Sr4 33 o U5 a i /61_ Fourth Progress Repor t PRIMING-COAT REDUCTIONS FOR PAINTING N W DSURFACE S A Joint Project o f Northwestern Paint and. Varnish Production Clu b Minnesota chapter of the International Associa tion of Master Painters and Decorator s Paint, Oil and Varnish Club of the Twin Citie s of the Twin Citie s Retail m4!!emi e -Ae .r,w rir with the assistance o f Forest Products Laboratory, Forest Service , U .S . Department of Agricultur e By F . L . Brown e For the St . Paul Test Fence Comm tte . W . J . Philippbar, Chairman - 'L . P . Warren T . J . MacMahon S . O . Sorenso n J . M . Olse n Peter Gydese n M. H . Sim e F . L . Browne ; • PRIMING-COAT REDUCTIONS FOR PAINTIN G NEW WOOD SURFACE S By F . L . Browne for the Test Fence Committee- The principal object of this study is to discove r the optimum priming-coat reduction in applying common hous e paints to softwoods and to determine whether the primin g coat should be reduced differently according to the natur e of the softwood painted . The experiments were described i n detail in a first progress report published in American Pain t and Varnish Manufacturers Association, Scientific Section , Circular 404 ; 596 (1031) . A second progress report appeare d in Federation of Paint and Varnish Production Clubs, Official Digest No . 121, 1068 (1932) and a third report in America n Paint and Varnish Manufacturers Association, Scientifi c Section, Circular 445, 454 (1933) : Oil,Paint and Drug Reporter 124, 68 (Nov . 16, 1933) ; Paint, Oil and Chemica l Review 95, 67 (Nov . 2, 1933) . • Four woods and three paints were used in th e experiments on priming-coat reduction . The woods were Norwa y pine, northern white pine, western red cedar, and redwood . The paints were white linseed oil house paints that differe d only in the nature of the pigments ; in one the pigment wa s entirely basic carbonate white lead, in the second the pigmen t contained 60 percent by weight basic carbonate white lead , 30 percent lead-free zinc oxide, and 10 percent magnesiu m silicate, and the pigment of the third contained 60 percen t titanox B, 30 percent lead-free zinc oxide, and 10 percen t magnesium silicate . All three paints were made in the for m of semi-pastes one gallon of which consisted of 0 .435 gallo n 1 • . J . Philippbar, Chairman, L . P . Warren, T . J . MacMahon , S . O . Sorenson, J . I . Olsen, Peter Gydesen, M . H . Sime , F . L . Browne . R1045 of pigment and 0 .555 gallon of linseed oil . For the variou s priming coats these paste paints were thinned with linsee d oil, turpentine, and paint drier as indicated in table 1 . Some of the painting was done in two-coat work and some i n three-coat work . For the final coat in two-coat paintin g the paste paints were thinned with 0 .655 gallon of linsee d oil, 0 .036 gallon of turpentine, and 0 .036 gallon of drie r per gallon of paste paint, making paint of 26 .4 percen t pigment volume . For three-coat work the second coat wa s made by mixing 1 gallon of paste paint, 0 .218 gallon o f linseed oil, 0 .437 gallon of turpentine, and 0 .036 gallon o f drier, making paint of 35 .9 percent pigment volume ; for th e third coat the mixtures were 1 gallon of paste paint, 0 .946 gallon of linseed oil, 0 .036 gallon of turpentine, and 0 .03 6 gallon of drier, uaaking paint of 22 .4 percent pigm-en-t volurn:e.. Panels were attached to both sides of test fences , providing both northern and southern expo•sura-s . 14e panels were made of boards of bevel siding 12 feet long +o tha t groups of 6 matched test areas each 2 feet hang were provide d on which six variations in priming-coat reduction were tested on the same boards . In table 1' the 6 priming praaadure :s tested on _subdivisions of the same boards are groro :p d together . Priming reduetiltOR 1-3 was re!p .e .ted on each s•e t of boards in order to reveal .differences due to characterij = tics of the boards in dif14 ;cLt panels of the same wood. aria to furnish z basis for oor Nr'.ng priming pro.oedutes•' e !ted on different panels . Since the third progress report was written tber e have been two formal inspections of t1 ;e fence, one in Jun e and the other in October 1934 . At the last ii spect'a )n th e coatings were 38 months old . The writer also inspedted 'W e fence in August 1934 in company with a group of visiting paint technologists but records were not made at that tiia e:: At 38 months the coatings on the south side of the fenc e were failing in integrity sufficiently to re v e, .!!: disttiiitc t differences caused by the variations in. pruning-coat reduction . ; On the north side of the fence, h! wever , coatings remained intact except for cexfta.in J gcal ca ' '• moisture failure mentioned in the third progri,se repo The present report is concerned chiefly witly i4,e trend s durability of the coatings on the s out- side of 'tie fenwt=; , . R1045 -2- . 1 1 S Effect of Priming-Coat Reductio n Table 1 ree ordlt the rat i - of the coatings i n integrity at age 38 maonttt, the ieJ0 4ii7 in months of thos e coatings that had become unserViceable,send were in the perio d of paint neglect, and an arbitrary estimate of the du abilit y of those coatings that still remained serviceable The r estimated durabilities are based on the assumption tha t coatings rated Poor plus at the last inspection will remai n serviceable 3 months longer, those rated Fair minus 6 months longer, and those rated Fair 9 months longer . The estimated durabilities calculated in this way greatly facilitat e discussion of the results but they are far from accurat e predictions of future behavior . Less than one-third of th e durabilities recorded in table 1, however] are estimated i n this way and for that reason the relative Merits of th e various priming procedures are as clearly revealed as the y will be when the tests have continued until all of th e coatings are unserviceable . • In table 1 the priming-coat reductions nu b,erAd 1=1 , 1-4, '4, 1 -4, and 1-5 were mixtures in whioh. the c.otc.entration of pigment is suitable for three-cat paintiog 4 ranging from 17 .2 to 23 .2 percent by volume of the mixtur e (including volatile) . Reduction-s numbered 2-1 ) 2-2, and. 2-3 had a higher concentration of pigment, 24 .1 to 26 . 3 percmi, suitable for two-coat painting . Among the reduction s of series 1 the best results were obtained with 1-1, in which no turpentine was used, and the tendency was for th e durability to decrease as the turpentine was increased an d the linseed oil decreased in the priming coat . Th e difference in results with primers 1-1, 1 .2 ; and 1-3 , however, was so small that they may well be cons .derod equall y serviceable : Reductions 1-4 and 1-5 were on the whole distinctly inferior although on redwood-1-4 wa . Still provin g nearly as good as 1-3, Threductions of series 2 wheal. used in two-coat work revealed a definite superiority o f the reduction 2-1 ; made with linseed oil and no turpent,i-n e over those in which there was linseed oil and turpent-U14 4 Of the two reductions of series 2 used for three-eoO vwa-rk , the one containing more oil and less turpentine prove d somewhat superior . It should be noted that, in three-coat work , reduction 2-2 was slightly superior to 1-3 in the case•"s- o f white lead and titanox and zinc paint and slightly inf :ri:o r in the case of lead and zinc paint . In other words , R1045 -3- O ma m-.1. H H am Ha m Ht ma OyI H H H - mro >d 0 0 I m I 0 I d dooa II)00cOOM c000LOCO 0 ON OT O, 'O H M MMMKIM LI) 4 1 t 4414 MMMMM4 M M M Icl Ifl O O cO cO 0 10 c0 Kl 001O,[-[ON 4MMI Cn14 I41N00004 MMMNICI 4M MI(1MIflL.0 M1010)1lcO M O' 11-IMO-3 444O(N MMMMN4MMMMM M M H HH H'04 lObcp'000cO 44441,14 0 .0 .0 .0 .0 .0 . o 434-lcICI4 M00 M41CN coco MM H .-1 r-1 r-110 NCO 10 cO0 1 44440 .4 4 H4MICIMM M 1. 1. F. .1 S . 1. 1. 1. f.+0 1. 00000H 0 1.0 0 0 0 0 0 0 0 00 00 001 0 0 4444 44 P.441.. 0 .4444 01444 4 . C . 1+, + H14 ..IQ H 14O14 0C. H C000010 0004 10 C.00 co d ad0Old P. .00 .444414 44 4444 1(1444 4 N 1. C. 1+. 1. si 1.. 1. O O0O0O0O0H0 00000 0 0 0) 00 00 4444444444 G. P.44 P.0 .444 4 r1 r-1 r1 C0 4. 4 4 .41 CO CO 40 .-1 CO 444 Kn14 K1MK14 M HHHHCO HOO CO'O4 N 4444 ln~ 4MI.INM M 4r=1HcO 44410 .4 C. 1. C. to 0 0 0 0 'd+ C. H as+.C000000 0 1. 0 C. 0 C. 0 00ti 0000443 C44 A,1:14. 44444444 444 4 I+O -. OC.O I+i O 1. O HC.01.0C.0 + 1. C0. 00 000000 oo o aso o P. 04 .440 . P. k. 0 .0WWP . P. L C. C. C. C.0 f+ •.. S. .-11+.0 0 0 f+0, .-I 0. 14 0 0 .H 4410000 a; 000 00 0 . A. P . P. 44 4,4 P. P.44 44 44 0 a'O b 440 H 0340MMI+IM'1MIC CO 4 cO' Ol M MM K.) N4 cO440 1O M NI0040N4 Ic1MMMN KI 00T IcnNKINN 4 N044NNCO N M M N N M M4441 MMN4 MM 000'+ 41o 000'+ o o o5aia3o 000000 o 0o 444444101444 444444 01 44 P. C.000'5'50 C .1. 1 S. C.+1. 1 .1.o 000 .aas0 oroo0o 0004410 0 4444 44014144 4444444444 P. .+1 .1.0 +++ I C. I.I.C ooo0o 'd'd'd'droo Id 44X0010)0. 000a30 0 004114 PI 40 P 44 444440444 4 QJc0O04cO4 cOCO'04 .0 4 KlK\0.'11c)al NNHNN N 0c)c0c0004 40H .-1cOl 011(1 MIc1My Mn4 MMKlO NO NHHN4 O)\0 N HNO N N 0 N N 0 4 M N N (UN N 1 I 0000 'd H 'd'd4414$'1 0000441 0 00014410X1 4444444440 44 1014131411041 4 O14 S.o 1.00000H C. C. S. f. C. 11.o'd Oro 00000441 0100/30 40 44 13.440 .11.P. 44014440444 1 I o ' + 'd 'd 'd -4 0 ' + d 'd 'l 'd o al 441 cd 0 443 0 0.i 443 cd al 0.S 10 44 411(1 40 41 C,, A) 41 10 10 10 M In In In In n NNI Ch n n KIMMMMM NN KIN KI M M Kl K1l\l)M NNIc\NKI lc) ON 1144 0H0 O.IR N NNN4 NN McO \O c0O N(lII[lOIfl NMINI±nKnnI OHKl44 NNK1'0NC 0 0HN01M 000011001f1 N NNN4 NK\N ntc) n 0HM44 0HN ON ICI 010004 to H"O t(-l{ 4 NO NO NOM1O rn K 0 0 0 0 0 0 0. 0 0. 0. 0 01H\0 N4 -NN s0I00) .'O 0N M MN 40 40M0N0H0n 0 0 0 0 0N 0 0 ll '1 H IO t-4 VD c0 c0.'O 0 M 44MNH MNN N 0 0 0 0 0 MN 00000 0 b 1-4 U 8 OM mro a. H r-I O 0 .-10 9 a 'd H C. [ala .0 41 4 .-) 0 al[ral 0o m .0a) ala) H aa 0 H a 1. 0 d .0 am mw a a3 1. O0 H a0 1.a) 0 H 4. O m a H mK a .0 mm a cod 0 03 1. 44 m4NO 0 a a 0.a) co O H $4 rcl a) C P. . a a)) H41 a-)aa) -4,`) 'ada) as H . i. 0 . 0 F . co H m m a m El 'd CH. CDla H0.i 0D O, a3m 4-. H H H 0 .p1 q co ca PH A oa f m .04 . 4O 0 amHd 0m o9 ,r+ H o. m m H a 44 m 4G 3 ~ A f I H1 'd H m It 0 0 H O+o. A ma as T c)a) E aH coa HO Atd a 'd§ H'03 OA .a 0 0) 0 ~m W'lA CIS 0 a, 4 C. a) .4 m as m V O.'H 0 1 C4 I a-) P. o o cd 1 1I ,s0 I 4 H I1 1 I I cI m I m I 'd 1 9 H I C. 0 1 a) I H> i w •0 a II 9 i 44 +~m 1. 1I H O I .' II f. '0 0.'d 1. Cl' m II 4ItlI 10 1 . 1 441 . -• I. • ., I m 1 0I I 443O 1 am I --0 I ' 1 1 44 1 u0) I m W 1 13 1 0 Q4 1 I. 44HCOH H 4440 .4 4 I 1. NKnC01f19 0\10 N N . H N [Qt-cO 1. o O I 91~IN O 1I'dm II .1. II H 0 as I O al .4O I al I tO II H II -. . C7 I 0 I 0,01 1 m9 I! N OT.' i 114 H al 0. a) H . 1 3, 1. LC) El 04(10 (1 N--'4 NI(lt-cO 1. NMKIN M O\CO c0 0v:0 N If.llON l(1 o 0 .4 I(1 co NO 10 C.-AO ON 1- 01 10'04 L- O 100 .3 H KlH H 0014 -4 '040 N4N HH O H .4 0. 0 H0 'd 0 HN0 .4 Ul HNKl Iclcu M I I I I 1 1 I NNHNNN 1 1 1 1 1 1 a' d HHHHH S 4-1 If l 0400 .000 041 0 Nlfl«1N111 • • O O C 441 tb ''0to x1t-40O't-01 O 0)404 H Ma-4 H 00h4N O m 1n 104Kl4O.04 N .C4 H H 0 N K\oO 10 a)44 01 N C- El N :0 I(INOO H 0 Q. NNMCON\ O N .130111 NMNMM M NO0 cV Kl CO K1tU M O O4OO 01cn N Ifl al CV I 0 Olt` 1001 C--- ON '0'04 t- O 1flln4 H M HV H 0 0.4 ¼04 0104 c HHO0 CO VI [C) H a) .JI NK141 1- I1 11 11 11 111 c 11 M1 I tHl Hri r-IH { NNHNNN 0 a! -4 E HNM41f1 HNMMN 1 H 1 1H 1H1 I1 N 1N 1 H1 N1 N1 M1 H1 H N reductions 2-2 and 1-3 on the whole proved about equall y serviceable . The pigment volume in 1-3 was 22 .3 percen t (of the non-volatile and the ratio of linseed oil t o turpentine by volume was about 2 .6 . In 2-2 the pigment volum e was 30 .2 percent and the ratio of oil to turpentine 3 .4. Reduction 1-4, which was inferior to 1-3 with all paints, ha d a pigment volume of 29 .4 but a ratio of oil to turpentine o f only 1 .4 . It seems, therefore, that the ratio of oil t o turpentine is more significant, at least within the range o f desirable reductions, than is the pigment volume . Apparently a good primer should have at least 2-1/2 times as much linsee d oil as turpentine and it is questionable whether there nee d be any turpentine in the primer at all . The pigment volum e in a good primer for three-coat painting presumably may b e anywhere in the range of 20 to 30 percent but for two-coa t painting practical considerations require that the pigmen t volume be in the upper portion of this range . Reductions for Different Wood s The notion has long prevailed that the optimu m priming-coat reduction differs according to the kind . of woo d painted . There is no published evidence in support of such a belief and its soundness may well be doubted in view of th e contradictory recommendations often made when writers try t o give specific priming-coat formulas for different woods . The data of table I suggest the same optimum priming-coa t reduction for all woods, namely, reduction with linseed oi l and little or no turpentine . The results are not at al l consistent with the view that the reduction for red ceda r or redwood should differ from the reduction for white pin e or Norway pine . It should be recognized, however, that th e present experiments were concerned principally with th e proportions of linseed oil and . turpentine in the primin g coat and did not cover possible variations in pigment concentration as adequately as could be desired . Further researc h may show that for woods like redwood and red cedar, whic h absorb paint oils quickly, a slightly lower pigment concentration may be advisable in order to avoid unduly lo w spreading rates and difficulty with painters' laps than i s appropriate for such woods as Norway pine, southern yello w pine, and Douglas fir . Nevertheless the present indication s are that a single recommendation for reducing priming coat s for all kinds of woods is entirely practical and probabl y advisable . The "easily paintable" woods probably differ fro m the "difficultly paintable" ones chiefly in degree o f sensitiveness to departure from the optimum reduction, tha t R1045 -4- is, less damage to the serviceableness of the coating may b e expected if the painter fails to use the optimum reduction i n painting redwood than will result when painting Norway pine . Order of Failure on the Four Wood s The order of failure of the three paints on the fou r kinds of wood is indicated in table 2, which records in eac h case the average durability for all priming-coat reduction s of the white paint . Certain physical properties of the board s of each of these woods were reported in table 1 of the thir d progress report . On cedar, white pine, and Norway pine th e average curability of the three paints was inversely proportional to the average density of the boards of those species . The durability on redwood, however, was about as great as it wa s on red cedar although the density of the boards was nearl y the same as the density of the white pine . These results ar e entirely in accord with results previously reported by th e Forest Products Laboratory (Federation of Paint and Varnish Production Clubs, Official Digest No . 95, p . 106 (1930) ) . Table 2 .--Order of failure of paints on the four wood s Kind_ o f wood :Average durability in months of coatings of :Density : : of :'mite mead : Lead and :Titanox : Average : wood : paint :zinc paint :and zinc : for al l : 3 paint s : paint :Lbs .per : :cu . ft . : Redwood Red cedar . . . White pine . . Norway pine . R1045 : : : : 26 .2 21 .5 26 .8 28 .9 . . . . I 38 .4 38 .8 35 .5 30 .0 39 .3 37 .4 33 .6 36 .5 -5- : : : . 38 .8 40 .6 30 .5 24 .3 : . . 38 . 8 38 . 9 33 . 2 30 .3 The relative behavior of the white lead paint, lea d and zinc paint, and titanox and zinc paint during the firs t two years of exposure was described in detail in the thir d progress report . Since that time all throe paints have bee n chalking freely enough on the south side of the fence t o dislodge most of the remaining dirt and the white lead an d lead and zinc paints at 38 months were nearly as clean an d white as the titanox and zinc paint . On the north side of th e fence the titanox and zinc paint still remained almost a s clean and white as it was on the south side, the lead an d zinc paint had thrown off most of the dirt previousl y accumulated and was only slightly more gray than the titano x and zinc paint, but the white lead paint still retained muc h dirt, was very spotted in discoloration, and was still rate d Bad in appearance . On the south side of the fence at the last inspectio n the characteristic reticulate checking of white lead pain t was readily visible on close examination without a magnifyin g g lass . The checking was then undoubtedly deep . The lead and zinc paint was likewise checking visibly and the checking wa s gradually becoming reticulate . The titanox and zinc pain t remained free from checking . Disintegration of the white lead paint proceede d entirely by crumbling . The lead and zinc paint and the titano x and zinc paint disintegrated by slitting or cracking followe d by curling and flaking . Chalking of the titanox and zin c paint had reduced the thickness of the film enough to impai r the opacity observably although very close inspection wa s necessary to disclose that fact . There had, however, been n o washing of the chalk over the black identification number s with which the test areas were marked . The extent to which disintegration of the three paint s had gone after 38 months may be seen by referring again t o table 2 . On redwood and red cedar they were provin g practically equal in durability but on white pine and Norwa y pine the titanox and zinc paint had disintegrated earlier tha n the other two paints . As a result there was a greate r variation in durability on different woods with the titano x and zinc paint than with either of the other two paints . As was pointed out in the third progress report , there was more difference in durability between any one of th e paints on the four woods than there was between that of that R1045 -6-- r~.■ , r "Moe .-1 11 1- 1 n L 11 11 - -■ 1 • a 'I 11 1 1 - , three paints on any one wood . It is also true that the r was more difference in durability between the best and t e worst priming-coat reduction with any one paint than ther e was between tlat he thre•j paints on redwood r e p .cedar , .. -% or white ' 1, .4 WI --- '_ -. ~ - 1■ 1 1 e 1 .m 0 1 r1 !' Coat and Three-Coat Paint ing 1 ■' ~ 11 1 _ Al ir With the white lead paint and the titanox and zinc paint the best two-coat job (priming-coat reduction 2-1 } • proved equal or superior in durability on the whole to th e - hest three-coat job (with white primer) applied on the sam e -r boards . With the lead and zinc paint the best two-coat job r was slighly inferior to the best three-coat job on the s ' boards except on red cedar, where it was better . Table 3 I 'm - the first progress report recorded the total amounts o f y% paint applied in the two-coat and three-coat jobs and s wed _ _• - that, by reason of the higher pigment concentrations and lower spreading rates followed in the two-coat painting , roughly similar total quantities of paint were applied i n 1 ▪ _ two-coat and three-coat jobs, It is evident that two-coatpainting when done in the manner followed in these experiment s ' - is thoroughly practicable and gives coatings that closel y % approach good three-coat work in durability and prove die 1 tinctly better than poor three-coat work . -r - 11 1 ▪ r_ ■ 1 1 % ' ▪ ~ J i~ = A t~linum Priming Paint _1' ice' Y - ~. ~ -- s ;•!1J ▪ -%. -~~-~ Table I indicates that the best results were ob tamed with aluminum primin g iming paint ~ followed by two coats o f - white paint . On all woods except white pine the coatings o f 1 all three paints over aluminum primer were still rated Fai r , ► - minus or better in integrity at the last inspection and i n all cases except that of lead and zinc paint on white pi n :1 0 •• the coating over aluminum primer was rated as high or highe r 1 in integrity than the best coating over a white primer o n the same boards . On 10 out of 12 panels the coating over , -- aluminum primer had the highest rating, on 1 panel it s .% rating (Fair minus) was equalled only by white priming-coa _ { reduction 1-1, and on 1 panel it was distinctly superior t o - - reductions 1-4 and 1-5 but inferior to reductions 1-1, 1-2 , and 1-3 . On the last panel, however, failure was confined t o r% r two of the four boards which developed loose grain toward th e end on which the aluminum primer was applied but not on th e 11 end that received reductions 1-2, and 1-3 . This panel, -. ~~ rb' nu -1 11=115 41-1■ 1 1 J~ ■ - - 1 iv I t ■ • 11 11 " II - r ■ be therefore, was not an exce p tion to the rule that the aluminum primer in these tests tended to hold the coating s intact longer than any of the priming-coat reductions of th e white paint . Unusually Early Failure of the Paint% Failure of the coatings in integrity took plac e unusually rapidly on the St . Paul test fence . Coatings o f the white paints used should be expected to remain service able in the Lake States region for at least 4 years on suc h woods as red cedar, redwood, and white pine, yet th e failures took place in less than 4 years . The coatings o f white lead paint and of lead and zinc paint applied wit h priming-coat reduction 1-3 as recorded in table 1 ma y reasonably be compared with certain tests by the Forest H Products Laboratory in which the same paints were applie d with very similar reductions and on some of the same kinds o f wood at Fargo, N . P ., and at Madison, Wis ., in 1930 . Table 3 records data suitable for comparing the results with thos e at St . Paul . The reason for faster disintegration of the paint s at St . Paul is unknown but the fact that there is unmistakable evidence of some moisture failure on the north sid e of the fence, as pointed out in the third progress report , suggests that moisture getting into the fence at some tim e may have hastened disintegration on the south side eve n though the moisture conditions were not severe enough t o result in typical blistering or other developments clearl y recognizable as moisture failures . It has been reported t o the test fence committee that at one time during the winte r of 1932-33 snow drifted against the fence to the extent o f practically covering one side . This snow was not shovele d away and there is a possibility that entrance of moistur e within the fence took place when it melted . Miscellaneous Tests on Units 7 and 8 In addition to the main portion of the test fenc e there were two units added for the purpose of trying th e effect of special primers made with white pigments in th e 81045 f • Bakelite varnish used as a vehicle for the aluminum prime r on units 1 to 6 and for trying the recommendations fo r thinning white lead paint made by the National Lead Compan y and the Eagle-Picher Lead Company and certain paints suggeste d by the New Jersey Zinc Company and the Titanium Pigment s Company. The condition of these paints with respect t o integrity of the coatings at the last inspection is recorde d in table 4 . Of the special primers made with white pigments i n Bakelite varnish the one made with zinc oxide gave distinctl y inferior results . The ones made with white lead and titano x were better but by no means so good as the aluminum prime r reported in table 1 . The type of failure of the white lea d paint over these priers was not the same as that of whit e lead paint over white lead primer or over aluminum primer bu t took the form of flaking as distinguished from crumblin g over the bands of summerwood . F-i 0 H -p a) Sri F~ cd cd ho O co 00 f-i +' • 4H cd 0 o U 'd O 11 +' CO co ,0+'' ,L) a) Fi •r I' -I ~i -HU) ri bC g .1-i O CO +D r d -H Fi cd rP.'d ~, a) 00 •r+ r-I U a) a+ UJ a) cd cd rd l rd 0 o N 'd 4- N rn rn rn cd a. 4.- l50 4- F-I 4- , -z rn 4- 4 RI rI I -Z' H LC\ H • w -H+' ) ,c cd ▪ o 1 I Fr • r-1 1 I I O I I ; I .. I I +' I ' I •r-I CO Q) CO O +' R' a) Fi cd R, 0 co 4 i r CO a) F-1 co H a~i I cdcdcd 1 1 I ai d I -± rn m 1d a) O Fa 0 FI rr 1 cd R I I m r-I a) cd pRcd ~ O 1 •rI RI O • 4-' . . 1; I CJ d r I rn Lf1 111 a) 1 . . . . . . . . . . . . . . . . . . .. . . . . . . H I r-1 1 ,~ . RI 0 NI N I co d Fi a) cd + ' � Fib H q 6 d ad o cd a) 0 0 +' ,RI I O R I +' i H 9-1 cd p . R} •ri w da cd CD ~ O r-l 0 .' 4 0 0 cd 0 U) CJ H I % U rI I O 0 I 'd F- 1 0 4-•ri LO 150 O a 1 N rn Lf1 11 1 F-I •R 0 F-I a cdd,c ` " O co 'd F-I a) o cd O +' o I • H 2i .Q c Q) 0d r-I U O o 'd CU a) a) 1 4. I cd rn a +' I RI I +' F; q •r 1 F-I C) i rr o a) ' C) + o H rf) • cd +'cd F-i 'C O a) ad cd 0 .4 +'3 -1 +'Fa u) a) H R, cO I. 6 630 F-i . . -- . . . . . . . . . . . . a) 'd (74 0 'd I 0 I 00)a) r-n4.~ „0 R, rd d) cd '60 +' R I N O 6:3 0 1 . . d 4-4 cd F-i o cd CO +' rI d O cd I 1 F4 oa, a O +' Co w U) +'r-I R. O -'' cd 0+' •r-I ~, cd a) rI RI F4 0 F-l cd cd +3 I Fi +~o a) 4.) d, 4- 1 0 +3 .H a)U) O H h ,R O 0 1 cd cl cd +' U) I w U b 4- 'd +' cd 0 0 +' 0 'd 0 cd RI w cd' Pa, H ri 4-3 I 1 I RI aa, +5' WI' O O I~ Cl) Rcd ~ rl +' O o +3 cr3 W 4-I co -4 qa) HI NI Lf\ _d- O H + o t f~ t q I +3 •ri 1 rz i . . Fi T:1 cd tar) N 66 r 66 + U I o I q Pa 0 0 cd Pi P-. f4 1 •i 66 66 66 66 66 66 6 6 66 66 66 66 66 66 6 6 + Fi + O ocd o I 9-4 + F-I q q Pi Fi 'd o 1 -0 p, I Fzp I + + Fi w ti 0 0 •H + Fi q Fi Fi 0 0 Pi P-i Pi •H I 14)a) I • +~ 'H I -H -H I 4-t a. a q w I t . . .. . . . . . . . . . . . . . . . . . . + o ,• 0 66 1 +-31 Fa w°onPo 66 w ++ i 0 P-1 P'-) Pi + + Fi Fi 0 0 0 0 P-. Pi Fi 0 0 P4 66 66 66 9 . 66 66 66 66 66 66 66 64 66 •6 66 66 +3 .6 6 6 cd 1 cd a) c i 1 I Fi -r 4 i I O p, I I I I + F+ H O o O cd P. W Pa o 66 66 66 66 6 66 66 66 66 .6 66 66 66 66 6 6 H d C p H 6.0 +p taO • ,.0 • • -d a) c 4 •U co ro w q • FA p ed cd Fi cd O • a) 0 • .Hu) .~ • 3 P cd cd a) -N •k ~ 0 R, +-y +' a) cd a) o H M o cdcd ~Pg cd O •rl m Fi o • • F U U d rd •r1 b N -k a) a) -t k cd H 0 ~, ^ cd ~d m+' a W . cd cd F i P., CD 0 Cd H •rl P co I ci) o a) .0 F-1 pz I k F+ Fa k q O 0 -H q O O cd a P- Pi w 'd O Pa O •ri N U O F+ •r i-1 H • • k a) N •rl rl •r-S -N q ra •' 0 0 •rl •ri •r-4 0 •ri • rd rx) o •• r~4 M O a) HO +' 4-s -P U cd cd O•ri +•' q r -r 4 •ri q ' ;? N E+ cd o O • U E+ td N a) Cd • r 4 rd Q) a) Et) -P 4' 'd u) -ri S'+ Pi •H -ri C13 Z p O 0 -rl Q 'd .~, Cd H E+ `7. a) _0 +3 Cd H 0 P. 0 p1'd O 'd I rd o -p 1--t p., 71 -id a) 0 0 a) a) - 0 ri C7 r•I Ha)>= .' D o cd F o'd a)-00+3 0 Cd Oo Co -p 0 •ri -p cd -P U p U •ri a) •rl .H '3a • HoI q H H H O 4 1 r•f a a 0 ~. +-' a)