Math of Chemical Formulas Review Key Please answer on a separate sheet of paper 1. What is the difference between empirical formula and molecular formula? Empirical Formula: Simplest form of the formula Molecular Formula: Depends on how much the molecular mass is and is not the simplest form. 2. A compound contains 18.8% sodium, 29.0% chlorine, and 52.2% oxygen, by mass. If the molar mass of the compound is 122.44 g/mol, determine the empirical and molecular formulas. Empirical Formula: NaClO4 Molecular Formula: NaClO4 3. A 4.99 gram sample of a compound contains 1.52 grams of nitrogen atoms and 3.47 grams of oxygen atoms. The molar mass of the compound is between 90.0 g and 95.0 g. Determine the empirical and molecular formulas. *Use 92 g/mol as the molar mass* Empirical Formula:NO2 Molecular Formula: N2O4 4. Naphthalene is a carbon and hydrogen containing compound often used in moth balls. The empirical formula is C5H4 and its molar mass is 128.16g/mol. Find the molecular formula. Molecular Formula: C10H8 5. A compound with the following composition has a molar mass of 60.10g/mol: 39.97% carbon; 13.41% hydrogen; 46.62% nitrogen. Find the molecular formula. Molecular Formula: C2H8N2 6. How is a hydrate different from other chemical compounds? The water is wrote separately from the salt when writing the formulas. 7. A hydrate of magnesium sulfate has a mass of 13.52 g. This sample is heated until no water remains. The MgSO4 anhydrate has a mass of 6.60 g. Find the formula of the hydrate. MgSO4 × 7 H2O 8. A sample of copper (II) sulfate hydrate has a mass of 3.97 g. After heating, the CuSO4 that remains has a mass of 2.54 g. Determine the correct formula of the hydrate. CuSO4 × 5 H2O 9. When 5.00 g of FeCl3 · xH2O are heated, 2.00 g of H2O are driven off. Find the chemical formula and the name of the hydrate. FeCl3 × 6 H2O 10. How many moles of tin (II) fluoride are there in 908 grams of tin (II) fluoride? Tin (II) fluoride = SnF2 5.80 moles of Tin (II) fluoride 11. What would be the mass, in grams, of 1.505 x 1023 molecules of carbon disulfide? Carbon disulfide = CS2 19.03 g of carbon disulfide 12. What volume, expressed in liters, would 50.0 grams of fluorine occupy? 59.0 L of Fluorine 13. How many molecules are there in 995 liters of sulfur dioxide? 2.67 × 1025 molecules of sulfur dioxide