Chapter 8 “Chemical Reactions” Chemistry Judson High School Mr. Trotts 1 Describing Chemical Reactions OBJECTIVES: –Describe how to write a word equation. 2 Describing Chemical Reactions OBJECTIVES: –Describe how to write a skeleton equation. 3 Describing Chemical Reactions OBJECTIVES: –Describe the steps for writing a balanced chemical equation. 4 All chemical reactions… have two parts: –Reactants - the substances you start with –Products- the substances you end up with The reactants turn into the products. Reactants Products 5 Products Reactants 6 CHEMICAL REACTION: a reaction in which one or more substances are changed to new substances. 7 REACTANTS: substances involved in a chemical reaction. 8 PRODUCTS: new substances produced in a chemical reaction. 9 The relationship between reactants and products can be written as: REACTANTS PRODUCTS 10 In a chemical reaction Atoms aren’t created or destroyed. A reaction can be described several ways: 1. In a sentence (every item is a word) Copper reacts with chlorine to form copper (II) chloride. 2. In a word equation (some symbols used) Copper + chlorine copper (II) chloride 11 Symbols in equations the arrow separates the reactants from the products –Read as “reacts to form” or yields The plus sign = “and” (s) after the formula = solid: AgCl(s) (g) after the formula = gas: CO2(g) (l) after the formula = liquid: H2O(l) 12 Symbols used in equations (aq) after the formula = dissolved in water, an aqueous solution: NaCl(aq) is a salt water solution used after a product indicates a gas has been produced: H2↑ used after a product indicates a solid has been produced: PbI2↓ 13 Symbols used in equations ■ indicates a reversible reaction (more later) heat ■ , shows that heat is supplied to the reaction Pt ■ is used to indicate a catalyst is supplied, in this case, platinum. 14 What is a catalyst? A substance that speeds up a reaction, without being changed or used up by the reaction. Enzymes are biological or protein catalysts. 15 3. The Skeleton Equation Uses formulas and symbols to describe a reaction –but doesn’t indicate how many; this means they are NOT balanced All chemical equations are a description that describe reactions. 16 Write a skeleton equation for: 1. 2. 17 Solid iron (III) sulfide reacts with gaseous hydrogen chloride to form iron (III) chloride and hydrogen sulfide gas. Nitric acid dissolved in water reacts with solid sodium carbonate to form liquid water and carbon dioxide gas and sodium nitrate dissolved in water. Now, read these: Fe(s) + O2(g) Fe2O3(s) Cu(s) + AgNO3(aq) Ag(s) + Cu(NO3)2(aq) Pt NO2 (g) N2(g) + O2(g) 18 4. Balanced Chemical Equations Atoms can’t be created or destroyed in an ordinary reaction: –All the atoms we start with we must end up with A balanced equation has the same number of each element on both sides of the equation. 19 I. CONSERVATION OF MASS: In a chemical reaction, matter is not created or destroyed but is conserved. 20 II. IN OTHER WORDS: The starting mass of the reactants equals the final mass of the products. 21 Rules for balancing: 1) Assemble the correct formulas for all the reactants and products, use + and → 2) Count the number of atoms of each type appearing on both sides 3) Balance the elements one at a time by adding coefficients where needed (the numbers in front) - save balancing the H and O until LAST! (I prefer to save O until the very last) 4) Check to make sure it is balanced. 22 Never change a subscript to balance an equation. – If you change the formula you are describing a different reaction. – H2O is a different compound than H2O2 Never put a coefficient in the middle of a formula 2NaCl is okay, but Na2Cl is not. 23 WRITING EQUATIONS 24 III. Chemical reactions can be described with words such as: 25 solid lead (II) nitrate, dissolved in water, plus solid potassium iodide, dissolved in water, produces solid lead (II) iodide plus potassium nitrate, dissolved in water 26 A. All of this information is important to letting a scientist know what the reactants and products are as well as their physical states. 27 B. A shorthand method has been developed to describe chemical reactions. 28 C. This method uses: 1. Chemical formulas (NaCl for sodium chloride) 29 2. Coefficients (numbers to indicate how many molecules) 3. Symbols (for physical state, catalysts, direction of reaction, etc.) 30 The reaction described above would look like this: Pb(NO3)2(aq) + 2KI(aq) PbI2(s) + 2KNO3(aq) 31 IV. COEFFICIENTS: are the numbers placed to the left of the formulas for the reactants and products. 32 A. The coefficients represent the number of units of each substance taking part in a reaction. 33 Pb(NO3)2(aq) + 2KI(aq) PbI2(s) + 2KNO3(aq) B. In the reaction above, there are: 1. 2 units each of KNO3(aq) and KI(aq) 2. 1 unit each of Pb(NO3)2(aq) and PbI2(s) 34 V. Symbols are used to indicate what is happening in the reaction. 35 A. The physical state of the reactants B. Things added to help the reaction take place 36 C. An indicator to show which chemicals are the reactants and which are the products 37 D. Some commonly used symbols are in the following table. 38 SYMBOLS USED IN CHEMICAL EQUATIONS SYMBOL + (s) (l) (g) (aq) heat light Zn 39 MEANING produces, yields or forms; placed between the reactants and the products plus; placed between individual reactants or products in the equation solid; placed after the formulas in parentheses on the same line liquid gas aqueous, a solid is dissolved in water the reactants are heated; things added to make the reaction happen are written over the arrow. the reactants are exposed to light Zinc was added as a catalyst. A catalyst increases the rate of a reaction, but is not consumed in the reaction. Reactants Products C3H8(g) + 5O2(g) 3CO2(g) + 4H2O(g) 1 5 3 4 40 unit propane gas; units oxygen gas units carbon dioxide gas; units water vapor VII. REACTION ENERGY -Chemical reactions either absorb heat (endothermic) or release heat (exothermic). 41 A. Endothermic reactions must have energy added (usually thermal, sometimes electrical, or light) for the reaction to take place. 42 1. This is due to more energy being required to break bonds than to make new bonds. 43 2. Some endothermic reactions cause the reaction container to feel cool to the touch. 44 b. Exothermic reactions have some form of energy released by the reaction (usually it is thermal or light). 45 1. This is due to less energy being required to break bonds than to form new bonds. 46 2. Exothermic reactions cause the reaction container to feel warm or even hot to the touch. 47 BALANCING EQUATIONS THERE ARE 5 STEPS TO BALANCING EQUATIONS. 48 Step 1: Remember these two rules: 49 Each capital letter begins a new element 50 Coefficients (numbers that multiply the whole formula) can only be placed in front of the chemical formula 51 Step 2: Determine each type of element present on both sides of the equation 52 Write the equation. 53 Make a table under the equation that lists each type of element. 54 List the elements in the center of the table 55 Example: MgO + Br2 56 MgBr2 + Mg Br O O2 Step 3: Determine the number of each type of element on both sides of the equation. 57 Example: MgO + Br2 MgBr2 + 1 Mg 1 2 Br 2 1 O 2 58 O2 Step 4: Determine which elements are not balanced. In the example, the unbalanced element is oxygen. 59 Step 5: to balance the number of atoms for the element, Put a coefficient in front of the formula with the lower number of atoms for that element to produce an equal number of atoms. 60 Remember: The coefficient multiplies all of the elements in the chemical formula. 61 Start balancing by trying to make the numbers of elements in all the other formulas equal with the most complicated chemical formula (the formula with the most elements and subscripts). 62 Always balance Hydrogen and Oxygen last. 63 Water can always be added to the equation 64 Example: Place a coefficient of 2 in front of the MgO. Then multiply the number of atoms in the table by the coefficient. 65 2 MgO + Br2 MgBr2 + O2 2 1 Mg 1 2 Br 2 2 1 O 2 The coefficient changed the number of Mg also. Now the Mg has to be balanced. 66 Go to the other side of the equation and place a coefficient of 2 in front of the MgBr2. 67 2 MgO + Br2 2 Mg Br2 + O2 2 1 Mg 1 2 2 Br 2 4 2 1 O 2 The coefficient changed the number of Br also. Now the Br has to be balanced. 68 Place a coefficient of 2 in front of the Br2. 69 2 MgO + 2 Br2 2 1 4 2 2 1 70 2 Mg Br O Mg Br2 + O2 1 2 2 4 2 The equation is now balanced with 2-Mg, 4-Br, and 2-O. 71 OTHER HINTS 72 The diatomic molecules (Br I N Cl H O F) are always written as two-atom molecules (Br2, I2, N2, Cl2, H2, O2, F2). 73 A coefficient can be changed when needed to get every element to balance. 74 Many times there can be an even amount of atoms on one side and an odd amount of atoms on the other side. ]Find a common multiple. 75 Example: N2 + H2 NH3 2 N 1 2 H 3 There are 2 hydrogen on the left side. There are 3 hydrogen on the right side. 76 1. Determine the common multiple between 2 and 3 (it is 6). 77 2. Multiply the H2 by 3 and the NH3 by 2. N2 + 3 H2 2 NH3 2 N 1 2 6 2 H 3 6 78 The equation is now balanced with 2-N and 6-H. 79 Sometimes hydrogen and oxygen can cause problems. Two or more sources of hydrogen or oxygen on one side of the equation can occur. 80 Example: ZnS + O2 ZnO + SO2 The product side has oxygen from 2 sources. 81 1. Make the odd source of oxygen even by multiplying ZnO by 2. ZnS + O2 2 ZnO + SO2 This 1 Zn 1 2 unbalances 1 S 1 the Zinc. 2 O 3 4 (2-O’s from 2ZnO plus 2-O’s from SO2) 82 2. Place a 2 in front of the ZnS. 2 ZnS 2 2 This unbalances the sulfur. 83 + O2 2 ZnO + SO2 1 Zn 1 2 1 S 1 2 O 3 4 3. Place a 2 in front of the SO2. 2 ZnS + O2 2 ZnO + 2 SO2 2 1 Zn 1 2 2 1 S 1 2 This 2 O 3 4 6 unbalances (2 O’s from 2ZnO plus the oxygen more. 4 O’s from 2SO2) 84 4. Multiply the O2 by 3 to balance the equation. 2 ZnS + 3 O2 2 ZnO + 2 SO2 2 1 Zn 1 2 2 1 S 1 2 6 2 O 3 4 6 85 The equation is now balanced with 2-Zn, 2-S, and 6-O on each side. 86 A polyatomic ion that is not broken into parts by the reaction (it stays the same on both sides) is treated like an element. 87 Example: The equation, H3PO4 + Ca(OH)2 Ca3(PO4)2 + H2O, has two polyatomic ions, phosphate (PO4) and hydroxide (OH). 88 The phosphate has remained intact. The hydroxide was broken up to form water. 89 1. Make a table and list all of the elements. H3PO4 + Ca(OH)2 Ca3(PO4)2 + H2O List the PO4 1 PO4 2 as if it is an 1 Ca 3 element. 5 H 2 List the H 2 O 1 and O separately and last. 90 Note that the oxygen in the phosphate ion is not included when the number of oxygen atoms is listed. 91 2. The most complicated formula is the Ca3(PO4)2. Make the other formulas balance with the Ca3(PO4)2. 92 Start by balancing the calcium, multiply Ca(OH)2 by 3. H3PO4 + 3 Ca(OH)2 Ca3(PO4)2 + H2O The PO4 1 PO4 2 is now Ca 3 3 1 unbalanced. 9 5 H 2 O 1 6 2 Do not worry about H and O yet. 93 3. Multiply the H3PO4 by 2. 2 H3PO4 + 3 Ca(OH)2 Ca3(PO4)2 + H2O 2 1 PO4 2 3 1 Ca 3 12 9 5 H 2 6 2 O 1 This leaves 12 H’s and 6 O’s. The ratio of H to O is 2:1. This means that the reaction made 6 molecules of water. 94 4. Finish balancing the equation by multiplying the water by 6. 2 H3PO4+3 Ca(OH)2 Ca3(PO4)2 + 6 H2O 2 1 PO4 2 3 1 Ca 3 12 9 5 H 2 6 2 O 16 The equation is now balanced with 2-PO4, 3-Ca, 12-H and 6-O. 95 Practice Balancing Examples 1. _AgNO3 + _Cu _Cu(NO3)2 + _Ag 2. _Mg + _N2 _Mg3N2 3. _P + _O2 _P4O10 4. _Na + _H2O _H2 + _NaOH 5. _CH4 + _O2 _CO2 + _H2O 96 Types of Chemical Reactions OBJECTIVES: –Describe the five general types of reactions. 97 Types of Chemical Reactions OBJECTIVES: –Predict the products of the five general types of reactions. 98 Types of Reactions There are millions of reactions. We can’t remember them all, but luckily they will fall into several categories. We will learn 5 major types. Will be able to predict the products. For some, we will be able to predict whether or not they will happen at all. We recognize them by their reactants 99 #1 - Combination Reactions or Synthesis Reactions Combine = put together 2 substances combine to make one compound. Ca +O2 CaO SO3 + H2O H2SO4 We can predict the products if the reactants are two elements. Mg + N2 100 Complete and balance: + Cl2 Fe + O2 (assume iron (II) oxide is product) Al + O2 Remember that the first step is to write the correct formulas – you can still change the subscripts at this point, but not later! Then balance by using the coefficients only Ca 101 #1 - Combination Note: a) Some nonmetal oxides react with water to produce an acid: SO2 + H2O H2SO3 b) Some metallic oxides react with water to produce a base: CaO + H2O Ca(OH)2 102 #2 - Decomposition Reactions decompose = fall apart one reactant breaks apart into two or more elements or compounds. electricity Na + Cl2 NaCl CaCO3 CaO + CO2 that energy (heat, sunlight, electricity, etc.) is usually required Note 103 #2 - Decomposition Reactions Can predict the products if it is a binary compound-Made up of only two elements –breaks apart into its elements: electricity H2O HgO 104 #2 - Decomposition Reactions If the compound has more than two elements you must be given one of the products –The other product will be from the missing pieces NiCO3 CO2 + ___ heat H2CO3(aq) CO2 + ___ 105 #3 - Single Replacement One element replaces another Reactants must be an element and a compound. Products will be a different element and a different compound. Na + KCl K + NaCl F2 + LiCl LiF + Cl2 106 #3 Single Replacement Metals replace other metals (and they can also replace hydrogen) K + AlN Zn + HCl Think of water as: HOH – Metals replace one of the H, and then combine with the hydroxide. Na + HOH 107 #3 Single Replacement We can even tell whether or not a single replacement reaction will happen: –Some chemicals are more “active” than others –More active replaces less active There is a list on page 333 - called the Activity Series of Metals Higher 108 on the list replaces lower. The Activity Series of the Metals Higher activity Lower activity 109 Lithium Potassium Calcium Sodium Magnesium Aluminum Zinc Chromium Iron Nickel Lead Hydrogen Bismuth Copper Mercury Silver Platinum Gold 1) Metals can replace other metals provided that they are above the metal that they are trying to replace. 2) Metals above hydrogen can replace hydrogen in acids. 3) Metals from sodium upward can replace hydrogen in water. #3 Single Replacement Practice: 6. Fe + CuSO4 7. Pb + KCl 8. Al + HCl 110 #4 - Double Replacement Two things replace each other. – Reactants must be two ionic compounds. – Usually in aqueous solution NaOH + FeCl3 – The positive ions change place. NaOH + FeCl3 Fe+3 OH- + Na+1 Cl-1 NaOH + FeCl3 Fe(OH)3 + NaCl 111 The Activity Series of the Halogens Higher Activity Fluorine Chlorine Bromine Iodine Lower Activity Halogens can replace other halogens in compounds, provided that they are above the halogen that they are trying to replace. 2NaCl(s) + F2(g) MgCl2(s) + Br2(g) 112 2NaF ??? (s) + Cl2(g) No ???Reaction #4 - Double Replacement Has certain “driving forces” –Will only happen if one of the products: a) doesn’t dissolve in water and forms a solid (a “precipitate”), or b) is a gas that bubbles out, or c) is a molecular compound (usually water). 113 Complete and balance: assume all of the following reactions actually take place: 9. CaCl2 + NaOH 10. CuCl2 + K2S 11. KOH + Fe(NO3)3 12. (NH4)2SO4 + BaF2 114 How to recognize which type Look at the reactants: E + E = Combination (synthesis) C = Decomposition E+C = Single replacement C + C = Double replacement 115 Practice Examples: reaction type and product 13. H2 + O2 14. H2O 15. Zn + H2SO4 16. HgO 17. KBr +Cl2 18. AgNO3 + NaCl 19. Mg(OH)2 + H2SO3 116 Means #5 - Combustion “add oxygen” Normally, a compound composed of only C, H, (and maybe O) is reacted with oxygen – usually called “burning” If the combustion is complete, the products will be CO2 and H2O. If the combustion is incomplete, the products will be CO (or possibly just C) and H2O. 117 Combustion Examples: C4H10 + O2 (assume complete) C4H10 + O2 (incomplete) C6H12O6 C8H8 118 + O2 (complete) +O2 (incomplete) SUMMARY: an equation... Describes a reaction Must be balanced in order to follow the Law of Conservation of Mass Can only be balanced by changing the coefficients. Has special symbols to indicate physical state, if a catalyst or energy is required, etc. 119 Reactions Come in 5 major types. We can tell what type they are by looking at the reactants. Single Replacement happens based on the Activity Series Double Replacement happens if the product is a precipitate (insoluble solid), water, or a gas. 120 Reactions in Aqueous Solution OBJECTIVES: –Describe the information found in a net ionic equation. 121 Reactions in Aqueous Solution OBJECTIVES: –Predict the formation of a precipitate in a double replacement reaction. 122 Net Ionic Equations Many reactions occur in water- that is, in aqueous solution Many ionic compounds “dissociate”, or separate, into cations and anions when dissolved in water Now we are ready to write an ionic equation 123 Net Ionic Equations Example: –AgNO3 + NaCl AgCl + NaNO3 1. this is the full equation 2. now write it as an ionic equation 3. can be simplified by eliminating ions not directly involved (spectator ions) = net ionic equation 124 PO43– 125 S2– 3Cl– 2Ca2+ Na+ Al3+ Net ionic equations Review: forming ions Ionic (i.e. salt) refers to +ve ion plus -ve ion Usually this is a metal + non-metal or metal + polyatomic ion (e.g. NaCl, NaClO3, Li2CO3) Polyatomic ions are listed on page 95 (aq) means aqueous (dissolved in water) For salts (aq) means the salt exists as ions NaCl(aq) is the same as: Na+(aq) + Cl–(aq) Acids form ions: HCl(aq) is H+(aq) + Cl–(aq), Bases form ions: NaOH(aq) is Na+ + OH– Q - how is charge determined (+1, -1, +2, etc.)? A - via valences (periodic table or see pg. 95) F, Cl gain one electron, thus forming F–, Cl– Ca loses two electrons, thus forming Ca2+ 126 Background: valences and formulas Charge can also be found via the compound E.g. in NaNO3(aq) if you know Na forms Na+, then NO3 must be NO3– (NaNO3 is neutral) By knowing the valence of one element you can often determine the other valences Q - Write the ions that form from Al2(SO4)3(aq)? Step 1 - look at the formula: Al2(SO4)3(aq) Step 2 - determine valences: Al3 (SO4)2 (Al is 3+ according to the periodic table) Step 3 - write ions: 2Al3+(aq) + 3SO42– (aq) Note that there are 2 aluminums because Al 127has a subscript of 2 in the original formula Practice with writing ions Q - Write ions for Na2CO3(aq) A - 2Na+(aq) + CO32–(aq) (from the PT Na is 1+. There are 2, thus we have 2Na+. There is only one CO3. It must have a 2- charge) Notice that when ions form from molecules, charge can be separated, but the total charge (and number of each atom) stays constant. Q - Write ions for Ca3(PO4)2(aq) & Cd(NO3)2(aq) A - 3Ca2+(aq) + 2PO43–(aq) A - Cd2+(aq) + 2NO3–(aq) Q - Write ions for Na2S(aq) and Mg3(BO3)2(aq) A - 2Na+(aq) + S2–(aq), 3Mg2+(aq)+ 2BO33–(aq) 128 Types of chemical equations Equations can be divided into 3 types 1) Molecular, 2) Ionic, 3) Net ionic Here is a typical molecular equation: Cd(NO3)2(aq) + Na2S(aq) CdS(s) + 2NaNO3(aq) We can write this as an ionic equation (all compounds that are (aq) are written as ions): Cd2+(aq) + 2NO3–(aq) + 2Na+(aq) + S2–(aq) CdS(s) + 2Na+(aq) + 2NO3–(aq) To get the NET ionic equation we cancel out all terms that appear on both sides: Net: 129 Cd2+(aq) + S2–(aq) CdS(s) Equations must be balanced There are two conditions for molecular, ionic, and net ionic equations Materials balance Both sides of an equation should have the same number of each type of atom Electrical balance Both sides of a reaction should have the same net charge Q- When NaOH(aq) and MgCl2(aq) are mixed, _______(s) and NaCl(aq) are produced. Mg(OH) Write balanced molecular, ionic & net ionic 2 equations 130 First write the skeleton equation 2 NaOH(aq) + MgCl2(aq) Mg(OH)2(s) +2 NaCl(aq) Next, balance the equation Ionic equation: 2Na+(aq) + 2OH-(aq) + Mg2+(aq) + 2Cl-(aq) Mg(OH)2(s) + 2Na+(aq) + 2Cl-(aq) 131 LiNO3 Ca3(PO4)2 NaC2H3O2 Net ionic equation: 2OH-(aq) + Mg2+(aq) Mg(OH)2(s) Write balanced ionic and net ionic equations: CuSO4(aq) + BaCl2(aq) CuCl2(aq) + BaSO4(s) Fe(NO3)3(aq) + LiOH(aq) ______(aq) + Fe(OH)3(s) Na3PO4(aq) + CaCl2(aq) _________(s) + NaCl(aq) Na2S(aq) + AgC2H3O2(aq) ________(aq) + Ag2S(s) 132 Cu2+(aq) + SO42–(aq) + Ba2+(aq) + 2Cl–(aq) Cu2+(aq) + 2Cl–(aq) + BaSO4(s) Net: SO42–(aq) + Ba2+(aq) BaSO4(s) Fe3+(aq) + 3NO3–(aq) + 3Li+(aq) + 3OH–(aq) 3Li+(aq) + 3NO3–(aq) + Fe(OH)3(s) Net: Fe3+(aq) + 3OH–(aq) Fe(OH)3(s) 133 For more lessons, visit www.chalkbored.com 2Na3PO4(aq) + 3CaCl2(aq) Ca3(PO4)2(s)+ 6NaCl(aq) 6Na+(aq) + 2PO43–(aq) + 3Ca2+(aq) + 6Cl–(aq) Ca3(PO4)2(s)+ 6Na+(aq) + 6Cl–(aq) Net: 2PO43–(aq) + 3Ca2+(aq) Ca3(PO4)2(s) 2Na+(aq) + S2–(aq) + 2Ag+(aq) + 2C2H3O2– (aq) 2Na+(aq) + 2C2H3O2–(aq) + Ag2S(s) Net: S2–(aq) + 2Ag+(aq) Ag2S(s) 134 Predicting the Precipitate Insoluble salt = a precipitate General solubility rules are found: a) Table 8.3, p. 227 b) Reference section - page 887 Table A.7 (back of textbook) gives combinations of cations and anions that are soluble or insoluble in water 135