Nutrition Functions of food: Energy Provides raw materials for growth and repair Makes chemicals needed for metabolic reactions Chemical elements present in food: There are six common elements: Carbon (C) Hydrogen (H) 99% of living organisms consist Nitrogen (N) of these four elements Oxygen (O) Phosphorous (P) Sulphur (S) Another five elements are found as dissolved salts: Sodium (Na) Magnesium (Mg) Chlorine (Cl) Potassium (K) Calcium (Ca) There are three trace elements (only found in small amounts): Iron (Fe) Copper (Cu) Zinc (Zn) Apart from carbon, hydrogen and oxygen the rest of these elements are often called minerals. Biomolecular Structure: The atoms of the above fourteen elements join together in different ratios to form most of the molecules found in living things – called biochemicals/biomolecules. The four major types of biomolecules are: Carbohydrates Lipids (fats and oils) Protein Vitamins Carbohydrates These contain the elements carbon, hydrogen and oxygen. Usually present in the ratio C (H O) where x=y. So there is always twice as much hydrogen as oxygen e.g. glucose has the formula C H O. The smallest unit of a carbohydrate is a monosaccharide. Monosaccharides – sweet to taste and soluble in water glucose and fructose Disaccharides – sweet to taste and soluble in water, two monosaccharides joined together sucrose (table sugar) = glucose +fructose maltose = glucose + glucose Polysaccharide – insoluble in water, many polysaccharide joined together starch – long chains of glucose molecules, storage of glucose in plants cellulose – chains of glucose in plant cell walls glycogen – glucose storage in animal muscles and liver Sources: bread, potatoes, rice, cakes, sugar, fruit, sweets Fats and Oils (Lipids) These contain the elements carbon, hydrogen and oxygen but in different ratios to carbohydrates. Fats are solid at room temperature. The smallest unit of a fat is a triglyceride. Triglyceride = glycerol + 3 fatty acids Oils have same basic structure as fats but contain different types of fatty acids and remain a liquid at room temperature. Phospholipids are fats-like substances where one of the fatty acid groups in the triglyceride is replaced with a phosphate group. Sources: Animal fats – butter, lard, fat on meat Plant fats – margarine, sunflowers, olives Protein These contain the elements carbon, hydrogen, oxygen and nitrogen. Some may contain sulphur, phosphorus and other elements. The smallest unit of a protein is an amino acid. H varies from R C COOH carboxylic group are amino acid to NH amine group another There are twenty common and several rare amino acids found in proteins. Many more amino acids are known to occur free in different cells and tissues but not in proteins. Amino acids join together by peptide bonds. A proteins function does not depend on the amino acid sequence alone but also on the way a protein folds and takes up a three-dimensional shape. Sources: meat, fish, eggs, nuts, milk, peas and beans. Vitamins These are complex organic substances that the body cannot make, they are only needed in tiny amounts. They may be referred to by letters or by names based n their chemical structure. Vitamin C (ascorbic acid) Water soluble Vegetables and fresh fruit especially citrus fruit e.g. oranges and lemons Vitamin D (calciferol) Fat soluble Liver, fish oils, milk, egg yolks and sunlight Energy Transfer Reactions All the reactions taking place in an organism are referred to as it’s metabolism. Metabolic reactions can be divided into: 1. 2. Anabolic reactions - convert smaller molecules into larger ones using enzymes and absorb energy e.g. photosynthesis CO + H O + Energy C H O + O Catabolic reactions – a complex molecule is broken down to simpler ones using enzymes and releases energy e.g. aerobic respiration C H O + O CO + H O + Energy Different pathways of enzymes are used for catabolism and anabolism and are not the opposite of one another. Structural Role of Biomolecules 1. Carbohydrates – the polysaccharide cellulose forms plant cell walls 2. Protein – fibrous protein such as keratin is found in skin and hair, myosin is found in muscles, when linked with phosphorous forms phosphoproteins which are found in the cell membranes 3. Lipids – these form important storage molecules in organisms, but they have a secondary role as heat insulation (fat under skin) and a protective function (fat surrounds heart and kidneys), when linked with phosphorous they form phopholipids which are found in the cell membranes Metabolic Role of Biomolecules 1. Carbohydrate and Lipids – are broken down in respiration in a catabolic reaction to produce energy. They are made during photosynthesis using sunlight in an anabolic reaction to produce food in plants. 2. Proteins – enzymes, which are proteins, are used to control reactions, antibiotics to fight infections, hormones are used to regulate body reactions. 3. Vitamin C – this is needed for the growth of connective tissue found in skin, gums, cartilage, ligaments and blood vessels. It is also needed for the growth of bones and teeth, it helps to heal wounds and keeps the immune system functioning properly. Deficiency of Vitamin C causes Scurvy – this causes poor healing of skin, bleeding that is often seen under the skin as bruising and bleeding gums with loose teeth. 4. Vitamin D – helps to absorb calcium from the intestine, so it is indirectly needed for healthy bones and teeth. Deficiency of Vitamin D in children leads to Rickets, in adults it leads to Osteomalacia – symptoms of both are weak deformed bones that break easily. Minerals Plants: Minerals are needed in small amounts by organisms and are used in four ways: To form part of the rigid body structure e.g. calcium in bones and cell walls To form soft body tissues e.g. nitrogen and sulphur in muscles They play a role in forming cell and body fluid e.g. sodium in saliva and liquid part of blood To form biomolecules e.g. iron in haemoglobin, magnesium in chlorophyll Symbol Source Calcium Ca Magnesiu m Mg Salts absorbed from soil Forms calcium pectate in cell walls Salts absorbed from soil Part of structure of chlorophyll Mineral Use Animals: Mineral Calcium Symbol Source Use Ca Milk, cheese, hard drinking water Forms bones and teeth Iron Fe Liver, meat, green vegetables Forms part of haemoglobin Water Water is important as: A component of cytoplasm and body fluids (70 –95% of cell mass) A good solvent (dissolves things) and provides a medium in which chemical reactions take place and transport occurs A participant in chemical reactions e.g. respiration and photosynthesis A participant in the movement of molecules in and out of cells and so controls cell shape Has a high specific heat capacity – the amount of energy needed to change the temperature of water by 1 C is quite large and so it keeps it’s temperature despite temperature changes around it which provides a stable environment for living organism and their reactions