Matter is recycled and rearranged for living organisms • Living matter is made up of different substances. CO2 • Example of substances: pure CO2, glucose, pure salt, H2O….. glucose Atoms, Molecules and Compounds Atoms - Smallest unit of an element (with properties of that element) • Nucleus - dense center containing: – Protons - positively charged particles – Neutrons - particles with no charge • Electrons (e-) - small, negatively charged particles that orbit nucleus in clouds or shells (2, 8, 8) – Valence - found in outermost energy level e- How many total e-? How many valence e-? What element? Lewis Dot Diagrams • The inner shells are not involved in bonding • Carbon is in group 14, so that means 4 valence electrons • We often write the element symbol and only the valence electrons You try… What does the Lewis dot diagram look like for Oxygen? What does the Lewis dot diagram look like for Sodium? Hydrogen? How about Lithium? Why are they all the same? Na H Li Ions = electrically charged matter OIL RIG Oxidation is losing, Reduction is gaining • Ions form when electrons are lost or gained. • Ionic bonds form when a positive ion is attracted to a negative ion. Covalent bond = two atoms sharing electrons • “Strong” • Relatively stable • H, O and N can readily form covalent bonds with C. Chemical Equations Reactants 2H2O2 Hydrogen peroxide → Products 2H2O + O2 coefficient Water & Oxygen Subscripts coefficient Yield sign • • • • How many hydrogen atoms are in the reactants? How many hydrogen atoms are in the products? How many water molecules are produced? How many molecules of hydrogen peroxide are broken down? Chemical reactions 6CO2 + 6H2O C6H12O6 + 6O2 • Lead to changes in substance or matter. • Occurs when electrons are transferred between two atoms (lost, gained or shared) The 17 essential elements in plants (autotrophs)… CHOPKINS Ca Fe Mg B Mn Cu Zn Mo Cl Carbon, Hydrogen, Oxygen, Phosphorous, Potassium, Iodine, Nitrogen, Sulfur, Calcium, Iron, Magnesium, Boron, Manganese, Copper, Zinc, Molybdenum, Chlorine C HOPKINS Café Managed by my cousin Mo Cline • 96% of living matter: C, H , O, and N • 4% of living matter: Ca, K, P, S, Na, Cl, Mg, Fe, and trace elements Hydrogen Bonding • Weak bonds between a hydrogen of one molecule to an adjacent negative molecule • Ex: attraction between water molecules. Properties of Water Check for Understanding • What is the name of the compound in the bottle? • What is the molecular formula? • What is the structural formula? • How many molecules of the substance are in the bottle? • How would you calculate this? Water The universal solvent in living things which makes up over 90% of cells and the majority of Earth Why water works well in living things 1. Water is Polar and is really good at dissolving substances 2. Water is needed for all cellular chemistry 3. Water molecules adhere to some things 4. Water molecules stick together 5. Water molecules form surface tension 6. Ice floats 7. Water has a high specific heat Universal solvent • Water is a solvent (it dissolves stuff for living things) • Water can dissociate (break apart) most ionic compounds such as salts. • Solutes + Solvent = Solutions The Lewis dot structure for water shows the electron from hydrogen and an electron from oxygen being shared in a covalent bond. The other four valence electrons in oxygen are in pairs at the bottom. The lines are a short-hand version of the two dots representing the covalent bonds. + + - Water is a Polar molecule • Polar or angular molecules have a non-linear shape. • For example, water (H2O), has an angle of about 105°. • A water molecule has two pairs of bonded electrons and two unshared lone pairs. Create a Polar Water molecule • On page 2 (left facing page side) of your learning journal and using construction paper, create a water molecule. Try to mimic the 105° angle using a protractor if possible. • Show the covalent bonds as solid lines between the Oxygen and the Hydrogens. Page 2 + + • The water molecule is Polar because…… ___________________________________ ___________________________________ ___________________________________ Page 3 Hydrogen Bonding • Hydrogen bonds show the attraction between …. __________________________________ __________________________________ Polarity • Water molecules are polar. • Polarity: one end of the molecule is positively (+) charged and the other end negatively (-) charged • Polarity causes hydrogen bonding between water molecules Cohesion • Water molecules are attracted to each other. • Water molecules “stick” together. Hydrogen Bonds Cohesion causes Surface Tension • Surface Tension • Water molecules tend to stick together, forming a sort of “skin” • Some animals can use this “skin” as surface on which it can walk. Water strider spider • What properties of water makes a belly flop hurt so bad? • http://www.youtube.com/watch?v=N8gave vFX-0&feature=fvsr Surface Tension Capillary action in Plants Adhesion • Water molecules are attracted to surfaces that have charges (hydrophilic). • Water molecules are repelled from surfaces that have no charge (hydrophobic). Density • Water becomes less dense (more space between molecules) when it freezes. Properties of water’s density • Ice floats, creating buffer from cold air, enabling organisms to still survive underneath the frozen surface. Why is carbon the basis for life? • It has 4 electrons in its outer (valence) electron shell. • Octet rule: The most stable elements have 8 electrons in its outer shell, with few exceptions. • Carbon forms 4 covalent bonds to fulfill the octet rule. • Therefore, Carbon is really good at forming rings and chains Some Carbon Compounds Section 2-3 Methane Acetylene Butadiene Benzene Isooctane Organic compounds • Always contain carbon (carbon can bond with many other elements) • Small units called monomers join together to form polymers Making polymers • Think of molecules as “mers” • When 2 monomers join, they form dimers. • Adding more monomers form polymers. 1 “mer” = monomer 2 “mers” (mer+mer) = dimer 3 or more “mers” (mer+mer+mer+mer) = polymer 4 Important carbon polymers & complex molecules 1. 2. 3. 4. Carbohydrates Proteins Lipids Nucleic acids Dehydration synthesis • Joining monomers into polymers while taking away water molecules • A-OH + B-HAB + H2O • Dehydrate – to take away water • Synthesis – to make Carbohydrates – sugars, starch, cellulose, chitin • Function: quick energy (4 calories per gram) • Building blocks: Monosaccharides or simple sugars like glucose C6H12O6 • Carbohydrates provide cellular energy • Cell Membrane functions and support • Examples: – Monosaccharides (glucose, fructose, etc) – Disaccharides (sucrose, lactose, etc) – Polysaccharides (starch, cellulose, glycogen, chitin) Section 2-3 Starch Starch Glucose Proteins – used for structure and function • Purpose: can be used for energy (4 calories per gram) but mostly used for cell structure and metabolism (enzymes) • Building blocks: amino acids (20) held together by peptide bonds • Sometimes very large, complex molecules Amino Acids Section 2-3 Amino group Carboxyl group General structure Alanine Serine ATP Synthase Hormones Enzymes Antibodies Hemoglobin Muscle fibers Lipids – fats, oils, waxes, sterols • Function: long term stored energy • (9 calories per gram) • Provides insulation & cushioning • Does NOT have monomer/polymer structure • Examples: – Saturated (animal fats) – Unsaturated (plant oils) – phospholipids are the basic structure of cell membranes. – Steroids are signal chemicals to initiate a process in the body Examples of Sterols • • • • cholesterol steroids estrogen testosterone Click on the testosterone molecule Lipid Structure Some examples of lipids Lipids are a vital component of cell membranes Nucleic acids • Functions: store & translate hereditary information. • Building blocks: Monomers of nucleotides (sugar, phosphate, base) • Examples: – DNA (stores code) – RNA (translates code to protein) Parts of a Nucelotide • Phosphate • Sugar • Nitrogen containing Base What does DNA do? • DNA does NOT govern cell activity directly!! • “DNA is the code for the making of proteins used for structure and function”. The 4 Bases found in DNA The 4 Bases found in DNA as Nucleotides DNA Structure Organic macromolecule Monomer (building block) Polymer Carbohydrates Monosaccharide Polysaccharides 4 calories per gram (ex: Glucose) (ex: sugars, starch, cellulose, glycogen, chitin, etc.) Proteins Amino acids Structural proteins and enzymes 9 calories per gram Glycerol and fatty acids Fats, oils, waxes, sterols Nucleic acids Nucleotides DNA, RNA 4 calories per gram Lipids Heredity information (Types)