
titanox B, 30 percent lead-free zinc oxide, and 10 percen t
magnesium silicate . All three paints were made in the for m
of semi-pastes one gallon of which consisted of 0 .435 gallo n
1
•
. J . Philippbar, Chairman, L . P . Warren, T . J . MacMahon ,
S . O . Sorenson, J . I . Olsen, Peter Gydesen, M . H . Sime ,
F . L . Browne .
R1045
of pigment and 0 .555 gallon of linseed oil .
For the variou s
priming coats these paste paints were thinned with linsee d
oil, turpentine, and paint drier as indicated in table 1 .
Some of the painting was done in two-coat work and some i n
three-coat work . For the final coat in two-coat paintin g
the paste paints were thinned with 0 .655 gallon of linsee d
oil, 0 .036 gallon of turpentine, and 0 .036 gallon of drie r
per gallon of paste paint, making paint of 26 .4 percen t
pigment volume . For three-coat work the second coat wa s
made by mixing 1 gallon of paste paint, 0 .218 gallon o f
linseed oil, 0 .437 gallon of turpentine, and 0 .036 gallon o f
drier, making paint of 35 .9 percent pigment volume ; for th e
third coat the mixtures were 1 gallon of paste paint, 0 .946
gallon of linseed oil, 0 .036 gallon of turpentine, and 0 .03 6
gallon of drier, uaaking paint of 22 .4 percent pigm-en-t volurn:e..
Panels were attached to both sides of test fences ,
providing both northern and southern expo•sura-s . 14e panels
were made of boards of bevel siding 12 feet long +o tha t
groups of 6 matched test areas each 2 feet hang were provide d
on which six variations in priming-coat reduction were tested
on the same boards . In table 1' the 6 priming praaadure :s
tested on _subdivisions of the same boards are groro :p d
together . Priming reduetiltOR 1-3 was re!p .e .ted on each s•e t
of boards in order to reveal .differences due to characterij =
tics of the boards in dif14 ;cLt panels of the same wood. aria
to furnish z basis for oor Nr'.ng priming pro.oedutes•' e !ted
on different panels .
Since the third progress report was written tber e
have been two formal inspections of t1 ;e fence, one in Jun e
and the other in October 1934 . At the last ii spect'a )n th e
coatings were 38 months old . The writer also inspedted 'W e
fence in August 1934 in company with a group of visiting
paint technologists but records were not made at that tiia e::
At 38 months the coatings on the south side of the fenc e
were failing in integrity sufficiently to re v e, .!!: disttiiitc t
differences caused by the variations in. pruning-coat
reduction . ; On the north side of the fence, h! wever ,
coatings remained intact except for cexfta.in J gcal ca
' '•
moisture failure mentioned in the third progri,se repo
The present report is concerned chiefly witly i4,e trend s
durability of the coatings on the s out- side of 'tie fenwt=;
,
.
R1045
-2-
.
1
1
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Effect of Priming-Coat Reductio n
Table 1 ree ordlt the rat i - of the coatings i n
integrity at age 38 maonttt, the ieJ0 4ii7 in months of thos e
coatings that had become unserViceable,send were in the perio d
of paint neglect, and an arbitrary estimate of the du abilit y
of those coatings that still remained serviceable The r
estimated durabilities are based on the assumption tha t
coatings rated Poor plus at the last inspection will remai n
serviceable 3 months longer, those rated Fair minus 6 months
longer, and those rated Fair 9 months longer . The estimated
durabilities calculated in this way greatly facilitat e
discussion of the results but they are far from accurat e
predictions of future behavior . Less than one-third of th e
durabilities recorded in table 1, however] are estimated i n
this way and for that reason the relative Merits of th e
various priming procedures are as clearly revealed as the y
will be when the tests have continued until all of th e
coatings are unserviceable . •
In table 1 the priming-coat reductions nu b,erAd 1=1 ,
1-4, '4, 1 -4, and 1-5 were mixtures in whioh. the c.otc.entration of pigment is suitable for three-cat paintiog 4
ranging from 17 .2 to 23 .2 percent by volume of the mixtur e
(including volatile) . Reduction-s numbered 2-1 ) 2-2, and.
2-3 had a higher concentration of pigment, 24 .1 to 26 . 3
percmi, suitable for two-coat painting . Among the reduction s
of series 1 the best results were obtained with 1-1, in which
no turpentine was used, and the tendency was for th e
durability to decrease as the turpentine was increased an d
the linseed oil decreased in the priming coat . Th e
difference in results with primers 1-1, 1 .2 ; and 1-3 ,
however, was so small that they may well be cons .derod equall y
serviceable : Reductions 1-4 and 1-5 were on the whole distinctly inferior although on redwood-1-4 wa . Still provin g
nearly as good as 1-3, Threductions of series 2 wheal.
used in two-coat work revealed a definite superiority o f
the reduction 2-1 ; made with linseed oil and no turpent,i-n e
over those in which there was linseed oil and turpent-U14 4
Of the two reductions of series 2 used for three-eoO vwa-rk ,
the one containing more oil and less turpentine prove d
somewhat superior .
It should be noted that, in three-coat work ,
reduction 2-2 was slightly superior to 1-3 in the case•"s- o f
white lead and titanox and zinc paint and slightly inf :ri:o r
in the case of lead and zinc paint . In other words ,
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reductions 2-2 and 1-3 on the whole proved about equall y
serviceable . The pigment volume in 1-3 was 22 .3 percen t
(of the non-volatile and the ratio of linseed oil t o
turpentine by volume was about 2 .6 . In 2-2 the pigment volum e
was 30 .2 percent and the ratio of oil to turpentine 3 .4.
Reduction 1-4, which was inferior to 1-3 with all paints, ha d
a pigment volume of 29 .4 but a ratio of oil to turpentine o f
only 1 .4 . It seems, therefore, that the ratio of oil t o
turpentine is more significant, at least within the range o f
desirable reductions, than is the pigment volume . Apparently
a good primer should have at least 2-1/2 times as much linsee d
oil as turpentine and it is questionable whether there nee d
be any turpentine in the primer at all . The pigment volum e
in a good primer for three-coat painting presumably may b e
anywhere in the range of 20 to 30 percent but for two-coa t
painting practical considerations require that the pigmen t
volume be in the upper portion of this range .
Reductions for Different Wood s
The notion has long prevailed that the optimu m
priming-coat reduction differs according to the kind . of woo d
painted . There is no published evidence in support of such a
belief and its soundness may well be doubted in view of th e
contradictory recommendations often made when writers try t o
give specific priming-coat formulas for different woods .
The data of table I suggest the same optimum priming-coa t
reduction for all woods, namely, reduction with linseed oi l
and little or no turpentine . The results are not at al l
consistent with the view that the reduction for red ceda r
or redwood should differ from the reduction for white pin e
or Norway pine . It should be recognized, however, that th e
present experiments were concerned principally with th e
proportions of linseed oil and . turpentine in the primin g
coat and did not cover possible variations in pigment concentration as adequately as could be desired . Further researc h
may show that for woods like redwood and red cedar, whic h
absorb paint oils quickly, a slightly lower pigment concentration may be advisable in order to avoid unduly lo w
spreading rates and difficulty with painters' laps than i s
appropriate for such woods as Norway pine, southern yello w
pine, and Douglas fir . Nevertheless the present indication s
are that a single recommendation for reducing priming coat s
for all kinds of woods is entirely practical and probabl y
advisable . The "easily paintable" woods probably differ fro m
the "difficultly paintable" ones chiefly in degree o f
sensitiveness to departure from the optimum reduction, tha t
R1045
-4-
is, less damage to the serviceableness of the coating may b e
expected if the painter fails to use the optimum reduction i n
painting redwood than will result when painting Norway pine .
Order of Failure on the Four Wood s
The order of failure of the three paints on the fou r
kinds of wood is indicated in table 2, which records in eac h
case the average durability for all priming-coat reduction s
of the white paint . Certain physical properties of the board s
of each of these woods were reported in table 1 of the thir d
progress report . On cedar, white pine, and Norway pine th e
average curability of the three paints was inversely proportional
to the average density of the boards of those species . The
durability on redwood, however, was about as great as it wa s
on red cedar although the density of the boards was nearl y
the same as the density of the white pine . These results ar e
entirely in accord with results previously reported by th e
Forest Products Laboratory (Federation of Paint and Varnish
Production Clubs, Official Digest No . 95, p . 106 (1930) ) .
Table 2 .--Order of failure of paints on the four wood s
Kind_ o f
wood
:Average durability in months of coatings of :Density :
: of
:'mite mead : Lead and :Titanox : Average
: wood : paint
:zinc paint :and zinc : for al l
: 3 paint s
: paint
:Lbs .per :
:cu . ft . :
Redwood
Red cedar . . .
White pine . .
Norway pine .
R1045
:
:
:
:
26 .2
21 .5
26 .8
28 .9
.
.
.
.
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38 .4
38 .8
35 .5
30 .0
39 .3
37 .4
33 .6
36 .5
-5-
:
:
:
.
38 .8
40 .6
30 .5
24 .3
:
.
.
38 . 8
38 . 9
33 . 2
30 .3
The relative behavior of the white lead paint, lea d
and zinc paint, and titanox and zinc paint during the firs t
two years of exposure was described in detail in the thir d
progress report . Since that time all throe paints have bee n
chalking freely enough on the south side of the fence t o
dislodge most of the remaining dirt and the white lead an d
lead and zinc paints at 38 months were nearly as clean an d
white as the titanox and zinc paint . On the north side of th e
fence the titanox and zinc paint still remained almost a s
clean and white as it was on the south side, the lead an d
zinc paint had thrown off most of the dirt previousl y
accumulated and was only slightly more gray than the titano x
and zinc paint, but the white lead paint still retained muc h
dirt, was very spotted in discoloration, and was still rate d
Bad in appearance .
On the south side of the fence at the last inspectio n
the characteristic reticulate checking of white lead pain t
was readily visible on close examination without a magnifyin g
g lass . The checking was then undoubtedly deep . The lead and
zinc paint was likewise checking visibly and the checking wa s
gradually becoming reticulate . The titanox and zinc pain t
remained free from checking .
Disintegration of the white lead paint proceede d
entirely by crumbling . The lead and zinc paint and the titano x
and zinc paint disintegrated by slitting or cracking followe d
by curling and flaking . Chalking of the titanox and zin c
paint had reduced the thickness of the film enough to impai r
the opacity observably although very close inspection wa s
necessary to disclose that fact . There had, however, been n o
washing of the chalk over the black identification number s
with which the test areas were marked .
The extent to which disintegration of the three paint s
had gone after 38 months may be seen by referring again t o
table 2 . On redwood and red cedar they were provin g
practically equal in durability but on white pine and Norwa y
pine the titanox and zinc paint had disintegrated earlier tha n
the other two paints . As a result there was a greate r
variation in durability on different woods with the titano x
and zinc paint than with either of the other two paints .
As was pointed out in the third progress report ,
there was more difference in durability between any one of th e
paints on the four woods than there was between that of that
R1045
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was more difference in durability between the best and t e
worst priming-coat reduction with any one paint than ther e
was between tlat
he thre•j paints on redwood
r e p .cedar ,
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With the white lead paint and the titanox and zinc
paint the best two-coat job (priming-coat reduction 2-1 }
• proved equal or superior in durability on the whole to th e
- hest three-coat job (with white primer) applied on the sam e
-r
boards . With the lead and zinc paint the best two-coat job
r was slighly inferior to the best three-coat job on the s '
boards except on red cedar, where it was better . Table 3
I
'm - the first progress report recorded the total amounts o f
y%
paint applied in the two-coat and three-coat jobs and s wed _
_• - that, by reason of the higher pigment concentrations and
lower spreading rates followed in the two-coat painting ,
roughly similar total quantities of paint were applied i n
1 ▪
_ two-coat and three-coat jobs, It is evident that two-coatpainting when done in the manner followed in these experiment s
' - is thoroughly practicable and gives coatings that closel y
% approach good three-coat work in durability and prove die 1
tinctly better than poor three-coat work .
-r - 11 1
▪
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t~linum Priming Paint
_1' ice'
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▪ -%. -~~-~ Table I indicates that the best results were ob tamed with aluminum primin g iming paint ~ followed by two coats o f
- white paint . On all woods except white pine the coatings o f
1 all three paints over aluminum primer were still rated Fai r ,
► - minus or better in integrity at the last inspection and i n
all cases except that of lead and zinc paint on white pi n
:1
0 •• the coating over aluminum primer was rated as high or highe r
1
in integrity than the best coating over a white primer o n
the same boards . On 10 out of 12 panels the coating over ,
-- aluminum primer had the highest rating, on 1 panel it s
.%
rating (Fair minus) was equalled only by white priming-coa _
{
reduction 1-1, and on 1 panel it was distinctly superior t o
- - reductions 1-4 and 1-5 but inferior to reductions 1-1, 1-2 ,
and 1-3 . On the last panel, however, failure was confined t o
r%
r
two of the four boards which developed loose grain toward th e
end on which the aluminum primer was applied but not on th e
11
end that received reductions
1-2, and 1-3 . This panel, -.
~~
rb'
nu
-1
11=115
41-1■
1
1
J~
■ -
-
1 iv I t
■
•
11 11 "
II -
r
■
be
therefore, was not an exce p tion to the rule that the
aluminum primer in these tests tended to hold the coating s
intact longer than any of the priming-coat reductions of th e
white paint .
Unusually Early Failure of the Paint%
Failure of the coatings in integrity took plac e
unusually rapidly on the St . Paul test fence . Coatings o f
the white paints used should be expected to remain service able in the Lake States region for at least 4 years on suc h
woods as red cedar, redwood, and white pine, yet th e
failures took place in less than 4 years . The coatings o f
white lead paint and of lead and zinc paint applied wit h
priming-coat reduction 1-3 as recorded in table 1 ma y
reasonably be compared with certain tests by the Forest
H
Products Laboratory in which the same paints were applie d
with very similar reductions and on some of the same kinds o f
wood at Fargo, N . P ., and at Madison, Wis ., in 1930 . Table 3
records data suitable for comparing the results with thos e
at St . Paul .
The reason for faster disintegration of the paint s
at St . Paul is unknown but the fact that there is unmistakable evidence of some moisture failure on the north sid e
of the fence, as pointed out in the third progress report ,
suggests that moisture getting into the fence at some tim e
may have hastened disintegration on the south side eve n
though the moisture conditions were not severe enough t o
result in typical blistering or other developments clearl y
recognizable as moisture failures . It has been reported t o
the test fence committee that at one time during the winte r
of 1932-33 snow drifted against the fence to the extent o f
practically covering one side . This snow was not shovele d
away and there is a possibility that entrance of moistur e
within the fence took place when it melted .
Miscellaneous Tests on Units 7 and 8
In addition to the main portion of the test fenc e
there were two units added for the purpose of trying th e
effect of special primers made with white pigments in th e
81045
f
•
Bakelite varnish used as a vehicle for the aluminum prime r
on units 1 to 6 and for trying the recommendations fo r
thinning white lead paint made by the National Lead Compan y
and the Eagle-Picher Lead Company and certain paints suggeste d
by the New Jersey Zinc Company and the Titanium Pigment s
Company. The condition of these paints with respect t o
integrity of the coatings at the last inspection is recorde d
in table 4 .
Of the special primers made with white pigments i n
Bakelite varnish the one made with zinc oxide gave distinctl y
inferior results . The ones made with white lead and titano x
were better but by no means so good as the aluminum prime r
reported in table 1 . The type of failure of the white lea d
paint over these priers was not the same as that of whit e
lead paint over white lead primer or over aluminum primer bu t
took the form of flaking as distinguished from crumblin g
over the bands of summerwood .
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